WO2008111659A1 - 燃料電池システム - Google Patents
燃料電池システム Download PDFInfo
- Publication number
- WO2008111659A1 WO2008111659A1 PCT/JP2008/054686 JP2008054686W WO2008111659A1 WO 2008111659 A1 WO2008111659 A1 WO 2008111659A1 JP 2008054686 W JP2008054686 W JP 2008054686W WO 2008111659 A1 WO2008111659 A1 WO 2008111659A1
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- WIPO (PCT)
- Prior art keywords
- fuel cell
- valve
- pressure
- pressure chamber
- gas
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
- H01M8/04126—Humidifying
- H01M8/04141—Humidifying by water containing exhaust gases
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
- H01M8/04225—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
- H01M8/04302—Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
- H01M8/04395—Pressure; Ambient pressure; Flow of cathode reactants at the inlet or inside the fuel cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
- H01M8/04753—Pressure; Flow of fuel cell reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
- H01M8/04761—Pressure; Flow of fuel cell exhausts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Definitions
- the present invention relates to a fuel cell system including a fuel cell that generates electric power by an electrochemical reaction between a fuel gas and an oxidizing gas.
- the fuel cell system includes a fuel cell that generates electricity by an electrochemical reaction of a reaction gas between a fuel gas and an oxidizing gas, a reaction gas supply channel for supplying the reaction gas to the fuel cell, and a reaction gas discharged from the fuel cell. And a reaction gas system discharge flow path. It is also considered to provide a fuel cell shut-off valve in the reaction gas supply channel and the reaction gas system discharge channel.
- a fuel cell system described in Patent Document 1 includes a shut-off valve provided in a reaction gas system discharge passage for discharging a reaction gas system gas from a battery stack, and a fuel gas supply flow for supplying fuel gas to the battery stack. Air is supplied through an accumulator to the three-way switching valve provided in the road and the valve provided in the oxidizing gas system supply flow path that supplies air to the battery stack, and the pilot valves are switched. .
- a valve that is closed by a pressure difference between the flow paths before and after the fuel gas stack is provided in the flow path for supplying the fuel gas to the fuel cell stack.
- the pressure difference between the first pressure between the valve and the fuel cell stack and the second pressure between the valve and the fuel cell stack at a second time is less than a predetermined value; Judged as an open failure.
- the valve is open, the fuel in the fuel cell stack is consumed and a differential pressure is generated between the flow paths before and after the valve.
- Patent Document 1 Japanese Patent Laid-Open No. 2 00 3-7 17
- Patent Document 2 Japanese Patent Laid-Open No. 2 0 0 5-3 4 7 1 8 5 Disclosure of Invention
- the shut-off valve provided in the reaction gas system discharge flow path, the three-way switching valve provided in the fuel gas supply flow path, and the oxidation gas system supply flow path are provided.
- the valve When the valve is used in a low-temperature environment such as below freezing, the periphery of the valve body freezes, or the valve body is caught by a fixed part when the shaft of the valve body is inclined with respect to the sliding part. If the pressure value that is normally driven is applied to the pressure chamber of the valve, the valve may not be driven. If the valve does not drive and does not open normally in this way, it will be difficult to supply gas to the battery stack or to exhaust gas from the pond stack. In some cases, the operation of the fuel cell system may stop automatically.
- An object of the present invention is to make it possible to more effectively use the power generated by a fuel cell in a fuel cell system, and to release this sticking even when the valve is stuck, thereby enabling stable operation.
- a fuel cell system includes a fuel cell that generates electricity by an electrochemical reaction between an oxidizing gas and a fuel gas, a valve that is driven in accordance with a change in pressure of a fluid supplied from a fluid supply unit, and a fluid supply By applying the first pressure value to the pressure chamber communicating with the section, the pressure applying means for driving the valve and the valve is driven even when the pressure chamber has the first pressure value.
- a fuel cell system comprising: a pressure changing means that changes the first pressure value in the pressure chamber in the case of an abnormality that does not move.
- Driving the valve includes a case where the valve is driven so as to change from opening to closing or from closing to opening.
- the oxidizing gas supply flow path for supplying the oxidizing gas to the fuel cell the oxidizing gas based gas discharge path for discharging the oxidizing gas based gas from the fuel cell, the oxidizing gas supply flow path, and the oxidizing gas based gas discharge are provided.
- the pressure changing means is
- the fluid supply unit control means increases the supply pressure of the fluid supplied to the pressure chamber by the fluid supply unit above the first pressure value.
- an oxidizing gas supply channel for supplying an oxidizing gas to the fuel cell
- an oxidizing gas-based gas discharge channel for discharging the oxidizing gas-based gas from the fuel cell
- an oxidation A fuel cell bypass passage connecting the gas supply passage and the oxidizing gas-based gas discharge passage by bypassing the fuel cell, and a fuel cell bypass valve provided in the fuel cell bypass passage
- the pressure changing means opens the fuel cell bypass valve at a predetermined opening at start-up, and throttles the opening of the fuel cell bypass valve when the valve does not drive even when the pressure chamber has the first pressure value.
- a fluid supply unit fuel cell bypass valve control means for increasing the fluid discharge flow rate by the fluid supply unit.
- the pressure changing means is
- the pressure changing means is fluid supply part control means for alternately changing the supply pressure of the fluid supplied to the pressure chamber by the fluid supply part.
- the pressure changing means has a configuration in which the pressure in the pressure chamber fluctuates up and down at an abnormal time when the valve does not drive even when the pressure chamber has the first pressure value.
- an oxidizing gas supply flow path for supplying an oxidizing gas to the fuel cell
- an oxidizing gas based gas discharge path for discharging an oxidizing gas based gas from the fuel cell
- an oxidizing gas supply flow path for oxidizing gas supply flow path
- an oxidizing gas based gas discharge flow A fuel cell bypass flow path that bypasses the fuel cell, and a fuel cell bypass valve provided in the fuel cell bypass flow path.
- a fuel cell bypass valve control means that changes the size of the fuel cell alternately.
- the fuel cell system of the present invention by causing the first pressure value to act on the valve that is driven according to the pressure change of the fluid supplied from the fluid supply unit and the pressure chamber that communicates with the fluid supply unit, A pressure applying means for driving the valve, and a pressure changing means for changing the first pressure value in the pressure chamber when there is an abnormality in which the valve does not drive even when the pressure chamber has the first pressure value.
- the pressure changing means is configured such that when the valve does not drive even when the pressure chamber has the first pressure value, the pressure in the pressure chamber fluctuates up and down. Even if the valve does not drive when the valve is locked by the valve body being stuck to a fixed part due to inclination or the like, and the pressure value of the normal drive is applied to the pressure chamber of the valve, Force can be applied alternately to one side in the axial direction and the other side in the axial direction, and the valve can be released and the valve can be driven.
- FIG. 1 is a diagram showing a basic configuration of a fuel cell system according to a first embodiment of the present invention.
- FIG. 2 is a sectional view showing the structure of the inlet shirt valve (or outlet shut valve) used in the fuel cell system of FIG. 1 in the opened state.
