WO2008123199A1 - Soluble polyfunctional vinyl aromatic copolymer, and method for production thereof - Google Patents

Soluble polyfunctional vinyl aromatic copolymer, and method for production thereof Download PDF

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Publication number
WO2008123199A1
WO2008123199A1 PCT/JP2008/055447 JP2008055447W WO2008123199A1 WO 2008123199 A1 WO2008123199 A1 WO 2008123199A1 JP 2008055447 W JP2008055447 W JP 2008055447W WO 2008123199 A1 WO2008123199 A1 WO 2008123199A1
Authority
WO
WIPO (PCT)
Prior art keywords
meth
polyfunctional vinyl
aromatic compound
acrylic acid
acid ester
Prior art date
Application number
PCT/JP2008/055447
Other languages
French (fr)
Japanese (ja)
Inventor
Masanao Kawabe
Hiroko Kitajima
Original Assignee
Nippon Steel Chemical Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Chemical Co., Ltd. filed Critical Nippon Steel Chemical Co., Ltd.
Priority to CN2008800094694A priority Critical patent/CN101641380B/en
Priority to JP2009509096A priority patent/JP5406709B2/en
Publication of WO2008123199A1 publication Critical patent/WO2008123199A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/40—Esters of unsaturated alcohols, e.g. allyl (meth)acrylate

Abstract

Disclosed is a soluble polyfunctional vinyl aromatic copolymer which exhibits excellent thermal decomposition resistance even when the copolymer experiences thermal history at higher temperatures, has excellent curability, processability and a controlled molecular weight distribution, and is soluble in a solvent. The soluble polyfunctional vinyl aromatic copolymer is produced by copolymerizing a divinyl aromatic compound, a monovinyl aromatic compound and a (meth)acrylic acid ester; has a constituent unit derived from the divinyl aromatic compound, a constituent unit derived from the monovinyl aromatic compound, and a constituent unit derived from the (meth)acrylic acid ester; has a Mn value of 500 to 1,000,000 and a Mw/Mn ratio of 50.0 or less; and is soluble in toluene, xylene, tetrahydrofuran, dichloroethane or chloroform. Also disclosed is a soluble polyfunctional vinyl aromatic copolymer which is produced in the same manner as in the above-mentioned soluble polyfunctional vinyl aromatic copolymer, except that a bifunctional (meth)acrylic acid ester having the properties of both of the divinyl aromatic compound and the (meth)acrylic acid ester is used in place of the divinyl aromatic compound and the (meth)acrylic acid ester.
PCT/JP2008/055447 2007-03-26 2008-03-24 Soluble polyfunctional vinyl aromatic copolymer, and method for production thereof WO2008123199A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008800094694A CN101641380B (en) 2007-03-26 2008-03-24 Soluble polyfunctional vinyl aromatic copolymer, and method for production thereof
JP2009509096A JP5406709B2 (en) 2007-03-26 2008-03-24 Soluble polyfunctional vinyl aromatic copolymer and method for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-079413 2007-03-26
JP2007079413 2007-03-26

Publications (1)

Publication Number Publication Date
WO2008123199A1 true WO2008123199A1 (en) 2008-10-16

Family

ID=39830696

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055447 WO2008123199A1 (en) 2007-03-26 2008-03-24 Soluble polyfunctional vinyl aromatic copolymer, and method for production thereof

Country Status (4)

