WO2008050812A1 - Ceramic porous membrane and ceramic filter - Google Patents

Ceramic porous membrane and ceramic filter Download PDF

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Publication number
WO2008050812A1
WO2008050812A1 PCT/JP2007/070761 JP2007070761W WO2008050812A1 WO 2008050812 A1 WO2008050812 A1 WO 2008050812A1 JP 2007070761 W JP2007070761 W JP 2007070761W WO 2008050812 A1 WO2008050812 A1 WO 2008050812A1
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WO
WIPO (PCT)
Prior art keywords
membrane
silica
titania
ceramic
porous
Prior art date
Application number
PCT/JP2007/070761
Other languages
French (fr)
Inventor
Manabu Isomura
Tatsuya Hishiki
Ichiro Wada
Original Assignee
Ngk Insulators, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ngk Insulators, Ltd. filed Critical Ngk Insulators, Ltd.
Priority to JP2009511293A priority Critical patent/JP5394234B2/en
Priority to CA 2666274 priority patent/CA2666274C/en
Priority to CN2007800388104A priority patent/CN101528330B/en
Priority to AU2007310055A priority patent/AU2007310055B2/en
Priority to EP07830495.3A priority patent/EP2083940B1/en
Priority to BRPI0717524-8A2A priority patent/BRPI0717524A2/en
Publication of WO2008050812A1 publication Critical patent/WO2008050812A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0048—Inorganic membrane manufacture by sol-gel transition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/066—Tubular membrane modules with a porous block having membrane coated passages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/28—Pore treatments
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y10T428/249956—Void-containing component is inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y10T428/249956—Void-containing component is inorganic
    • Y10T428/249957—Inorganic impregnant

Definitions

  • the present invention relates to a ceramic porous membrane and a ceramic filter. More particularly, it relates to a ceramic porous membrane having less defects and having a small and uniform thickness, and a ceramic filter.
  • Non-Patent Document 1 This is a method of rubbing a tube base with cloth containing a silica sol to apply the silica sol and thereby form a porous membrane on an outer surface of the heated tube base.
  • a method of forming a porous membrane on an inner surface of a porous base member having a tubular shape or a cylindrical lotus-root-like monolith shape by filtering membrane formation is also known (see Patent Documents 1, 2) .
  • the outer surface of the porous base member is held at a pressure lower than that of an inner surface thereof which comes in contact with a sol liquid to form the membrane on the inner surface of the porous base member.
  • Patent Document 1 Japanese Patent Application Laid- Open No. 3-267129
  • Patent Document 2 Japanese Patent Application Laid- Open No. 61-238315
  • Non-Patent Document 1 Journal of Membrane Science 149 (1988) 127 to 135 [0005]
  • the hot coating process has a problem that the membrane cannot uniformly be formed on the whole base surface, and the membrane can be formed on the only outer surface of the tube base.
  • the process cannot be applied to any monolith-type base.
  • the filtering membrane formation process during drying of the formed membrane, a solvent present in base pores sometimes flows out on a membrane side to cause membrane peeling. As a result, there is a problem that a defect is generated in the porous membrane formed on the fired base surface.
  • a dip coating process can be applied to the monolith type base, but the number of membrane formation times is large.
  • An object of the present invention is to provide a ceramic porous membrane formed with less membrane formation times and having less defects, a small and uniform thickness and a high resolution, and a ceramic filter.
  • the present inventors have found that the above- mentioned object can be achieved using a constitution in which the ceramic porous membrane is formed on an ultrafiltration membrane so as to partially permeate pores of the ultrafiltration membrane. That is, according to the present invention, the following ceramic porous membrane and ceramic filter are provided.
  • a ceramic porous membrane which is formed on an ultrafiltration membrane having an average pore diameter of 2 to 20 nm and which partially permeates pores of the ultrafiltration membrane.
  • a ceramic filter comprising: a porous base member; an ultrafiltration membrane formed on the porous base member and having an average pore diameter of 2 to 20 nm; and a ceramic porous membrane which is formed on the ultrafiltration membrane and which partially permeates pores of the ultrafiltration membrane.
  • the thin ceramic porous membrane having less defects can be formed using a constitution of the ceramic porous membrane which is formed on the ultrafiltration membrane having an average pore diameter of 2 to 20 nra and which partially permeates the pores of the ultrafiltration membrane. According to a structure in which a part of the ceramic porous membrane infiltrates the ultrafiltration membrane, influences of an uneven surface of a porous base member are reduced, and the ceramic porous membrane having less defects and having a dehydrating function with a high resolution can be obtained. Furthermore, when such a structure is used, the ceramic porous membrane having a high performance can be obtained with reduced costs.
  • the silica membrane is used as the ceramic porous membrane, the membrane is especially preferable for an application of dehydration of alcohol such as ethanol or isopropyl alcohol or an organic acid such as acetic acid.
  • FIG. 1 is a sectional view of a ceramic filter according to one embodiment of the present invention
  • FIG. 2 is a perspective view showing a ceramic filter according to one embodiment of the present invention
  • FIG. 3 is a schematic diagram schematically showing one example of a method of manufacturing a silica membrane of the ceramic filter according to the present invention
  • FIGS. 4 (a) (b) (c) are explanatory views of a silica membrane in a case where a titania UF membrane is formed;
  • FIGS. 5 (a) to 5(e) are explanatory views of a silica membrane in a case where any titania UF membrane is not formed;
  • FIGS. 6 (a) (b) (c) are explanatory views of formation of the silica membrane at a defective membrane;
  • FIG. 7 is a diagram showing a flux with respect to a separation factor.
