WO2009033331A1 - Carburant écologique à base d'hydrocarbure léger pour véhicules - Google Patents

Carburant écologique à base d'hydrocarbure léger pour véhicules Download PDF

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Publication number
WO2009033331A1
WO2009033331A1 PCT/CN2007/003170 CN2007003170W WO2009033331A1 WO 2009033331 A1 WO2009033331 A1 WO 2009033331A1 CN 2007003170 W CN2007003170 W CN 2007003170W WO 2009033331 A1 WO2009033331 A1 WO 2009033331A1
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weight
parts
light hydrocarbon
hydrocarbon fuel
fluorocarbon surfactant
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PCT/CN2007/003170
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English (en)
French (fr)
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Maosheng Lee
Yenchih Wu
Jianming Zhao
Chienchih Li
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Shanghai Chinamax New Energy Co., Ltd.
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Priority to EP07816782A priority Critical patent/EP2199376A4/en
Priority to JP2009539588A priority patent/JP2010511753A/ja
Priority to US12/530,922 priority patent/US20100146846A1/en
Publication of WO2009033331A1 publication Critical patent/WO2009033331A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
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    • C—CHEMISTRY; METALLURGY
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    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
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    • C10L10/00—Use of additives to fuels or fires for particular purposes
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    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only

Definitions

  • the present invention relates to an environmentally friendly light hydrocarbon fuel for vehicles, and more particularly to an environmentally friendly light hydrocarbon fuel for vehicles using pentane and heavier hydrocarbons as a main component extracted from a petrochemical refinery or natural gas condensate. . Background technique
  • the technical problem to be solved by the present invention is to disclose an environmentally friendly light hydrocarbon fuel for vehicles to overcome the above-mentioned defects and environmental pollution problems existing in the prior art, and to meet the needs of related parties.
  • the light hydrocarbon of the present invention is a fraction of pentane and heavier hydrocarbons extracted from a petrochemical refinery or natural gas condensate, and has a RON of 50. ⁇ 80.
  • the aromatic hydrocarbons of the present invention include toluene, xylene or a mixed aromatic hydrocarbon producing toluene.
  • the lead-free antiknock agent of the present invention is methyl tert-butyl ether (abbreviation)
  • MTBE tert-amyl methyl ether
  • TAME tert-amyl methyl ether
  • isobutanol anhydrous methanol or absolute ethanol.
  • the cationic fluorocarbon surfactant of the present invention is a fluoroalkylamine salt or a quaternary ammonium salt cationic fluorocarbon a surfactant selected from one of formula (1), (2) or (3) or a mixture thereof.
  • the cationic fluorocarbon surfactant is used in an amount of from 0 to 0.2 parts by weight, based on 100 parts by weight of the light hydrocarbon, preferably from 0 to 0.1 part by weight.
  • the surface active labeling agent of the present invention is one of the following components 1 to 6 mixed with the component 7 wherein the ratio of one of the components 1 to 6 to the component 7 is 100 parts by weight: 60 to 80 weight. Share.
  • the amount of the surface active agent to be used is, in terms of 100 parts by weight of the light hydrocarbon, generally used in an amount of 0.001 to 2 parts by weight; more preferably 0.01 to 0.2 part by weight.
  • the research method octane number (RON) of the environmentally friendly light hydrocarbon fuel of the present invention is 93, which is applicable to automobile engines of various compression ratios, and becomes an environmentally friendly light hydrocarbon fuel for vehicles.
  • An environmentally friendly light-duty vehicle fuel with surface active labeling agent can improve the self-ignition point of fuel, improve fuel distillation range, improve fuel burning rate, improve engine power, reduce engine wear, avoid carbon deposit of spark plug, and reduce Fuel consumption, calorific value 42000KJ kg, energy saving, environmental protection, low The cost of a new type of automotive alternative fuel.
  • the product of the invention is environmentally friendly light hydrocarbon fuel for vehicles, containing exhaust pollutants C ⁇ , HC, NOx
  • the product of the invention is an environmentally friendly light hydrocarbon fuel for vehicles.
  • the following components 8, 9, 10 or a mixture thereof may be used instead of the surface active agent.
  • the light hydrocarbon is a fraction mainly composed of pentane and heavier hydrocarbons extracted from petrochemical or condensate.
  • the cationic fluorocarbon surfactant is a fluorine-containing mercaptoamine quaternary ammonium salt type cationic fluorocarbon surfactant: (CF 3 ) 2 CF (CF 2 ) 6 CH 2 CH (OH) CU 2 ⁇ (CH 3 ) 3 I"
  • the surface active labeling agent is:
  • the ratio of the surfactant leveling agent component 3 to the component 7 is: 10:6 (by weight).
  • the product (1), (2), (3), (4) is mixed to obtain the product, and the research method has a RON of 93.
  • the light hydrocarbon is a fraction mainly composed of pentamidine and heavier hydrocarbons extracted from a petrochemical refinery or natural gas condensate.
  • the cationic fluorocarbon surfactant is:
  • the surface active labeling agent is:
  • the ratio of the surfactant concentration component 1 to the component 7 used is: 10:6 (weight ratio)
  • This example will be the components (1), (2), (3), (4) ), (5) mixing, that is, obtaining the product.
  • Result product The RON is 93,
  • Example exhaust pollutants present embodiment is CO, HC, NO x by the assays GB18352.3-2005 obtained as follows: Unit Test results Chinese national standard
  • the light hydrocarbon is a fraction mainly composed of pentane and heavier hydrocarbons extracted from a petrochemical refinery or natural gas condensate.
  • the surface active labeling agent is:
  • the ratio of the surfactant leveling agent component 3 to the component 7 is: 10: 6 (weight

