WO2008142453A1

WO2008142453A1 - Low emissivity film

Info

Publication number: WO2008142453A1
Application number: PCT/GB2008/050369
Authority: WO
Inventors: Colin Marshall; Paul Watters
Original assignee: Innovia Films Limited
Priority date: 2007-05-24
Filing date: 2008-05-21
Publication date: 2008-11-27
Also published as: AU2008252612B2; SI2147044T1; DK2147044T3; ES2434174T3; US20100173145A1; PT2147044E; EP2147044A1; HRP20131038T1; AU2008252612A1; EP2147044B1; PL2147044T3; US9822229B2; CY1114675T1

Abstract

The present invention concerns a functional film material comprising a substrate layer and a coating layer, the coating layer comprising a block copolymeric binder and a particulate metal pigment therein, the ratio of pigment to binder in the coating layer being selected with reference to the coat weight to provide the functional film material with an emissivity of less than 0.5, and the substrate and coating layer being selected to provide the film with a VWTR (ambient) in excess of 400 gm-2d-1bar-1.

Description

LOW EMISSIVITY FILM

The present invention relates to a low emissivity film,

Emissivity is a relative measure of the amount of energy radiated by an object. A true black body (in the theoretical physical sense) would have an emissivity (ε) of 1 whereas a real object has an emissivity of between 0 and 1. An object having low emissivity will emit relatively little of the radiation incident upon it. An object having higher emissivity will emit more of such incident radiation.

This invention is concerned with objects which have relatively low emissivity, and particularly with films having this property, which may then be used as insulating films.

US Patent No. 6,773,797 discloses breathable, porous films and articles made therefrom and a process for making such films,

EP-A- 1316419 discloses weatherable multilayer articles comprising a coating layer comprising a block copolyestercarbonate, a second layer comprising a polymer containing carbonate structural units, an adhesive layer, and a substrate layer. Similar disclosures are made in WO-A-2005/072959 and in US-A-2004/0166323.

EP-A-0099335 discloses a method of providing on a substrate a protected binder layer containing particles of size 10μm or less.

WO-A-03/047857 discloses multilayer articles comprising a coating layer comprising resorcinol arylate chain members bound to a support substrate via an optional intermediate tie layer.

According to the present invention there is provided a functional film material comprising a substrate layer and a coating layer, the coating layer comprising a block copolymeric binder and a particulate metal pigment therein, the ratio of pigment to binder in the coating layer being selected with reference to the coat weight to provide the functional film material with an emissivity of less than 0.5, and the substrate and the coating layer being selected to provide the film with a VWTR (ambient) in excess of 200 gm^"2d^"1bar^"1.

The films of the invention have the capability to provide an insulating regime (particularly with regard to heat) by virtue of their low emissivity, but are also able to transmit moisture to a relatively high degree.

The substrate layer may comprise any one or more of the following: polymeric materials: synthetic paper, films made from organic polymers, preferably biopolymers, more preferably films made from one or more suitable carbohydrates; polysaccharides (such as starch, cellulose, glycogen, hemi- cellulose, chitin, fructan inulin; lignin and/or pectic substances); gums; proteins, optionally cereal, vegetable and/or animal proteins (such as gluten [e.g. from wheat], whey protein, and/or gelatin); colloids (such as hydro- colloids, for example natural hydrocolloids, e.g. gums); polylactic, polygalactic and/or cellulosic films (e.g. microbial and/or regenerated cellulose film)]; thermoplastic films; polymeric films (for example films comprising: polyolefins [e.g. polypropylene and/or polyethylene] polyurethanes, polyvinylhalides [e.g. PVC], polyesters [e.g. polyethylene terephthalate -PET], polyamides [e.g. nylons] and/or non-hydrocarbon polymers); and/or multilayer and/or composite sheets formed by any suitable combinations and/or mixtures of thereof. The substrate may also be paper.

Substrate layers of films of the invention may be in the form of monolayers, or may comprise two or more layers which can be formed by coextrusion and/or by laminating.

