WO2008051548A2 - Apertured webs and methods and apparatus for making - Google Patents
Apertured webs and methods and apparatus for making Download PDFInfo
- Publication number
- WO2008051548A2 WO2008051548A2 PCT/US2007/022497 US2007022497W WO2008051548A2 WO 2008051548 A2 WO2008051548 A2 WO 2008051548A2 US 2007022497 W US2007022497 W US 2007022497W WO 2008051548 A2 WO2008051548 A2 WO 2008051548A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- non woven
- woven web
- softening
- web
- perforation
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26F—PERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
- B26F1/00—Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
- B26F1/24—Perforating by needles or pins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/18—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets by squeezing between surfaces, e.g. rollers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/558—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in combination with mechanical or physical treatments other than embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26D—CUTTING; DETAILS COMMON TO MACHINES FOR PERFORATING, PUNCHING, CUTTING-OUT, STAMPING-OUT OR SEVERING
- B26D7/00—Details of apparatus for cutting, cutting-out, stamping-out, punching, perforating, or severing by means other than cutting
- B26D7/08—Means for treating work or cutting member to facilitate cutting
- B26D7/10—Means for treating work or cutting member to facilitate cutting by heating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C23/00—Making patterns or designs on fabrics
- D06C23/04—Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
Definitions
- the present invention relates to apertured webs and methods for making such webs.
- apertured webs are used in various industrial and consumer products sectors. For example, apertured webs are used to produce disposable sheets, disposable garments and hygiene and sanitary products, such as sanitary napkins, incontinence pads and baby diapers.
- Apertured webs can be manufactured using various techniques.
- one technique for forming apertured webs entails extruding a plastic sheet of film using traditional film extrusion techniques (for example, a thin sheet of LDPE delivered through a cast or blown extrusion head,) and aperturing the film using solid or molten phase forming techniques as known in the art (e.g., water perforation techniques, mechanical perforation techniques, etc.)
- the film may be textured as well via mechanical or water embossing, or other methods as are known in the art.
- thermo-mechanical contact perforation such as pin perforation or engraved cylinder that is in contact with a smooth cylinders as described in Patents # Giacometti 5814389; Pohland US 4128679 and Van Iten 4886632, however thermo-mechanical contact perforation may lead to an undesirable crispiness around the perimeter of the holes, however.
- the web and any products produced from the web may be less than pleasingly soft, as during the perforation step the heat and pressure that was used to assist in forming the aperture may render the material stiff around the hole because it forces the fibers adjacent to the hole to become oriented in a cluster of tangled densified fibers. As a consequence the web and/or product made from the web may have a stiff or scratchy or similar, generally unpleasant, sensation.
- FIG. 1 shows an embodiment of pin perforation system
- FIG. 2 shows a view of another embodiment.
- the present invention relates to apertured webs and methods for making such webs.
- Webs are perforated using a mechanical process such as pin perforation or a cylinder with raised protuberances.
- the web is then softened using a mechanical process. It should be noted that softening can occur after the perforation during assembly of product using a web.
- machine direction means the direction in which webs are formed, which is the longitudinal direction of an uncut web.
- transverse direction means the cross direction, disposed at 90° to the machine direction, and extending across the width of the initially formed precursor web.
- the web is a thermoplastic sheet.
- Embodiments may also be subsequently finished or semi finished or treated in some manner, e.g., a nonwoven with fiber like surface.
- a web comprised of a thermoplastic nonwoven, with a fiber like surface, is pin perforated and so an aperture is created.
- the aperture comprises a ring of molten mass of plastic surrounding a perforation.
- a fiber reorientation device called ring roll is used to soften the web.
- a set of adjacent rings on a roller stretches the web in the cross direction. Hole geometry generally remains as it was when perforated. However, the area around the perforation is stressed by passing over the rings, and so the fibers planar orientation is disrupted, and caused to extend out of the plane of the web. This disruption and subsequent fiber extension out of the plane of the web renders the web softer to the touch.
- the basis weight of the web subsequent to the softening is decreased however by an amount less than 25%.
- FIG. 1 an embodiment is seen in the pin perforation stage.
- Web 10 passes through thermo-mechanical contact process consisting of pin perforation rollers seen generally at 20.
- Roller 22 contains pins as are desired, which perforate web 10, as web 10 moves past the roller.
