WO2009019733A1 - Improved drier for dehumidifying the air intended for oil expansion tank used in electrical equipments - Google Patents
Improved drier for dehumidifying the air intended for oil expansion tank used in electrical equipments Download PDFInfo
- Publication number
- WO2009019733A1 WO2009019733A1 PCT/IT2008/000513 IT2008000513W WO2009019733A1 WO 2009019733 A1 WO2009019733 A1 WO 2009019733A1 IT 2008000513 W IT2008000513 W IT 2008000513W WO 2009019733 A1 WO2009019733 A1 WO 2009019733A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dryer
- air
- dehumidification container
- dehumidification
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0438—Cooling or heating systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0454—Controlling adsorption
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N5/00—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
- G01N5/02—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by absorbing or adsorbing components of a material and determining change of weight of the adsorbent, e.g. determining moisture content
- G01N5/025—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by absorbing or adsorbing components of a material and determining change of weight of the adsorbent, e.g. determining moisture content for determining moisture content
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40007—Controlling pressure or temperature swing adsorption
- B01D2259/40009—Controlling pressure or temperature swing adsorption using sensors or gas analysers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/08—Cooling; Ventilating
- H01F27/10—Liquid cooling
- H01F27/12—Oil cooling
- H01F27/14—Expansion chambers; Oil conservators; Gas cushions; Arrangements for purifying, drying, or filling
Definitions
- This invention relates to an improved dryer for dehumidifying the air intended for oil expansion tanks used in electrical equipments, particularly oil isolated such as, for example, power transformers, on load switches and so forth.
- a drier of the known type includes a dehumidification container, which has an inlet for the air to be dehumidified and an outlet for the dehumidified air, and absorption means, contained in the dehumidification container, suitable for dehumidifying the air coming from the outside .
- the absorption means consist of a plurality of granules or salts thermally regenerable .
- the dryer also includes heating means, usually a resistor element, positioned inside the dehumidification container and responsible for the thermal regeneration of ' ' the " absorption- -means .• - .. .
- the dryer includes detection means of the moisture degree of the dehumidified air, operatively connected with the heating means , Typically, such detection means include a moisture sensor placed outside the dehumidification container, preferably in the vicinity of the exit aperture of the dehumidified air, in any case being able to be positioned in any other position along the path of dry air .
- the moisture sensor detects the value of residual moisture in the dry air and causes the activation of the heating means if such a value exceeds a maximum allowable value: in fact, this means that the absorption means have lost or are ' losing their absorbent capacity and must be regenerated.
- the detection of the moisture content of the dry air does not always ensure, ultimately, the complete regeneration of the absorption means because sometimes the air entering the dehumidification container follows preferential routes, this distorting the detection itself.
- the moisture sensor sets going with high frequency the resistor element responsible to regenerate the absorption means, with the consequence that " the " " continuing cycles of -switching. on and switching off cause unavoidable problems of reliability of the same resistor element.
- the present invention aims to solve this problem of the known technique .
- the primary purpose of the invention is to provide an improved dryer for dehumidifying the air intended to expansion tanks of the oil used in electrical equipments more reliable and efficient than the equivalent dryers of the known type . It a second purpose of the present invention monitoring the status of dehumidification of the absorption means of the aforesaid dryer more effectively than the known art.
- a third purpose of the attached invention is to getready an improved dryer for dehumidifying air intended to expansion tanks of simple construction.
- the aforesaid purposes are achieved through an improved dryer for dehumidifying the air intended for oil expansion tanks used in electrical equipments as the attached claim 1, which they refer for the sake of brevity.
- ⁇ -the - improved- -dryer .of ..the invention allows to perform accurate measures of the level of dehumidification of the absorption means and, indirectly, of the degree of moisture of the air just dehumidified while keeping in any case a high level of functional efficiency of the involved members, in particular the heating means .
- the improved dryer object of the present invention is of simple construction, comparable to that of the dryers of the known art .
