WO2008045578A1 - Non-water soluble polymeric surfactants - Google Patents
Non-water soluble polymeric surfactants Download PDFInfo
- Publication number
- WO2008045578A1 WO2008045578A1 PCT/US2007/022057 US2007022057W WO2008045578A1 WO 2008045578 A1 WO2008045578 A1 WO 2008045578A1 US 2007022057 W US2007022057 W US 2007022057W WO 2008045578 A1 WO2008045578 A1 WO 2008045578A1
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- WO
- WIPO (PCT)
- Prior art keywords
- ink
- inks
- polymeric surfactant
- water
- oil
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Definitions
- the invention relates to a non-water soluble polymeric surfactant that is used to stabilize emulsion heatset printing inks .
- lithographic web offset heat set inks contain between 30% and 45% volatile organic compounds (VOC) . Besides being detrimental to the environment, VOCs are also flammable and hazardous to the printers who operate the press. Thus, it is desirable to reduce the VOC content in lithographic web offset heat set inks as much as possible.
- Initial attempts at solving this problem involved the use of chemical reactions that were triggered in a press oven. However, such oven cured ink systems did not have shelf stability.
- a heat setting web offset ink will typically contain the following major components (a) a high molecular weight ink resin to disperse the pigment and also to provide the toughness and gloss the ink requires on drying, (b) solvents to provide the fluidity to the ink before it is placed on the web and dried in an oven, (c) pigment, and (d) other minor components such as gellants, which provide structure to the ink, plasticizers (non volatile solvents), waxes, thickeners, and antioxidants.
- Conventional heatset inks set or dry by evaporation of the ink oil on heating at 250 to 300°F, and, to some degree, by penetration of the ink oil into the paper, leaving behind a hard polymeric film.
- EP 731150 and EP 960911 describes rapid thermosetting low VOC web offset lithographic ink systems comprising solid resin, drying oil alkyds, bodied drying oil, vegetable oil, fatty acids, multifunctional unsaturated polyester, reducing agents and transition metal salts of organic acids and may also include an aqueous fountain solution containing peroxides that promote free radical polymerization of the ink.
- WO 96/34922, U.S. Pat. No. 5,431,721, and U.S. Pat. No. 5,545,741, 1996 respectively describe lithographic inks which employ non-volatile solvents, but they set by penetration of the non-volatile solvent into the stock.
- US Patent No. 7,018,453 describes a low VOC web offset heat set inks that contain a latex polymer. Due to its inherent incompatibility the gloss of printed film is dramatically reduced and at high speed piling occurs.
- WO 2005/113694 describes an emulsion composition comprising water, a hydrocarbon distillate having a boiling point of 215 to 235 0 C, and a surfactant having a hydrophilic lipophilic balance number of 10 or less.
- the surfactant described in WO 2005/113694 is monomeric and the stability of the emulsified composition is not very good.
- US Patent No. 5,417,749 describes a printing ink useful for "waterless” printing processes comprising a water-in-oil microemulsion wherein the water is present in an amount of about 5 to 20 wt.%, based on the weight of the ink.
- the water phase contains about 0.5 to 3wt.%, based on the weight of the ink, of a water soluble surfactant which will not lower the surface tension (as measured at ambient temperature) of the ink.
- VOC Volatile Organic Content
- the present invention provides a non-water soluble polymeric surfactant prepared by reacting a polymerized/bodied unsaturated oil with maleic anhydride followed by a further partial or complete reaction with: (i) an amine to form an amide; or (ii) an alcohol to form an ester.
- Figure 1 shows dot gain values at 50% screens for the standard and new set of inks of Example 8. This proves that the printability of emulsion inks is equal to standard inks .
- Figure 2 shows print densities of the 2 Black and Cyan standard and experimental inks of Example 8 obtained across the keys of the press and plotted versus the densities of the standard set of inks. This proves that the runnability of emulsion inks is equal to standard inks.
- Figure 3 shows print densities of 2 Magenta and Yellow standard and experimental inks of Example 8 obtained across the keys of the press and plotted versus the densities of the standard set of inks. This proves that the runnability of emulsion inks is equal to standard inks .
- Figure 4 shows High shear viscosity as measured by Duke Viscometer at 2,500 S -1 versus time for the Black standard and experimental inks (WM) of Example 8. This proves that the experimental inks are equally stable with time at high shear rates.