- FIG. 3 is a cross-sectional view showing the valve closed state.
- FIG. 4 is a schematic cross-sectional view for explaining the switching of PSV in time series when the inlet short valve is shifted from the open state to the closed state.
- FIG. 5 is a schematic cross-sectional view for explaining the switching of PSV in time series when the inlet short valve is shifted from the closed state to the open state.
- FIG. 6 is a flowchart showing a start-up control method in the fuel cell system according to the first embodiment of the present invention.
- FIG. 7 is a flowchart showing a start-up control method in the fuel cell system according to the second embodiment of the present invention.
- FIG. 8a is a schematic diagram showing a state in which the valve body is fixed to be inclined with respect to the axial direction of the sliding portion, which is a problem to be solved by the fuel cell system according to the fourth embodiment of the present invention. .
- Fig. 8b is a schematic diagram showing a state in which force is alternately applied to the valve body in both directions in order to release the sticking of the valve body to the sliding portion.
- FIG. 8c is a schematic diagram showing a state in which force is alternately applied to the valve body in both directions in order to release the sticking of the valve body to the sliding portion.
- FIG. 9 is a flowchart showing a start-up control method in the fuel cell system according to the fourth embodiment of the present invention.
- FIG. 10 is a diagram (a) showing the time change of the discharge flow rate of the air compressor in step S4 of FIG. 9 and the time change of the valve driving force acting on the valve body of the humidifier bypass valve. (B). Explanation of symbols
- 1 0 Fuel cell system 1 2 Fuel cell stack, 1 4 Oxidation gas supply flow path, 1 6 Oxidation gas discharge flow path, 1 8 Humidifier bypass valve, 2 0 Inlet shut valve, 2 2 Outlet shut valve, 2 4 Air compressor, 2 6 in evening cooler, 2 8 humidifier, 3 0 path, 3 2 humidifier bypass path, 3 4 'pressure regulating valve, 3 6 Fuel cell bypass path, 3 8 Fuel cell bypass valve, 4 0 Pressure control flow path, 4 2 Housing, 4 4 Partition, 4 6 Main diaphragm, 4 8 Sub-diaphragm, 5 0 Valve closing pressure chamber, 5 2 Valve opening pressure chamber, 5 atmospheric pressure chamber, 5 6 flow path configuration pressure chamber, 5 8 valve body, 60 drive shaft, 6 2 valve body, 6 3 drive shaft side cylindrical surface, 6 4 cylindrical member , 6 6 Diaphragm side cylindrical part, 6 7 Annular deformed part, 6 8 Housing side cylindrical surface part, 70 Second diaphragm side cylindrical part, 7 2 Atmospheric communication pipe, 7 4 Suppression
- FIG. 1 is a schematic configuration diagram of a fuel cell system according to the present embodiment.
- the fuel cell system 10 includes a fuel cell stack 12, an oxidant gas supply channel 14, an oxidizing gas system discharge channel 16, a humidifier bypass valve 18, an inlet shut valve 20, and an outlet shut Valve 2 and 2.
- the fuel cell stack 1 2 generates electricity by an electrochemical reaction between oxygen and hydrogen. That is, by supplying hydrogen gas, which is a fuel gas, and air, which is an oxidizing gas, to the fuel cell stack 12, in a plurality of fuel cell cells (not shown) in the fuel cell stack 12, oxygen and hydrogen And an electrochemical reaction produces electric energy.
- the fuel battery cell includes a membrane-one electrode assembly in which an electrolyte membrane is sandwiched between an anode electrode and a force sword electrode, and separators on both sides thereof.
- the fuel cell system 10 of the present embodiment is mounted on a vehicle, for example, for a fuel cell vehicle, and the fuel cell stack 12 is used as a power source for vehicle running.
- the fuel cell system of the present embodiment can also be used for purposes other than vehicle driving.
- an oxidizing gas supply channel 14 In order to supply air, which is an oxidizing gas, to the fuel cell stack 12, an oxidizing gas supply channel 14 is provided. An air compressor 24 and an intake cooler 26 are provided upstream of the oxidizing gas supply flow path 14. Pressurized by air compressor 2 4 The air thus cooled is cooled by the internal cooler 26, humidified by the humidifier 28, and then supplied to the flow path on the power sword electrode side of the fuel cell stack 12.
- a humidifier bypass path 32 which is the second gas flow path and is a bypass of the main path 30, is provided.
- the air passing through the humidifier bypass path 3 2 is supplied to the fuel cell stack 1 2 without passing through the humidifier 2 8.
- a humidifier bypass valve 18 is provided in the middle of the humidifier bypass path 3 2.
- an oxidizing gas system discharge flow path 1 6 is provided in order to discharge air off-gas, which is air supplied to the fuel cell stack 1 2 and subjected to an electrochemical reaction in each fuel cell, from the fuel cell stack 1 2, an oxidizing gas system discharge flow path 1 6 is provided.
- the air off-gas discharged through the oxidizing gas system discharge flow path 16 is sent to the humidifier 28 via the pressure regulating valve 34, and then released to the atmosphere via a diluter (not shown).
- the pressure regulating valve 34 is controlled so that the pressure (back pressure) of the air discharged from the fuel cell stack 12 becomes an appropriate pressure value according to the operating state of the fuel cell stack 12.
- the pressure of the air corresponding to the position of the pressure sensor P 2 in the oxidizing gas system discharge flow path 16 is adjusted by the valve opening degree of the pressure regulating valve 34.
- the humidifier 28 serves to humidify the moisture obtained from the air discharged from the fuel cell stack 12 2 to the air before being supplied to the fuel cell stack 12.
- the fuel cell stack 1 2 is connected to a hydrogen gas supply channel for supplying hydrogen gas and a hydrogen gas system discharge channel for discharging hydrogen gas.
- the illustration is omitted.
- the humidifier is connected between the upstream side connection part of the humidifier bypass path 3 2 and the humidifier 28 and in the oxidizing gas discharge path 16.
- a fuel cell bypass path 3 6 is connected between the gas downstream side of 2 8 so that the gas flow is parallel to the fuel cell stack 1 2.
- a fuel cell bypass valve 38 is provided in the middle of the fuel cell bypass path 36. The fuel cell bypass valve 3 8 is used to control the pressure of the air supplied to the fuel cell stack 1 2. That is, depending on the valve opening of the fuel cell bypass valve 38, The pressure of the air corresponding to the position of the inlet pressure sensor P 1 of the gas supply channel 14 is adjusted.
- the air pressure corresponding to the position of the inlet pressure sensor P 1 can be adjusted by the flow rate of the air discharged from the air compressor 24.
- the fuel cell system 10 quickly raises the temperature of the fuel cell stack 12 at a low temperature start such as below freezing. For this reason, compared with the amount of hydrogen gas supplied to the fuel cell stack 1 2, the amount of air supplied to the fuel cell stack 1 2 is an amount commensurate with generating electricity by reaction with the hydrogen gas.
- the temperature of the fuel cell stack 12 can be increased rapidly by reducing the power sword stoichiometric ratio and generating power with low efficiency.