  • FIG. 1 shows a silica membrane 1 which is a ceramic porous membrane of the present invention.
  • the silica membrane 1 is formed on a titania UF membrane 14 which is an ultrafiltration membrane (also referred to as the UF membrane) formed on a porous base member 11 as a microfiltration membrane (also referred to as the MF membrane) and having an average pore diameter smaller than that of the porous base member 11.
  • the silica membrane has an average pore diameter smaller than that of the titania UF membrane 14, and a part of the silica membrane permeates the titania UF membrane.
  • the porous base member 11 is the microfiltration membrane (the MF membrane) having pore diameters of about 0.1 to 0.6 ⁇ m at an outermost layer.
  • the titania UF membrane 14 which is an ultrafiltration membrane having pore diameters of about 2 to 20 ran (preferably about 8 ran) is formed on the microfiltration membrane (the MF membrane) 11, and the silica membrane 1 is formed on the titania UF membrane 14. It is assumed that the silica membrane 1 has an infiltration structure to infiltrate the titania UF membrane 14. In other words, a part of silica forming the silica membrane 1 permeates the titania UF membrane 14.
  • silica permeates the titania UF membrane 14 it is indicated according to EDX element analysis that a portion having a silica/titania oxide weight ratio of 0.2 or more has a thickness of 1/2 or more of that of the UF membrane from the outermost surface of the UF membrane. It is assumed that the silica/titania oxide weight ratio is an average value of ten measurements of spot analysis based on the EDX element analysis .
  • the silica membrane 1 is formed on the titania UF membrane 14 having pore diameters of about 2 to 20 nm as described above, when a membrane surface of the titania UF membrane 14 is smooth and has less defects, the silica membrane 1 can be formed to be thin without any defect. That is, the silica membrane 1 having a high separability and a high flux (a transmitted and filtered flux) can be prepared with reduced costs. [0025]
  • the silica membrane 1 when the silica membrane 1 is formed on titania having pore diameters of 20 nm or more, owing to the unevenness of the surface, a silica layer constitutes a thick membrane in order to cover the whole surface with the silica membrane 1, thereby resulting in a low flux. Owing to the unevenness of the surface, the silica membrane 1 becomes non-uniform, and defects such as cracks are easily generated. That is, a low separation performance is obtained. Furthermore, to prevent the generation of the cracks, an only thin membrane is formed once. The number of steps increases, and hence the costs increase. [0026]
  • the titania UF membrane 14 is used as a base for the formation of the silica membrane 1 and the silica membrane 1 is formed on the titania UF membrane 14 to constitute a structure in which silica infiltrates the titania UF membrane 14, influences of the unevenness of the MF membrane are reduced, and the silica membrane 1 having less defects, that is, the silica membrane 1 having a high separability can be formed.
  • a ceramic filter 10 in which the silica membrane 1 is formed according to the present invention will be described with reference to FIG. 2.
  • the ceramic filter 10 of the present invention has a monolith shape including a plurality of cells 23 defined by partition walls 22 to form channel passages in an axial direction.
  • the cells 23 have a circular section, and the silica membrane 1 shown in FIG. 1 is formed on an inner wall surface of each of the cells.
  • the cells 23 may be formed so as to have a hexagonal or quadrangular section. According to such a structure, for example, when a mixture (e.g., water and acetic acid) is introduced into the cells 23 from an inlet-side end surface 25, one of constituting elements of the mixture is separated at the silica membrane 1 formed on an inner wall of each cell 23, transmitted through the porous partition walls 22 and discharged from an outermost wall of the ceramic filter 10, so that the mixture can be separated. That is, the silica membrane 1 formed in the ceramic filter 10 can be used as a separation membrane, and has a high separation characteristic with respect to water and acetic acid. [0028]
  • a mixture e.g., water and acetic acid
  • the porous base member 11 which is a base main body is formed as a columnar monolith-type filter element formed of a porous material by extrusion or the like.
  • alumina can be used, because this material has a resistance to corrosion, pore diameters of a filtering portion scarcely change even with a temperature change and a sufficient strength can be obtained.
  • a ceramic material such as cordierite, mullite or silicon carbide may be used.
  • the silica membrane 1 of the present invention is formed on an inner peripheral surface (the inner wall surface) of the porous base member 11, a comparatively long cylindrical base having a length of 50 cm or more, or a porous base member having a lotus-root-like shape can preferably be used.
  • the titania UF membrane 14 is formed on the porous base member 11, and the silica membrane 1 is formed on the titania UF membrane 14. That is, an ultrafiltration membrane (the UF membrane) is formed on at least a silica membrane 1 forming surface of the base formed of the porous material.
  • a titania membrane which inhibits generation of particles or polymers in a range of 0.1 ⁇ m to 2 nm. It is assumed that an average pore diameter of the titania membrane is smaller than that of the porous material.
  • a coating liguid (a silica sol liquid) 40 for forming the silica membrane 1 is prepared.
  • tetraethoxy silane is hydrolyzed in the presence of nitric acid to form a sol liquid, and the sol liquid is diluted with ethanol .
  • the liquid may be diluted with water instead of ethanol .
  • an outer peripheral surface of the porous base member 11 provided with the titania UF membrane 14 is sealed with a masking tape 41.
  • the porous base member 11 is fixed to, for example, a lower end of a wide-mouthed rotor (not shown) , and the coating liquid (the silica sol liquid) 40 is passed through the cells 23 from an upper portion of the base.
  • a membrane formation process by usual dipping may be used.
