WO2009004950A1 - Method for production of monosaccharide and/or water-soluble polysaccharide by hydrolysis of cellulose-containing material - Google Patents

Method for production of monosaccharide and/or water-soluble polysaccharide by hydrolysis of cellulose-containing material Download PDF

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Publication number
WO2009004950A1
WO2009004950A1 PCT/JP2008/061466 JP2008061466W WO2009004950A1 WO 2009004950 A1 WO2009004950 A1 WO 2009004950A1 JP 2008061466 W JP2008061466 W JP 2008061466W WO 2009004950 A1 WO2009004950 A1 WO 2009004950A1
Authority
WO
Grant status
Application
Patent type
Prior art keywords
cellulose
monosaccharide
hydrolysis
water
containing material
Prior art date
Application number
PCT/JP2008/061466
Other languages
French (fr)
Japanese (ja)
Inventor
Shinichirou Yanagawa
Hidesato Kondo
Michikazu Hara
Original Assignee
Nippon Oil Corporation
Tokyo Institute Of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28Regeneration or reactivation
    • B01J27/30Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02Monosaccharides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/06Oligosaccharides, i.e. having three to five saccharide radicals attached to each other by glycosidic linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13KSACCHARIDES, OTHER THAN SUCROSE, OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DI-, OLIGO- OR POLYSACCHARIDES
    • C13K1/00Glucose; Glucose-containing syrups
    • C13K1/02Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08Ion-exchange resins
    • B01J31/10Ion-exchange resins sulfonated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of products other than chlorine, adipic acid, caprolactam, or chlorodifluoromethane, e.g. bulk or fine chemicals or pharmaceuticals
    • Y02P20/58Recycling
    • Y02P20/584Recycling of catalysts

Abstract

A monosaccharide and/or a water-soluble polysaccharide can be produced with a high degree of efficiency by hydrolyzing a cellulose-containing material with a sulfonate-containing carbonaceous material. The used sulfonate-containing carbonaceous material can be reactivated and reused by carbonization and sulfonation, without the need of separating the sulfonate-containing carbonaceous material from the unreacted portion of the cellulose-containing material. This method enables to reduce the cost for hydrolysis, can reduce the amount of waste materials, and therefore can contribute to the global environmental conservation.
PCT/JP2008/061466 2007-06-29 2008-06-24 Method for production of monosaccharide and/or water-soluble polysaccharide by hydrolysis of cellulose-containing material WO2009004950A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2007172608 2007-06-29
JP2007-172608 2007-06-29

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2009521585A JPWO2009004950A1 (en) 2007-06-29 2008-06-24 Monosaccharides and / or a water-soluble polysaccharide manufacturing method by hydrolysis of material containing cellulose

Publications (1)

Publication Number Publication Date
WO2009004950A1 true true WO2009004950A1 (en) 2009-01-08

Family

ID=40225997

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/061466 WO2009004950A1 (en) 2007-06-29 2008-06-24 Method for production of monosaccharide and/or water-soluble polysaccharide by hydrolysis of cellulose-containing material

Country Status (2)

Country Link
JP (1) JPWO2009004950A1 (en)
WO (1) WO2009004950A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009296919A (en) * 2008-06-12 2009-12-24 Tokyo Univ Of Agriculture & Technology Method for liquefying cellulose-based biomass
WO2010035832A1 (en) * 2008-09-29 2010-04-01 株式会社日本触媒 Process for producing monosaccharide
WO2010137039A2 (en) 2009-05-26 2010-12-02 Arvind Mallinath Lali Method for production of fermentable sugars from biomass
CN104650935A (en) * 2015-02-11 2015-05-27 中原工学院 Effective treatment method of biomass

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5925801A (en) * 1982-06-01 1984-02-09 Ici Ltd Solubilization and/or hydrolysis for cellulose-containing material
JP2002085100A (en) * 2000-09-11 2002-03-26 Fukuoka Prefecture Method for solubilizing cellulose
JP2004238311A (en) * 2003-02-05 2004-08-26 Japan Science & Technology Agency Polycyclic aromatic carbon-based solid strong acid
WO2005029508A1 (en) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering Sulfonated amorphous carbon, process for producing the same and use thereof
JP2006238728A (en) * 2005-03-01 2006-09-14 Nippon Paper Chemicals Co Ltd Method for producing sugars from drainage during papermaking
WO2008001696A1 (en) * 2006-06-26 2008-01-03 Tokyo Institute Of Technology Method for production of polysaccharide and/or monosaccharide by hydrolysis of other polysaccharide