- hydrogen enters the cathode channel from the anode channel of the fuel cell stack 12 via the electrolyte membrane, and the hydrogen concentration in the oxidizing gas discharge channel 16 is high.
- the fuel cell bypass valve 38 is used to reduce the hydrogen concentration in the oxidant gas discharge passage 16 by air that does not pass through the fuel cell stack 12 in such a case. You can also.
- each of them is a fuel cell valve and a fluid control valve that regulates the flow of air in the flow path, and includes an inlet shut valve 20 and an outlet shut valve 22, and the humidifier bypass valve 18 described above.
- Three pressure switching valves (PSVs), each of which is a normally closed solenoid valve, are connected via a pressure control flow path 40.
- the humidifier bypass valve 18 is connected to three PSVs Vb S, VbC, and VbO.
- three PSVs V i S, V i C, and V i O are connected to the inlet shut valve 20, and three PSVs, Vo S, VoC, and Vo 0, are connected to the outlet shut valve 22. It is connected.
- These PSVs are connected to the upstream side of the main passage 30 of the oxidizing gas supply passage 14 via the pressure control passage 40, for example, the air conditioner. Connected between the presser 24 and the humidifier 28.
- All these PSVs, Vb S, VbC, VbO, V i S, V i C, V i O, Vo S, V o C, VdO are controlled by a control unit such as ECU (Electronic Control Unit) not shown. Controlled.
- the humidifier bypass valve 18, the inlet shut-off valve 20, and the outlet shut-off valve 22 are all driven by a gas pressure difference that is a fluid existing in the internal pressure chamber.
- the pressure control flow path 40 supplies gas, which is a fluid for generating a pressure difference, to the valves 18, 20, and 22.
- the configuration and operation of the inlet shut valve 20 and the outlet shut valve 22 will be described mainly by using the inlet shut valve 20 as a representative.
- the configuration itself of the inlet shut valve 20 and the outlet shut valve 22 is the same.
- the configuration of the humidifier bypass valve 18 will be described later.
- the inlet shut-off valve 20 is a normally open type shut-off valve in which the valve body is opened in a normal state where all the pressure chambers provided therein are at the same pressure.
- the inlet shut-off valve 20 is provided with two upper and lower spaces partitioned by a partition 44 in a housing 42 formed by connecting a plurality of housing elements.
- a main diaphragm 46 and a sub-diaphragm 48 are respectively provided in the two spaces.
- a flow path configuration pressure chamber 56 is provided on the lower surface side.
- valve closing pressure chamber 50, the valve opening pressure chamber 52, the atmospheric pressure chamber 54, and the flow path constituting pressure chamber 56 are separated from each other, and any one of these pressure chambers 50, 52, 54, 56
- the pressure chambers of the main diaphragm 46 and the sub-diaphragm 48 are connected to the valve body 58. That is, a valve body 58 having a drive shaft 60 is provided inside the housing 42, and the valve body 58 is supported by the housing 42 so as to be displaceable in the axial direction of the drive shaft 60.
- the valve body 58 includes a drive shaft 60 and a disc-shaped valve body main body 62 coupled to the lower end portion of the drive shaft 60.
- a cylindrical member 64 having a bottomed cylindrical shape having a drive shaft side cylindrical surface portion 63 on the outer peripheral surface is coupled to the lower end of the intermediate portion of the drive shaft 60. Further, between the bottom surface of the bottom plate portion of the tubular member 64 and the top surface of the valve body 62, the inner peripheral side end of the secondary diaphragm 4 8 made of elastic material such as rubber is sandwiched, and the secondary diaphragm 4 The inner periphery of 8 is coupled to the drive shaft 60.
- the outer peripheral end of the sub-diaphragm 48 is coupled to the inner peripheral portion of the housing 4 2 so as to be sandwiched by two housing elements constituting the housing 42. As a result, the upper side and the lower side of the space below the partition portion 4 4 in the housing 42 are separated into the atmospheric pressure chamber 54 and the flow path constituting pressure chamber 56 by the sub diaphragm 48.
- a diaphragm side cylindrical portion 66 that is elastically deformed so as to be pressed along the drive shaft side cylindrical surface portion 63 is provided near the inner diameter of the sub diaphragm 48 in the radial direction. Then, from the closed state as shown in FIG. 3, the sub-diaphragm 48 is located between the drive shaft side cylindrical surface portion 63 of the cylindrical member 64 and the inner surface of the housing 42, and has an upward chevron shape. The lower surface of the annular deformed portion 67 deformed into an annular shape receives the pressure of the flow path constituting pressure chamber 56.
- the lower surface of the annular deformed portion 67 receives the pressure of the flow path constituting pressure chamber 56, so that the upper part of the diaphragm side cylindrical portion 66 is peeled off from the drive shaft side cylindrical surface portion 63 as shown in FIG.
- the drive shaft 60 is displaced upward while being elastically deformed.
- the second diaphragm side cylindrical portion 70 which is elastically deformed so as to be pressed along the housing side cylindrical surface portion 68 provided on the inner surface of the housing 42 near the outer diameter of the intermediate portion of the sub diaphragm 48. Provided.
- the drive shaft 60 is displaced downward as shown in FIG. 3 from the open state as shown in FIG. 2, the upper part of the second diaphragm side cylindrical portion 70 is pulled from the housing side cylindrical surface portion 68. It is designed to be elastically deformed so as to peel off.
- the flow path constituting pressure chamber 5 6 constitutes a part of the oxidizing gas supply flow path 14 (see Fig. 1) (in the case of the outlet shut valve 2 2, the oxidizing gas system discharge flow path 1 6). As a result, the gas upstream side and the gas downstream side are blocked or connected.
- the atmospheric pressure chamber 54 is connected to an atmospheric communication pipe 72 having one end communicating with the atmosphere, and the atmospheric pressure chamber 54 is open to the atmosphere.
- a restraining member 7 4 formed by joining two substantially disc-shaped elements is joined to the upper end portion of the valve body 58, and an elastic material such as rubber is interposed between the two substantially disc-shaped elements.
- Main diaphragm made of The inner peripheral side end of the mud 46 is clamped.
- the outer peripheral side end portion of the main diaphragm 46 is coupled to the inner peripheral portion of the housing 42 so as to be sandwiched by two housing elements constituting the housing 42.
- a supply / exhaust pipe 76 is connected to the valve closing pressure chamber 50 and the valve opening pressure chamber 52.
- a coil spring 78 is provided between the lower surface of the restraining member 74 and the upper surface of the partition portion 44, and the valve body 58 is in the upward direction, that is, the valve opening state. Is given elasticity.
- the valve body 58 is displaced downward, the lower surface of the valve body main body 62 is seated on the valve seat 80 to block the flow path. In other words, the inside of the flow path is blocked or connected by the axial displacement of the drive shaft 60.
- the diameter of the pressure receiving area of the upper portion of the drive shaft 60 including the main diaphragm 46 is sufficiently larger than the diameter of the pressure receiving area of the lower portion of the drive shaft 60 including the sub diaphragm 48. .