  • a temperature is raised at a ratio of 100°C/hr, retained at 500°C for one hour, and then lowered at a ratio of 100°C/hr. Operations such as the passing of the coating liquid (the silica sol liquid) 40, drying, temperature raising and temperature lowering are repeated three to five times.
  • the silica membrane 1 is formed on the titania UF membrane 14. That is, as shown in FIG. 4 (b) , the titania UF membrane 14 is formed on the porous base member 11 shown in FIG. 4 (a) . In consequence, influences of the unevenness of the surface of the porous base member 11 are reduced by the titania UF membrane 14. Therefore, as shown in FIG. 4 (c) , the silica membrane can be formed as a thin membrane having less defects. That is, the silica membrane 1 having a high flux and a high separability- can be formed with reduced costs. [0034]
  • the ceramic filter 10 obtained as described above and including the nano-level thin-membrane-like silica membrane 1 formed on the inner wall surface thereof can preferably be used as a filter which separates a mixed liquid or the like. It is to be noted that when the cells 23 are submerged into acetic acid or acetic acid is passed through the cells, a separation factor can be improved.
  • the silica membrane is formed as the ceramic porous membrane has been described, but the present invention is not limited to this embodiment, and a titania membrane, a zirconia membrane, a zeolite membrane or the like may be formed.
  • a material provided with an alumina membrane having an average pore diameter of 0.2 ⁇ m and having a monolith shape (an outer diameter of 30 mm, a cell inner diameter 3 mm x 37 cells and a length of 500 mm) was used as a base. It is to be noted that opposite end portions of the base were sealed with glass. The average pore diameter of the base was measured based on an air flow process described in ASTM F306.
  • a sol particle diameter measured by a dynamic optical scattering process was 100 nm.
  • the titania sol liquid was diluted with water to obtain a sol liquid for membrane formation.
  • the liquid was circulated through base cells to come in contact with the cells, whereby the membrane was formed in the cells.
  • the sample was thermally treated at 500°C.
  • This sample was used as a titania UF base provided with the titania UF membrane.
  • an average pore diameter was 8 nm.
  • a measurement principle of the pore diameters is the same as that of the method described in Non- Patent Document 1, but in the Non-Patent Document 1, water vapor and nitrogen were used, whereas in the measurement method used in the present invention, n-hexane and nitrogen were used.
  • silica sol liquid was diluted with ethanol, and regulated into 0.7 wt% in terms of silica to prepare a sol liquid for membrane formation.
  • the porous base member was sealed with a masking tape.
  • the porous base member was fixed to a lower end of a wide-mouthed rotor, and 60 ml of silica sol liquid was passed through the cells from an upper portion of the base. It was confirmed that the membrane was formed on the whole inner wall by this membrane formation step.
  • the porous base member through which a silica sol was passed was dried at 30 0 C for 2 hr on a condition of a humidity of 50%.
  • Example 1 A temperature was raised at a ratio of 100°C/hr, retained at 500°C for one hour and lowered at the ratio of 100°C/hr. It is to be noted that the operations of (6) to (8) were repeated three to five times to obtain Example 1. [0047]
  • a titania UF membrane was formed in the same manner as in the membrane formation of Example 1, but a sample was thermally treated at 400°C. This sample was used as a titania UF base provided with the titania UF membrane. When pore diameters of the titania UF base were measured, an average pore diameter was 2 nm. This base was subjected to silica sol membrane formation of (5) to (8) . [ 0048 ]
  • a titania UF membrane was formed in the same manner as in the membrane formation of Example 1, but a sample was thermally treated at 700°C. This sample was used as a titania UF base provided with the titania UF membrane. When pore diameters of the titania UF base were measured, an average pore diameter was 40 ran. This base was subjected to silica sol membrane formation of (5) to (8). [0049]
  • Example 1 In the membrane formation of Example 1, any titania UF membrane was not formed, and an alumina porous base member was directly subjected to silica sol membrane formation of (5) to (8) .
  • Example 1 and Comparative Example 1 an infiltration depth into titania UF was measured.
  • Comparative Examples 2, 3 when a membrane was formed using a membrane formation sol liquid having a silica concentration of 0.7 wt%, cracks were generated in the membrane surface, and any membrane could not be formed. Therefore, in Comparative Example 2, a membrane was formed with 0.3 wt%, but cracks were generated. Furthermore, a membrane was formed with 0.1 wt%, the cracks were reduced, and membranes were formed 20 times. In Comparative Example 3, the cracks were reduced at 0.3 wt%, and membranes were formed seven times. However, in either case, it was recognized that micro cracks were left in the membrane surface, and any sound membrane could not be formed. [0052]
  • Example 1 and Comparative Examples 1, 2 and 3 a permeation evaporating separation test was conducted for two hours. In the test, 90% ethanol was circulated through monolith cells at 70°C and a liquid flow rate of 10 L/min, and the outside of monolith was evacuated in a range of 2 to 10 Pa. The sampling was performed four times every 30 minutes. As results of the separation tests of Example 1 and Comparative Examples 1 to 3, a relation between a separation factor and a flux is shown in FIG. 7. [0053]
  • Example 1 indicated a high ⁇ (a separation factor) as compared with Comparative Example 1, and indicated a high ⁇ and a high flux as compared with Comparative Examples 2, 3.
  • Comparative Examples 2, 3 to form the membrane surface without any crack, a slurry having a small silica concentration as compared with the example needs to be used. As a result, the number of membrane formation times increases. When the number of the membrane formation times increases, steps lengthen, and costs increase.
