WO2008054631A1 - Selective oxidation catalyst injection based on temperature - Google Patents
Selective oxidation catalyst injection based on temperature Download PDFInfo
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- WO2008054631A1 WO2008054631A1 PCT/US2007/021913 US2007021913W WO2008054631A1 WO 2008054631 A1 WO2008054631 A1 WO 2008054631A1 US 2007021913 W US2007021913 W US 2007021913W WO 2008054631 A1 WO2008054631 A1 WO 2008054631A1
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- Prior art keywords
- exhaust
- catalyst
- temperature
- fuel
- constituent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/029—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles by adding non-fuel substances to exhaust
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/029—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles by adding non-fuel substances to exhaust
- F01N3/0293—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles by adding non-fuel substances to exhaust injecting substances in exhaust stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/021—Introducing corrections for particular conditions exterior to the engine
- F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
- F02D41/027—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
- F02D41/029—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus the exhaust gas treating apparatus being a particulate filter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
- F02M27/02—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
- F02M63/02—Fuel-injection apparatus having several injectors fed by a common pumping element, or having several pumping elements feeding a common injector; Fuel-injection apparatus having provisions for cutting-out pumps, pumping elements, or injectors; Fuel-injection apparatus having provisions for variably interconnecting pumping elements and injectors alternatively
- F02M63/0225—Fuel-injection apparatus having a common rail feeding several injectors ; Means for varying pressure in common rails; Pumps feeding common rails
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2430/00—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics
- F01N2430/04—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics by adding non-fuel substances to combustion air or fuel, e.g. additives
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/06—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a temperature sensor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/01—Adding substances to exhaust gases the substance being catalytic material in liquid form
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/0025—Controlling engines characterised by use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/14—Introducing closed-loop corrections
- F02D41/1438—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor
- F02D41/1444—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor characterised by the characteristics of the combustion gases
- F02D41/1446—Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor characterised by the characteristics of the combustion gases the characteristics being exhaust temperatures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M37/00—Apparatus or systems for feeding liquid fuel from storage containers to carburettors or fuel-injection apparatus; Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines
- F02M37/0047—Layout or arrangement of systems for feeding fuel
- F02M37/0064—Layout or arrangement of systems for feeding fuel for engines being fed with multiple fuels or fuels having special properties, e.g. bio-fuels; varying the fuel composition
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present disclosure is directed to a system for injecting an oxidation catalyst solution into a fuel or exhaust stream and, more particularly, to a system that selectively injects the oxidation catalyst solution based on an exhaust temperature.
- a particulate trap is a filter, typically consisting of a wire mesh or ceramic honeycomb medium, which is designed to trap particulate matter.
- a particulate trap for extended periods of time may cause the particulate matter to build up in the medium, thereby reducing the functionality of the filter and subsequent performance of the engine.
- Built-up particulate matter may be removed from the filter through a process called regeneration. To initiate regeneration of the filter, the temperature of the particulate matter captured within the filter must be elevated to a combustion threshold, at which the particulate matter may slowly burn away.
- the temperature of the exhaust flow as emitted by the engine raises the particulate temperature to that sufficient for regeneration.
- the temperature of the exhaust may be insufficient to raise the particulate matter to the required combustion threshold.
- the compound-bonded particle has a lower ignition temperature than non-bonded particles.
- the soot particles and metal compounds are burned, leaving behind ash, which may be effectively removed from the filter during periodic maintenance of the engine.
- the system of the '584 patent may suitably regenerate a particulate filter, it may be costly and problematic, hi particular, the low- temperature situations requiring the injection of the additive may be intermittent and, because the system of the '584 patent always injects that additive, some additive may be wasted. This wasted additive drives up the cost of the system.
- the additive is converted to ash during the regeneration process, excessive amounts of additive may result in excessive amounts of ash.
- the maintenance interval of the engine may be at least partially based on the accumulation rate of ash within the particle filter, the excessive amounts of ash may significantly reduce the maintenance interval.
- a reduced maintenance interval in addition to creating an inconvenience for the vehicle owner, also serves to increase the operating cost of the vehicle.
