WO2008064148A3 - Method for removal of mercury from hydrocarbon feedstocks - Google Patents

Method for removal of mercury from hydrocarbon feedstocks Download PDF

Info

Publication number
WO2008064148A3
WO2008064148A3 PCT/US2007/085081 US2007085081W WO2008064148A3 WO 2008064148 A3 WO2008064148 A3 WO 2008064148A3 US 2007085081 W US2007085081 W US 2007085081W WO 2008064148 A3 WO2008064148 A3 WO 2008064148A3
Authority
WO
WIPO (PCT)
Prior art keywords
mercury
composition
removal
hydrocarbon feedstocks
hydrocarbon stream
Prior art date
Application number
PCT/US2007/085081
Other languages
French (fr)
Other versions
WO2008064148A2 (en
Inventor
Madan M Bhasin
Mark K Brayden
Foppe Dupius
Peter E Groenendijk
Seyed R Seyedmonir
Michael C Smith
Fredrick W Vance
Buren Frederik R Van
Marc A Mangnus
Original Assignee
Dow Global Technologies Inc
Madan M Bhasin
Mark K Brayden
Foppe Dupius
Peter E Groenendijk
Seyed R Seyedmonir
Michael C Smith
Fredrick W Vance
Buren Frederik R Van
Marc A Mangnus
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Madan M Bhasin, Mark K Brayden, Foppe Dupius, Peter E Groenendijk, Seyed R Seyedmonir, Michael C Smith, Fredrick W Vance, Buren Frederik R Van, Marc A Mangnus filed Critical Dow Global Technologies Inc
Priority to BRPI0717195-1A2A priority Critical patent/BRPI0717195A2/en
Priority to MX2009005354A priority patent/MX2009005354A/en
Priority to US12/446,529 priority patent/US8382881B2/en
Priority to CA002670070A priority patent/CA2670070A1/en
Priority to EP07864579.3A priority patent/EP2108031B1/en
Publication of WO2008064148A2 publication Critical patent/WO2008064148A2/en
Publication of WO2008064148A3 publication Critical patent/WO2008064148A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/31—Pore size distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention provides a method for removing mercury from a liquid or gas hydrocarbon stream, mixtures thereof, including mixtures of liquid streams with a solid carbonaceous substance, by contacting the hydrocarbon stream with a composition comprising silver and a support material, wherein the composition as measured by ammonia chemisorption has a surface acidity in the range of 0.1-10.0 μmole of irreversible NH3 /g of the composition.
PCT/US2007/085081 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks WO2008064148A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0717195-1A2A BRPI0717195A2 (en) 2006-11-21 2007-11-19 "METHOD FOR REMOVING MERCURY FROM A LIQUID OR GAS CURRENT MARKET UNDERSTANDING MERCURY"
MX2009005354A MX2009005354A (en) 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks.
US12/446,529 US8382881B2 (en) 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks
CA002670070A CA2670070A1 (en) 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks
EP07864579.3A EP2108031B1 (en) 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86028806P 2006-11-21 2006-11-21
US60/860,288 2006-11-21

Publications (2)

Publication Number Publication Date
WO2008064148A2 WO2008064148A2 (en) 2008-05-29
WO2008064148A3 true WO2008064148A3 (en) 2009-02-26

Family

ID=39430532

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/085081 WO2008064148A2 (en) 2006-11-21 2007-11-19 Method for removal of mercury from hydrocarbon feedstocks

Country Status (9)