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Description

环保型车用轻烃燃料
技术领域
本发明涉及环保型车用轻烃燃料， 更具体的说， 涉及利用石油化工炼厂或 天然气凝析油中提取的以戊烷及更重的烃类为主要成份的环保型车用轻烃燃 料。 背景技术
国家从 2006年 8月 1 日起， 北京、 上海二市率先实施机动车污染物排放 国家标准 (国 III标准)。 使用汽油的机动车由于馏程分布广， 高沸点组分在燃烧 时易产生 CO、 HC， 不易达到国 III， 由于轻烃馏程低、 沸点也低、 燃烧完全， CO、 HC污染物排放极少。 能达到 （国 III)排放限值。 发明内容
本发明需要解决的技术问题是公开一种环保型车用轻烃燃料，以克服现有 技术存在的上述缺陷及环境污染问题， 满足有关方面的需要。
本发明所要解决的技术问题可以通过以下技术方案来实现- 一种环保型车用轻烃燃料， 其特征在于， 组份的重量份如下：
( 1 )轻烃 100重量份
(2)芳烃 4~60重量份
(3)无铅抗爆剂 0〜20重量份
(4) 阳离子氟碳表面活性剂 0〜0.2重量份
(5)表面活性增标剂 0.001〜2重量份 本发明所述的轻烃是石油化工炼厂或天然气凝析油提取的以戊烷及更重的烃 类为主的馏分， 其 RON为 50〜80。
本发明所述的芳烃包括甲苯、 二甲苯或生产甲苯之混合芳烃。
本发明所述的无铅抗爆剂为甲基叔丁基醚 (methyl tert-butyl ether, 简称
MTBE)、 甲基叔戊基醚 (tert-amyl methyl ether、简称 TAME) ， 叔丁基醇、异丁 醇、 无水甲醇或无水乙醇。
本发明所述的阳离子氟碳表面活性剂为氟烷基胺盐或季铵盐阳离子氟碳 表面活性剂， 选自式 (1)、 （2)或 (3)中的一种或其混合物。 阳离子氟碳表面活性 剂使用量， 以轻烃 100重量份计算，一般使用量为 0〜0.2重量份；较佳为 0〜0.1 重量份。
(1)含氟烷基胺季铵盐型阳离子氟碳表面活性剂：
(CF3) 2CF (CF2) 6CH2CH (OH) CH2N+(CH3)3r
(2)全氟烷基酰胺季铵盐型阳离子氟碳表面活性剂：
C FisCONH (C¾ N+(CH3)3r
(3)氟烷基胺盐型阳离子氟碳表面活性剂：
I F (CF2) 8CH (OH) CH2 ) 2NCH2CH2NH2. 腿 2SO。
本发明所述的表面活性增标剂为下列组分①〜⑥之一与组分⑦混合而成 其中组分①〜⑥之一与组分⑦之用量比为 100重量份 :60~80重量份。表面活性 增标剂之使用量.， 以轻烃 100重量份计算， 一般使用量为 0.001〜2重量份； 较 佳为 0.01〜0.2重量份。
① .C8F17S02N(CH3)CH2OP(0)(OH)2
② . CsF17SO2N(CH3)CH20P(0)(ONa)2
③ .C8F17S02N(C )CH2CH2OP(0)(OH)2
④ . C8F17S02N(CH3)CH2CH2OP(0)( ONa )2
⑤ .C8F17S02N(C2H5)CH2CH2OP(0)(OH)2
⑥ . C8F17S02N(C2H5)CH2CH2OP(0)( ONa)2
⑦ . C17H35CONH(CH2)2NHCOC17H35 本发明的环保型车用轻烃燃料的制备方法为一种物理混合方法，将各种原 料混合， 即可。
经添加表面活性增标剂，使本发明环保型轻烃燃料的研究法辛烷值 (RON) ^93, 适用各种压缩比的汽车发动机， 成为环保型车用轻烃燃料。
添加表面活性增标剂的环保型车用轻烃燃料， 可提高燃料的自燃点， 改善 燃料馏程分布， 提高燃料的燃烧速率， 提高发动机动力， 减少发动机磨损， 避 免火花塞的积碳现象，降低燃油消耗， 热值 42000KJ kg， 具有节能， 环保， 低 成本的新型汽车替代燃料。
