WO2008016388A3 - Method and apparatus for growth of high quality carbon single-walled nanotubes - Google Patents

Method and apparatus for growth of high quality carbon single-walled nanotubes Download PDF

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Publication number
WO2008016388A3
WO2008016388A3 PCT/US2007/002513 US2007002513W WO2008016388A3 WO 2008016388 A3 WO2008016388 A3 WO 2008016388A3 US 2007002513 W US2007002513 W US 2007002513W WO 2008016388 A3 WO2008016388 A3 WO 2008016388A3
Authority
WO
WIPO (PCT)
Prior art keywords
growth
high quality
carbon single
walled nanotubes
quality carbon
Prior art date
Application number
PCT/US2007/002513
Other languages
French (fr)
Other versions
WO2008016388A2 (en
Inventor
Avetik Harutyunyan
Original Assignee
Honda Motor Co Ltd
Avetik Harutyunyan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd, Avetik Harutyunyan filed Critical Honda Motor Co Ltd
Priority to JP2008552497A priority Critical patent/JP5550833B2/en
Publication of WO2008016388A2 publication Critical patent/WO2008016388A2/en
Publication of WO2008016388A3 publication Critical patent/WO2008016388A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes

Abstract

Method and processes for synthesizing single- wall carbon nanotubes is provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 50 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon.
PCT/US2007/002513 2006-01-30 2007-01-30 Method and apparatus for growth of high quality carbon single-walled nanotubes WO2008016388A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008552497A JP5550833B2 (en) 2006-01-30 2007-01-30 Method and apparatus for high quality single-walled carbon nanotube growth

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US76381306P 2006-01-30 2006-01-30
US60/763,813 2006-01-30

Publications (2)

Publication Number Publication Date
WO2008016388A2 WO2008016388A2 (en) 2008-02-07
WO2008016388A3 true WO2008016388A3 (en) 2008-04-17

Family

ID=38997607

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/002513 WO2008016388A2 (en) 2006-01-30 2007-01-30 Method and apparatus for growth of high quality carbon single-walled nanotubes

Country Status (3)