Country Link
JP (1) JP5406709B2 (en)
KR (1) KR101469592B1 (en)
CN (2) CN102718914B (en)
WO (1) WO2008123199A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008239781A (en) * 2007-03-27 2008-10-09 Nippon Steel Chem Co Ltd Method for producing soluble polyfunctional vinyl aromatic copolymer, and the copolymer
WO2009110453A1 (en) * 2008-03-04 2009-09-11 新日鐵化学株式会社 Polyfunctional vinyl aromatic copolymer, process for producing the same, and resin composition
JP2011127008A (en) * 2009-12-18 2011-06-30 Nippon Steel Chem Co Ltd Soluble multi-functional (meth)acrylic acid ester copolymer having alicyclic structure and method for producing the same
WO2011105473A1 (en) * 2010-02-26 2011-09-01 新日鐵化学株式会社 Curable resin composition, cured article thereof, and optical material
JP2011207968A (en) * 2010-03-29 2011-10-20 Nippon Steel Chem Co Ltd Soluble polyfunctional (meth)acrylic acid ester copolymer having alcoholic hydroxyl group and method for producing the same
JP2012184344A (en) * 2011-03-07 2012-09-27 Nippon Steel Chem Co Ltd Soluble polyfunctional (meth)acrylate copolymer having alicyclic structure, curable resin composition, cured material and optical material
JP2012530836A (en) * 2009-06-22 2012-12-06 ユニリーバー・ピーエルシー Branched polymer dispersant
WO2013069077A1 (en) * 2011-11-07 2013-05-16 新日鉄住金化学株式会社 Method for producing styrene-based resin composition comprising highly branched ultra-high-molecular-weight polymer, and composition
EP3858877A4 (en) * 2018-09-28 2022-05-25 NIPPON STEEL Chemical & Material Co., Ltd. Polyfunctional vinyl aromatic copolymer and method for manufacturing same, copolymer rubber obtained therefrom, rubber composition, rubber crosslinked material, and tire member

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI529182B (en) * 2011-03-07 2016-04-11 Nippon Steel & Sumikin Chem Co Acluble polyfunctional (meth) acrylate copolymer having an alicyclic structure, a hardened resin composition and a hardened product
TW201329618A (en) * 2011-09-26 2013-07-16 Nippon Steel & Sumikin Chem Co Photosensitive resin composition, and dry film resist
KR102498471B1 (en) * 2014-12-26 2023-02-10 닛테츠 케미컬 앤드 머티리얼 가부시키가이샤 Terminal-modified soluble polyfunctional vinyl aromatic copolymer, and curable resin composition and optical waveguide produced using same
CN109906238B (en) * 2016-11-01 2021-09-28 日铁化学材料株式会社 Copolymer rubber and method for producing same, and crosslinked rubber composition and method for producing same
CN109385021A (en) * 2017-08-04 2019-02-26 广东生益科技股份有限公司 A kind of compositions of thermosetting resin and prepreg and metal-clad laminate using its production
CN111620982B (en) * 2020-06-04 2023-02-10 南亚新材料科技股份有限公司 Thermosetting resin composition, and adhesive sheet, metal-clad laminate and printed wiring board produced using same
CN114516962A (en) * 2020-11-19 2022-05-20 北京鼎材科技有限公司 High-light-transmittance sensitive resin and color photosensitive resin composition using same
CN114276627A (en) * 2021-11-30 2022-04-05 南亚新材料科技股份有限公司 Thermosetting resin composition containing vinyl copolymer and use thereof
US11945885B1 (en) 2022-12-23 2024-04-02 Industrial Technology Research Institute Vinyl-containing copolymer and resin composition

Citations (5)

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Publication number Priority date Publication date Assignee Title
JPH0892322A (en) * 1994-07-28 1996-04-09 Nippon Steel Chem Co Ltd Cross-linked resin
JPH08176240A (en) * 1994-12-26 1996-07-09 Hitachi Chem Co Ltd Transparent resin, its production and plastic lens
JPH08208746A (en) * 1994-10-28 1996-08-13 Sumitomo Chem Co Ltd Methyl methacrylate polymer
JPH10330425A (en) * 1997-05-30 1998-12-15 Mitsubishi Rayon Co Ltd Processing auxiliary for styrene-based resin and styrene-based resin composition using the same
JP2000128908A (en) * 1998-10-23 2000-05-09 Daicel Chem Ind Ltd Styrene-based polymer and its production

Family Cites Families (8)