本发明产品环保型车用轻烃燃料,经排气污染物 C〇,HC,NOx的含
其量均低于 GB18352.3-2005之标准甚多。
单位 试验结果 中国国家标准要求
CO g/km 1.209 2.3
HC g/km 0.075 0.20
NOx g/km 0.046 0.15
本发明产品环保型车用轻烃燃料，为降低成本，也可使用下列组分⑧、⑨、 ⑩或其混合物来替代表面活性增标剂之部分
⑧ . C8F17S02NHCH2CH3
⑨ . CsF17S03K
⑩ . C8F17S03N (C2H5) 4 具体实施方式
实施例 1
( 1 ) 轻烃 （RON为 70) 100重量份
(2) 甲苯 30重量份
(3 ) 阳离子氟碳表面活性剂 0.006重量份
(4) 表面活性增标剂 0.05重量份 上述实施例中，轻烃为石油化工烁 或大然气凝析油提取的以戊烷及更重 的烃类为主的馏分。
上述实施例中， 阳离子氟碳表面活性剂为含氟垸基胺季铵盐型阳离子氟碳 表面活性剂： (CF3) 2CF (CF2) 6CH2CH (OH) CU2^ (CH3) 3I"
上述实施例中， 表面活性增标剂为：
③. C8F17S02N(C¾)CH2CH2OP(0)(OH)2
⑦. C17H35CONH(CH2)2 HCOC17H35
在实施例中， 表面活性增标剂组分③与组分⑦之用量比例为： 10: 6 (重量 比）。
将组份 （1 )、 （2)、 （3)、 （4)混合， 即获得产品， 其研究法辛垸值 (RON) 为 93。
实施例
( 1 ) 轻烃 （RON为 70) 100重量份
(2) 二甲苯 20重量份
(3) MTBE 10重量份 （4) 阳离 子氟碳表面活性剂 0.006重 份
(5)表面活性增标剂 0.09重量份
上述实施例中，所述的轻烃是石油化工炼厂或天然气凝析油提取的以戊垸 及更重的烃类为主的馏分。
上述实施例中，所述的阳离子氟碳表面活性剂为：
全氟烷基酰胺季铵盐型阳离子氟碳表面活性剂：
C7F15CONH (CH2) 3Ν^ (CH3) 3Γ
上述实施例中,所述的表面活性增标剂为：
① .C8F17S02N(CH3)CH2OP(0)(OH)2
⑦. C17H35CONH(CH2)2NHCOC17H35
在实施例中，表面活性增标剂组份①与组分⑦的使用量比例为： 10:6 (重 量比） 本实施例将组分（1 )、 （2)、 (3)、 (4)、 (5)混合， 即获得产品。 所得产品 的 RON为 93,
本实施例所得产品的排气污染物 CO，HC，NOx经 GB18352.3-2005之测试法 所得资料如下： 单位 试验结果 中国国家标准要求
CO g/km 1.209' 2.3
HC g/km 0.075 0.20
NOx g/km 0.046 < 0.15
实施例 3
( 1 ) 轻烃 （RON为 70 ) 100重量份
(2) 甲苯 30重量份
( 3 ) 表面活性增标剂 0.1重量份 上述实施例中，轻烃为石油化工炼厂或天然气凝析油提取的以戊烷及更重 的烃类为主的馏分。
上述实施例中， 表面活性增标剂为：
③. CsF17S02N(CH3)CH2CH2OP(0)(OH)2
⑦ .C17H35CO H(CH2)2NHCOC17H35
在实施例中， 表面活性增标剂组分③与组分⑦之用量比例为： 10: 6 (重
将组份 （1 )、 （2)、 （3)混合， 即获得产品， 其研究法辛垸值 RON为 93。 需要说明的是， 以上所述仅为本发明的优选具体的实施例， 若依本发明的 构想所作的改变， 其产生的功能作用， 仍未超出说明书所涵盖的精神时， 均应 在本发明的范围内。