Preferred substrate materials have a VWTR (ambient) in excess of 400 grrf²d^" ¹bar^"1.

Preferred substrate materials have an oxygen permeability (OTR) (which may be measured for example in standard test ASTM D 3985 at 23°C and 0 to 5% RH) of less than about 30 cm³m^"2d^"1bar^"1, preferably less than about 25 cm³nrf²cT¹ bar^"1 , more preferably less than about 20 cm³m^"2d^'1bar^"1 , and most preferably less than about 10 cm³m^"2d^*1bar^'1. A relatively low OTR may contribute towards low emissivity of the film.

Particularly preferred substrate materials include cellulose and derivatives thereof (including cellulose acetate), regenerated cellulose (Cellophane™, cuprammonium cellulose), benzoylated cellulose, collagen, polyurethanes and Goretex™.

One especially preferred material for the substrate is regenerated cellulose. The substrate may be produced by one or several known manufacturing methods, such as xanthate, cuprammonium, carbamate or organic solvent (e.g. NMMO) processes when a regenerated cellulose material is used.

Another preferred material is cellulose acetate.

Preferably, the substrate is a semi-permeable membrane.

In the event that the substrate is not a semi-permeable membrane then preferably the substrate is microporous.

Preferably at least one of the substrate and the coating is a semi-permeable membrane. In the event that only one of the substrate and the coating is semi-permeable membrane then preferably the other, non-semi-permeable membrane, is microporous.

The coating layer may be formed as a coating in the traditional sense, from a solvent or water based dispersion or solution, or even from a solvent-less system in some cases, or may be an extrusion coating. The coating layer may be applied directly on the substrate, or there may be provided one or more intervening layers. The substrate may be primed or otherwise treated to aid adherence of the coating layer thereon. The coating layer can be composed of cellulose derivatives (e.g. ethers, esters, nitrocellulose, etc.), synthetic organic polymers (e.g. polyacrylic ester, polyvinyl acetate copolymers, polyurethanes, aliphatic polyamides such as nylon 6, nylon 6.6, nylon 4.6, polysulfone and polyethersulfone and the like), modified or unmodified naturally occurring polymers (e.g. starches, proteins, etc.). Mixtures of these with or without the addition of inorganic additives (e.g. fumed silica) can also be used. However, it is generally preferred that such inorganic additives be substantially absent from the coating layer since such additives tend to increase the emissivity of the film.

The block copolymeric binder is preferably selected from materials comprising a hard and soft segment polymer of the type designated for fabrics allowing breathability. Particularly preferred examples include styrene butadiene styrene resins and hydrophilic polyurethanes. Hydrophilic polyurethanes which may be used according to the invention as preferred material for the binder are the reaction product of (a) polyisocyanates; and (b) polyols containing at least two isocyanate reactive groups; and (c) optionally an active hydrogen-containing chain extender.

Suitable polyisocyanates comprise aliphatic, cycloaliphatic, or aromatic polyisocyanates. As examples of suitable aliphatic diisocyanates, there may be mentioned 1 ,4-diisocyanatobutane, 1 ,6-diisocyanatohexane, 1 ,6- diisocyanato-2, 2 ,4-trimethylhexane and 1 ,1 , 2 - diisocyanatododecane, either alone or in admixture. Particularly suitable cycloaliphatic diisocyanates include 1 ,3- and 1 ,4-diisocyanatocyclohexane, 2,4-diisocyanato-1- methylcyclohexane, 1 ,3-diisocyanato-2-methylcyclohexane, 1 -isocyanato-2- (isocyanatomethyl)cyclopentane, 1 ,1'-methylenebis [4-isocyanato- cyclohexane, 1 ,1-(1-methylethylidene) bis (4-isocyanatocyclohexanej, 5- isocyanato- 1-isocyanatomethyl- 1 ,3.3- trimethylcyclohexane (isophorone diisocyanate), 1 ,3- and 1 ,4bis(isocyanatornethyi)cyc!ohexane,1 ,1 methylenebis[4-isocyanato-3 -methylcyclohexane, 1 -isocyanato-4(or3)- isocvanatomethyl-1-methylcyclohexane, either alone or in admixture. Particularly suitable aromatic diisocyanates include 1 ,4-diisocyanatobenzene, 1 , 1 '-methylenebis[4-isocyanatobenzene], 2,4-diisocyanato-1 -methylbenzene, 1 ,3-diisocyanato-2-methylbenzene, 1 ,5-diisocyanatonaphthalene, 1 ,1 -(1 - methylethylidene)bis[4- isocyanatobenzene, 1 ,3- and 1 ,4-bis(1-isocyanato-1- methylethyi)benzene, either alone or in admixture. Aromatic polyisocyanates containing 3 or more isocyanate groups may also be used such as 1 ,1',1"- methylidynetris[4-isocyanatobenzene] and polyphenyl polymethylene polyisocyanates obtained by phosgenation of aniline/formaldehyde condensates.