  • a thin and uniform membrane having less coarse and large pores and less defects can be obtained with less membrane formation times. Therefore, a ceramic filter provided with such a silica membrane can preferably be used as a filter.
  • a ceramic filter including a nano-level thin-membrane-like silica membrane formed on the inner wall surface thereof can be used in a portion where an organic filter cannot be used, for example, separation removal or the like in an acidic or alkaline solution or an organic solvent.

Abstract

There are disclosed a ceramic porous membrane formed with less membrane formation times and having less defects, a small and uniform thickness and a high resolution, and a ceramic filter. A silica membrane (1) as a ceramic porous membrane is formed on a titania UF membrane (14) as an ultrafiltration membrane (a UF membrane) formed on a porous base member (11) which is a microfiltration membrane (also referred to as an MF membrane) and having an average pore diameter smaller than that of the porous base member (11), the silica membrane has an average pore diameter smaller than that of the titania UF membrane (14) and a part of the silica membrane permeates the titania UF membrane.

Description

DESCRIPTION
CERAMIC POROUS MEMBRANE AND CERAMIC FILTER
Technical Field [0001]
The present invention relates to a ceramic porous membrane and a ceramic filter. More particularly, it relates to a ceramic porous membrane having less defects and having a small and uniform thickness, and a ceramic filter.
Background Art [0002]
Heretofore, various methods of forming a ceramic porous membrane on a porous base member have been known. For example, a hot coating process is known (see Non-Patent Document 1) . This is a method of rubbing a tube base with cloth containing a silica sol to apply the silica sol and thereby form a porous membrane on an outer surface of the heated tube base. [0003]
A method of forming a porous membrane on an inner surface of a porous base member having a tubular shape or a cylindrical lotus-root-like monolith shape by filtering membrane formation is also known (see Patent Documents 1, 2) . The outer surface of the porous base member is held at a pressure lower than that of an inner surface thereof which comes in contact with a sol liquid to form the membrane on the inner surface of the porous base member. [ 0004 ]
[Patent Document 1] Japanese Patent Application Laid- Open No. 3-267129
[Patent Document 2] Japanese Patent Application Laid- Open No. 61-238315
[Non-Patent Document 1] Journal of Membrane Science 149 (1988) 127 to 135 [0005]
However, the hot coating process has a problem that the membrane cannot uniformly be formed on the whole base surface, and the membrane can be formed on the only outer surface of the tube base. The process cannot be applied to any monolith-type base. On the other hand, in the filtering membrane formation process, during drying of the formed membrane, a solvent present in base pores sometimes flows out on a membrane side to cause membrane peeling. As a result, there is a problem that a defect is generated in the porous membrane formed on the fired base surface. A dip coating process can be applied to the monolith type base, but the number of membrane formation times is large.
Disclosure of Invention
[0006]
An object of the present invention is to provide a ceramic porous membrane formed with less membrane formation times and having less defects, a small and uniform thickness and a high resolution, and a ceramic filter.
[0007]
The present inventors have found that the above- mentioned object can be achieved using a constitution in which the ceramic porous membrane is formed on an ultrafiltration membrane so as to partially permeate pores of the ultrafiltration membrane. That is, according to the present invention, the following ceramic porous membrane and ceramic filter are provided.
[0008]
[1] A ceramic porous membrane which is formed on an ultrafiltration membrane having an average pore diameter of 2 to 20 nm and which partially permeates pores of the ultrafiltration membrane.
[0009]
[2] The ceramic porous membrane according to the above [1] , wherein a permeation depth in the ultrafiltration membrane is 1/2 or more of a thickness of the ultrafiltration membrane from the outermost surface of the ultrafiltration membrane .
[0010]
[3] The ceramic porous membrane according to the above [1] or [2] , wherein the ultrafiltration membrane is a titania membrane.
[0011]
[4] The ceramic porous membrane according to any one of the above [1] to [3], which is a silica membrane. [0012]
[5] The ceramic porous membrane according to any ' one of the above [1] to [4], wherein a ceramic sol permeates the ultrafiltration membrane to solidify.
[0013] [6] A ceramic filter comprising: a porous base member; an ultrafiltration membrane formed on the porous base member and having an average pore diameter of 2 to 20 nm; and a ceramic porous membrane which is formed on the ultrafiltration membrane and which partially permeates pores of the ultrafiltration membrane.
[0014]
[7] The ceramic filter according to the above [6], wherein a permeation depth of the ceramic porous membrane in the ultrafiltration membrane is 1/2 or more of a thickness of the ultrafiltration membrane from the outermost surface of the ultrafiltration membrane.
[0015]
[8] The ceramic filter according to the above [6] or [7], wherein the ultrafiltration membrane is a titania membrane .
[0016]
[9] The ceramic filter according to any one of the above [6] to [8], wherein the ceramic porous membrane is a silica membrane.
[0017]
[10] The ceramic filter according to any one of the above [6] to [9] , wherein the ceramic porous membrane is formed by allowing a ceramic sol to permeate the ultrafiltration membrane and solidify.
[0018]
The thin ceramic porous membrane having less defects can be formed using a constitution of the ceramic porous membrane which is formed on the ultrafiltration membrane having an average pore diameter of 2 to 20 nra and which partially permeates the pores of the ultrafiltration membrane. According to a structure in which a part of the ceramic porous membrane infiltrates the ultrafiltration membrane, influences of an uneven surface of a porous base member are reduced, and the ceramic porous membrane having less defects and having a dehydrating function with a high resolution can be obtained. Furthermore, when such a structure is used, the ceramic porous membrane having a high performance can be obtained with reduced costs. When the silica membrane is used as the ceramic porous membrane, the membrane is especially preferable for an application of dehydration of alcohol such as ethanol or isopropyl alcohol or an organic acid such as acetic acid.