- valve closing pressure chamber 50 is connected to the pressure control flow path 40 on the V i C side, which is PSV, via the supply / discharge pipe 7 6 (FIGS. 2 and 3). Connected to. Also, open the pressure chamber 5 2 for valve opening via the supply / discharge pipe 7 6? 3 Connected to the pressure control channel 40 on the 10 side. Due to the axial displacement of the drive shaft 60, the central portion of the main diaphragm 46 is displaced so as to warp up and down.
- the inlet 82 and the outlet 84 are reversed with respect to the inlet shut valve 20.
- the valve body 58 is driven upward by the displacement of the drive shaft 60 (FIGS. 2 and 3)
- the inlet 8 2 of the outlet shut valve 2 2 from the upstream side of the oxidizing gas discharge passage 16 Air off-gas flowing toward the outlet is discharged from the outlet 8 4 of the outlet shut valve 22 to the humidifier 28 side.
- drive shaft 6 0 When the valve body 58 is driven downward due to the displacement of the valve, the inlet 82 is blocked, and the flow of the off gas from the upstream side of the oxidant gas discharge channel 16 to the humidifier 28 is blocked.
- Directional displacement is controlled by three P SVs. That is, in the case of the inlet shut-off valve 20, the pressures in the valve opening pressure chamber 52 and the valve closing pressure chamber 50 are controlled by three PSVs of V i S, V i C, and V i Q. In the case of the outlet shirt ⁇ valve 22, the pressures in the valve opening pressure chamber 52 and the valve closing pressure chamber 50 are controlled by three PSVs of Vo S, VoC, and VoO.
- V i S (or Vo S) shown in Fig. 1 is 3-way, that is, a three-way PSV, and one of the pressure chambers 50 and 52 is selectively used.
- the gas compressor 24 is connected to the gas upstream side of the air compressor 24, and the other pressure chamber is shut off from the gas upstream side of the air conditioner presser 24.
- V i C, V i o, VoC, and V o o are all 2-way PSVs, and function as exhaust valves, that is, pressure relief valves.
- V i S changes the connection state of the flow path depending on the energized state;
- V i S is the air compressor 24 in the non-energized state (non-energized state).
- the gas discharge side of the valve and the valve opening pressure chamber 52 are connected.
- V i S (or Vo S) connects the gas discharge side of the air compressor and the valve closing pressure chamber 50 in an energized state (energized state).
- V i C, V i O, VoC and Vo 0 all close the valve in the non-energized state and open the valve in the energized state, that is, normally closed to shut off the flow path when not in operation.
- Type solenoid valve is
- V i S (Vo S), V i C (VoC), V i O
- the triangles filled with black indicate that the flow path is blocked, and the open triangles indicate that the flow path is connected.
- the inlet short valve 20 and the outlet short valve 22 are closed when the fuel cell stack 12 stops generating power.
- the inlet shut valve 20 (or the outlet shut valve 22) is changed from the open state (the state shown in Fig. 2) to the closed state (see Fig. 3). To move to the state shown) This is explained on behalf of the entrance shirt ⁇ ben 20.
- Fig. 4 (a) when the inlet shut-off valve 20 is open, all of V i S, V i C, and VoO are not energized. In this state, air whose pressure has increased from the air compressor 24 (FIG. 1) is introduced into the valve-opening pressure chamber 52 via the pressure control flow path 40.
- the shaded area indicates that air with increased pressure is introduced (the same applies to Fig. 5).
- V i S is energized, and the increased pressure from the air compressor 24 (Fig. 1) controls the pressure in the valve closing pressure chamber 50. It is introduced through the use flow path 40.
- V i O energized, that is, opened, the pressure chamber 52 for valve opening is opened to the atmosphere.
- a first force F 1 directed downward is applied to the drive shaft 60 due to a pressure difference generated between the pressure in the valve closing pressure chamber 50 and the pressure in the valve opening pressure chamber 52 (atmospheric pressure).
- V i S is deenergized, that is, the discharge side of the air compressor 24 communicates with the valve opening pressure chamber 52.
- V i O is open, the pressure in the valve opening pressure chamber 52 does not increase.
- the pressure in the valve closing pressure chamber 50 and the pressure in the pressure control flow path 40 leading to the valve closing pressure chamber 50 are maintained at a high pressure.
- V iO is brought into a non-energized state, that is, a valve closed state.
- the pressure in the valve-opening pressure chamber 52 is reduced, the pressure in the valve-closing pressure chamber 50 is reduced in the valve-opening pressure chamber 52.
- the state larger than the pressure remains maintained.
- the normally open outlet shut valve 22 (Fig. 1) also changes from the open state to the closed state when the fuel cell stack 12 stops generating power by controlling Vo S, VoC, and VoO. And keep the valve closed when all P SVs of Vo S, VoC, and VoO are de-energized.
- the humidifier bypass valve 18 shown in FIG. 1 is a normally closed shut valve in which the valve body 58 is closed in a normal state in which all the pressure chambers provided therein are all at the same pressure. Yes.
- the detailed structure of the humidifier bypass valve 18 is not shown, it has the same structure as the inlet shut-off valve 20 or the outlet shut-off valve 22 shown in FIGS. 2 and 3, and a coil spring 78 (see FIGS. 2 and 3). Is provided between the upper surface of the bottom plate portion of the cylindrical member 64 and the lower surface of the partition portion 44.
- a coil spring is provided between the upper surface of a member fixed to the upper end of the valve body 58, such as a restraining member 74 (see FIGS. 2 and 3), and the lower surface of the housing 42. It is also possible to provide a normally closed shut valve (see the schematic diagram in Fig. 1).
- such a humidifier bypass valve 18 has a valve closing pressure chamber 50 in the pressure control flow path 40 on the side and a valve opening pressure valve 40 in the pressure control flow path 40 on the VbO side of the PSV. Pressure chambers 52 are connected to each other.
- the axial displacement of the drive shaft 60 is controlled by three PSVs, Vb S, VbC, and Vb 0, as in the case of the inlet shut valve 20 and the outlet shut valve 22.
- Vb S three PSVs
- VbC three PSVs
- VbO three PSVs
- the triangles filled with black indicate the state where the flow path is blocked.
- the shape represents a state in which the flow paths are connected.
- Vb S changes the connection state of the flow path depending on the energized state.
- Vb S is connected to the gas discharge side of the air compressor 24 and the valve closing pressure chamber 50 in a non-energized state (non-energized state), and in the energized state (energized state), the air compressor 24
- the gas discharge side and the valve opening pressure chamber 52 are connected.
- VbC and VbO are both normally closed solenoid valves that close the valve when not energized and open the valve when energized, that is, shut off the flow path when not operating.
- Such a humidifier bypass valve 18 is closed when power generation of the fuel cell stack 12 is stopped.
- the humidifier bypass valve 18 is closed, as shown in Fig. 1, the spring of the valve spring 58 is pressed against the valve seat by the elasticity of the coil spring, and the slip of V b S, VbC, VbO Turn the power off.