The polyols containing at least two isocyanate reactive groups may be polyester polyols, polyether polyols, polycarbonate polyols, polyacetal polyols, polyesteramide polyols or polythioether polyols. The polyester polyols, polyether polyols and polycarbonate polyols are preferred.

Suitable polyester polyols which may be used include the hydroxyl-terminated reaction products of polyhydric, preferably dihydric alcohols (to which trihydric alcohols may be added) with polycarboxylic, preferably dicarboxylic acids or their corresponding carboxylic acid anhydrides. Polyester polyols obtained by the ring opening polymerization of lactones such as e-caprolactone may also be included.

The polycarboxylic acids which may be used for the formation of these polyester polyols may be aliphatic, cycioaliphatic, aromatic and/or heterocyclic and they may be substituted (e.g. by halogen atoms) and saturated or unsaturated. As examples of aliphatic dicarboxylic acids, there may be mentioned, succinic acid, glutaric acid, adipic acid, suberic acid, azelaic acid, sebacic acid and dodecanedicarboxylic acid. As an example of a cycioaliphatic dicarboxylic acid, there may be mentioned hexahydrophthalic acid. Examples of aromatic dicarboxyϋc acids include isophthaiic acid, terephthalic acid, ortho-phthalic acid, tetrachlorophthalic acids and 1 ,5- naphthalenedicarboxylic acid. Among the unsaturated aliphatic dicarboxylic acids which may be used, there may be mentioned fumaric acid, maleic acid, itaconic acid, citraconic acid, mesaconic acid and tetrahydrophthalic acid. Examples of tπ- and tetracarboxylic acids include tπmellitic acid tπmesic acid and pyromellitic acid

The polyhydπc alcohols which may be used for the preparation of the polyester polyols include ethylene glycol, propylene glycol, 1 ,3-propanediol, 1 ,3-butanedιol, 1 ,4-butanedιol, 1 ,5pentanedιol, 1 ,6-hexanedιol, neopentyl glycol, diethylene glycol, dipropylene glycol, triethylene glycol, tetraethylene glycol, dibutylene glycol, 2-methyl-1 ,3-pentanedιol, 2,2,4-tπmethyl-1 ,3- pentanediol, 1 ,4-cyclohexanedιmethanol, ethylene oxide adducts or propylene oxide adducts of bisphenol A or hydrogenated bisphenol A Triols or tetraols such as trimethylolethane, tπmethylolpropane, glycerine and pentaerythritol may also be used These polyhydπc alcohols are generally used to prepare the polyester polyols by polycondensation with the above mentioned polycarboxylic acids, but according to a particular embodiment they can also be added as such to the reaction mixture

Suitable polyether polyols include polyethylene glycols, polypropylene glycols and polytetraethylene glycols

Suitable polycarbonate polyols which may be used include the reaction products of diols such as 1 ,3-propanedιol, 1 ,4-butanediol, 1 ,6-hexanediol, diethylene glycol, triethylene glycol or tetraethylene glycol with phosgene, with diarylcarbonat.es such as diphenylcarbonate or with cyclic carbonates such as ethylene and/or propylene carbonate