- Figure 5 shows High shear viscosity as measured by Duke Viscometer at 2,500 s "1 versus time for the Cyan standard and experimental inks of Example 8. This proves that the experimental inks are equally stable with time at high shear rates.
- Figure 6 shows High shear viscosity as measured by Duke Viscometer at 2,500 s "1 versus time for the Magenta standard and experimental inks of Example 8. This proves that the experimental inks are equally stable with time at high shear rates.
- Figure 7 shows High shear viscosity as measured by Duke Viscometer at 2,500 s "1 versus time for the Yellow standard and experimental inks of Example 8. This proves that the experimental inks are equally stable with time at high shear rates .
- This new class of non-water soluble polymeric surfactants promotes water-in-oil emulsion stability for pre-emulsified heatset and offset inks.
- Polymerized/bodied unsaturated oils are reacted with maleic anhydride (preferably 4-5 wt.%), and are subsequently reacted, partially or totally, with an amine or alcohol to form an amide or ester, respectively.
- the polymerized/bodied unsaturated oil is selected from the group consisting of linseed oil, polymerized linseed oil, soy oil, soy fatty acid ester, dehydrated castor fatty acid ester. Most preferably, the unsaturated oil is polymerized linseed oil.
- the amine is selected from the group consisting of ethanolamine, diethylamine, isobutylamine, octyleamine, morpholine, benzylamine and aniline.
- the alcohol is tridecylalcohol .
- the stabilized emulsion heatset printing ink of the present invention comprises water of more than 20% by weight, more preferably from about 5 to about 50% by weight, again more preferably from about 5 to about 20 % by weight, and most preferably from about 5 to about 15% by weight.
- a printing ink containing the polymeric surfactant of the present invention is a lithographic water-in-oil microemulsion printing ink having a viscosity between about 30 and about 300 poise and VOC content of less than about 35% by weight, more preferably less than about 20% by weight.
- the amount of non-water soluble polymeric surfactant present in the printing ink is preferably less than about 5% by weight, more preferably from about 1 to 3 % by weight.
- the printing ink of the present invention does not contain a latex polymer.
- non-water soluble polymeric surfactant can be produced by the above mentioned procedure provided that any polymerized/bodied unsaturated oil is used and at least one of the following is used:
- a secondary monoamine or monoalcohol 2. A primary monoamine or monoalcohol;
- a cyclic secondary monoamine is used; or
- the addition of the non-water soluble polymeric surfactant has another advantage when used in letterpress inks.
- Letterpress inks are printed directly onto the paper, that is, neat inks are applied to the paper.
- the addition of water to the ink will absorb into the paper causing the paper fibers to swell. This swelling of the paper fibers affects the ink/paper interaction such that the printed image will appear smoother and sharper resembling offset printed inks.
- the purpose of the non- water soluble polymeric surfactant is to prevent the water from evaporating as the ink travels along the roller train.
- the printing ink containing the non-water soluble polymeric surfactant may optionally contain a water-soluble polymer.
- suitable modified polymers which are soluble in the water phase of the ink regardless of the pH of the water phase include: carboxymethylcellulose, hydroxyethylcellulose, hydroxypropyl-cellulose, hydroxybutylmethy1cellulose, poly (Cl,- C4) alkylene oxides, polyethyleneimine, polyvinyl alcohol, polyvinyl acetate, polyvinylpyrollidone, polyvinyl-oxazolidone and polyacrylamide polymers.
- Gums is a class of widely used water-soluble polymers. Gums consist of polysaccharides with varying polymerization degrees. They include the polysaccharide hydrocolloids, which are usually prepared from gums, and they may have been chemically modified, e.g. by partial acetylation, to make them more water-soluble and/or stable in the presence of the other ingredients in the liquid media. Biopolymers also belonging to this class of polysaccharide hydrocolloids. Typical examples of commercially available, gum-type thickening agents are xanthan gums and their derivatives. These include a partially acetylated xanthan gum, KELZAN ex Kelco Company of N.