- the humidifier bypass valve 18 can also be closed by introducing the air whose pressure has been increased by the air compressor 24 into the valve closing pressure chamber 50 and opening the valve opening pressure chamber 52 to the atmosphere. State and can.
- the drive shaft 60 is driven downward by the force acting downward on the drive shaft 60 due to the pressure difference between the valve opening pressure chamber 52 and the valve closing pressure chamber 50 and the elasticity of the coil spring.
- a force acts on the drive shaft 60 due to the pressure difference between the flow path constituting pressure chamber 56 and the atmospheric pressure chamber 54, but the upper side of the drive shaft 60 including the main diaphragm 46 (see FIGS. 2 and 3).
- the diameter of the pressure receiving area of the part is sufficiently larger than the diameter of the pressure receiving area of the lower part of the drive shaft 60 including the sub-diaphragm 48 (see FIGS. 2 and 3), and the elasticity of the coil spring Together, the drive shaft 60 is displaced downward. Then, the humidifier bypass valve 18 is closed.
- the PSV for controlling the pressure of the humidifier bypass valve 18, the inlet shut valve 20, and the outlet shut valve 22 is Vb S, VbC, VbO, V i S, V i C, V i O , Vo S, VoC, VoO are controlled by a control unit (not shown) such as an ECU. That is, when the power generation of the fuel cell stack 12 is stopped, the control unit shuts off all of the inlet shut valve 20, the humidifier bypass valve 18 and the outlet shut valve 22, that is, closes the fuel cell stack. 1 Closely close the gas upstream side and gas downstream side of the flow path on the force sword electrode side.
- the control unit also includes an inlet shut-off valve 20, a humidifier bypass valve 18 and an outlet shut-off valve.
- a first pressure value that is, a pressure corresponding to the first discharge pressure of the air conditioner presser 24 is applied to the valve-opening pressure chamber 52 that communicates with the air compressor 24.
- the valve-closing pressure chamber 50 is opened.
- Pressure applying means for driving the motor by opening the valve-closing pressure chamber 50 to the atmosphere through PSV corresponding to any valve of VbC, V i C, and Vo C, which are PSV.
- FIG. 5 (a) corresponds to Figure 4 (d) above.
- the air compressor 24 (see Fig. 1) is started in Fig. 5 (a) with V i S kept in the de-energized state, and then as shown in Fig. 5 (b).
- V i C is energized, that is, in a valve open state, and the valve closing pressure chamber 50 is opened to the atmosphere.
- the air whose pressure has increased in the valve closing pressure chamber 50 is released to the atmosphere, and the pressure decreases. Further, the air whose pressure has increased from the air compressor 24 is introduced into the valve-opening pressure chamber 52 through the pressure control flow path 40. As a result, a pressure difference is generated between the pressure in the valve opening pressure chamber 52 and the pressure in the valve closing pressure chamber 50 (atmospheric pressure).
- the drive shaft 60 has the third force F 3 acting upward on the drive shaft 60 due to the pressure difference between the flow path constituting pressure chamber 56 and the atmospheric pressure chamber 54, and the valve closing pressure chamber 50 and the valve opening.
- the fourth force F4 acting on the drive shaft 60 due to the pressure difference between the pressure chamber 52 and the force F3, F4 and the elasticity of the coil spring 78 (Figs. 2 and 3) Drive upwards.
- V C is not energized, that is, the valve is closed, so that the valve closing pressure chamber 50 and the atmosphere are shut off. Then, when all PSVs of VIS, V i C, V iO are not energized, the inlet shut-off valve 20 is opened. Maintain valve status.
- the outlet shut valve 2 2 (Fig. 1), by controlling V o C, the fuel cell stack 12 2 is changed from the closed state to the opened state at the start of power generation operation. Keep the valve open with all PSVs in V o S, V o C, and V oO non-conductive.
- the inlet shut valve 20 As described above with reference to the inlet short valve 20 in FIG. 4, when the power generation of the fuel cell stack 12 is stopped, the inlet shut valve 20, the humidifier bypass valve 18, and the outlet shut valve 2 2 Are closed, that is, the valve is closed.
- the outlet shut valve 20 and the inlet shut valve 20 and One of the humidifier bypass valves 1 8 is opened.
- the humidifier bypass valve 1 8 of the inlet short valve 20 and the humidifier bypass valve 1 8 is opened first, and the humidifier bypass path 3 2 and the main path 30 are Air is supplied to the fuel cell stack 1 2 only through the humidifier bypass path 3 2.
- one of the inlet shut-off valve 20 and the humidifier bypass valve 18 is fixed by freezing or the like when it is closed by leaving it in a sub-freezing environment, that is, the valve body 58 is fixed. If the part is stuck due to freezing, etc., it is possible that one valve will not open if the normal opening pressure is applied to the valve opening pressure chamber 52 of one valve. For this reason, in the case of the present embodiment, the control unit such as the ECU has the inside of the valve opening pressure chamber 52 of one of the inlet shutter valve 20 and the humidifier bypass valve 18. Even if the first pressure value corresponding to the first discharge pressure of the air compressor 24 is 1, the first pressure value in the valve-opening pressure chamber 52 is changed when one of the valves does not drive. And a fuel cell bypass valve control means which is a pressure changing means.
- the fuel cell bypass valve control means opens the fuel cell bypass valve 3 8 (FIG. 1) at a predetermined opening (for example, 50%, etc.) at the time of start-up, and opens the pressure chamber for opening one of the above valves 5 2 Even when the inside is the first pressure value, the opening degree of the fuel cell bypass valve 38 is reduced when the above-mentioned one valve does not drive (for example, 20% opening degree, 0% opening degree, that is, Thus, it has a function of increasing the pressure value of the air supplied to the valve-opening pressure chamber 52 of the one of the valves above the first pressure value.
- a predetermined opening for example, 50%, etc.
- step S 1 when supplying air to the fuel cell stack 12 at the start of power generation, first, in step S 1, when a start command is sent to the fuel cell system 10 by turning on the ignition key or the like, control is performed. Based on the opening command of the humidifier bypass valve 18, the pressure applying means of the section controls the opening and closing of V b S, V b C and V bO so as to open the humidifier bypass valve 18. Issue command signal.
- step S2 in FIG. 6 the pressure applying means opens the fuel cell bypass valve 38 to a certain opening, such as half-opening (for example, 50% opening), and operates the air conditioner 24. Send out the air with increased pressure.
- step S 3 the fuel cell bypass valve control means of the control unit monitors the pressure detection value of the inlet pressure sensor P 1 located at the outlet of the air compressor 24 (FIG. 1), while the inlet pressure sensor P 1 It is determined whether or not the detected pressure value has decreased to the pressure threshold value P s (kP a) or less after the stable time has elapsed.
- the stabilization time is, for example, a time for waiting for a predetermined time of t 1 sec after the air discharge flow rate (feed amount) by the air compressor 24 reaches, for example, 80% of the set value and reaches that point.
- the air discharge flow rate by the air compressor 24 is monitored by an air flow meter (not shown).