- FIG. 2 shows a softening embodiment.
- perforated web 102 moves past ring rollers shown generally at 132.
- Rollers 134 and 136, with rings 160 and 161 and interring spacing at 162 and 163, provide the stress required to soften apertures such as those seen at 204.
- embodiments may provide for varying sizes, shapes, etc. in whole or part, of apertures through varying parameters in various embodiments.
- Embodiments may also provide for varying degrees of softening, through varying various parameters in the process.
- rings may be of various geometries, spacing and the like.
- a nonwoven formed in accordance with the embodiments may be used as desired.
- various embodiments may be used, in whole or part, in various types of articles, such as, for example, a topsheet or other parts of absorbent articles, including adult, child or infant incontinence products (for example, diapers, briefs, etc.,) female hygiene products (for example, female menstrual products, sanitary napkins, pantiliners, etc.,) wraps, including sterile and nonsterile (e.g.
- bandages with and without absorbent sections,) as well as other disposable and/or multiple use products e.g., articles proximate to a human or animal body, such as for example, garments, apparel, including undergarments, under- and outer-wear, for example, undershirts, bras, briefs, panties, etc., bathing suits, coveralls, socks, head coverings and bands, hats, mitten and glove liners, medical clothing, etc.; bed sheets; medical drapes; packaging materials; protective covers; household; office; medical or construction materials; wrapping materials; etc. therapeutic devices and wraps.
- garments, apparel including undergarments, under- and outer-wear, for example, undershirts, bras, briefs, panties, etc., bathing suits, coveralls, socks, head coverings and bands, hats, mitten and glove liners, medical clothing, etc.
- bed sheets medical drapes
- packaging materials protective covers
- household office
- medical or construction materials wrapping materials
- wrapping materials etc. therapeutic devices and wraps.
- Further treatment may also be desired, such as supplementary bonding processes, embossing processes, perforation processes, mechanical activation processes, combinations of these, etc.
- Embodiments may also be combined with a component or components to form laminate or composite materials, finished and semi-finished, etc. which, if desired, may be further treated through embossing, perforating etc. sewing, bonding, printing, cutting, shaping, gluing, fluting, sterilizing, etc. combination with or independently of other processes as are known in the art.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Forests & Forestry (AREA)
- Textile Engineering (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Methods, Apparatus and Articles of Manufacture are shown for softening an apertured web.
Description
APERTURED WEBS AND METHODS AND APPARATUS FOR MAKING
FIELD OF THE INVENTION
The present invention relates to apertured webs and methods for making such webs.
BACKGROUND OF THE INVENTION
Apertured webs are used in various industrial and consumer products sectors. For example, apertured webs are used to produce disposable sheets, disposable garments and hygiene and sanitary products, such as sanitary napkins, incontinence pads and baby diapers.
Apertured webs can be manufactured using various techniques. For example, one technique for forming apertured webs entails extruding a plastic sheet of film using traditional film extrusion techniques (for example, a thin sheet of LDPE delivered through a cast or blown extrusion head,) and aperturing the film using solid or molten phase forming techniques as known in the art (e.g., water perforation techniques, mechanical perforation techniques, etc.) The film may be textured as well via mechanical or water embossing, or other methods as are known in the art.
Another technique manufacturers for creating apertured webs particularly fiber based apertured webs calls for using thermo-mechanical contact perforation such as pin perforation or engraved cylinder that is in contact with a smooth cylinders as described in Patents # Giacometti 5814389; Pohland US 4128679 and Van Iten 4886632, however
thermo-mechanical contact perforation may lead to an undesirable crispiness around the perimeter of the holes, however. The web and any products produced from the web may be less than pleasingly soft, as during the perforation step the heat and pressure that was used to assist in forming the aperture may render the material stiff around the hole because it forces the fibers adjacent to the hole to become oriented in a cluster of tangled densified fibers. As a consequence the web and/or product made from the web may have a stiff or scratchy or similar, generally unpleasant, sensation.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows an embodiment of pin perforation system
FIG. 2 shows a view of another embodiment.
DETAILED DESCRIPTION OF THE EMBODIMENTS
The present invention relates to apertured webs and methods for making such webs. Webs are perforated using a mechanical process such as pin perforation or a cylinder with raised protuberances. The web is then softened using a mechanical process. It should be noted that softening can occur after the perforation during assembly of product using a web.