Country Link
US (1) US8382881B2 (en)
EP (1) EP2108031B1 (en)
CN (1) CN101547995A (en)
BR (1) BRPI0717195A2 (en)
CA (1) CA2670070A1 (en)
MX (1) MX2009005354A (en)
RU (1) RU2443758C2 (en)
TW (1) TW200835783A (en)
WO (1) WO2008064148A2 (en)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9144765B2 (en) * 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
US8489231B2 (en) * 2009-09-18 2013-07-16 Raf Technology, Inc. Loop mail processing
CA2774488A1 (en) * 2009-09-18 2011-03-24 Conocophillips Company Mercury removal from water
US8673133B2 (en) 2010-09-16 2014-03-18 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8728304B2 (en) 2010-09-16 2014-05-20 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8663460B2 (en) 2010-09-16 2014-03-04 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8702975B2 (en) 2010-09-16 2014-04-22 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8721874B2 (en) 2010-11-19 2014-05-13 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8728303B2 (en) 2010-11-19 2014-05-20 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8721873B2 (en) 2010-11-19 2014-05-13 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
GB2502030C (en) 2011-02-07 2018-08-15 Velocys Tech Limited Catalysts
GB2571648B (en) * 2011-12-06 2020-04-08 Cameron Tech Ltd Floating liquefied natural gas pretreatment system
CN104093819A (en) * 2011-12-30 2014-10-08 雪佛龙美国公司 Process, method, and system for removing heavy metals from fluids
US9447675B2 (en) 2012-05-16 2016-09-20 Chevron U.S.A. Inc. In-situ method and system for removing heavy metals from produced fluids
CA2872793C (en) 2012-05-16 2020-08-25 Chevron U.S.A. Inc. Process, method, and system for removing mercury from fluids
EP2850155B1 (en) 2012-05-16 2018-04-04 Chevron U.S.A., Inc. Process for removing mercury from fluids
WO2013173593A1 (en) 2012-05-16 2013-11-21 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
FR2992233B1 (en) * 2012-06-26 2018-03-16 IFP Energies Nouvelles ELEMENTARY SULFUR COMPOUND CAPTURING MASS REMOVED FROM POROUS SUPPORT FOR CAPTURING HEAVY METALS
US9023255B2 (en) 2012-08-21 2015-05-05 Uop Llc Production of nitrogen compounds from a methane conversion process
US9434663B2 (en) 2012-08-21 2016-09-06 Uop Llc Glycols removal and methane conversion process using a supersonic flow reactor
US9656229B2 (en) 2012-08-21 2017-05-23 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US20140058091A1 (en) * 2012-08-21 2014-02-27 Uop Llc Mercury compound removal and methane conversion process using a supersonic flow reactor
US20140058084A1 (en) * 2012-08-21 2014-02-27 Uop Llc Mercury removal and methane conversion process using a supersonic flow reactor
US20140058096A1 (en) * 2012-08-21 2014-02-27 Uop Llc Heavy metals removal and methane conversion process using a supersonic flow reactor
US8933275B2 (en) 2012-08-21 2015-01-13 Uop Llc Production of oxygenates from a methane conversion process
US9370757B2 (en) 2012-08-21 2016-06-21 Uop Llc Pyrolytic reactor
US8927769B2 (en) 2012-08-21 2015-01-06 Uop Llc Production of acrylic acid from a methane conversion process
US9205398B2 (en) 2012-08-21 2015-12-08 Uop Llc Production of butanediol from a methane conversion process
US9308513B2 (en) 2012-08-21 2016-04-12 Uop Llc Production of vinyl chloride from a methane conversion process
US9327265B2 (en) 2012-08-21 2016-05-03 Uop Llc Production of aromatics from a methane conversion process
US8937186B2 (en) 2012-08-21 2015-01-20 Uop Llc Acids removal and methane conversion process using a supersonic flow reactor
US9707530B2 (en) 2012-08-21 2017-07-18 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US9689615B2 (en) 2012-08-21 2017-06-27 Uop Llc Steady state high temperature reactor
WO2014036253A2 (en) 2012-08-30 2014-03-06 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
WO2014039758A2 (en) 2012-09-07 2014-03-13 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
MY175441A (en) * 2013-01-29 2020-06-26 Oilfield Mineral Solutions Ltd Method of mercury decontamination
US9169445B2 (en) 2013-03-14 2015-10-27 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from oily solids
US9023196B2 (en) 2013-03-14 2015-05-05 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US9234141B2 (en) 2013-03-14 2016-01-12 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from oily solids
MY175927A (en) * 2015-03-03 2020-07-15 Petroliam Nasional Berhad Petronas Process for removing heavy metals from hydrocarbons
CN106693882B (en) * 2016-12-09 2020-01-24 清华大学 Coal-fired power plant flue gas demercuration adsorbent and preparation method thereof
EP3648871A1 (en) * 2017-07-06 2020-05-13 Ecolab USA, Inc. Enhanced injection of mercury oxidants
CN109253996B (en) * 2018-10-31 2021-05-28 中国石油天然气股份有限公司 Mercury isotope testing method and device for crude oil
CN109253995B (en) 2018-10-31 2021-06-01 中国石油天然气股份有限公司 Mercury isotope testing method and device for natural gas
CN109253994B (en) 2018-10-31 2021-05-28 中国石油天然气股份有限公司 Oil and gas source mercury isotope detection method and device
JP6973359B2 (en) * 2018-11-26 2021-11-24 昭和電工マテリアルズ株式会社 Vacuum insulation equipment
CN116059958B (en) * 2021-10-29 2024-10-11 中国石油化工股份有限公司 Cerium-loaded silver-loaded catalytic adsorbent for flue gas mercury removal and denitration as well as preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4094777A (en) * 1975-12-18 1978-06-13 Institut Francais Du Petrole Process for removing mercury from a gas or a liquid by absorption on a copper sulfide containing solid mass
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
US4902662A (en) * 1987-05-26 1990-02-20 Institut Francais Du Petrole Processes for preparing and regenerating a copper containing mercury collecting solid mass
FR2673191A1 (en) * 1991-02-27 1992-08-28 Inst Francais Du Petrole Process for removing mercury and/or arsenic from feedstocks for solvent dearomatisation units
WO2007147781A1 (en) * 2006-06-21 2007-12-27 Basf Se Absorption composition and process for removing mercury