- step S 3 the detected pressure value of the inlet pressure sensor P 1 is not less than or equal to the pressure threshold value P s (kP a) after the stable time has elapsed by the fuel cell bypass valve control means. If it is determined that the valve 18 is not normally opened (the valve open determination is NG), then in step S4, the opening degree of the fuel cell bypass valve 38 is set (for example, 50% From the opening) Throttle, humidifier bypass valve 18 Increase the pressure of the air supplied to the valve opening pressure chamber 52.
- step S6 the fuel cell bypass valve control means determines whether or not the detected pressure value of the inlet pressure sensor P1 has decreased to the pressure threshold value P s (k Pa) or less again after a predetermined time has passed. Determine. Even in the determination in step S 6, the detected pressure value of the inlet pressure sensor P 1 is not less than the pressure threshold value P s (k Pa), that is, the humidifier bypass valve 18 is not normally opened. If it is determined that the valve open determination is NG, it is determined that the humidifier bypass valve 18 cannot be opened in the opening control of the fuel cell bypass valve 38, and then in step S7, the valve Move to abnormal sequence control.
- step S3 the pressure detection value of the inlet pressure sensor P1 becomes equal to or lower than the pressure threshold value Ps (kPa) after the stabilization time has elapsed, i.e., the humidifier bypass valve 18 is operating normally. If it is determined that the valve is open (the valve open determination is OK), the startup sequence process is continued in step S5. As a result, the air discharged from the air compressor 24 is supplied to the fuel cell stack 12 through the humidifier bypass path 32 and power generation is started.
- step S 6 the pressure detection value of the inlet pressure sensor P 1 becomes equal to or lower than the pressure threshold value P s (k Pa) after the stabilization time has elapsed, that is, the humidifier bypass valve 18 opens normally. Even if it is determined that the valve is open (the valve open determination is OK), the startup sequence process is continued in step S5, and the air discharged from the air compressor 2 4 is fueled through the humidifier bypass path 3 2. Supply to battery stack 1 2 so that power generation starts. After the sequence of any one of steps S5 and S7 is completed, that is, after the start-up process is completed, the fuel cell bypass valve 3 8 is fully closed.
- the air is first supplied to the fuel cell stack 1 2 only through the humidifier bypass path 3 2 out of the humidifier bypass path 3 2 and the main path 30 when power generation is started.
- the present embodiment is not limited to such a case.
- the inlet short valve 20 is first opened among the inlet short valve 20 and the humidifier bypass valve 18. Even when the air is supplied to the fuel cell stack 12 through this path 30, the operation can be performed.
- step S 1 the valve opening command for the inlet shut valve 20 is issued, and in step S 7, the valve opening command for the humidifier bypass valve 18 is issued in the case of shifting to valve abnormality sequence control. .
- air is supplied to the fuel cell stack 1 2 through the humidifier bypass path 3 2 and power generation is started.
- the fuel cell system 10 includes a humidifier bypass valve 18 and an inlet short valve 20 that are driven according to a change in pressure of the air supplied from the air compressor 24, and a humidifier.
- the first pressure value is applied to the valve opening pressure chamber 52 that communicates with the air compressor 24, thereby Pressure applying means for driving;
- the opening of the fuel cell bypass valve 38 can be reduced by reducing the opening of the one valve.
- a fuel cell bypass valve control means which is a pressure changing means for changing the first pressure value in the valve opening pressure chamber 52, that is, for increasing the pressure.
- the first pressure in the valve-opening pressure chamber 52 that communicates with the air compressor 24 is maintained in this one valve.
- the value is changed by increasing the opening degree of the fuel cell bypass valve 38, thereby releasing the sticking of the valve and enabling stable operation.
- FIG. 7 is a flowchart showing the activation control method of the second embodiment.
- the same reference numerals are given to the same components as those in FIG. To explain.
- a starting control method when only the inlet shut-off valve 2 0 is opened will be described.
- the valve opening pressure chamber 5 2 communicating with the air compressor 24 is connected to the first air compressor 24.
- Pressure-applying means for driving the one valve by applying a first pressure value corresponding to the discharge pressure of 1 is provided.
- Air compressor control means which is fluid supply control means for changing the first pressure value in the valve pressure chamber 52, is provided.
- step S 3 of FIG. 7 the air compressor control means of the control unit is an inlet pressure sensor P 1 located at the outlet of the air compressor 24. It is determined whether the pressure detection value of the inlet pressure sensor P 1 has dropped below the pressure threshold value P s (kPa) after the stabilization time has elapsed.
- step S 3 the air compressor control means does not detect the pressure detection value of the inlet pressure sensor P 1 below the pressure threshold value P s (k Pa) after the stabilization time has elapsed, that is, the humidifier bypass valve 18 If it is determined that the valve is not normally opened (valve open determination is NG), in step S4, the air conditioner presser control means sets the discharge flow rate of the air compressor 24 (Fig. 1) to the current flow rate. On the other hand, the pressure of the air supplied to the valve-opening pressure chamber 52 of the humidifier bypass valve 18 is increased above the first pressure value by increasing it by a predetermined flow rate.
- step S6 the air compressor control means determines again whether or not the pressure detection value of the inlet pressure sensor P1 has decreased to the pressure threshold value P s (k Pa) or less after a predetermined time has elapsed. . Even in the determination in step S 6, the pressure detection value of the inlet pressure sensor P 1 is not less than or equal to the pressure threshold value P s (k Pa), that is, the humidifier bypass valve 18 is not normally opened. If it is determined that the state (valve opening determination is NG), it is determined that the humidifier bypass valve 18 cannot be opened by increasing the discharge flow rate of the air compressor 24.
- step S7 the above diagram is displayed. As in the first embodiment shown in FIG. 6, the process shifts to valve abnormality sequence control.
- step S3 the detected pressure value of the inlet pressure sensor P1 becomes equal to or lower than the pressure threshold value Ps (kPa) after the stabilization time has elapsed, i.e., the humidifier bypass valve 18 is normally opened. If it is determined that the valve is in a valved state (the valve open determination is OK), the startup sequence process is continued in step S5.
- step S 6 the pressure detection value of the inlet pressure sensor P 1 becomes equal to or lower than the pressure threshold value P s (k Pa) after the stabilization time has elapsed, that is, the humidifier bypass valve 18 is normally opened. Even if it is determined that the valve is open (valve open determination is OK), the startup sequence process is continued in step S5, and the air compressor 24 The discharged air is supplied to the fuel cell stack 1 2 through the humidifier bypass path 3 2.
- the air is first supplied to the fuel cell stack 1 2 only through the humidifier bypass path 3 2 out of the humidifier bypass path 3 2 and the main path 30 when power generation is started.
- the present embodiment is not limited to such a case, and, similar to the first embodiment described above, when power generation is started, the inlet shut valve 20 and the humidifier bypass valve 18 are Thus, even when only the inlet shut valve 20 is opened first and air is supplied to the fuel cell stack 12 through this route 30, the operation can be performed.