- the aforesaid purposes and advantages will appear better evident with the description of a preferred embodiment of the invention given by illustrative but not limiting way with the aid of the enclosed drawing which shows In simplified longitudinal section the dryer of which protection is hereby required.
- the improved dryer for dehumidifying the air intended for oil expansion tanks used in electrical equipments is shown in figure 1 globally numbered with 1.
- a dehumidification container 2 which present a plurality of inlet micro apertures, not visible, for the air to be dehumidified and an outlet 3 for the dehumidified air; absorption means, as a whole marked with 4, - - -contained i-n- the .dehumidi.fi.ca.tion container 2 and suitable for dehumidifying the air coming from the outside ; heating means, as a whole reported with 5, positioned inside the dehumidification container 2 , intended to regenerate the absorption means 4 ; - detection means, overall marked with 6, operatively connected with the heating means 5 , suitable for determining the saturation state of the absorption means 4.
- the detection means 6 include a transducer 7, coupled to the dehumidification container 2, which directly measure the degree of dehumidification of the absorption means 4.
- the transducer 7 includes an electronic load cell of the compression type, which converts an applied force in a variation of the electrical resistance.
- the protection casing 10 is provided at a first ends 10a with a closing flange 11 and at a second end 10b with a collecting sump 12 which receives the condensate that, during use, comes out from the inlet micro apertures of the dehumidification container 2 to convey it outside.
- the improved dryer 1 comprises a filtering body 16, produced for example in metallic material and arranged at the second end 10b of the protection casing 10.
- the collection sump 12 presents an inner wall 12a inclined and converging toward the centre so that it defines an essentially triangular profile in cross section.
- the collection sump 12 is also provided with a projecting spout 17 which has a central opening 18 suitable for the exhaust at the outside of the condensate and into which the filtering body 16 is inserted which, so, is crossed in one direction by the air to be dehumidified and in the opposite direction from the condensate to drain off, produced during the functioning in the dehumidification container 2.
- the inlets of the air to be dehumidified are made on the side wall 2a of the dehumidification container 2 and where they are uniformly distributed.
- the dehumidification container 2 and the protection casing 10 are coaxial one each other identifying the same longitudinal axis of symmetry Y.
- the _clpsing flange 11 includes a main body 19, suitable to be coupled with the expansion tank, and a central shank 20, projecting from the main body 19 and partly inserted into the dehumidification container 2.
- the through axial hole 21 of the closing flange 11 is coaxial to the longitudinal axis Y.
- the dehumidification container 2 is provided on one side with a shaped bottom 22 to the transducer 7 is coupled and on the opposite side with a sealing plug 23, sliding on the central shank 20 of the closing flange 11 along the longitudinal axis Y.
- the dehumidification container 2 is free to slide along the longitudinal axis Y, performing movements of small entity which allow the transducer 7 to perform the function for which is nominally intended to.
- the absorption means 4 are of the type in itself known to the person skilled in the art, such as salt granules capable to absorb the air moisture and thermally regenerable.
- the air to be dehumidified enters the central opening 18 of the collection sump 12 and, after passing through the filtering body 16, occupies the interspace 25 defined between the dehumidification container 2 and the protection casing 10.
- the air to be dehumidified passes through the inlet micro apertures and enters inside the dehumidification container 2 where it is dehumidified by the absorption means 4 before being conveyed outside passing through the outlet 3.