- the system of the present disclosure solves one or more of the problems set forth above.
- the exhaust treatment system may include a supply of catalyst configured to lower the combustion threshold value of an exhaust constituent, and an injector operable to selectively pass the catalyst to the exhaust constituent.
- the exhaust treatment system may further include a controller in communication with the injector. The controller may be configured to determine a temperature of an exhaust flow, and operate the injector to pass the catalyst in response to the combustion threshold value being greater than the determined temperature.
- Yet another aspect of the present disclosure is directed to a method of treating exhaust.
- the method may include collecting a constituent of the exhaust, and determining a temperature of the collected constituent.
- the method may further include mixing a catalyst with the constituent to lower the combustion threshold of the collected constituent when the combustion threshold is greater than the determined temperature.
- Fig. l is a schematic and diagrammatic illustration of an exemplary disclosed power system
- Fig. 2 is a flowchart depicting an exemplary disclosed operation of the power system of Fig. 1. Detailed Description
- Fig. 1 illustrates a power system including a power unit 10, a fuel system 12, and an exhaust treatment system 14.
- the power system may be associated with a mobile vehicle such as a passenger vehicle, a vocational vehicle, a farming vehicle or a construction vehicle.
- the power system may be associated with a stationary machine such as an industrial power generator or a furnace.
- power unit 10 is depicted and described as a four-stroke diesel engine.
- power unit 10 may be any other type of internal combustion engine such as, for example, a gasoline engine, a gaseous fuel-powered engine, or a turbine engine.
- Power unit 10 may include an engine block 16 that at least partially defines a plurality of combustion chambers 18.
- power unit 10 includes four combustion chambers.
- power unit 10 may include a greater or lesser number of combustion chambers and that the combustion chambers may be disposed in an "in-line" configuration, a "V" configuration, or any other suitable configuration. As also shown in Fig.
- power unit 10 may include a crankshaft 20 that is rotatably disposed within engine block 16.
- a connecting rod (not shown) may connect a plurality of pistons (not shown) to crankshaft 20 so that a sliding motion of each piston within its respective combustion chamber results in a rotation of crankshaft 20.
- a rotation of crankshaft 20 may result in a sliding motion of the pistons.
- Rotation of crankshaft 20 may function as output from power unit 10 for effecting a desired work such as rotation of a generator or rotation of one or more drive axels of an associated vehicle.
- Fuel system 12 may include a fuel tank 22.
- Fuel tank 22 may be configured to store a supply of fuel such as, for example, diesel fuel.
- Fuel from fuel tank 22 may be initially drawn into a system of fuel lines by a transfer pump 24, which may be in fluid communication with the tank and a high pressure pump 26.
- Transfer pump 24 may have at least sufficient power to convey fuel from tank 22 to high pressure pump 26.
- High pressure pump 26 may be powered either directly or indirectly by rotation of crankshaft 20.
- a system of meshing gears between crankshaft 20 and the shaft input to high pressure pump 26 may provide a proportionally desired rotation. According to one embodiment, rotation of crankshaft 20 may bring the pressure of the fuel from high pressure pump 26 to approximately 300 MPa.
- High pressure pump 26 may also be in fluid communication with a common rail 28 and may be configured so as to convey pressurized fuel to common rail 28.
- Common rail 28 also known as a fuel manifold, may be in fluid communication with one or more fuel injectors 30. As illustrated in Fig. 1, each injector may be disposed within one of the four combustion chambers 18. Therefore common rail 28 may provide a supply of fuel at the desired pressure as induced by high pressure pump 26 to each of the fuel injectors 30. In such a configuration of the presently disclosed fuel supply system, each fuel injector of injectors 30 may selectively convey pressurized fuel from common rail 28 to a respective one of combustion chambers 18.
- Fuel system 12 may also work in conjunction with exhaust treatment system 14.
- Exhaust treatment system 14 may include an exhaust manifold 32 having exhaust passageways, each passageway being in fluid communication with an associated one of combustion chambers 18 of power unit 10.
- Exhaust manifold 32 may expel exhaust flow away from power unit 10 towards a housing 34 located downstream from exhaust manifold 32.