Suitable polyacetal polyols which may be used include those prepared by reacting glycols such as diethyleneglycol with formaldehyde Suitable polyacetals may also be prepared by polymerizing cyclic acetais

The active hydrogen-containing chain extender which may optionally be used is suitably an aliphatic, alicyclic, aromatic or heterocyclic primary or secondary polyamine having up to 80 preferably up to 12 carbon atoms, or water In the latter case a fully reacted polyurethane polymer is obtained with no residual free 'socyanate groups Where the chain extension of the polyurethane prepolymer is effected with a polyamine, the total amount of polyamine should be calculated according to the amount of isocyanate groups present in the polyurethane prepolymer in order to obtain a fully reacted polyurethane urea polymer with no residual free isocyanate groups: the polyamine used in this case has an average functionality of 2 to 4, preferably 2 to 3.

The degree of non-linearity of the polyurethane urea polymer is controlled by the functionality of the polyamine used for the chain extension. The desired functionality can be achieved by mixing polyamines with different amine functionalities. For example, a functionality of 2.5 may be achieved by using equimolar mixtures of diamines and triamines.

Examples of such chain extenders useful herein include hydrazine, ethylene diamine, piperazine, diethylene triamine, triethylene tetramine, tetraethylene pentamine, pentaethylene hexamine, N₁ N, N-tris(2-aminoethyl)amine, N-(2~ piperazinoethyl)ethylenediamine, N,N'-bis(2-aminoethyl) piperazine, N₁N₁N'- tris(2-aminoethyl)ethylenediamine, N-[N-(2-aminoethyl)-2-aminoethyl-N'-(2- aminoethyl)piperazine, N-(2-aminoethyl)-N'-(2piperazinoethyl)ethylene diamine, N,N-bis(2-aminoethyl)-N-(2-piperazinoethyl)amine, N₁N- bis(2piperazinoethyl)amine, guanidine, melamine,N-(2-aminoethyl) -1 , 3- propanediamine, 3,3"- diaminobenzidine, 2,4,6-triaminopyrimidine, dipropylenetriamine, tetrapropylenepentamine, tripropylenetetramine, N₁N- bis(6-aminohexyl)amine, N,N'-bis(3-aminopropyl)ethyienediamine, 2 ,4-bis(4'- aminobenzyl)aniline. 1 ,4-butanediamine,1 , 6-hexanediamine, 1 ,8- octanediamine,1 ,1 0-decanediamine. 2-methylpentamethylenediamine,1 ,12 - dodecanediamine, isophorone diamine (or1 -amino-3-amιnomethyl-3 '5 ,5- trimethyl-cyclohexane), bis(4aminocyclohexyi)methane(or bis(aminocyclohexane-4-yl).methane( and bis(4-arnino~

3methylcyclohexyl)methane(or bis(amino-2-methylcyclohexane-4-yl)methane, polyethylene imines, polyoxyethylene amines and/orpolyoxypropylene amines (e.g. Jeffamines from TEXACO) The total amount of polyamines should be calculated according to the amount of isocyanate groups present in the polyurethane prepolymer. The ratio of isocyanate groups in the prepolymer to active hydrogen in the chain extender during the chain extension is in the range of from about 1.0:0.7 to about 1.0:1.1 , preferably from about 1.0:0.9 to about 1.0:1.02 on an equivalent basis.

Preferably, the polyisocyanate is a diisocyanate and more preferably it is selected from 1 ,1'methylenebis-[4-isocyanatobenzene] and 1 ,1'-methylenebis (4-isocyanatocyclohexane]. Preferably the polyol is a polyethylene glycol selected from ethylene glycol, polyethylene glycol, polytetramethylene glycol and the like, eventually in admixture with other polyether polyols.

Even more preferably, the polyethylene glycol has a very low molecular weight (from 300 to 900). This is rather unconventional as usually the polyurethanes incorporate polyethylene glycol with a molecular weight above

2000 in order to achieve the well known properties of the polyurethanes (long soft and hard segments, melting point, strength). Breathability is also known to decrease with the molecular weight of the polyethylene glycol. However, in this embodiment, the low molecular weight of the polyethylene glycol is supposed to be responsible for the amelioration of the flux.