Brief Description of the Drawings [0019]
FIG. 1 is a sectional view of a ceramic filter according to one embodiment of the present invention; FIG. 2 is a perspective view showing a ceramic filter according to one embodiment of the present invention;
FIG. 3 is a schematic diagram schematically showing one example of a method of manufacturing a silica membrane of the ceramic filter according to the present invention; FIGS. 4 (a) (b) (c) are explanatory views of a silica membrane in a case where a titania UF membrane is formed;
FIGS. 5 (a) to 5(e) are explanatory views of a silica membrane in a case where any titania UF membrane is not formed; FIGS. 6 (a) (b) (c) are explanatory views of formation of the silica membrane at a defective membrane; and
FIG. 7 is a diagram showing a flux with respect to a separation factor.
Best Mode for Carrying Out the Invention [0020]
An embodiment of the present invention will hereinafter be described with reference to the drawings. The present invention is not limited to the following embodiment, can be changed, modified or improved without departing from the scope of the present invention. [0021]
FIG. 1 shows a silica membrane 1 which is a ceramic porous membrane of the present invention. The silica membrane 1 is formed on a titania UF membrane 14 which is an ultrafiltration membrane (also referred to as the UF membrane) formed on a porous base member 11 as a microfiltration membrane (also referred to as the MF membrane) and having an average pore diameter smaller than that of the porous base member 11. The silica membrane has an average pore diameter smaller than that of the titania UF membrane 14, and a part of the silica membrane permeates the titania UF membrane. [0022]
It is preferable that the porous base member 11 is the microfiltration membrane (the MF membrane) having pore diameters of about 0.1 to 0.6 μm at an outermost layer. [0023] Moreover, the titania UF membrane 14 which is an ultrafiltration membrane having pore diameters of about 2 to 20 ran (preferably about 8 ran) is formed on the microfiltration membrane (the MF membrane) 11, and the silica membrane 1 is formed on the titania UF membrane 14. It is assumed that the silica membrane 1 has an infiltration structure to infiltrate the titania UF membrane 14. In other words, a part of silica forming the silica membrane 1 permeates the titania UF membrane 14. Here, when silica permeates the titania UF membrane 14, it is indicated according to EDX element analysis that a portion having a silica/titania oxide weight ratio of 0.2 or more has a thickness of 1/2 or more of that of the UF membrane from the outermost surface of the UF membrane. It is assumed that the silica/titania oxide weight ratio is an average value of ten measurements of spot analysis based on the EDX element analysis .
[0024]
In a case where the silica membrane 1 is formed on the titania UF membrane 14 having pore diameters of about 2 to 20 nm as described above, when a membrane surface of the titania UF membrane 14 is smooth and has less defects, the silica membrane 1 can be formed to be thin without any defect. That is, the silica membrane 1 having a high separability and a high flux (a transmitted and filtered flux) can be prepared with reduced costs. [0025]
On the other hand, when the silica membrane 1 is formed on titania having pore diameters of 20 nm or more, owing to the unevenness of the surface, a silica layer constitutes a thick membrane in order to cover the whole surface with the silica membrane 1, thereby resulting in a low flux. Owing to the unevenness of the surface, the silica membrane 1 becomes non-uniform, and defects such as cracks are easily generated. That is, a low separation performance is obtained. Furthermore, to prevent the generation of the cracks, an only thin membrane is formed once. The number of steps increases, and hence the costs increase. [0026]
In a case where the titania UF membrane 14 is used as a base for the formation of the silica membrane 1 and the silica membrane 1 is formed on the titania UF membrane 14 to constitute a structure in which silica infiltrates the titania UF membrane 14, influences of the unevenness of the MF membrane are reduced, and the silica membrane 1 having less defects, that is, the silica membrane 1 having a high separability can be formed. [0027] Next, one embodiment of a ceramic filter 10 in which the silica membrane 1 is formed according to the present invention will be described with reference to FIG. 2. The ceramic filter 10 of the present invention has a monolith shape including a plurality of cells 23 defined by partition walls 22 to form channel passages in an axial direction. In the present embodiment, the cells 23 have a circular section, and the silica membrane 1 shown in FIG. 1 is formed on an inner wall surface of each of the cells. The cells 23 may be formed so as to have a hexagonal or quadrangular section. According to such a structure, for example, when a mixture (e.g., water and acetic acid) is introduced into the cells 23 from an inlet-side end surface 25, one of constituting elements of the mixture is separated at the silica membrane 1 formed on an inner wall of each cell 23, transmitted through the porous partition walls 22 and discharged from an outermost wall of the ceramic filter 10, so that the mixture can be separated. That is, the silica membrane 1 formed in the ceramic filter 10 can be used as a separation membrane, and has a high separation characteristic with respect to water and acetic acid. [0028]
The porous base member 11 which is a base main body is formed as a columnar monolith-type filter element formed of a porous material by extrusion or the like. As the porous material, for example, alumina can be used, because this material has a resistance to corrosion, pore diameters of a filtering portion scarcely change even with a temperature change and a sufficient strength can be obtained. However, instead of alumina, a ceramic material such as cordierite, mullite or silicon carbide may be used. [0029]
Since the silica membrane 1 of the present invention is formed on an inner peripheral surface (the inner wall surface) of the porous base member 11, a comparatively long cylindrical base having a length of 50 cm or more, or a porous base member having a lotus-root-like shape can preferably be used. [0030] Moreover, the titania UF membrane 14 is formed on the porous base member 11, and the silica membrane 1 is formed on the titania UF membrane 14. That is, an ultrafiltration membrane (the UF membrane) is formed on at least a silica membrane 1 forming surface of the base formed of the porous material. It is preferable to form, as the ultrafiltration membrane, a titania membrane which inhibits generation of particles or polymers in a range of 0.1 μm to 2 nm. It is assumed that an average pore diameter of the titania membrane is smaller than that of the porous material. [0031]