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US909926A (en) * 1907-10-09 1909-01-19 James L Mcdonald Heating-furnace.
US4012337A (en) * 1974-03-13 1977-03-15 Exxon Research And Engineering Company High surface area alpha aluminas
US4916243A (en) * 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
AU559284B2 (en) * 1982-07-08 1987-03-05 Takeda Chemical Industries Ltd. Adsorption of mercury vapour
US4708853A (en) * 1983-11-03 1987-11-24 Calgon Carbon Corporation Mercury adsorbent carbon molecular sieves and process for removing mercury vapor from gas streams
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4833261A (en) * 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
FR2628338B1 (en) * 1988-03-10 1991-01-04 Inst Francais Du Petrole PROCESS FOR THE REMOVAL OF MERCURY FROM HYDROCARBONS
US4874525A (en) * 1988-10-26 1989-10-17 Uop Purification of fluid streams containing mercury
US4909926A (en) * 1989-02-01 1990-03-20 Mobil Oil Corporation Method for removing mercury from hydrocarbon oil by high temperature reactive adsorption
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5202301A (en) * 1989-11-22 1993-04-13 Calgon Carbon Corporation Product/process/application for removal of mercury from liquid hydrocarbon
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
AU656537B2 (en) * 1990-10-12 1995-02-09 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts having enhanced activity and/or stability
US5082569A (en) * 1990-12-03 1992-01-21 Uop Removal of metals from liquefied hydrocarbons
WO1993012201A1 (en) * 1991-12-09 1993-06-24 Dow Benelux N.V. Process for removing mercury from organic media
US5856263A (en) * 1992-08-28 1999-01-05 Union Carbide Chemicals & Plastics Technology Corporation Catalysts comprising substantially pure alpha-alumina carrier for treating exhaust gases