Preferably the chain extender is isophorone diamine (or l-amino-3- aminomethyl-3,5,5,trimethylcyclohexane) alone or in admixture with hydrazine.

The films of the invention can be of a variety of thicknesses according to the end use requirements of the films which are to be produced. The thickness of the film is preferably from about 20μm to about 350μm, more preferably from about 25μm to about 3Q0μm, and most preferably from about 30μm to about 250μm. Other preferred thickness ranges include from about 10μm to about 300μm, from about 14μm to about 300μm and from about 17μm to about 300μm. The particulate metal material is preferably a polished metal material, selected for example from aluminium, bronze, stainless steel, brass, gold, nickel, silver, silver coated glass, tin or copper, or mixtures of two or more thereof

The particulate metal material preferably has a predominantly lamellar or plate-like form Preferably the median aspect ratio of the material is at least about 10 1 , more preferably at least about 20 1 and most preferably at least about 30 1 The aspect rations of certain specific materials useful in the present invention are given below These values are given as typical diameter to thickness ratios for metallic flakes of median diameter (d50) c 12um -

• Miraroto Silver Dollar (thin silver dollar) 120 1

• Silver Dollar 35 1

• Mirasheen (VMP) 400 1 • Aluminium Cornflake 60 1

• Bronze Cornflake 45 1

These are approximations only and will vary from manufacturer to manufacturer and on the feed size and milling conditions used to generate the pigment

Generally speaking, the materials with higher aspect ratios tend to be more expensive, and their selection or otherwise in the films of the invention will depend on the end application of the film and as to whether the selection of a relatively expensive material is justified in the end use

The particulate metal material when provided in flake form is preferably of a "non-leafing" variety meaning that the metal particles are not coated with stearic acid or functionally similar material

The emissivity of the film in accordance with the invention is less than about 0 5, preferably less than about 0 45 more preferably less than about 0 4, still more preferably less than about 0 35 and most preferably less than about 0 3 in selecting the materials of the film to obtain emissivity within the stated ranges, particular attention must be paid to two aspects in particular:

• The ratio in the coating layer of pigment to binder (p:b).

• The coat weight on the substrate.

Generally speaking, the higher the p:b ratio, the lower the emissivity of the film because, for a given coat weight, the coating layer has a relatively higher proportion of pigment - in this case metal particle pigment, which is responsible at least in part for reducing the emissivity of the film. However, if the p:b ratio is too high then the integrity of the coating layer can be compromised, and metal particles may disintegrate from the film, being insufficiently bound.

On the other hand, a relatively low p:b ratio can still give rise to a film with acceptably low emissivity, provided that the coat weight is high enough. However, if the coat weight is too high then, as well as adding cost to the film, the WVTR of the film may also be compromised and made unacceptably high.

Preferably the film substrate has a higher VWTR than the coating layer. In this case the determining factor of the VWTR of the film as a whole is the coating layer. The VWTR of the substrate is preferably at least about 10, more preferably at least about 50 and most preferably at least about 100 gnf ²d^"1bar^"1 higher than that of the coating layer.

Because of the competing variable contribution made to emissivity by the two variables mentioned above, it is not always possible to define in absolute terms what range of those variables will produce a film in accordance with the invention. A relatively low p:b ratio can be offset by a higher coat weight, and vice versa. However, in most cases the p:b ratio in the coating layer will be from about 3:1 to about 1 :10, preferably from about 2.5:1 to about 1 :5, more preferably from about 2.25:1 to about 1 :4, and most preferably from about 2:1 to about 1 :3.

In most case the coat weight will be from about 0.8 to about 2.5 gm^"2, preferably from about 0.9 to about 2.4 gm^"2, more preferably from about 1.0 to about 2.3 gm^"2 and most preferably from about 1.1 to about 2.2 gm^"2

Other variables which may affect the emissivity of the film include the nature of the particulate metal and the nature of the binder material.

The films of the invention will now be more particularly described with reference to the following examples.