- Housing 34 of exhaust treatment system 14 may be a cylindrical or tubular conduit for directing exhaust gasses and particulates away from power unit 10 for processing by various emission controlling devices.
- exhaust manifold 32 may be integral with housing 34.
- an exhaust manifold and housing may be integrally stamped or forged from metal.
- exhaust manifold 32 may be secured to housing 34 by one or more fasteners (e.g., rivets, nuts and bolts, etc.) or by deformation (e.g., hemming).
- Housing 34 may also constitute structural support for at least one emission controlling device of the system.
- the at least one emission controlling device of exhaust treatment system 14 may include a particulate filter 36.
- Particulate filter 36 may be disposed across the cylindrical width (i.e., cross section) of housing 34. Furthermore, particulate filter 36 may be either removably or fixedly secured at its perimeter to housing 34.
- Particulate filter 36 may be any variety of diesel particulate filter ("DPF") such as, for example, a corderite or silicon carbide wall- flow filter, a metal fiber flow-through filter or a partial filter. According to one embodiment of the present disclosure, particulate filter 36 may be a wall-flow filter having at least 99% efficiency of particulate filtration.
- DPF diesel particulate filter
- exhaust treatment system 14 may include other components such as, for example, a turbine, an exhaust gas recirculation system, a catalytic treatment device, or any other exhaust system component known in the art. Exhaust treatment system 14 may also include devices that provide a supply of catalyst solution to a fuel or exhaust flow. Specifically, exhaust treatment system 14 may include a catalyst tank 38 configured to store a supply of catalyst.
- the catalyst also known as a fuel born catalyst (“FBC”), may include, for example, platinum, copper, cerium, manganese and/or iron compounds.
- FBC fuel born catalyst
- Exemplary commercial catalysts contemplated for use include Eolys®, which is marketed by Rhodia; Platinum Plus®, which is marketed by Clean Diesel Technologies; Octimax 4800®, which is marketed by Octel; and, MMT, which is marketed by Ethyl Corporation.
- the catalyst may be drawn from catalyst tank 38 by a pump 40, which is in fluid communication with catalyst tank 38.
- Pump 40 may also be in fluid communication with a catalyst injector 42 such that it may provide a supply of catalyst to the injector.
- catalyst injector 42 may be disposed at an upstream end of common rail 28.
- catalyst injector 42 may be mounted to common rail 28 such that the nozzle of the injector is in fluid communication with the pressurized fuel therein.
- catalyst injector 42 could alternatively inject catalyst directly into fuel tank 22, into fuel lines between tank 22 and common rail 28, or into fuel lines between common rail 28 and the individual injectors 30.
- it may be advantageous to inject the catalyst as close as possible to particulate filter 36 along the length of the fuel or exhaust flow in order to improve the responsiveness of the catalyst injection to a detected temperature deficiency.
- a catalyst injector may alternatively be disposed so as to inject the catalyst directly into an exhaust flow of exhaust treatment system 14.
- a catalyst injector 48 may replace catalyst injector 42 in the event that injection into an exhaust flow is desired over injection into a fuel supply.
- catalyst injector 48 may be mounted to housing 34 such that the nozzle of the injector is in fluid communication with the exhaust flow therein. Because catalyst injector 48 may be disposed upstream from particulate filter 36, injection of catalyst may affect regeneration at particulate filter 36.
- a sensor 46 may be disposed downstream from particulate filter 36. Specifically, sensor 46 may be mounted to housing 34 such that it may measure a temperature of the exhaust flow therein. Alternatively, sensor 46 may measure a temperature of particulate filter 36 and/or a temperature of its captured particulates. That is, sensor 46 may be thermally coupled with the particulate filter 36 so as to determine its temperature. Sensor 46 may also be located upstream of filter 36, if desired. In either embodiment, sensor 46 may be operable to generate a signal indicative of the temperature of particulate matter trapped within filter 36.
- Exhaust treatment system 14 may also include a controller 44 such as an electronic engine control module (“ECM”) or an injector control module.
- Controller 44 may be disposed in communication with sensor 46 and catalyst injector 42 to receive a temperature signal from sensor 46 and to transmit an injection signal to catalyst injector 42 in response thereto.