- METHOCEL and ETHOCEL cellulose ether products are available in two basic types: methylcellulose and hydroxypropyl methylcellulose. Both METHOCEL types have the polymeric backbone of cellulose, a natural carbohydrate that contains a basic repeating structure of anhydroglucose units. During the manufacture of cellulose ethers, cellulose fibers are treated with methyl chloride, yielding the methyl ether of cellulose. These are METHOCEL A brand products . For hydroxypropyl methylcellulose products (METHOCEL E, F, J, and K brand products), propylene oxide is used in addition to methyl chloride to obtain hydroxypropyl substitution on the anhydroglucose units.
- METHOCEL A brand products For hydroxypropyl methylcellulose products (METHOCEL E, F, J, and K brand products), propylene oxide is used in addition to methyl chloride to obtain hydroxypropyl substitution on the anhydroglucose units.
- This substituent group contains a secondary hydroxyl on the number two carbon and may also be considered to form a propylene glycol ether of cellulose.
- These products possess varying ratios of hydroxypropyl and methyl substitution, a factor which influences organic solubility and the thermal gelation temperature of aqueous solutions.
- ETHOCEL ethylcellulose polymers are derived from and have the polymeric "backbone" of cellulose, which is a naturally occurring polymer.
- the molecule has a structure of repeating anhydroglucose units . Note that each anhydroglucose unit (ring) has three reactive -OH
- CELLOSIZE HEC polymers are named after their two components: cellulose and hydroxyethyl side chains.
- Cellulose itself is a water-insoluble, long-chain molecule consisting of repeating anhydroglucose units.
- a purified cellulose is reacted with sodium hydroxide to produce a swollen alkali cellulose.
- This alkali-treated cellulose is more chemically reactive than cellulose.
- ethylene oxide By reacting the alkali cellulose with ethylene oxide, a series of hydroxyethyl cellulose ethers is produced. In this reaction, the hydrogen atoms in the hydroxyl groups of cellulose are replaced by hydroxyethyl groups, which confer water solubility to the product.
- non-water soluble polymeric surfactants of the present invention were evaluated by shearing a weighed quantity of the polymeric surfectant in a jar using a mixer at high speed. A weighed quantity of water was then pipetted into the mixing solution and further sheared for 10 minutes. The emulsion was than transferred into a vial and capped. A visual assessment is made periodically for water/oil separation and color. The ratings of these sheared/mixed emulsions were based on whether the emulsion is stable for a least one week and the color.
- a whitish color has been determined to be more desirable due to the smaller particle size which provides a more stable emulsion.
- a non-water soluble polymeric surfactant is classified as excellent if there is no separation of the emulsion after one week and is white in color.
- a non-water soluble polymeric surfactant is classified as good if there is no separation of the emulsion after one week and is tan or brown in color.
- a non-water soluble polymeric surfactant is classified as acceptable if there is no separation of the emulsion after 3 - 5 days. Any separation that takes place in less than 3 days is considered poor.
- Emulsified ink (5 mg) was put on a slide glass, and another slide glass was piled on it. The ink was observed at a magnifying power of 450 and drops of water may be observed.
- Maximum diameter of drops is xnot acceptable more than 13 micrometer
- Maximum diameter of drops is ⁇ acceptable between 5 and 13 micrometer
- Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037] Emulsified ink (1.0 g) was put on a Hoover Muller [000037]
- a non-water soluble polymeric surfactant was prepared by reacting polymerized linseed oil with maleic anhydride (4-5 wt . %) followed by a stoichiometric amount of diethylamine .
- Emulsified inks were prepared as indicated below in Table 1.
- the standard ink did not contain an emuls ifier while the Experimental ink contained the polymeric surfactant as described in Example 1 .
- a heatset ink was formulated with conventional monomeric surfactant that create water in oil emulsion as follows :
- Example 2 had poor ink water balance on a Didde web press at 1000 fpm.
- Example 3 Three heatset inks were formulated with a polymeric surfactant prepared as described in Example 1 The three formulations (wohs yellow #1, wohs cyan and wohs magenta) are as follows:
- Example 3 had good ink water balance on a Didde press at 1000 fpm.
- VOC levels were30, 20 and 30 % as compared to a 40% VOC for a non emulsified ink.
- the non-water soluble polymeric surfactant prepared was evaluated by shearing a weighed quantity of the polymeric surfactant in a jar using a mixer at high speed as described above. It produced good to excellent stable emulsions.