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Drying Of Gases (AREA)
Abstract
Description
Claims
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0813591A BRPI0813591B8 (en) | 2007-08-07 | 2008-07-29 | DRYER FOR DEHUMIDIFYING THE AIR INTENDED FOR THE OIL EXPANSION TANK USED IN ELECTRICAL EQUIPMENT |
| CN200880110553.5A CN101820972B (en) | 2007-08-07 | 2008-07-29 | Improved dryer for dehumidification of air used for expansion tanks |
| ES08790084T ES2392576T3 (en) | 2007-08-07 | 2008-07-29 | Improved dryer for dehumidification of the air intended for oil expansion tank used in electrical equipment |
| MX2010001439A MX2010001439A (en) | 2007-08-07 | 2008-07-29 | Improved drier for dehumidifying the air intended for oil expansion tank used in electrical equipments. |
| EP08790084A EP2175965B1 (en) | 2007-08-07 | 2008-07-29 | Improved drier for dehumidifying the air intended for oil expansion tank used in electrical equipments |
| CA2695200A CA2695200C (en) | 2007-08-07 | 2008-07-29 | Improved drier for dehumidifying the air intended for oil expansion tanks used in electrical equipments |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITVI2007A00222 | 2007-08-07 | ||
| IT000222A ITVI20070222A1 (en) | 2007-08-07 | 2007-08-07 | PERFECT DRYER TO DEHUMIDIFY THE AIR INTENDED FOR OIL EXPANSION VESSELS USED IN ELECTRICAL EQUIPMENT. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2009019733A1 true WO2009019733A1 (en) | 2009-02-12 |
Family
ID=39870193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IT2008/000513 Ceased WO2009019733A1 (en) | 2007-08-07 | 2008-07-29 | Improved drier for dehumidifying the air intended for oil expansion tank used in electrical equipments |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2175965B1 (en) |
| CN (1) | CN101820972B (en) |
| BR (1) | BRPI0813591B8 (en) |
| CA (1) | CA2695200C (en) |
| CO (1) | CO6260109A2 (en) |
| ES (1) | ES2392576T3 (en) |
| IT (1) | ITVI20070222A1 (en) |
| MX (1) | MX2010001439A (en) |
| RU (1) | RU2463099C2 (en) |
| UA (1) | UA96500C2 (en) |
| WO (1) | WO2009019733A1 (en) |
| ZA (1) | ZA201000533B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITVI20100031A1 (en) * | 2010-02-12 | 2011-08-13 | Comem Spa | PROCEDURE FOR THE CONTROL OF A DRYER TO DEHUMIDIFY THE AIR INTENDED FOR OIL EXPANSION VESSELS USED IN ELECTRICAL EQUIPMENT |
| EP2514511A1 (en) * | 2011-04-20 | 2012-10-24 | ABB Technology AG | Air dehydrating breather assembly for providing dehumidified air to electrical devices, and related method |
| CN104036926A (en) * | 2014-07-01 | 2014-09-10 | 国家电网公司 | Main transformation respirator with online regeneration function and use method |
| CN116666056A (en) * | 2023-06-08 | 2023-08-29 | 华能澜沧江水电股份有限公司 | Hygroscopic Absorbers, Transformers and Sorbent Dehumidification Methods |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102446618B (en) * | 2011-12-05 | 2014-10-22 | 国家电网公司 | FC cooling medium drying device for evaporating cooling power transformer |
| EP2728289B1 (en) | 2012-10-31 | 2017-12-06 | ABB Technology Oy | Arrangement for removing water from an equipment space |
| CN105374516A (en) * | 2014-08-28 | 2016-03-02 | 广西电网公司桂林供电局 | Self-healing type moisture absorber for transformer |
| CN106377982A (en) * | 2016-11-16 | 2017-02-08 | 国网江苏省电力公司宿迁供电公司 | Intelligent drying moisture absorber and dry moisture absorbing method thereof |
| CN107934784A (en) * | 2017-11-24 | 2018-04-20 | 徐州重型机械有限公司 | A kind of fuel tank pressue device, control method and its crane |