- Various circuits may be associated with controller 44 such as, for example, power supply circuitry, signal conditioning circuitry, solenoid driver circuitry, and other appropriate circuitry.
- controller 44 may be disposed in a location remote from housing 34 or common rail 28, if desired.
- the temperature of the exhaust flow and particulate filter may be estimated by controller 44 rather than measured by sensor 46.
- controller 44 may determine the temperature as a function of variables relating to one or more known operating conditions of power unit 10 and/or a vehicle associated therewith. For example, one or more engine performance maps relating a fueling amount, ignition timing, power output, engine speed, boost pressure, engine temperature, an air/fuel ratio, and/or other known parameters may be stored within the memory of controller 44. Each of these maps may be in the form of tables, graphs, and/or equations and include a compilation of data collected from lab and/or field operation of power unit 10. Controller 44 may reference one or more of these maps in order to estimate a temperature associated with particulate filter 36 for a given operating condition of power unit 10. Controller 44 may therefore create and store a continuous history of either measured or estimated temperature data from which decisions about catalyst injection may be made.
- Fig. 2 depicts an exemplary method according to one embodiment of the present disclosure. Fig. 2 will be described in the following section to better illustrate the disclosed system.
- the disclosed exhaust treatment system of the present disclosure may be applicable to any combustion-type device such as, for example, an engine, a furnace, or any other device known in the art wherein it is desirable to remove particulate pollutants from an exhaust flow.
- the disclosed exhaust treatment system may be a simple, inexpensive and compact solution for selectively injecting a fuel-born catalyst solution into a fuel stream or exhaust flow, as necessary, based on a measured or estimated temperature.
- power unit 10, fuel system 12 and exhaust treatment system 14 will now be explained.
- a supply of fuel may be stored in fuel tank 22 and drawn by transfer pump 24 for conveyance to high pressure pump 26. There, the fuel pressure may be increased substantially for delivery to common rail 28, which is in fluid communication with fuel injectors 30. Fuel may be injected into combustion chambers 18 of power unit 10 by fuel injectors 30, mixed with the air therein, and combusted by power unit 10 to produce a mechanical work output and an exhaust flow of hot gases.
- the exhaust flow may contain a complex mixture of air pollutants, which can include solid particulates such as soot. The release of soot into the environment may be minimized by passing the exhaust flow through particulate filter 36 of housing 34.
- soot laden exhaust flow is directed from the combustion chambers through particulate filter 36, soot may build up in the filter thereby adversely affecting engine performance.
- the soot will slowly "burn off' of the particulate filter over time.
- the temperature of the exhaust flow is lower than the oxidation temperature of the soot, such as during low load or during winter months, it may be desirable to inject a catalyst into either the fuel or exhaust flow in order to lower the oxidation temperature of the soot.
- catalyst injection may increase the soot oxidation rate to that sufficient for passive regeneration (i.e., soot removal at a rate equal to or higher than the soot filtration rate).
- the catalyst also known as a fuel born catalyst ("FBC"), may include, for example, platinum, copper, cerium, manganese and/or iron compounds. These oxidized metals may end up bonded to the soot that is trapped in the particulate filter so as to have the effect of catalyzing soot oxidation. That is, the oxidizing metals may lower the combustion threshold temperature of the soot to lower than the exhaust temperature, thereby facilitating relatively lower temperature regeneration.
- a passive-"plus" configuration may be employed wherein a supplemental heating source promotes regeneration.
- the temperature of the exhaust flow, particulate filter and/or particulates may be determined by sensor 46 (step 201). Temperature data may be communicated from sensor 46 to controller 44.
- controller 44 may estimate the exhaust flow temperature based on a known operation of power unit 10 (i.e., determined as a function of variables relating to power unit 10 and/or a vehicle associated therewith). Controller 44 may compare the measured or estimated exhaust temperature to the combustion threshold temperature of the particulates in order to determine whether or not the exhaust temperature is sufficient to support regeneration (step 203). Controller 44 may then send a signal instructing catalyst injection to a catalyst injector, such as catalyst injectors 42 and 44, in response to a determination that the exhaust temperature is insufficient for regeneration (step 205). In one embodiment, controller 44 sends an injection signal in response to a determination that the exhaust temperature has been continually insufficient for regeneration over a particular time interval.