As used herein, the term "machine direction" means the direction in which webs are formed, which is the longitudinal direction of an uncut web.
As used herein, the term "transverse direction" means the cross direction, disposed at 90° to the machine direction, and extending across the width of the initially formed precursor web.
In preferred embodiments, the web is a thermoplastic sheet. Embodiments may also be subsequently finished or semi finished or treated in some manner, e.g., a nonwoven with fiber like surface.
In especially preferred embodiments, a web, comprised of a thermoplastic nonwoven, with a fiber like surface, is pin perforated and so an aperture is created. The aperture comprises a ring of molten mass of plastic surrounding a perforation.
Following perforation the web is introduced into a softening device. In this especially preferred embodiment, a fiber reorientation device called ring roll is used to soften the web. A set of adjacent rings on a roller, stretches the web in the cross direction. Hole geometry generally remains as it was when perforated. However, the area around the perforation is stressed by passing over the rings, and so the fibers planar orientation is disrupted, and caused to extend out of the plane of the web. This disruption and subsequent fiber extension out of the plane of the web renders the web softer to the touch. The basis weight of the web subsequent to the softening is decreased however by an amount less than 25%.
It may be desired in certain preferred embodiments to treat various areas of a web, or semi finished or finished products differently (referred to herein as "products,") such as when patterns or other areas are interposed through perforations. Moreover, as was
described above, softening may occur to a web, to a semi finished product or to a finished product.
Turing briefly to Figure 1, an embodiment is seen in the pin perforation stage. Web 10 passes through thermo-mechanical contact process consisting of pin perforation rollers seen generally at 20. Roller 22 contains pins as are desired, which perforate web 10, as web 10 moves past the roller.
Figure 2 shows a softening embodiment. As can be seen perforated web 102 (with perforations shown at 202) moves past ring rollers shown generally at 132. Rollers 134 and 136, with rings 160 and 161 and interring spacing at 162 and 163, provide the stress required to soften apertures such as those seen at 204.
It should be noted as well that embodiments may provide for varying sizes, shapes, etc. in whole or part, of apertures through varying parameters in various embodiments. Embodiments may also provide for varying degrees of softening, through varying various parameters in the process. For example, in fiber reorientation or ring rolling embodiment, rings may be of various geometries, spacing and the like.
A nonwoven formed in accordance with the embodiments may be used as desired. For example, various embodiments may be used, in whole or part, in various types of articles, such as, for example, a topsheet or other parts of absorbent articles, including adult, child or infant incontinence products (for example, diapers, briefs, etc.,) female hygiene products (for example, female menstrual products, sanitary napkins, pantiliners, etc.,) wraps, including sterile and nonsterile (e.g. bandages with and without absorbent
sections,) as well as other disposable and/or multiple use products; e.g., articles proximate to a human or animal body, such as for example, garments, apparel, including undergarments, under- and outer-wear, for example, undershirts, bras, briefs, panties, etc., bathing suits, coveralls, socks, head coverings and bands, hats, mitten and glove liners, medical clothing, etc.; bed sheets; medical drapes; packaging materials; protective covers; household; office; medical or construction materials; wrapping materials; etc. therapeutic devices and wraps.
Further treatment may also be desired, such as supplementary bonding processes, embossing processes, perforation processes, mechanical activation processes, combinations of these, etc.
Embodiments may also be combined with a component or components to form laminate or composite materials, finished and semi-finished, etc. which, if desired, may be further treated through embossing, perforating etc. sewing, bonding, printing, cutting, shaping, gluing, fluting, sterilizing, etc. combination with or independently of other processes as are known in the art.
Although the present invention has been described with respect to various specific embodiments, various modifications will be apparent from the present disclosure and are intended to be within the scope of the following claims.
Claims
1. A method for softening apertured non woven webs, comprising;
- aperturing a non woven web through thermo-mechanical contact perforation; and,
- softening said non woven web through the re-orientation of the fibers while keeping the basis weight of the webs within an acceptable range.
2. A method as in claim 1 wherein said non woven web is comprised of a thermoplastic non woven web and a polymeric film.
3. A method for softening products, comprised of a non woven web, comprising:
- aperturing said non woven web through thermo-mechanical contact perforation; and,
- softening said non woven web through the re-orientation of the fibers while keeping the basis weight of the webs within an acceptable range.