Claims

权利要求
1. 一种环保型车用轻烃燃料， 其特征在于， 组份的重量份如下:
( 1 ) 轻烃 100重量份
(2)芳烃 4〜60重量份
(3)无铅抗爆剂 0〜20重量份
(4)阳离子氟碳表面活性剂 0〜0. 2重量份
(5)表面活性增标剂 0.001-2重量份
2. 根据权利要求 1所述的环保型车用轻烃燃料，其特征在于，所述的轻烃 是石油化工炼厂或天然气凝析油提取的以戊烷及更重的烃类为主的馏分。
3.根据权利要求 1所述的环保型车用燃料， 其特征在于， 所述的芳烃包括 甲苯、 二甲苯或生产甲苯之混合芳烃。
4. 根据权利要求 1所述的环保型车用轻烃燃料，其特征在于，所述的无铅 抗爆剂为甲基叔丁基醚、 甲基叔戊基醚、 叔丁基醇、 异丁醇、 无水甲醇或无水 乙醇。 *
5. 根据权利要求 1所述的环保型车用轻烃燃料，其特征在于，所述的阳离 子氟碳表面活性剂为氟垸基胺盐或季铵盐阳离子氟碳表面活性剂， 选自式 (1)、 (2)或 (3)中的一种或其混合物： ω含氟烷基胺季铵盐型阳离子氟碳表面活性剂：
(CFs) 2CF (CF2) 6CH2CH (OH) C腿 + (CH3)3r
(2)全氟垸基酰胺季铵盐型阳离子氟碳表面活性剂 - C7Fi5CONH (CH2) 3N+ (CH3)3r
(3)氟垸基胺盐型阳离子氟碳表面活性剂：
( F (CF2) sCH (OH) CH2 ) 2NCH2CH2NH2. 丽 2S〇4。
6. 根据权利要求 1所述的环保型车用轻烃燃料，其特征在于，所述的表面 活性增标剂为下列组分①〜⑥之一与组分⑦混合而成：
① .C8F17S02N(CH3)CH2OP(0)(OH)2
② . C8F17S02N(CH3)CH2OP(0)(ONa)2
③ .C8F17S02N(CH3)CH2CH2OP(0)(OH)2 ④ . C8F17S02N(CH3)CH2CH2OP(0)( ONa )2
⑤ .C8F17S02N(C2H5)CH2C OP(0)(OH)2
⑥ . C8F17S02N(C2H5)CH2CH2OP(0)( ONa)2
⑦ . C17H35CONH(CH2)2NHCOC17H35
7. 根据权利要求 6所述的环保型车用轻烃燃料，其特征在于，所述的表面 活性增标剂为权利要求 6所述的组分①〜⑥之一与组分⑦之用量比为 100重量 份: 60~80重量份
8. 根据权利要求 1所述的环保型车用轻烃燃料， 其特征在于， 以轻烃 100 重量份计算，其中阳离子氟碳表面活性剂用量，较佳为 0 ~0.1重量份
9. 根据权利要求 1所述的环保型车用轻烃燃料， 其特征在于， 以轻烃 100 重量份计算,其中表面活性增标剂使用量， 较佳为 0.01~0.2重量份。
10. 根据权利要求 1所述的环保型车用轻烃燃料， 其特征在于， 必要时亦可 添加下列组分之一或其混合物：
⑧ GFnSO扁 CH2C
⑨ GFnSC K
⑩ CsFnSC N (GR 4
PCT/CN2007/003170 2007-09-10 2007-11-08 Carburant écologique à base d'hydrocarbure léger pour véhicules WO2009033331A1 (fr)

Priority Applications (3)

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EP07816782A EP2199376A4 (en) 2007-09-10 2007-11-08 ECOLOGICAL FUEL BASED ON LIGHT HYDROCARBON FOR VEHICLES
JP2009539588A JP2010511753A (ja) 2007-09-10 2007-11-08 環境保護型車両用軽質炭化水素燃料
US12/530,922 US20100146846A1 (en) 2007-09-10 2007-11-08 Environmental friendly vehicle light hydrocarbon fuel

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CN2007100457534A CN101386797B (zh) 2007-09-10 2007-09-10 环保型车用轻烃燃料
CN200710045753.4 2007-09-10

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CN102373102A (zh) * 2010-08-23 2012-03-14 长三角徐州石油科技有限公司 一种高清洁调和汽油及制备方法
TWI451685B (zh) * 2012-06-05 2014-09-01 Motech Ind Inc 換流器
CN105885969B (zh) * 2016-04-20 2018-07-10 上海千茂化工科技有限公司 一种超低硫、抗磨的车用轻烃燃料及其生产方法
CN110551537A (zh) * 2019-08-26 2019-12-10 珠海市三悦石油化工有限公司 一种含有石油沥青的燃料组合物

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JP2010511753A (ja) 2010-04-15
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EP2199376A4 (en) 2011-05-18
KR20100049114A (ko) 2010-05-11
US20100146846A1 (en) 2010-06-17

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