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4094777A (en) * 1975-12-18 1978-06-13 Institut Francais Du Petrole Process for removing mercury from a gas or a liquid by absorption on a copper sulfide containing solid mass
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
US4902662A (en) * 1987-05-26 1990-02-20 Institut Francais Du Petrole Processes for preparing and regenerating a copper containing mercury collecting solid mass
FR2673191A1 (en) * 1991-02-27 1992-08-28 Inst Francais Du Petrole Process for removing mercury and/or arsenic from feedstocks for solvent dearomatisation units
WO2007147781A1 (en) * 2006-06-21 2007-12-27 Basf Se Absorption composition and process for removing mercury

Also Published As

Publication number Publication date
MX2009005354A (en) 2009-06-05
EP2108031B1 (en) 2018-10-17
CN101547995A (en) 2009-09-30
CA2670070A1 (en) 2008-05-29
WO2008064148A2 (en) 2008-05-29
US20100126909A1 (en) 2010-05-27
US8382881B2 (en) 2013-02-26
RU2009123455A (en) 2010-12-27
TW200835783A (en) 2008-09-01
RU2443758C2 (en) 2012-02-27
BRPI0717195A2 (en) 2014-01-21
EP2108031A2 (en) 2009-10-14

Similar Documents

Publication Publication Date Title
WO2008064148A3 (en) Method for removal of mercury from hydrocarbon feedstocks
WO2010002444A3 (en) Sorbent comprising activated carbon particles, sulfur and metal catalyst
EP1922389A4 (en) Absorbent composition containing molecules with a hindered amine and a metal sulfonate, phosphonate or carboxylate structure for acid gas scrubbing process
WO2007031441A3 (en) Dropping method for liquids
TWI347215B (en) Water dispersion liquid and method for producing the same, and composition, binding agent and coating agent
ZA201000665B (en) Composition, production and use of sorbent particles for flue gas desulfurization
EP1877161A4 (en) Scavengers for removal of acid gases from fluid streams
ATE535370T1 (en) CHANNEL WITH COVER WITH REDUCED PERMEABILITY FOR ACID COMPOUNDS
WO2005116170A3 (en) Process for removing sulfur compounds from hydrocarbon streams and adsorbent used in this process
GB2442841B (en) Compounds from the reaction of polyacrylates, phenols, and amines; and methods of use thereof
WO2006113266A3 (en) Coated filter media
EP1930701A4 (en) Flowmeter for fine channel, and analyzer and cartridge for analyzer that use the flowmeter
WO2008021968A3 (en) Process for removal of mercury from gas stream
GB2427230B (en) Method for increasing the production of hydrocarbon liquids and gases
WO2010080613A3 (en) Coated flow-through substrates and methods for making and using them
WO2009073467A3 (en) Process and catalyst for desulfurization of hydrocarbonaceous oil stream
WO2007136980A3 (en) Diagnostic test media and methods for the manufacture thereof
EP1951849A4 (en) Process, system and apparatus for passivating carbonaceous materials
EP1857181A4 (en) Photocatalyst, method for producing same, liquid dispersion containing photocatalyst and photocatalyst coating composition
WO2007147783A3 (en) Adsorption mass and method for eliminating co from streams of substances
ZA200807784B (en) Adsorption composition and process for removal of co from material streams
ZA200702156B (en) Process for simulating the corrosive effects of refinery feedstocks on refinery mettalurgy
WO2007092827A3 (en) Improved separation method
WO2009037600A3 (en) Solid substrate with surface bound molecules and methods for producing and using the same
WO2010080602A3 (en) Flow-through substrates and methods for making and using them

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780043111.9

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2007864579

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2728/CHENP/2009

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 2670070

Country of ref document: CA

Ref document number: MX/A/2009/005354

Country of ref document: MX

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07864579

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2009123455

Country of ref document: RU

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 12446529

Country of ref document: US

ENP Entry into the national phase

Ref document number: PI0717195

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20090515