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Publication number Priority date Publication date Assignee Title
US2294467A (en) * 1940-07-20 1942-09-01 Fleetwings Inc Landing gear
JPH04252213A (en) * 1990-12-26 1992-09-08 Akira Matsumoto Production of vinyl polymer having (meth)acryloyl group on side chain
JPH09286822A (en) * 1996-04-24 1997-11-04 Mitsui Toatsu Chem Inc Thermosetting resin
JP4507381B2 (en) * 2000-10-11 2010-07-21 日油株式会社 Method for producing decrosslinked resin
JP4338951B2 (en) * 2002-10-01 2009-10-07 新日鐵化学株式会社 Soluble polyfunctional vinyl aromatic copolymer and polymerization method thereof
JP4717358B2 (en) * 2004-01-30 2011-07-06 新日鐵化学株式会社 Method for producing soluble polyfunctional vinyl aromatic polymer
US7595362B2 (en) * 2004-01-30 2009-09-29 Nippon Steel Chemical Co., Ltd. Curable resin composition
JP4745333B2 (en) * 2005-03-08 2011-08-10 新日鐵化学株式会社 Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0892322A (en) * 1994-07-28 1996-04-09 Nippon Steel Chem Co Ltd Cross-linked resin
JPH08208746A (en) * 1994-10-28 1996-08-13 Sumitomo Chem Co Ltd Methyl methacrylate polymer
JPH08176240A (en) * 1994-12-26 1996-07-09 Hitachi Chem Co Ltd Transparent resin, its production and plastic lens
JPH10330425A (en) * 1997-05-30 1998-12-15 Mitsubishi Rayon Co Ltd Processing auxiliary for styrene-based resin and styrene-based resin composition using the same
JP2000128908A (en) * 1998-10-23 2000-05-09 Daicel Chem Ind Ltd Styrene-based polymer and its production

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008239781A (en) * 2007-03-27 2008-10-09 Nippon Steel Chem Co Ltd Method for producing soluble polyfunctional vinyl aromatic copolymer, and the copolymer
WO2009110453A1 (en) * 2008-03-04 2009-09-11 新日鐵化学株式会社 Polyfunctional vinyl aromatic copolymer, process for producing the same, and resin composition
JP5315334B2 (en) * 2008-03-04 2013-10-16 新日鉄住金化学株式会社 Polyfunctional vinyl aromatic copolymer, process for producing the same, and resin composition
US8404797B2 (en) 2008-03-04 2013-03-26 Nippon Steel Chemical Co., Ltd. Polyfunctional vinyl aromatic copolymer, process for producing the same, and resin composition
JP2012530836A (en) * 2009-06-22 2012-12-06 ユニリーバー・ピーエルシー Branched polymer dispersant
JP2011127008A (en) * 2009-12-18 2011-06-30 Nippon Steel Chem Co Ltd Soluble multi-functional (meth)acrylic acid ester copolymer having alicyclic structure and method for producing the same
WO2011105473A1 (en) * 2010-02-26 2011-09-01 新日鐵化学株式会社 Curable resin composition, cured article thereof, and optical material
JP5281710B2 (en) * 2010-02-26 2013-09-04 新日鉄住金化学株式会社 Curable resin composition, cured product and optical material
US8853291B2 (en) 2010-02-26 2014-10-07 Nippon Steel & Sumikin Chemical Co., Ltd. Curable resin composition, cured article thereof, and optical material
JP2011207968A (en) * 2010-03-29 2011-10-20 Nippon Steel Chem Co Ltd Soluble polyfunctional (meth)acrylic acid ester copolymer having alcoholic hydroxyl group and method for producing the same
JP2012184344A (en) * 2011-03-07 2012-09-27 Nippon Steel Chem Co Ltd Soluble polyfunctional (meth)acrylate copolymer having alicyclic structure, curable resin composition, cured material and optical material
WO2013069077A1 (en) * 2011-11-07 2013-05-16 新日鉄住金化学株式会社 Method for producing styrene-based resin composition comprising highly branched ultra-high-molecular-weight polymer, and composition
EP3858877A4 (en) * 2018-09-28 2022-05-25 NIPPON STEEL Chemical & Material Co., Ltd. Polyfunctional vinyl aromatic copolymer and method for manufacturing same, copolymer rubber obtained therefrom, rubber composition, rubber crosslinked material, and tire member

Also Published As

Publication number Publication date
CN101641380B (en) 2013-09-25
JPWO2008123199A1 (en) 2010-07-15
CN102718914A (en) 2012-10-10
KR101469592B1 (en) 2014-12-05
JP5406709B2 (en) 2014-02-05
KR20100015575A (en) 2010-02-12
CN101641380A (en) 2010-02-03
CN102718914B (en) 2015-04-22

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