- a catalyst injector such as catalyst injectors 42 and 44
- Catalyst may be injected into either fuel tank 22, common rail 28 (e.g., by catalyst injector 42 as illustrated), the fuel lines between fuel tank 22 and common rail 28, or the fuel lines between common rail 28 and fuel injectors 30. Catalyst may alternatively be injected into the exhaust flow at a location upstream from particulate filter 36 by catalyst injector 48. Once particulate filter 36 has been regenerated or the engine has attained sufficiently high temperatures, controller 44 may instruct the one or more catalyst injectors to cease FBC injection.
- the presently disclosed use of selective catalyst injection may be an ideal way to induce more efficient oxidation of trapped particulates. For example, it has been found that when used with a wall-flow filter, approximately 99% of fuel born catalysts may be filtered out or left in the engine oil or liner. Moreover, FBC injection may reduce the threshold temperature for passive regeneration by as much as 100°C from the average combustion temperature of 300-350°C. That is, particulate material may be oxidized at the same rate from which it is filtered from the exhaust, even at only 250-300°C. However, the ash created during oxidation of FBC-bonded particulates may make it especially desirable to streamline catalyst injection by use of the presently disclosed concepts.
- the benefit of selective catalyst additive may be evidenced in that even with only a 5 ppm FBC additive level, the amount of ash trapped by the filter is doubled over that trapped without use of an additive (250,000 miles: roughly 25 g/liter ash from lube oil, 25 g/liter ash due to FBC).
- the advantages of FBC dosing reduction on ash production was further established by a study in "Diesel Particulate Filter Maintenance: Current Practices and Experience", June 2005, MECA. There, it was found that a reduction in FBC dosing from 25 ppm of FBC to 10 ppm of FBC resulted in a reduction in the proportion of FBC ash mass from approximately 80% to about 57%. Thus, there is a great incentive to reducing the amount of catalyst additive.
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- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE112007002555T DE112007002555T5 (en) | 2006-10-31 | 2007-10-12 | Temperature-based selective injection of an oxidation catalyst |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/589,833 US7669409B2 (en) | 2006-10-31 | 2006-10-31 | Selective oxidation catalyst injection based on temperature |
US11/589,833 | 2006-10-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008054631A1 true WO2008054631A1 (en) | 2008-05-08 |
Family
ID=39113969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/021913 WO2008054631A1 (en) | 2006-10-31 | 2007-10-12 | Selective oxidation catalyst injection based on temperature |
Country Status (5)
Country | Link |
---|---|
US (1) | US7669409B2 (en) |
CN (1) | CN101529060A (en) |
DE (1) | DE112007002555T5 (en) |
RU (1) | RU2464428C2 (en) |
WO (1) | WO2008054631A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2415988A1 (en) | 2010-08-06 | 2012-02-08 | Caterpillar Motoren GmbH & Co. KG | Two-stage turbocharged engine |
EP2527610A1 (en) | 2011-05-27 | 2012-11-28 | Caterpillar Motoren GmbH & Co. KG | SCR catalyst for a two-stage turbocharged engine |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US9194272B2 (en) * | 2008-12-02 | 2015-11-24 | Caterpillar Inc. | Power system |
DE102010039020A1 (en) * | 2010-08-06 | 2012-02-09 | Robert Bosch Gmbh | Method and apparatus for regeneration of a particulate filter |