- the inside of the pressure chamber 52 for opening one of the humidifier bypass valve 18 and the inlet shirt valve 20 is the first one. Even if it is a pressure value, the first pressure value in the valve opening pressure chamber 5 2 of one valve is changed by increasing the discharge flow rate of the air compressor 2 4 in the event that one of the valves does not drive. That is, air compressor control means, which is pressure changing means for raising the pressure value in the valve-opening pressure chamber 52 above the first pressure value, is provided. For this reason, even when one of the humidifier bypass valve 18 and the inlet short valve 20 is fixed, the pressure value in the valve-opening pressure chamber 52 connected to the air compressor 24 can be reduced in this one valve. By increasing the discharge flow rate of the air compressor 24 by increasing the release flow rate, it is possible to release the sticking of one valve, thereby enabling stable operation.
- the third embodiment is a combination of the first embodiment shown in FIGS. 1 to 6 and the second embodiment shown in FIG. You can also. That is, the following description will be made using the reference numerals in FIG. 1 representing the first embodiment.
- the humidifier bypass valve 18 and the inlet are the same as in each of the above embodiments.
- Shirt valve 2 One of the 0 valves Pressure applying means for driving one of the above valves by applying a first pressure value corresponding to the first discharge pressure of the air compressor 24 to the valve opening pressure chamber 52 connected to the presser 24 Is provided.
- the pressure changing means included in the control unit is configured such that the inside of the valve opening pressure chamber 52 of the one valve corresponds to the first discharge pressure of the air compressor 24.
- One valve does not drive even if the pressure value is 1.
- Air compressor that throttles the opening of the fuel cell bypass valve 3 8 and raises the air discharge flow rate by the air compressor 2 4 that is the fluid supply unit in the event of an abnormality Use fuel cell bypass valve control means.
- step S4 the air compressor fuel cell bypass valve control means performs the discharge flow rate of the air compressor 24. And increase the pressure of the air supplied to the opening pressure chamber 5 2 of the humidifier bypass valve 1 8 or the inlet shut valve 2 0 as well as the opening degree of the fuel cell bypass valve 3 8 . In such a configuration, it becomes easier to drive one of the humidifier bypass valve 18 and the inlet shut valve 20 even when one of the valves is fixed.
- FIG. 8a, FIG. 8b, FIG. 8c, and FIG. 9 to FIG. 10 show a fourth embodiment.
- the same reference numerals are given to the same components as those in FIG. To explain.
- Fig. 8a, Fig. 8b, and Fig. 8c are schematic diagrams showing inconveniences to be solved by this embodiment and the principle for solving these inconveniences. That is, FIG. 8 a, FIG. 8 b, and FIG. 8 c are the sliding parts for sliding the valve body 5 8 and the valve body 5 8 in the humidifier bypass valve 18 or the inlet shut valve 20. The relationship with the hole provided in the cut portion 4 4 is shown.
- the inconvenience to be solved by the present embodiment is that the valve body 5 8 of the humidifier bypass valve 18 or the inlet short valve 20 has a hole portion provided in the partition portion 44.
- the valve body 5 8 is caught in the corner of the hole, etc. while tilting with respect to the axial direction, and is stuck in a state where the valve is not fully opened. Is Rukoto.
- the pressure to normally open is set to the humidifier bypass valve as in the case where the valve body 58 adheres to the fixed part due to freezing and does not open.
- 1 8 or inlet shirt valve 2 0 Opening pressure chamber 5 2 Actuating the humidifier bypass valve 1 8 or inlet shirt valve 2 0 may not open completely.
- the control unit such as the ECU, as in each of the above embodiments, is one of the humidifier bypass valve 18 and the inlet short valve 20.
- Pressure applying means for driving one valve by applying a first pressure value to the valve opening pressure chamber 52 communicating with the air compressor 24 (FIG. 1) is provided.
- the control unit will set the valve opening pressure chamber 52 of one valve in the valve opening pressure chamber 52 of the one valve when there is an abnormality that does not drive even if the valve 1 is in the first pressure value.
- the second air compressor control means is a pressure change means for changing the pressure value of the air pressure, that is, the pressure change means for changing the pressure value alternately up and down.
- the second air compressor control means causes the air compressor 24 to alternately and vertically change the supply pressure of the air supplied to the valve opening pressure chamber 52 of the one valve.
- the second air compressor control means changes the discharge flow M of the air compressor 24 so as to alternately repeat increasing and decreasing in a pulsed manner or at predetermined time intervals.
- FIG. 9 shows an activation control method when only the humidifier bypass valve 18 is first opened among the humidifier bypass valve 18 and the inlet shut-off valve 20 when power generation is activated.
- step S 1 when supplying air to the fuel cell switch 12 at the start of power generation, first, in step S 1, an activation command is sent to the fuel cell system 10 by turning on the ignition key or the like.
- the pressure applying means of the control unit opens the humidifier bypass valve 18 as in the first embodiment shown in FIG.
- a command signal for opening / closing control of V b S, V b C, and V b O is issued.
- step S2 the pressure applying means opens the fuel cell bypass valve 3 8 to a certain opening such as half-open (for example, 50% opening), operates the air compressor 2 4, pressure Send out the rising air.
- step S3 the second air compressor control means of the control unit monitors the pressure detection value of the inlet pressure sensor P 1 located at the outlet of the air compressor 24. On the other hand, it is determined whether or not the pressure detection value of the inlet pressure sensor P 1 has decreased to a pressure threshold value P s (k Pa) or less after the stabilization time has elapsed.
- step S3 the second air compressor control means does not detect the pressure detection value of the inlet pressure sensor P1 to be equal to or lower than the pressure threshold value P s (k Pa) after the stable time has elapsed, that is, the humidifier If it is determined that the bypass valve 1 8 is not fully opened (valve open determination is NG), in step S4, the second air compressor control means determines the discharge flow rate of the air compressor 24. Are changed so as to alternate between increasing and decreasing in a pulsed manner or at predetermined time intervals.
- FIG. 10 (a) shows an example of a time change in which the discharge flow rate of the air compressor 24 is changed so as to alternately increase and decrease every predetermined time.
- the driving force of the humidifier bypass valve 18, which is the driving force acting on the valve body 58 of the humidifier bypass valve 18, also increases every predetermined time. It will change so that the decrease is repeated alternately.
- the second air compressor control means again determines that the pressure detection value of the inlet pressure sensor P 1 is less than or equal to the pressure threshold value P s (k Pa) after a predetermined time has passed in step S 6. It is determined whether or not it has dropped to. Even in the determination in step S 6, the detected pressure value of the inlet pressure sensor P 1 does not fall below the pressure threshold value P s (k Pa), that is, the humidifier bypass valve 18 has not opened normally. If it is determined that there is no state (valve open determination is NG), it is determined that the humidifier bypass valve 1 8 cannot be fully opened in the control that changes the discharge flow rate of the air compressor 2 4. In step S7, the control shifts to valve abnormality sequence control as in the first embodiment shown in FIG.