Next, a method of manufacturing the silica membrane 1 will be described with reference to FIG. 3. First, a coating liguid (a silica sol liquid) 40 for forming the silica membrane 1 is prepared. To prepare the coating liquid 40, tetraethoxy silane is hydrolyzed in the presence of nitric acid to form a sol liquid, and the sol liquid is diluted with ethanol . The liquid may be diluted with water instead of ethanol . [0032]
Next, as shown in FIG. 3, an outer peripheral surface of the porous base member 11 provided with the titania UF membrane 14 is sealed with a masking tape 41. The porous base member 11 is fixed to, for example, a lower end of a wide-mouthed rotor (not shown) , and the coating liquid (the silica sol liquid) 40 is passed through the cells 23 from an upper portion of the base. Alternatively, instead of this process, a membrane formation process by usual dipping may be used. Subsequently, a temperature is raised at a ratio of 100°C/hr, retained at 500°C for one hour, and then lowered at a ratio of 100°C/hr. Operations such as the passing of the coating liquid (the silica sol liquid) 40, drying, temperature raising and temperature lowering are repeated three to five times. [0033]
According to the above steps, the silica membrane 1 is formed on the titania UF membrane 14. That is, as shown in FIG. 4 (b) , the titania UF membrane 14 is formed on the porous base member 11 shown in FIG. 4 (a) . In consequence, influences of the unevenness of the surface of the porous base member 11 are reduced by the titania UF membrane 14. Therefore, as shown in FIG. 4 (c) , the silica membrane can be formed as a thin membrane having less defects. That is, the silica membrane 1 having a high flux and a high separability- can be formed with reduced costs. [0034]
On the other hand, in a case where the silica membrane 1 is directly formed on the surface of the porous base member 11 shown in FIG. 5 (a) , even when a silica membrane Ia is formed as shown in FIG. 5 (b) , the whole surface cannot be covered, and cracks are easily generated in the silica membrane 1 owing to unevenness. As shown in FIGS. 5(c) to 5(e), when silica membranes Ib, Ic and Id are superimposed to form a thick membrane, the silica membrane 1 can be flattened, but in this case, a low flux results. Since the number of the steps increases, the costs increase. [0035] Characteristics of a case where silica of the silica membrane 1 infiltrates the titania UF membrane 14 will be described with reference to FIGS. 6 (a) (b) (c) . As shown in FIG. 6 (a), in a case where there is a foreign matter 51 on the titania UF membrane 14 and a structure in which the silica membrane 1 infiltrates the titania UF membrane 14 as shown in FIG. 6 (b) is formed, even when there are foreign matters and defects, the silica membrane 1 infiltrates so as to cover the titania UF membrane 14. Even when the titania UF membrane 14 has a hole 52, the silica membrane 1 is formed so as to cover the hole 52. A structure in which the surface of the titania UF membrane 14 is covered with the silica membrane 1 can be obtained. That is, a foreign matter trace defect and a hole defect can be repaired by the silica membrane 1. [0036]
On the other hand, as shown in FIG. β(c), in a structure in which the silica membrane 1 does not infiltrate the titania UF membrane 14, when the titania UF membrane 14 has the foreign matter defect, the corresponding portion is not covered with the silica membrane 1. Even when the titania UF membrane 14 has the hole defect, the silica membrane 1 is not easily formed at a portion of the hole 52, and a portion where the surface of the titania UF membrane 14 is not covered with the silica membrane 1 is easily generated. [0037]
The ceramic filter 10 obtained as described above and including the nano-level thin-membrane-like silica membrane 1 formed on the inner wall surface thereof can preferably be used as a filter which separates a mixed liquid or the like. It is to be noted that when the cells 23 are submerged into acetic acid or acetic acid is passed through the cells, a separation factor can be improved. In the above embodiment, the case where the silica membrane is formed as the ceramic porous membrane has been described, but the present invention is not limited to this embodiment, and a titania membrane, a zirconia membrane, a zeolite membrane or the like may be formed.
Examples
[0038]
A manufacturing method of the present invention will hereinafter be described in accordance with examples in more detail, but the present invention is not limited to these examples. First, a porous base member, a ceramic sol liquid, a membrane forming method and the like used in the present example will be described. [0039] (Example 1) (1) Porous base member
A material provided with an alumina membrane having an average pore diameter of 0.2 μm and having a monolith shape (an outer diameter of 30 mm, a cell inner diameter 3 mm x 37 cells and a length of 500 mm) was used as a base. It is to be noted that opposite end portions of the base were sealed with glass. The average pore diameter of the base was measured based on an air flow process described in ASTM F306. [0040] (2) Titania Sol Liquid Titanium isopropoxide was hydrolyzed in the presence of nitric acid to obtain a titania sol liquid. A sol particle diameter measured by a dynamic optical scattering process was 100 nm. [0041]
(3) Titania UF Membrane Formation
The titania sol liquid was diluted with water to obtain a sol liquid for membrane formation. The liquid was circulated through base cells to come in contact with the cells, whereby the membrane was formed in the cells. [0042]
(4) Drying, Firing
After a sample was dried, the sample was thermally treated at 500°C. This sample was used as a titania UF base provided with the titania UF membrane. When pore diameters of the titania UF base were measured, an average pore diameter was 8 nm. A measurement principle of the pore diameters is the same as that of the method described in Non- Patent Document 1, but in the Non-Patent Document 1, water vapor and nitrogen were used, whereas in the measurement method used in the present invention, n-hexane and nitrogen were used.