4. Apparatus for softening apertured non woven webs, comprising;
- raised protuberances as perforation means for aperturing a non woven web through thermo-mechanical contact perforation;
and,
- in means for softening said non woven web through a set of rolls that alter the orientation of the fibers from planar to three dimensional.
5. An apparatus as in claim 4 wherein said non woven web is comprised of a thermoplastic non woven web.
6. Apparatus for softening products, comprised of a non woven web, comprising:
- A thermo-mechanical contact perforation means for aperturing said non woven web through protuberances perforation; and,
- incrementally stretching means for softening said non woven web through ring rolling.
7. A non woven web comprising; - an apertured, softened non woven web, wherein said apertures have been provided through thermo-mechanical contact perforation; and, said softening has been provided through an incremental stretching device means.
8. An article as in claim 7 wherein said non woven web is comprised of a thermoplastic non woven web.
9. An article comprised of an apertured, softened non woven web, wherein said apertures have been provided through thermo-mechanical contact perforation; and, said softening has been provided through fiber re-orientation means.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07852907.0A EP2089566B1 (en) | 2006-10-23 | 2007-10-23 | Methods for making of apertured webs |
CN2007800392129A CN101529005B (en) | 2006-10-23 | 2007-10-23 | Apertured webs and methods and apparatus for making same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US85360106P | 2006-10-23 | 2006-10-23 | |
US60/853,601 | 2006-10-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008051548A2 true WO2008051548A2 (en) | 2008-05-02 |
WO2008051548A3 WO2008051548A3 (en) | 2008-09-18 |
Family
ID=39325167
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/022497 WO2008051548A2 (en) | 2006-10-23 | 2007-10-23 | Apertured webs and methods and apparatus for making |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2089566B1 (en) |
CN (1) | CN101529005B (en) |
WO (1) | WO2008051548A2 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9067334B2 (en) | 2009-03-24 | 2015-06-30 | Advantage Creation Enterprise Llc | Embossed textured webs and method for making |
US9849602B2 (en) | 2009-12-18 | 2017-12-26 | Advantage Creation Enterprise Llc | Method for making extrusion coated perforated nonwoven web |
US11083641B2 (en) | 2017-03-13 | 2021-08-10 | Fitesa Film Products Llc | Method of manufacturing an activated composite web and an activated composite web for absorptive devices |
US11149360B2 (en) | 2017-06-30 | 2021-10-19 | The Procter & Gamble Company | Method for making a shaped nonwoven |
US11160694B2 (en) * | 2017-01-31 | 2021-11-02 | The Procter & Gamble Company | Three-dimensional substrates and absorbent articles having the same |
US11214893B2 (en) | 2017-06-30 | 2022-01-04 | The Procter & Gamble Company | Shaped nonwoven |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102862185B (en) * | 2012-09-19 | 2015-09-16 | 缪国兴 | A kind of amenities punch device and apply the amenities production technology of this equipment |
JP6830864B2 (en) * | 2017-06-30 | 2021-02-17 | ユニ・チャーム株式会社 | Absorbent article and manufacturing method of absorbent article |
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US4128679A (en) | 1971-11-17 | 1978-12-05 | Firma Carl Freudenberg | Soft, non-woven fabrics and process for their manufacture |
US4285100A (en) | 1975-03-31 | 1981-08-25 | Biax Fiberfilm Corporation | Apparatus for stretching a non-woven web or an orientable polymeric material |
US4886632A (en) | 1985-09-09 | 1989-12-12 | Kimberly-Clark Corporation | Method of perforating a nonwoven web and use of the web as a cover for a feminine pad |
US5814389A (en) | 1992-11-17 | 1998-09-29 | Pantex, S.R.L. | Apertured three-dimensional product in membrane or film form for covering sanitary, disposable absorbent products |
DE19750459A1 (en) | 1997-11-14 | 1999-05-27 | Kuesters Eduard Maschf | Calender for perforating a nonwoven web |