- the non-water soluble polymeric surfactant prepared was evaluated by shearing a weighed quantity of the polymeric surfactant in a jar using a mixer at high speed as described above. It produced good to excellent stable emulsions.
- the non-water soluble polymeric surfactant prepared was evaluated by shearing a weighed quantity of the polymeric surfactant in a jar using a mixer at high speed as described above. It produced good to excellent stable emulsions .
- Example 8 The microemulsified inks of Example 8 were tested as described below and had: (1) Lithographic performance equal to commercial inks, (2) equal fountain solution consumption, (3) similar dot gains, (4) similar ink transfer, (5) similar ink feed back, ink consumption.
- a heatset ink was formulated as indicated below with a polymeric surfactant prepared as described in Example 1 :
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200780044493.7A CN101547979B (en) | 2006-10-13 | 2007-10-15 | Non-water soluble polymeric surfactants |
JP2009532479A JP5685374B2 (en) | 2006-10-13 | 2007-10-15 | Water-insoluble polymer surfactant |
CA002666436A CA2666436A1 (en) | 2006-10-13 | 2007-10-15 | Non-water soluble polymeric surfactants |
AU2007308079A AU2007308079B2 (en) | 2006-10-13 | 2007-10-15 | Non-water soluble polymeric surfactants |
EP07839594A EP2074180A4 (en) | 2006-10-13 | 2007-10-15 | Non-water soluble polymeric surfactants |
TW097139333A TWI444444B (en) | 2006-10-13 | 2008-10-14 | Non-water soluble polymeric surfactants |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82941306P | 2006-10-13 | 2006-10-13 | |
US60/829,413 | 2006-10-13 | ||
US85332906P | 2006-11-03 | 2006-11-03 | |
US60/853,329 | 2006-11-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008045578A1 true WO2008045578A1 (en) | 2008-04-17 |
Family
ID=39283176
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/022057 WO2008045578A1 (en) | 2006-10-13 | 2007-10-15 | Non-water soluble polymeric surfactants |
PCT/US2007/022056 WO2008048590A1 (en) | 2006-10-13 | 2007-10-15 | Stable offset emulsion inks containing non-water soluble polymeric surfactants |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/022056 WO2008048590A1 (en) | 2006-10-13 | 2007-10-15 | Stable offset emulsion inks containing non-water soluble polymeric surfactants |
Country Status (7)
Country | Link |
---|---|
US (2) | US7985820B2 (en) |
EP (2) | EP2074182A4 (en) |
JP (3) | JP5685374B2 (en) |
AU (2) | AU2007313251B2 (en) |
CA (2) | CA2666432A1 (en) |
TW (2) | TWI445776B (en) |
WO (2) | WO2008045578A1 (en) |
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EP2086934A2 (en) * | 2006-11-03 | 2009-08-12 | Sun Chemical Corporation | Water tolerant emulsion stabilizers |
JP2015525279A (en) * | 2012-06-15 | 2015-09-03 | サン ケミカル コーポレイション | Lithographic offset ink with water and filler components |
RU2695205C2 (en) * | 2014-12-17 | 2019-07-22 | Зирокс Корпорейшн | Acrylate ink composition for digital lithographic printing based on ink |
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US7644225B2 (en) | 2006-10-17 | 2010-01-05 | Intel Corporation | Performance or power-optimized code/data storage for nonvolatile memories |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2893886A (en) * | 1957-09-24 | 1959-07-07 | California Ink Company Inc | Iron blue pigment composition and process for its manufacture |
US5981625A (en) * | 1995-06-23 | 1999-11-09 | Videojet Systems International, Inc. | Non-rub off printing inks |