[0043]
(5) Silica Sol Liquid Tetraethoxy silane was hydrolyzed in the presence of nitric acid to obtain a silica sol liquid. The silica sol liquid was diluted with ethanol, and regulated into 0.7 wt% in terms of silica to prepare a sol liquid for membrane formation. [ 0044 ]
(6) Membrane Formation
An outer peripheral surface of the sample (the porous base member) was sealed with a masking tape. The porous base member was fixed to a lower end of a wide-mouthed rotor, and 60 ml of silica sol liquid was passed through the cells from an upper portion of the base. It was confirmed that the membrane was formed on the whole inner wall by this membrane formation step. [0045]
(7) Drying
The porous base member through which a silica sol was passed was dried at 300C for 2 hr on a condition of a humidity of 50%. [0046]
(8) Firing
A temperature was raised at a ratio of 100°C/hr, retained at 500°C for one hour and lowered at the ratio of 100°C/hr. It is to be noted that the operations of (6) to (8) were repeated three to five times to obtain Example 1. [0047]
(Comparative Example 1)
A titania UF membrane was formed in the same manner as in the membrane formation of Example 1, but a sample was thermally treated at 400°C. This sample was used as a titania UF base provided with the titania UF membrane. When pore diameters of the titania UF base were measured, an average pore diameter was 2 nm. This base was subjected to silica sol membrane formation of (5) to (8) . [ 0048 ]
(Comparative Example 2)
A titania UF membrane was formed in the same manner as in the membrane formation of Example 1, but a sample was thermally treated at 700°C. This sample was used as a titania UF base provided with the titania UF membrane. When pore diameters of the titania UF base were measured, an average pore diameter was 40 ran. This base was subjected to silica sol membrane formation of (5) to (8). [0049]
(Comparative Example 3)
In the membrane formation of Example 1, any titania UF membrane was not formed, and an alumina porous base member was directly subjected to silica sol membrane formation of (5) to (8) .
[0050]
In Example 1 and Comparative Example 1, an infiltration depth into titania UF was measured. In Example 1, a portion in which a silica/titania oxide weight ratio according to EDX element analysis was 0.2 or more reached 3/4 of a UF thickness from the outermost surface of the UF membrane. Therefore, an infiltration structure could be confirmed. In Comparative Example 1, a portion in which a silica/titania oxide weight ratio according to EDX element analysis was 0.2 or more stayed at 1/10 of a UF thickness from the outermost surface of the UF membrane. Therefore, it could be confirmed that any infiltration structure was not obtained.
[0051] In Comparative Examples 2, 3, when a membrane was formed using a membrane formation sol liquid having a silica concentration of 0.7 wt%, cracks were generated in the membrane surface, and any membrane could not be formed. Therefore, in Comparative Example 2, a membrane was formed with 0.3 wt%, but cracks were generated. Furthermore, a membrane was formed with 0.1 wt%, the cracks were reduced, and membranes were formed 20 times. In Comparative Example 3, the cracks were reduced at 0.3 wt%, and membranes were formed seven times. However, in either case, it was recognized that micro cracks were left in the membrane surface, and any sound membrane could not be formed. [0052]
In Example 1 and Comparative Examples 1, 2 and 3, a permeation evaporating separation test was conducted for two hours. In the test, 90% ethanol was circulated through monolith cells at 70°C and a liquid flow rate of 10 L/min, and the outside of monolith was evacuated in a range of 2 to 10 Pa. The sampling was performed four times every 30 minutes. As results of the separation tests of Example 1 and Comparative Examples 1 to 3, a relation between a separation factor and a flux is shown in FIG. 7. [0053]
Example 1 indicated a high α (a separation factor) as compared with Comparative Example 1, and indicated a high α and a high flux as compared with Comparative Examples 2, 3. In Comparative Examples 2, 3, to form the membrane surface without any crack, a slurry having a small silica concentration as compared with the example needs to be used. As a result, the number of membrane formation times increases. When the number of the membrane formation times increases, steps lengthen, and costs increase.
[0054] As described above, when the titania UF membrane is formed on the MF membrane and the silica membrane is formed on the titania UF membrane, a silica dehydration membrane having a high performance can be obtained with reduced costs. The structure in which silica infiltrates titania UF is constituted, and hence a higher separation factor can be developed.
Industrial Applicability [0055] According to the present invention, a thin and uniform membrane having less coarse and large pores and less defects can be obtained with less membrane formation times. Therefore, a ceramic filter provided with such a silica membrane can preferably be used as a filter. A ceramic filter including a nano-level thin-membrane-like silica membrane formed on the inner wall surface thereof can be used in a portion where an organic filter cannot be used, for example, separation removal or the like in an acidic or alkaline solution or an organic solvent.

Claims

1. A ceramic porous membrane which is formed on an ultrafiltration membrane having an average pore diameter of 2 to 20 nm and which partially permeates pores of the ultrafiltration membrane.