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5925801A (en) * 1982-06-01 1984-02-09 Ici Ltd Solubilization and/or hydrolysis for cellulose-containing material
JP2002085100A (en) * 2000-09-11 2002-03-26 Fukuoka Prefecture Method for solubilizing cellulose
JP2004238311A (en) * 2003-02-05 2004-08-26 Japan Science & Technology Agency Polycyclic aromatic carbon-based solid strong acid
WO2005029508A1 (en) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering Sulfonated amorphous carbon, process for producing the same and use thereof
JP2006238728A (en) * 2005-03-01 2006-09-14 Nippon Paper Chemicals Co Ltd Method for producing sugars from drainage during papermaking
WO2008001696A1 (en) * 2006-06-26 2008-01-03 Tokyo Institute Of Technology Method for production of polysaccharide and/or monosaccharide by hydrolysis of other polysaccharide

Non-Patent Citations (11)

* Cited by examiner, † Cited by third party
Title
ABBADI A. ET AL.: "Study on solid acid catalyzed hydrolysis of maltose and related polysaccharides.", STARCH, vol. 50, 1998, pages 23 - 28, XP000739810, DOI: doi:10.1002/(SICI)1521-379X(199801)50:1<23::AID-STAR23>3.3.CO;2-K *
ATSUSHI FUKUOKA ET AL.: "Sulfonated Mesoporous Silica ni yoru Torui no Henkan Hanno", THE 48TH THE JAPAN PETROLEUM INSTITUTE NENKAI KOEN YOSHI, 2005, pages 67 - 68 *
ATSUSHI FUKUOKA: "Sulfonated Mesoporous Silica ni yoru To no Kasui Bunkai Hanno", FINE CHEMICAL, vol. 34, no. 5, 2005, pages 11 - 18 *
DHEPE P.L. ET AL.: "Hydrolysis of sugars by sulfonated mesoporous silicas.", SHOKUBAI, vol. 47, 2005, pages 122 - 124 *
DHEPE P.L. ET AL.: "Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas.", CATAL. LETT., vol. 102, 2005, pages 163 - 169, XP019275199 *
DHEPE, PARESH ET AL.: "Sulfonated Mesoporous Silica ni yoru Suichu deno Torui Kasui Bunkai Hanno", THE 85TH ANNUAL MEETING ON CHEMICAL SOCIETY OF JAPAN IN SPRING - KOEN YOKOSHU I, 2005, pages 53, 4 B4 - 06 *
KEIKO ICHIKAWA ET AL.: "Biomass Zairyo o Genryo to shita Kotaisan Shokubai no San Shokubai Kassei to Characterization", T HE 86TH ANNUAL MEETING ON CHEMICAL SOCIETY OF JAPAN IN SPRING - KOEN YOKOSHU I, 2006, pages 131, 2 Dl - 38 *
MICHIKAZU HARA: "Kankyo · Energy Mondai no Kaiketsu o Mezashita Kotaisan Shokubai no Kaihatsu", ENEOS TECHNICAL REVIEW, vol. 48, 2006, pages 142 - 146 *
MICHIKAZU HARA: "Ryusan Daitai Shokubai no Tenkai", PREPRINTS OF SYMPOSIUM ON CATALYSIS, 2006, pages 15 - 20 *
MICHIKAZU HARA: "Sato kara Tsukuru Ecology Shokubai", CHEMISTRY, vol. 61, 2006, pages 30 - 33, XP003019688 *
SATOSHI SUGANUMA ET AL.: "Torui o Genryo to shita Kotaisan Shokubai ni yoru beta-1,4glycoside Ketsugo no Kasui Bunkai", THE 87TH ANNUAL MEETING ON CHEMICAL SOCIETY OF JAPAN IN SPRING - KOEN YOKOSHU I, March 2007 (2007-03-01), pages 490, 3 M2 - 18 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009296919A (en) * 2008-06-12 2009-12-24 Tokyo Univ Of Agriculture & Technology Method for liquefying cellulose-based biomass
WO2010035832A1 (en) * 2008-09-29 2010-04-01 株式会社日本触媒 Process for producing monosaccharide
WO2010137039A2 (en) 2009-05-26 2010-12-02 Arvind Mallinath Lali Method for production of fermentable sugars from biomass
US8338139B2 (en) 2009-05-26 2012-12-25 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
US8673596B2 (en) 2009-05-26 2014-03-18 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
US8709763B2 (en) 2009-05-26 2014-04-29 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
CN104650935A (en) * 2015-02-11 2015-05-27 中原工学院 Effective treatment method of biomass
CN104650935B (en) * 2015-02-11 2017-02-01 中原工学院 An effective method of processing raw material

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