DE102010038143A1 (en) * | 2010-10-13 | 2012-04-19 | Hjs Emission Technology Gmbh & Co. Kg | A method of lowering the soot ignition temperature of soot accumulated on a particulate filter |
GB201021887D0 (en) | 2010-12-21 | 2011-02-02 | Johnson Matthey Plc | Oxidation catalyst for a lean burn internal combustion engine |
JP2013076366A (en) * | 2011-09-30 | 2013-04-25 | Kubota Corp | Common rail engine |
JP2016094845A (en) | 2014-11-12 | 2016-05-26 | いすゞ自動車株式会社 | Internal combustion engine and particular substance removal method of internal combustion engine |
US10215144B1 (en) * | 2017-10-11 | 2019-02-26 | Robert Bosch Gmbh | Fuel system with switchable pressure regulation |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61164015A (en) * | 1985-01-14 | 1986-07-24 | Mazda Motor Corp | Exhaust gas purifying device of engine |
US4631076A (en) * | 1983-11-30 | 1986-12-23 | Tokyo Roki Co., Ltd. | Apparatus for removing carbon particles from exhaust gas from internal combustion engine |
DE19504182A1 (en) * | 1995-02-09 | 1996-08-14 | Eberspaecher J | Operating diesel particle filter equipped with auxiliary burner |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4359862A (en) * | 1980-10-27 | 1982-11-23 | Texaco Inc. | Method for treating an exhaust gas stream |
US4665690A (en) * | 1985-01-14 | 1987-05-19 | Mazda Motor Corporation | Exhaust gas cleaning system for vehicle |
US6051040A (en) * | 1988-12-28 | 2000-04-18 | Clean Diesel Technologies, Inc. | Method for reducing emissions of NOx and particulates from a diesel engine |
RU2027870C1 (en) * | 1990-09-10 | 1995-01-27 | Романов Геннадий Николаевич | Method and device for reduction of toxicity of exhaust gases of power plant |
RU2049242C1 (en) * | 1991-10-15 | 1995-11-27 | Иван Иванович Кутыш | Method of catalytic purifying of exhaust gases |
DE69306715T2 (en) * | 1992-09-28 | 1997-04-30 | Ford Werke Ag | Device for controlling particle and exhaust gas emissions |
US6003303A (en) * | 1993-01-11 | 1999-12-21 | Clean Diesel Technologies, Inc. | Methods for reducing harmful emissions from a diesel engine |
JP3562004B2 (en) * | 1995-02-02 | 2004-09-08 | 日産自動車株式会社 | Catalyst purification device for internal combustion engine |
DE19504450A1 (en) * | 1995-02-10 | 1996-08-22 | Florian Gamel | Exhaust gas purification device for internal combustion engines |
AU707792B2 (en) * | 1995-04-24 | 1999-07-22 | Associated Octel Company Limited, The | Improved combustion |
JP3089989B2 (en) * | 1995-05-18 | 2000-09-18 | トヨタ自動車株式会社 | Diesel engine exhaust purification system |
CA2205143C (en) * | 1996-05-14 | 2003-07-15 | Ethyl Corporation | Enhanced combustion of hydrocarbonaceous burner fuels |
TW509719B (en) * | 1997-04-17 | 2002-11-11 | Clean Diesel Tech Inc | Method for reducing emissions from a diesel engine |
US6237326B1 (en) | 1999-08-24 | 2001-05-29 | Ford Global Technolgies, Inc. | Engine control system and method with lean catalyst and particulate filter |
FR2804175B1 (en) | 2000-01-20 | 2002-04-12 | Peugeot Citroen Automobiles Sa | SYSTEM FOR AIDING THE REGENERATION OF A PARTICLE FILTER INTEGRATED IN AN EXHAUST LINE OF A DIESEL ENGINE OF A MOTOR VEHICLE |
FR2804169B1 (en) * | 2000-01-20 | 2002-04-12 | Peugeot Citroen Automobiles Sa | SYSTEM FOR AIDING THE REGENERATION OF A PARTICLE FILTER INTEGRATED IN AN EXHAUST LINE OF A DIESEL ENGINE OF A MOTOR VEHICLE |
US6629407B2 (en) * | 2000-12-12 | 2003-10-07 | Ethyl Corporation | Lean burn emissions system protectant composition and method |
JP3757856B2 (en) | 2001-12-07 | 2006-03-22 | トヨタ自動車株式会社 | Exhaust gas purification device |