US6858678B2 (en) * | 1998-07-10 | 2005-02-22 | Johnson Polymer, Llc | Continuous bulk polymerization and esterification process and compositions including the polymeric product |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3293201A (en) * | 1962-03-07 | 1966-12-20 | Pittsburgh Plate Glass Co | Emulsions of curable resinous compositions and a salt of an adduct of an unsaturateddicarboxylic acid and a fatty oil |
US3629119A (en) * | 1969-12-22 | 1971-12-21 | Shell Oil Co | Water-in-oil emulsions |
US3719623A (en) * | 1971-04-01 | 1973-03-06 | American Cyanamid Co | Rubbery polymeric mixtures comprising a maleinized type oil |
US3960935A (en) * | 1972-06-22 | 1976-06-01 | The Kendall Company | Nonionic monomeric emulsion stabilizers |
JPS512705A (en) * | 1974-06-28 | 1976-01-10 | Asahi Denka Kogyo Kk | JUNKATSUZAI |
US4428855A (en) * | 1982-08-25 | 1984-01-31 | Mobil Oil Corporation | Oil-in-water emulsion fluids |
DE4011376A1 (en) * | 1990-04-07 | 1991-10-10 | Basf Lacke & Farben | OXIDATIVELY CROSSLINKING URETHANE RESIN |
US5417749A (en) * | 1994-03-29 | 1995-05-23 | Sun Chemical Corporation | Microemulsion printing ink |
JP3877802B2 (en) * | 1995-05-02 | 2007-02-07 | 株式会社リコー | Emulsion ink and printing method using the same |
AU717158B2 (en) * | 1995-06-13 | 2000-03-16 | Sun Chemical Corporation | Intaglio printing ink |
JP3393971B2 (en) * | 1996-06-18 | 2003-04-07 | 理想科学工業株式会社 | Emulsion ink for stencil printing |
JP3775531B2 (en) * | 1996-12-11 | 2006-05-17 | 東北リコー株式会社 | W / O emulsion ink for stencil printing |
ATE305845T1 (en) * | 1998-02-06 | 2005-10-15 | Lonza Ag | WOOD Preservative |
JP3895046B2 (en) * | 1998-06-24 | 2007-03-22 | サカタインクス株式会社 | Emulsion ink composition for offset printing and offset printing method |
JP4080121B2 (en) * | 1999-06-03 | 2008-04-23 | 東北リコー株式会社 | Water-in-oil emulsion ink for stencil printing |
JP2000345088A (en) * | 1999-06-03 | 2000-12-12 | Riso Kagaku Corp | Stenciling emulsion ink |
US6544322B2 (en) * | 2001-01-05 | 2003-04-08 | Sun Chemical Corporation | Printing inks having low volatile organic compounds and methods of producing same |
JP2002265838A (en) * | 2001-02-28 | 2002-09-18 | Sun Chemical Corp | Water-based offset lithography ink for printing newspaper |
JP2002338867A (en) * | 2001-05-11 | 2002-11-27 | Riso Kagaku Corp | Emulsion ink for stencil printing |
CN100545221C (en) * | 2002-08-30 | 2009-09-30 | 大日本油墨化学工业株式会社 | Printing-ink is with siccative and contain the printing-ink of this siccative |
US6709503B1 (en) * | 2002-12-19 | 2004-03-23 | Sun Chemical Corporation | Waterbased heatset offset ink compositions |
US7008474B2 (en) * | 2003-01-31 | 2006-03-07 | Tohoku Ricoh Co., Ltd. | Water-in-oil type emulson ink for stencil printing |
WO2005044934A1 (en) * | 2003-10-29 | 2005-05-19 | Sun Chemical Corporation | Vegetable oil ester imide as a dispersant of carbon black in oil-based inks |
GB0326198D0 (en) * | 2003-11-10 | 2003-12-17 | Gr Advanced Materials Ltd | Emulsion ink |
EP1704214A1 (en) * | 2004-01-09 | 2006-09-27 | The Lubrizol Corporation | Maleated vegetable oils and derivatives, as self-emulsifying lubricants in metalworking |
CA2555834C (en) * | 2004-02-13 | 2012-04-03 | Hexion Specialty Chemicals, Inc. | Tackifier dispersion |
US7857899B2 (en) | 2004-05-21 | 2010-12-28 | The Lubrizol Corporation | Emulsion composition and vehicle and ink compositions and printing process and method thereof |
US8486915B2 (en) | 2004-08-12 | 2013-07-16 | Isp Investments Inc. | Compositions of water-insoluble active organic compounds |
GB0424505D0 (en) * | 2004-11-05 | 2004-12-08 | Gr Advanced Materials Ltd | Emulsion ink |