WO2004007158A1 (en) | 2002-07-16 | 2004-01-22 | Corovin Gmbh | Device and method of liquid-permeable perforation of a nonwoven |
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US4276336A (en) * | 1979-04-23 | 1981-06-30 | Sabee Products, Inc. | Multi-apertured web with incremental orientation in one or more directions |
US4588630A (en) * | 1984-06-13 | 1986-05-13 | Chicopee | Apertured fusible fabrics |
CA2148289C (en) * | 1994-05-20 | 2006-01-10 | Ruth Lisa Levy | Perforated nonwoven fabrics |
US6025050A (en) * | 1994-06-15 | 2000-02-15 | Bba Nonwovens Simpsonville, Inc. | Thermally appertured nonwoven laminates for wipes and coverstock for hygienic articles |
CN1046977C (en) * | 1996-11-06 | 1999-12-01 | 优雅不织布工业股份有限公司 | Method for processing nonwoven fabrics by heat treatment and mechanic treatment |
ATE541543T1 (en) * | 1999-12-21 | 2012-02-15 | Procter & Gamble | MULTI-LAYER WEB COMPRISING AN APERIFIED LAYER AND METHOD FOR PRODUCING THE SAME |
US20040121120A1 (en) * | 2002-12-20 | 2004-06-24 | The Procter & Gamble Company | Apparatus for making a polymeric web exhibiting a soft and silky tactile impression |
-
2007
- 2007-10-23 EP EP07852907.0A patent/EP2089566B1/en not_active Not-in-force
- 2007-10-23 WO PCT/US2007/022497 patent/WO2008051548A2/en active Application Filing
- 2007-10-23 CN CN2007800392129A patent/CN101529005B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US4128679A (en) | 1971-11-17 | 1978-12-05 | Firma Carl Freudenberg | Soft, non-woven fabrics and process for their manufacture |
US4285100A (en) | 1975-03-31 | 1981-08-25 | Biax Fiberfilm Corporation | Apparatus for stretching a non-woven web or an orientable polymeric material |
US4886632A (en) | 1985-09-09 | 1989-12-12 | Kimberly-Clark Corporation | Method of perforating a nonwoven web and use of the web as a cover for a feminine pad |
US5814389A (en) | 1992-11-17 | 1998-09-29 | Pantex, S.R.L. | Apertured three-dimensional product in membrane or film form for covering sanitary, disposable absorbent products |
DE19750459A1 (en) | 1997-11-14 | 1999-05-27 | Kuesters Eduard Maschf | Calender for perforating a nonwoven web |
WO2004007158A1 (en) | 2002-07-16 | 2004-01-22 | Corovin Gmbh | Device and method of liquid-permeable perforation of a nonwoven |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9067334B2 (en) | 2009-03-24 | 2015-06-30 | Advantage Creation Enterprise Llc | Embossed textured webs and method for making |
US10729597B2 (en) | 2009-03-24 | 2020-08-04 | Advantage Creation Enterprise Llc | Embossed textured webs and method for making |
US9849602B2 (en) | 2009-12-18 | 2017-12-26 | Advantage Creation Enterprise Llc | Method for making extrusion coated perforated nonwoven web |
US10821622B2 (en) | 2009-12-18 | 2020-11-03 | Advantage Creation Enterprise Llc | Extrusion coated perforated nonwoven web and method for making |
US11160694B2 (en) * | 2017-01-31 | 2021-11-02 | The Procter & Gamble Company | Three-dimensional substrates and absorbent articles having the same |
US11083641B2 (en) | 2017-03-13 | 2021-08-10 | Fitesa Film Products Llc | Method of manufacturing an activated composite web and an activated composite web for absorptive devices |
US11149360B2 (en) | 2017-06-30 | 2021-10-19 | The Procter & Gamble Company | Method for making a shaped nonwoven |
US11214893B2 (en) | 2017-06-30 | 2022-01-04 | The Procter & Gamble Company | Shaped nonwoven |
US11634838B2 (en) | 2017-06-30 | 2023-04-25 | The Procter & Gamble Company | Shaped nonwoven |
US11746441B2 (en) | 2017-06-30 | 2023-09-05 | The Procter & Gamble Company | Method for making a shaped nonwoven |
US11939701B2 (en) | 2017-06-30 | 2024-03-26 | The Procter & Gamble Company | Shaped nonwoven |
Also Published As
Publication number | Publication date |
---|---|
CN101529005B (en) | 2012-10-10 |
EP2089566A4 (en) | 2011-06-08 |
CN101529005A (en) | 2009-09-09 |
WO2008051548A3 (en) | 2008-09-18 |
EP2089566B1 (en) | 2014-01-22 |
EP2089566A2 (en) | 2009-08-19 |
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