WO2008033335A3 - Process for preparing fluorinated carboxylic acids - Google Patents

Process for preparing fluorinated carboxylic acids Download PDF

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Publication number
WO2008033335A3
WO2008033335A3 PCT/US2007/019721 US2007019721W WO2008033335A3 WO 2008033335 A3 WO2008033335 A3 WO 2008033335A3 US 2007019721 W US2007019721 W US 2007019721W WO 2008033335 A3 WO2008033335 A3 WO 2008033335A3
Authority
WO
WIPO (PCT)
Prior art keywords
carboxylic acids
fluorinated carboxylic
preparing fluorinated
fluorinated
acid
Prior art date
Application number
PCT/US2007/019721
Other languages
French (fr)
Other versions
WO2008033335A2 (en
Inventor
Haridassan K Nair
Sandra L Bell
Original Assignee
Honeywell Int Inc
Haridassan K Nair
Sandra L Bell
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honeywell Int Inc, Haridassan K Nair, Sandra L Bell filed Critical Honeywell Int Inc
Priority to JP2009528256A priority Critical patent/JP2010503670A/en
Priority to EP07838023A priority patent/EP2081883A2/en
Publication of WO2008033335A2 publication Critical patent/WO2008033335A2/en
Publication of WO2008033335A3 publication Critical patent/WO2008033335A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/29—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with halogen-containing compounds which may be formed in situ

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process for the preparation of a fluorinated acid of the formula RfCOOH, wherein the process includes the step of contacting: (i) a fluorinated alcohol of the formula RfCH2OH; and (ii) periodic acid; wherein each Rf is independently selected from linear, branched or cyclic hydrocarbyl of 1-12 carbon atoms having 1-25 fluorine atoms and any range there between; and wherein the contacting step is carried out in the presence of a catalyst and optionally in a reaction medium, at a temperature and length of time sufficient to produce the fluorinated acid.
PCT/US2007/019721 2006-09-12 2007-09-11 Process for preparing fluorinated carboxylic acids WO2008033335A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009528256A JP2010503670A (en) 2006-09-12 2007-09-11 Process for preparing fluorinated acids
EP07838023A EP2081883A2 (en) 2006-09-12 2007-09-11 Process for preparing fluorinated acids

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US84396506P 2006-09-12 2006-09-12
US60/843,965 2006-09-12
US11/900,079 US20080064900A1 (en) 2006-09-12 2007-09-10 Process for preparing fluorinated acids
US11/900,079 2007-09-10

Publications (2)

Publication Number Publication Date
WO2008033335A2 WO2008033335A2 (en) 2008-03-20
WO2008033335A3 true WO2008033335A3 (en) 2008-05-08

Family

ID=38969788

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/019721 WO2008033335A2 (en) 2006-09-12 2007-09-11 Process for preparing fluorinated carboxylic acids

Country Status (4)

Country Link
US (1) US20080064900A1 (en)
EP (1) EP2081883A2 (en)
JP (1) JP2010503670A (en)
WO (1) WO2008033335A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0918616D0 (en) 2009-10-23 2009-12-09 3M Innovative Properties Co Method of preparing highly fluorinated carboxylic acids and their salts
US20140128469A1 (en) 2011-05-10 2014-05-08 Concert Pharmaceuticals Inc. Deuterated n-butyl bumetanide

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999052850A1 (en) * 1998-04-09 1999-10-21 Merck & Co., Inc. Oxidation process using periodic acid
WO2001053240A1 (en) * 2000-01-19 2001-07-26 Dsm Fine Chemicals Austria Nfg Gmbh & Cokg Method for producing carboxylic acids by alcohol oxidation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2802028A (en) * 1956-03-28 1957-08-06 Du Pont Preparation of polyfluorocarboxylic acids and amides from 1, 1-difluoro-1-alkenes, alkali metal cyanides and water
US5736012A (en) * 1996-09-10 1998-04-07 Alliedsignal Inc. Process for the preparation of a fluorinated acid
US6150554A (en) * 1998-04-09 2000-11-21 Merck & Co., Inc. Oxidation process using periodic acid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999052850A1 (en) * 1998-04-09 1999-10-21 Merck & Co., Inc. Oxidation process using periodic acid
WO2001053240A1 (en) * 2000-01-19 2001-07-26 Dsm Fine Chemicals Austria Nfg Gmbh & Cokg Method for producing carboxylic acids by alcohol oxidation

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CARLSEN ET AL: "A Greatly Improved Procedure for Ruthenium Tetraoxide Catalyzed Oxidations of Organic Compounds", J.ORG.CHEM., vol. 46, 1981, pages 3936 - 3938, XP002467337 *
MO HUNSEN: "Fluorochromate-catalyzed periodic acid oxidation of alcohols and aldehydes", J.FLUORINE CHEM., vol. 126, 2005, pages 1356 - 1360, XP002467338 *

Also Published As

Publication number Publication date
WO2008033335A2 (en) 2008-03-20
EP2081883A2 (en) 2009-07-29
US20080064900A1 (en) 2008-03-13
JP2010503670A (en) 2010-02-04

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