JP3757894B2 (en) | 2002-04-15 | 2006-03-22 | トヨタ自動車株式会社 | Exhaust purification device for internal combustion engine and exhaust purification method for internal combustion engine |
US20030226312A1 (en) * | 2002-06-07 | 2003-12-11 | Roos Joseph W. | Aqueous additives in hydrocarbonaceous fuel combustion systems |
US6820414B2 (en) | 2002-07-11 | 2004-11-23 | Fleetguard, Inc. | Adsorber aftertreatment system having downstream soot filter |
US20040074140A1 (en) * | 2002-10-16 | 2004-04-22 | Guinther Gregory H. | Method of enhancing the operation of a diesel fuel combustion after treatment system |
JP4288985B2 (en) | 2003-03-31 | 2009-07-01 | 株式会社デンソー | Exhaust gas purification device for internal combustion engine |
US7031827B2 (en) * | 2003-04-11 | 2006-04-18 | Ford Global Technologies, Llc | Computer algorithm to estimate particulate filter regeneration rates |
US7047729B2 (en) | 2003-10-27 | 2006-05-23 | Ford Global Technologies, Llc | Control method and system for diesel particulate filter regeneration |
US7152397B2 (en) * | 2003-11-07 | 2006-12-26 | Peugeot Citroen Automobiles Sa | Additional system for assisting regeneration of pollution control means of a motor vehicle |
US6862881B1 (en) * | 2003-12-05 | 2005-03-08 | Caterpillar Inc | Method and apparatus for controlling regeneration of a particulate filter |
JP4301070B2 (en) | 2004-04-30 | 2009-07-22 | 株式会社デンソー | Exhaust gas purification device for internal combustion engine |
US7210286B2 (en) | 2004-12-20 | 2007-05-01 | Detroit Diesel Corporation | Method and system for controlling fuel included within exhaust gases to facilitate regeneration of a particulate filter |
-
2006
- 2006-10-31 US US11/589,833 patent/US7669409B2/en not_active Expired - Fee Related
-
2007
- 2007-10-12 RU RU2009120591/06A patent/RU2464428C2/en not_active IP Right Cessation
- 2007-10-12 CN CNA2007800403458A patent/CN101529060A/en active Pending
- 2007-10-12 DE DE112007002555T patent/DE112007002555T5/en not_active Withdrawn
- 2007-10-12 WO PCT/US2007/021913 patent/WO2008054631A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4631076A (en) * | 1983-11-30 | 1986-12-23 | Tokyo Roki Co., Ltd. | Apparatus for removing carbon particles from exhaust gas from internal combustion engine |
JPS61164015A (en) * | 1985-01-14 | 1986-07-24 | Mazda Motor Corp | Exhaust gas purifying device of engine |
DE19504182A1 (en) * | 1995-02-09 | 1996-08-14 | Eberspaecher J | Operating diesel particle filter equipped with auxiliary burner |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2415988A1 (en) | 2010-08-06 | 2012-02-08 | Caterpillar Motoren GmbH & Co. KG | Two-stage turbocharged engine |
EP2415989A1 (en) | 2010-08-06 | 2012-02-08 | Caterpillar Motoren GmbH & Co. KG | Two-stage turbocharged engine |
WO2012016712A1 (en) | 2010-08-06 | 2012-02-09 | Caterpillar Motoren Gmbh & Co. Kg | Two-stage turbocharged engine |
US8978359B2 (en) | 2010-08-06 | 2015-03-17 | Caterpillar Motoren Gmbh & Co. Kg | Two-stage turbocharged engine |
EP2527610A1 (en) | 2011-05-27 | 2012-11-28 | Caterpillar Motoren GmbH & Co. KG | SCR catalyst for a two-stage turbocharged engine |
WO2012163510A1 (en) | 2011-05-27 | 2012-12-06 | Caterpillar Motoren Gmbh & Co. Kg | Scr catalyst for a two-stage turbocharged engine |
Also Published As
Publication number | Publication date |
---|---|
RU2009120591A (en) | 2010-12-10 |
DE112007002555T5 (en) | 2009-09-10 |
RU2464428C2 (en) | 2012-10-20 |
US20080098727A1 (en) | 2008-05-01 |
US7669409B2 (en) | 2010-03-02 |
CN101529060A (en) | 2009-09-09 |
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