JP2010509052A (en) * | 2006-11-03 | 2010-03-25 | サン ケミカル コーポレイション | Water-tolerant emulsion stabilizer |
-
2007
- 2007-10-15 US US11/907,641 patent/US7985820B2/en not_active Expired - Fee Related
- 2007-10-15 AU AU2007313251A patent/AU2007313251B2/en not_active Ceased
- 2007-10-15 EP EP07839593A patent/EP2074182A4/en not_active Withdrawn
- 2007-10-15 CA CA002666432A patent/CA2666432A1/en not_active Abandoned
- 2007-10-15 EP EP07839594A patent/EP2074180A4/en not_active Withdrawn
- 2007-10-15 CA CA002666436A patent/CA2666436A1/en not_active Abandoned
- 2007-10-15 WO PCT/US2007/022057 patent/WO2008045578A1/en active Application Filing
- 2007-10-15 JP JP2009532479A patent/JP5685374B2/en not_active Expired - Fee Related
- 2007-10-15 US US11/907,642 patent/US7909924B2/en not_active Expired - Fee Related
- 2007-10-15 WO PCT/US2007/022056 patent/WO2008048590A1/en active Application Filing
- 2007-10-15 AU AU2007308079A patent/AU2007308079B2/en not_active Ceased
- 2007-10-15 JP JP2009532478A patent/JP5568308B2/en not_active Expired - Fee Related
-
2008
- 2008-10-14 TW TW097139337A patent/TWI445776B/en not_active IP Right Cessation
- 2008-10-14 TW TW097139333A patent/TWI444444B/en not_active IP Right Cessation
-
2014
- 2014-10-15 JP JP2014210688A patent/JP2015014010A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2893886A (en) * | 1957-09-24 | 1959-07-07 | California Ink Company Inc | Iron blue pigment composition and process for its manufacture |
US5981625A (en) * | 1995-06-23 | 1999-11-09 | Videojet Systems International, Inc. | Non-rub off printing inks |
US6858678B2 (en) * | 1998-07-10 | 2005-02-22 | Johnson Polymer, Llc | Continuous bulk polymerization and esterification process and compositions including the polymeric product |
Non-Patent Citations (1)
Title |
---|
See also references of EP2074180A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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EP2086934A2 (en) * | 2006-11-03 | 2009-08-12 | Sun Chemical Corporation | Water tolerant emulsion stabilizers |
EP2086934A4 (en) * | 2006-11-03 | 2011-04-13 | Sun Chemical Corp | Water tolerant emulsion stabilizers |
US8013034B2 (en) | 2006-11-03 | 2011-09-06 | Sun Chemical Corporation | Stable offset emulsion inks containing water tolerant emulsion stabilizer |
US8013033B2 (en) | 2006-11-03 | 2011-09-06 | Sun Chemical Corporation | Water tolerant emulsion stabilizers |
JP2015525279A (en) * | 2012-06-15 | 2015-09-03 | サン ケミカル コーポレイション | Lithographic offset ink with water and filler components |
RU2695205C2 (en) * | 2014-12-17 | 2019-07-22 | Зирокс Корпорейшн | Acrylate ink composition for digital lithographic printing based on ink |
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US20080139743A1 (en) | 2008-06-12 |
EP2074180A1 (en) | 2009-07-01 |
TWI444444B (en) | 2014-07-11 |
JP2015014010A (en) | 2015-01-22 |
CA2666432A1 (en) | 2008-04-24 |
US7909924B2 (en) | 2011-03-22 |
AU2007308079A1 (en) | 2008-04-17 |
AU2007313251A1 (en) | 2008-04-24 |
JP5568308B2 (en) | 2014-08-06 |
TWI445776B (en) | 2014-07-21 |
WO2008048590A1 (en) | 2008-04-24 |
JP5685374B2 (en) | 2015-03-18 |
TW200930767A (en) | 2009-07-16 |
JP2010506969A (en) | 2010-03-04 |
US20080132675A1 (en) | 2008-06-05 |
EP2074182A1 (en) | 2009-07-01 |
EP2074182A4 (en) | 2011-04-27 |
TW200925222A (en) | 2009-06-16 |
CA2666436A1 (en) | 2008-04-17 |
AU2007313251B2 (en) | 2013-04-04 |
JP2010528117A (en) | 2010-08-19 |
EP2074180A4 (en) | 2011-04-20 |
AU2007308079B2 (en) | 2013-05-02 |
US7985820B2 (en) | 2011-07-26 |
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