Examples

Films in accordance with the invention were prepared (lab and pilot) by coating regenerated cellulose films (thickness of around 35μm) with a coating comprising a polyurethane binder and a pigment. The coatings were applied by direct gravure coating to produce the films identified in Table 1 and with the properties identified therein. In the plant trials the coatings were applied to a cellulose acetate substrate available from Clarifoil, PO Box 5, Spondon, Derby, UK, DE21 7BP. W

Table 1

^* measured by the Standard Test Methods for Water Vapor Transmission of Material - ASTM E96/E96M-04

* from Silberline Manufacturing Co , lnc , 130 Lincoln Drive, P O Box B, Tamaqua, Pennsylvania 18252

^Λ from Cytec Surface Specialties S A , Anderlechtstraat 33 - Rue d'Anderlecht, 1620

Drogenbos

+ from Eckart GmbH & Co KG, Guentersthal, 91235 Velden Germany

* from Albion Colours, High Level Way, Halifax, HX1 4PN

Claims

CLAiMS

1. A functional film material comprising a substrate layer and a coating layer, the coating layer comprising a block copolymeric binder and a particulate metal pigment therein, the ratio of pigment to binder in the coating layer being selected with reference to the coat weight to provide the functional film material with an emissivity 0.5 or less and the substrate and coating layer being selected to provide the film with a VWTR (ambient) in excess of 400 gm^"2d^"1bar^"1.

2. A functional film material according to claim 1 wherein the substrate layer has a WVTR (ambient) in excess of 400 gm^"2d^"1bar^'1.

3. A functional film material according to claim 1 or claim 2 wherein the substrate layer has an oxygen permeability (OTR) of less than about 30 cm³m^"2d^'1bar^"1.

4. A functional film material according to any one of claims 1 to 3 wherein the substrate layer is selected from cellulose and derivatives thereof, regenerated cellulose (Cellophane™, cupammonium cellulose), benzoylated cellulose, collagen, polyurethanes and Goretex™.

5. A functional film material according to claim 4 wherein the substrate layer is cellulose acetate.

8. A functional film material according to claim 4 wherein the substrate layer is regenerated cellulose.

7 A functional film material according to any one of claims 1 to 6 wherein the block copolymeric binder is selected from materials comprising a hard and soft segment polymer of the type designated for fabrics allowing breathability. A functional film material according to claim 7 wherein the block copolymers binder is selected from hydrophilic polyurethanes

A functional film material according to any one of claims 1 to 8 wherein the particulate metal material is a polished metal material

A functional film material according to claim 9 wherein the polished metal material is selected from aluminium, bronze, stainless steel, brass, gold, nickel, silver, silver coated glass, tin or copper, or mixtures of two or more thereof

A functional film material according to any one of claims 1 to 10 wherein the particulate metal material has a predominantly lamellar or plate-like form

A functional film material according to claim 11 wherein the median aspect ratio of the particulate metal material is at least about 10 1

A functional film according to any one of claims 1 to 12 wherein the emissivity of the film is less than about 0 45

A functional film according to claim 13 wherein the emissivity of the film is less than about 0 4

A functional film according to any one of claims 1 to 14 wherein the film substrate has a higher VWTR than the coating layer

A functional film according to any one of claims 1 to 15 wherein the pigment to binder (p b) ratio in the coating layer is from about 3 1 to about 1 10

A functional film according to any one of claims 1 to 16 wherein the coat weight is from about 0 8 to about 2 5 gm ²

18. A functional film material according to any one of claims 1 to 17 wherein the film or the substrate layer has a VWTR (ambient) in excess of 500 grrr²cT¹bar^~1.

19. A functional film material according to claim 17 wherein the film or tthhee ssuubstrate layer has a WVTR (ambient) in excess of 1000 grτf²d^" ¹bar¹.

20. A functional film material according to any one of claims 1 to 19 wherein at least one of the substrate and the coating is a semipermeable membrane.

21. A functional film material according to any one of claims 1 to 20 wherein at least one of the substrate and the coating is microporous.