| CN109036792A (en) * | 2018-08-01 | 2018-12-18 | 湖北科技学院 | A kind of dehumidification device in transformer breather |
| CN109036793A (en) * | 2018-08-01 | 2018-12-18 | 湖北科技学院 | It is a kind of can the wet transformer breather of free removal |
| CN108597784A (en) * | 2018-08-01 | 2018-09-28 | 湖北科技学院 | A kind of circumscribed dehumidification equipment of transformer breather and respirator |
| DE102018213341A1 (en) * | 2018-08-08 | 2020-02-13 | Siemens Aktiengesellschaft | Determination of the moisture input in a drying agent for transformers |
| RU188572U1 (en) * | 2018-12-27 | 2019-04-17 | Общество с ограниченной ответственностью "Радиан" | Oil Transformer Air Dryer |
| RU2704352C1 (en) * | 2019-05-06 | 2019-10-28 | Елена Владимировна Величко | Method of restoration of insulation resistance of current conductors of working equipment of power plants |
| WO2022015208A1 (en) * | 2020-07-14 | 2022-01-20 | Евгений Анатольевич ПРОСКУРИН | Dehumidifier |
| RU2743877C1 (en) * | 2020-08-11 | 2021-03-01 | Григорий Соломонович Марголин | A method for installing a voice prosthesis into an opening in the tracheoesophageal wall in a tracheostomy after a larynx removal surgery, and a device for its implementation |
| IT202100012281A1 (en) * | 2021-05-13 | 2022-11-13 | Comem Spa | PROCEDURE FOR REPLACING THE SALTS PRESENT IN SELF-REGENERATING DRYERS FOR POWER ELECTRIC EQUIPMENT |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57153721A (en) * | 1981-03-18 | 1982-09-22 | Toshiba Corp | Air dehumidifying apparatus for ozone generator |
| JPS59179129A (en) * | 1983-03-30 | 1984-10-11 | Daihou Giken Kk | Humidity controlling device |
| AU539707B2 (en) * | 1978-10-26 | 1984-10-11 | Pall Corporation | Downflow or upflow adsorbent fractionator flow control system |
| US20030089238A1 (en) * | 2001-11-13 | 2003-05-15 | Messko Albert Hauser Gmbh & Co. Kg | Air demoisturizer for oil-insulated transformers, chokes and tap changers |
| WO2004043574A1 (en) * | 2002-11-12 | 2004-05-27 | Alfred Wiedl | Installation for drying or dehydrating goods |
| WO2004088679A2 (en) * | 2003-04-04 | 2004-10-14 | Maschinenfabrik Reinhausen Gmbh | Air de-humidifier for oil-insulated transformers, choke coils and step switches |
| WO2005055255A1 (en) * | 2003-12-06 | 2005-06-16 | Maschinenfabrik Reinhausen Gmbh | Method for dehumidifying air and air dehumidifier for oil-insulated transformers, reactance coils and step switch |
| EP1980312A2 (en) * | 2007-04-03 | 2008-10-15 | Faiveley Transport Italia S.p.A. | Adsorption drying unit with optimised management of the flowrate and/or the regeneration phase and air treatment plant comprising such a unit |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2140808C1 (en) * | 1998-08-04 | 1999-11-10 | Друцкий Алексей Васильевич | Gas drying plant |
-
2007
- 2007-08-07 IT IT000222A patent/ITVI20070222A1/en unknown
-
2008
- 2008-07-29 BR BRPI0813591A patent/BRPI0813591B8/en active IP Right Grant
- 2008-07-29 MX MX2010001439A patent/MX2010001439A/en active IP Right Grant
- 2008-07-29 UA UAA201002399A patent/UA96500C2/en unknown
- 2008-07-29 WO PCT/IT2008/000513 patent/WO2009019733A1/en not_active Ceased
- 2008-07-29 ES ES08790084T patent/ES2392576T3/en active Active
- 2008-07-29 EP EP08790084A patent/EP2175965B1/en active Active
- 2008-07-29 CA CA2695200A patent/CA2695200C/en active Active
- 2008-07-29 CN CN200880110553.5A patent/CN101820972B/en active Active
- 2008-07-29 RU RU2010102794/05A patent/RU2463099C2/en not_active IP Right Cessation
-
2010