2. The ceramic porous membrane according to claim 1, wherein a permeation depth in the ultrafiltration membrane is 1/2 or more of a thickness of the ultrafiltration membrane from the outermost surface of the ultrafiltration membrane.
3. The ceramic porous membrane according to claim 1 or 2, wherein the ultrafiltration membrane is a titania membrane.
4. The ceramic porous membrane according to any one of claims 1 to 3, which is a silica membrane.
5. The ceramic porous membrane according to any one of claims 1 to 4, wherein a ceramic sol permeates the ultrafiltration membrane to solidify.
6. A ceramic filter comprising: a porous base member; an ultrafiltration membrane formed on the porous base member and having an average pore diameter of 2 to 20 nm; and a ceramic porous membrane which is formed on the ultrafiltration membrane and which partially permeates pores of the ultrafiltration membrane.
7. The ceramic filter according to claim 6, wherein a permeation depth of the ceramic porous membrane in the ultrafiltration membrane is 1/2 or more of a thickness of the ultrafiltration membrane from the outermost surface of the ultrafiltration membrane.
8. The ceramic filter according to claim 6 or 7, wherein the ultrafiltration membrane is a titania membrane.
9. The ceramic filter according to any one of claims 6 to
8, wherein the ceramic porous membrane is a silica membrane.
10. The ceramic filter according to any one of claims 6 to
9, wherein the ceramic porous membrane is formed by allowing a ceramic sol to permeate the ultrafiltration membrane and solidify.
PCT/JP2007/070761 2006-10-18 2007-10-18 Ceramic porous membrane and ceramic filter WO2008050812A1 (en)

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JP2009255035A (en) * 2008-03-26 2009-11-05 Ngk Insulators Ltd Ceramic filter
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4711719A (en) * 1983-09-05 1987-12-08 Leenaars Adriaan F M Process for the production of crack-free semi-permeable inorganic membranes
EP0327687A2 (en) * 1987-12-11 1989-08-16 Norton Company Ultrafiltration membranes
US20010001453A1 (en) * 1996-10-21 2001-05-24 Valerie Thoraval Inorganic nanofiltration membrane and its application in the sugar industry
US20040071894A1 (en) * 2002-10-04 2004-04-15 Korea Research Institute Of Chemical Technology Preparation of composite silica membranes with thermal stability by a soaking-rolling method

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61238315A (en) 1985-04-12 1986-10-23 Ngk Insulators Ltd Preparation of double-layered filter
JPH0745010B2 (en) 1990-03-16 1995-05-17 日本碍子株式会社 Ceramic membrane filter
US5194200A (en) * 1991-10-08 1993-03-16 Wisconsin Alumni Research Foundation Method of creating silica ceramic membranes
US5186833A (en) * 1991-10-10 1993-02-16 Exxon Research And Engineering Company Composite metal-ceramic membranes and their fabrication
JPH0899027A (en) * 1994-09-30 1996-04-16 Kyocera Corp Ceramic structure for gas separation and manufacture of the same
JP3905461B2 (en) * 1995-11-24 2007-04-18 株式会社ノリタケカンパニーリミテド Method for producing zeolite membrane
FR2754737B1 (en) * 1996-10-21 1999-01-15 Tech Sep INORGANIC NANOFILTRATION MEMBRANE AND ITS APPLICATION IN THE SUGAR INDUSTRY
CN1053650C (en) * 1997-06-20 2000-06-21 清华大学 Method for preparing ceramic thin sheet contg. alumina, silicon oxide and titanium oxide
US6536604B1 (en) * 1999-06-25 2003-03-25 C. Jeffrey Brinker Inorganic dual-layer microporous supported membranes
JP2003220319A (en) * 2002-01-30 2003-08-05 Kyocera Corp Separation membrane module and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4711719A (en) * 1983-09-05 1987-12-08 Leenaars Adriaan F M Process for the production of crack-free semi-permeable inorganic membranes
EP0327687A2 (en) * 1987-12-11 1989-08-16 Norton Company Ultrafiltration membranes
US20010001453A1 (en) * 1996-10-21 2001-05-24 Valerie Thoraval Inorganic nanofiltration membrane and its application in the sugar industry
US20040071894A1 (en) * 2002-10-04 2004-04-15 Korea Research Institute Of Chemical Technology Preparation of composite silica membranes with thermal stability by a soaking-rolling method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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US8465648B2 (en) 2009-05-18 2013-06-18 Ngk Insulators, Ltd. Ceramic pervaporation membrane and ceramic vapor-permeable membrane
WO2012128217A1 (en) 2011-03-22 2012-09-27 日本碍子株式会社 Honeycomb-shaped ceramic separation-membrane structure
WO2013054794A1 (en) 2011-10-11 2013-04-18 日本碍子株式会社 Ceramic filter
US9427687B2 (en) 2011-10-11 2016-08-30 Ngk Insulators, Ltd. Ceramic filter
US9555377B2 (en) 2012-02-29 2017-01-31 Ngk Insulators, Ltd. Ceramic separation membrane and dehydration method
WO2013147272A1 (en) 2012-03-30 2013-10-03 日本碍子株式会社 Honeycomb shaped porous ceramic body, manufacturing method for same, and honeycomb shaped ceramic separation membrane structure
DE112017001673T5 (en) 2016-03-31 2019-01-10 Ngk Insulators, Ltd. Porous support, process for the preparation of the porous support, separation membrane structure and process for the preparation of the separation membrane structure
WO2022260063A1 (en) 2021-06-08 2022-12-15 日本碍子株式会社 Membrane reactor
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