- step S3 the pressure detection value of the inlet pressure sensor P1 becomes equal to or lower than the pressure threshold value Ps (kPa) after the stabilization time has elapsed, i.e., the humidifier bypass valve 18 is operating normally. If it is determined that the valve is open (the valve open determination is OK), the startup sequence process is continued in step S5.
- step S6 after the stabilization time has elapsed, the pressure detection of the inlet pressure sensor P1 Even when it is determined that the output value is equal to or less than the pressure threshold P s (k Pa), that is, the humidifier bypass valve 1 8 is normally open (the valve open determination is OK)
- step S5 the start-up sequence process is continued so that the air discharged from the air compressor 24 is supplied to the fuel cell stack 12 through the humidifier bypass path 32.
- the air is first supplied to the fuel cell stack 1 2 only through the humidifier bypass path 3 2 out of the humidifier bypass path 3 2 and the main path 30 when power generation is started.
- the present embodiment is not limited to such a case. Similar to the first embodiment shown in FIGS. 1 to 6, the inlet shut-off valve 20 and the humidification are generated at the start of power generation. This can be implemented even when only the inlet short valve 20 is first opened and the air is supplied to the fuel cell stack 12 through this path 30.
- the valve opening pressure chamber 52 connected to the air compressor 24 is provided in one of the humidifier bypass valve 18 and the inlet short valve 20.
- the pressure applying means for driving the one of the valves and the valve opening pressure chamber 52 of the one of the valves even if the pressure in the valve opening pressure chamber 52 is the first pressure value.
- a pressure changing means that changes the first pressure value in the valve opening pressure chamber 52 of one valve, that is, changes the discharge flow rate of the air compressor 24 alternately up and down in the event of an abnormality that does not drive. Air compressor control means. For this reason, the driving shaft 60 (see FIGS.
- valve body 58 of the one valve is a sliding portion, and the driving shaft 60 is inclined with respect to the hole of the partition portion 44.
- the valve body 5 8 is made to act on the valve body 58 by alternately applying force to the valve body 58 on both sides in the up-down direction due to the vertical change in the discharge flow rate of the air compressor 24. Even if it is not possible to release the catch of the valve body 5 8 only by applying a force in the direction, this catch can be released, and the inclination of the valve body 5 8 with respect to the sliding part is corrected, The valve can be driven smoothly. As a result, stable operation can be achieved. Moreover, it is not necessary to consume the fuel in the fuel cell stack 1 2 to drive any one of the humidifier bypass valve 18 and the inlet shut valve 20, and the generated power of the fuel cell stack 1 2 Can be used more effectively.
- the inlet shut-off valve 20 Opening pressure chamber for one of the 0 and humidifier bypass valves 1 8 5
- the pressure changing means for changing the pressure value in the pressure chamber 5 2 up and down can be used as the second fuel cell bypass valve control means.
- the second fuel cell bypass valve control means changes the degree of opening of the humidifier bypass valve 18 so as to alternately repeat large and small at the time of the abnormality. Even when such a second fuel cell bypass valve control means is provided, both sides of the valve body 5 8 (see FIGS.
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Abstract
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Priority Applications (4)
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KR1020097018758A KR101126665B1 (ko) | 2007-03-09 | 2008-03-07 | 연료전지 시스템 |
DE112008000547T DE112008000547B4 (de) | 2007-03-09 | 2008-03-07 | Brennstoffzellensystem |
CN2008800077627A CN101632193B (zh) | 2007-03-09 | 2008-03-07 | 燃料电池系统 |
US12/523,939 US8642194B2 (en) | 2007-03-09 | 2008-03-07 | Fuel cell system |
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JP2007059709A JP5023743B2 (ja) | 2007-03-09 | 2007-03-09 | 燃料電池システム |
JP2007-059709 | 2007-03-09 |
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WO2008111659A1 true WO2008111659A1 (ja) | 2008-09-18 |
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PCT/JP2008/054686 WO2008111659A1 (ja) | 2007-03-09 | 2008-03-07 | 燃料電池システム |
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US (1) | US8642194B2 (ja) |
JP (1) | JP5023743B2 (ja) |
KR (1) | KR101126665B1 (ja) |
CN (1) | CN101632193B (ja) |
DE (1) | DE112008000547B4 (ja) |
WO (1) | WO2008111659A1 (ja) |
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DE102012022627A1 (de) * | 2012-11-20 | 2013-11-28 | Daimler Ag | Befeuchtungsanordnung für ein Brennstoffzellensystem und Verfahren zum Betreiben einer Befeuchtungsanordnung |
DE102012024716A1 (de) * | 2012-12-18 | 2014-06-18 | Daimler Ag | Verfahren zum Regeln eines Brennstoffzellensystems |
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DE102014007677A1 (de) * | 2014-05-20 | 2015-11-26 | Daimler Ag | Behandlungseinrichtung zum Behandeln von Abgas eines Brennstoffzellenstapels, Brennstoffzellensystem und Fahrzeug mit einem Brennstoffzellensystem |
JP6278119B2 (ja) * | 2014-08-20 | 2018-02-14 | 日産自動車株式会社 | 燃料電池システム及び燃料電池システムの制御方法 |
US10069157B2 (en) | 2015-05-18 | 2018-09-04 | Hyundai Motor Company | Fuel cell system having valve module between fuel cell stack and humidifier |
KR101795137B1 (ko) * | 2015-06-03 | 2017-11-08 | 현대자동차주식회사 | 연료전지 스택의 공기 공급 제어 장치 및 그 방법 |
US10033056B2 (en) | 2015-09-13 | 2018-07-24 | Honeywell International Inc. | Fuel cell regulation using loss recovery systems |
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KR102552485B1 (ko) * | 2016-12-16 | 2023-07-06 | 현대자동차주식회사 | 연료전지 시스템 |
US11739852B2 (en) * | 2019-04-17 | 2023-08-29 | Aisan Kogyo Kabushiki Kaisha | Air valve and fuel cell system using air valve |
DE102020110604A1 (de) | 2020-04-20 | 2021-10-21 | Audi Aktiengesellschaft | Brennstoffzellenvorrichtung, Verfahren zum Betreiben einer Brennstoffzellenvorrichtung und Kraftfahrzeug mit einer solchen |
US11611091B2 (en) * | 2021-02-10 | 2023-03-21 | Cummins Inc. | Air tank and variable geometry air handling in hydrogen fuel cells |
DE102022128711A1 (de) | 2022-10-28 | 2024-05-08 | MTU Aero Engines AG | Flugzeug-Brennstoffzellen-Antrieb |
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Publication number | Publication date |
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DE112008000547B4 (de) | 2011-09-08 |
CN101632193B (zh) | 2012-08-22 |
JP5023743B2 (ja) | 2012-09-12 |
US20100021783A1 (en) | 2010-01-28 |
CN101632193A (zh) | 2010-01-20 |
KR20090108132A (ko) | 2009-10-14 |
JP2008226520A (ja) | 2008-09-25 |
KR101126665B1 (ko) | 2012-04-13 |
US8642194B2 (en) | 2014-02-04 |
DE112008000547T5 (de) | 2010-01-07 |
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