- 2010-01-25 ZA ZA201000533A patent/ZA201000533B/en unknown
- 2010-03-05 CO CO10026469A patent/CO6260109A2/en not_active Application Discontinuation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU539707B2 (en) * | 1978-10-26 | 1984-10-11 | Pall Corporation | Downflow or upflow adsorbent fractionator flow control system |
| JPS57153721A (en) * | 1981-03-18 | 1982-09-22 | Toshiba Corp | Air dehumidifying apparatus for ozone generator |
| JPS59179129A (en) * | 1983-03-30 | 1984-10-11 | Daihou Giken Kk | Humidity controlling device |
| US20030089238A1 (en) * | 2001-11-13 | 2003-05-15 | Messko Albert Hauser Gmbh & Co. Kg | Air demoisturizer for oil-insulated transformers, chokes and tap changers |
| WO2004043574A1 (en) * | 2002-11-12 | 2004-05-27 | Alfred Wiedl | Installation for drying or dehydrating goods |
| WO2004088679A2 (en) * | 2003-04-04 | 2004-10-14 | Maschinenfabrik Reinhausen Gmbh | Air de-humidifier for oil-insulated transformers, choke coils and step switches |
| WO2005055255A1 (en) * | 2003-12-06 | 2005-06-16 | Maschinenfabrik Reinhausen Gmbh | Method for dehumidifying air and air dehumidifier for oil-insulated transformers, reactance coils and step switch |
| EP1980312A2 (en) * | 2007-04-03 | 2008-10-15 | Faiveley Transport Italia S.p.A. | Adsorption drying unit with optimised management of the flowrate and/or the regeneration phase and air treatment plant comprising such a unit |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITVI20100031A1 (en) * | 2010-02-12 | 2011-08-13 | Comem Spa | PROCEDURE FOR THE CONTROL OF A DRYER TO DEHUMIDIFY THE AIR INTENDED FOR OIL EXPANSION VESSELS USED IN ELECTRICAL EQUIPMENT |
| WO2011099046A1 (en) * | 2010-02-12 | 2011-08-18 | Abb S.P.A. | Process for controlling dryer capable of dehumidifying air entering the oil expansion vessels used in electrical appliances |
| CN102811792A (en) * | 2010-02-12 | 2012-12-05 | Abb技术有限公司 | Process for controlling dryer capable of dehumidifying air entering the oil expansion vessels used in electrical appliances |
| EP2514511A1 (en) * | 2011-04-20 | 2012-10-24 | ABB Technology AG | Air dehydrating breather assembly for providing dehumidified air to electrical devices, and related method |
| WO2012143285A1 (en) * | 2011-04-20 | 2012-10-26 | Abb Technology Ag | Air dehydrating breather assembly for providing dehumidified air to electrical devices, and related method |
| US9108149B2 (en) | 2011-04-20 | 2015-08-18 | Abb Technology Ag | Air dehydrating breather assembly for providing dehumidified air to electrical devices, and related method |
| CN104036926A (en) * | 2014-07-01 | 2014-09-10 | 国家电网公司 | Main transformation respirator with online regeneration function and use method |
| CN116666056A (en) * | 2023-06-08 | 2023-08-29 | 华能澜沧江水电股份有限公司 | Hygroscopic Absorbers, Transformers and Sorbent Dehumidification Methods |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101820972A (en) | 2010-09-01 |
| BRPI0813591A2 (en) | 2015-10-13 |
| ZA201000533B (en) | 2010-09-29 |
| CN101820972B (en) | 2013-06-05 |
| ITVI20070222A1 (en) | 2009-02-08 |
| BRPI0813591B8 (en) | 2022-10-18 |
| RU2010102794A (en) | 2011-09-20 |
| EP2175965B1 (en) | 2012-08-29 |
| BRPI0813591B1 (en) | 2018-10-30 |
| CA2695200A1 (en) | 2009-02-12 |
| UA96500C2 (en) | 2011-11-10 |
| CA2695200C (en) | 2016-07-05 |
| CO6260109A2 (en) | 2011-03-22 |
| ES2392576T3 (en) | 2012-12-11 |
| MX2010001439A (en) | 2010-06-02 |
| RU2463099C2 (en) | 2012-10-10 |
| EP2175965A1 (en) | 2010-04-21 |
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