Country Link
US (1) US20080279753A1 (en)
JP (1) JP5550833B2 (en)
WO (1) WO2008016388A2 (en)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009530214A (en) 2006-01-30 2009-08-27 本田技研工業株式会社 Catalyst for the growth of carbon single-walled nanotubes
US8158217B2 (en) 2007-01-03 2012-04-17 Applied Nanostructured Solutions, Llc CNT-infused fiber and method therefor
US9005755B2 (en) 2007-01-03 2015-04-14 Applied Nanostructured Solutions, Llc CNS-infused carbon nanomaterials and process therefor
US8951632B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused carbon fiber materials and process therefor
US8951631B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused metal fiber materials and process therefor
US9174847B2 (en) * 2008-05-01 2015-11-03 Honda Motor Co., Ltd. Synthesis of high quality carbon single-walled nanotubes
US8591858B2 (en) 2008-05-01 2013-11-26 Honda Motor Co., Ltd. Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes
JP5497021B2 (en) * 2008-06-19 2014-05-21 本田技研工業株式会社 Low temperature synthesis of single-walled carbon nanotubes
WO2010014650A2 (en) * 2008-07-29 2010-02-04 Honda Motor Co., Ltd. Preferential growth of single-walled carbon nanotubes with metallic conductivity
CA2750484A1 (en) 2009-02-17 2010-12-16 Applied Nanostructured Solutions, Llc Composites comprising carbon nanotubes on fiber
WO2010141130A1 (en) 2009-02-27 2010-12-09 Lockheed Martin Corporation Low temperature cnt growth using gas-preheat method
US20100224129A1 (en) 2009-03-03 2010-09-09 Lockheed Martin Corporation System and method for surface treatment and barrier coating of fibers for in situ cnt growth
WO2010120581A1 (en) 2009-04-17 2010-10-21 Noyes Dallas B Method for producing solid carbon by reducing carbon oxides
US9111658B2 (en) 2009-04-24 2015-08-18 Applied Nanostructured Solutions, Llc CNS-shielded wires
CA2758570A1 (en) 2009-04-24 2010-12-16 Applied Nanostructured Solutions, Llc Cnt-based signature control material
JP5744008B2 (en) 2009-04-27 2015-07-01 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ CNT-based resistive heating for deicing composite structures
WO2011017200A1 (en) 2009-08-03 2011-02-10 Lockheed Martin Corporation Incorporation of nanoparticles in composite fibers
EP2504164A4 (en) 2009-11-23 2013-07-17 Applied Nanostructured Sols Ceramic composite materials containing carbon nanotube-infused fiber materials and methods for production thereof
JP5643835B2 (en) 2009-11-23 2014-12-17 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ CNT-adapted sea-based composite structure
US8545963B2 (en) 2009-12-14 2013-10-01 Applied Nanostructured Solutions, Llc Flame-resistant composite materials and articles containing carbon nanotube-infused fiber materials
US9167736B2 (en) 2010-01-15 2015-10-20 Applied Nanostructured Solutions, Llc CNT-infused fiber as a self shielding wire for enhanced power transmission line
CA2785803A1 (en) 2010-02-02 2011-11-24 Applied Nanostructured Solutions, Llc Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom
BR112012021634A2 (en) 2010-03-02 2019-09-24 Applied Nanostructured Sols electrical devices containing infused carbon nanotube fibers and methods for reproducing them.
CN102934267A (en) 2010-03-02 2013-02-13 应用奈米结构公司 Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof
TWI491555B (en) * 2010-04-01 2015-07-11 Hon Hai Prec Ind Co Ltd One dimensional nano structure, method for making the same and using the same as label
US8780526B2 (en) 2010-06-15 2014-07-15 Applied Nanostructured Solutions, Llc Electrical devices containing carbon nanotube-infused fibers and methods for production thereof
US9017854B2 (en) 2010-08-30 2015-04-28 Applied Nanostructured Solutions, Llc Structural energy storage assemblies and methods for production thereof
CA2808242A1 (en) 2010-09-14 2012-03-22 Applied Nanostructured Solutions, Llc Glass substrates having carbon nanotubes grown thereon and methods for production thereof
CN103118975A (en) 2010-09-22 2013-05-22 应用奈米结构公司 Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof
CA2782976A1 (en) 2010-09-23 2012-03-29 Applied Nanostructured Solutions, Llc Cnt-infused fiber as a self shielding wire for enhanced power transmission line
US9085464B2 (en) 2012-03-07 2015-07-21 Applied Nanostructured Solutions, Llc Resistance measurement system and method of using the same
WO2013158156A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Methods and structures for reducing carbon oxides with non-ferrous catalysts
JP6242858B2 (en) 2012-04-16 2017-12-06 シーアストーン リミテッド ライアビリティ カンパニー Method and system for capturing and sequestering carbon and reducing the mass of carbon oxide in a waste gas stream
JP6379085B2 (en) 2012-04-16 2018-08-22 シーアストーン リミテッド ライアビリティ カンパニー Method for treating off-gas containing carbon oxides
JP2015514669A (en) 2012-04-16 2015-05-21 シーアストーン リミテッド ライアビリティ カンパニー Method for producing solid carbon by reducing carbon dioxide
NO2749379T3 (en) 2012-04-16 2018-07-28
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
WO2014011631A1 (en) 2012-07-12 2014-01-16 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
MX2015000580A (en) 2012-07-13 2015-08-20 Seerstone Llc Methods and systems for forming ammonia and solid carbon products.
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
US9650251B2 (en) 2012-11-29 2017-05-16 Seerstone Llc Reactors and methods for producing solid carbon materials
KR101414560B1 (en) * 2013-01-09 2014-07-04 한화케미칼 주식회사 method for producing conductive film
US10086349B2 (en) 2013-03-15 2018-10-02 Seerstone Llc Reactors, systems, and methods for forming solid products
WO2014151898A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Systems for producing solid carbon by reducing carbon oxides
US9783416B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Methods of producing hydrogen and solid carbon
EP3129321B1 (en) 2013-03-15 2021-09-29 Seerstone LLC Electrodes comprising nanostructured carbon
EP3113880A4 (en) 2013-03-15 2018-05-16 Seerstone LLC Carbon oxide reduction with intermetallic and carbide catalysts
US11752459B2 (en) 2016-07-28 2023-09-12 Seerstone Llc Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
US10584072B2 (en) 2017-05-17 2020-03-10 Eden Innovations Ltd. Methods and systems for making nanocarbon particle admixtures and concrete
CN111372681A (en) 2017-09-18 2020-07-03 西弗吉尼亚大学 Catalyst and process for tunable substrate growth of multi-walled carbon nanotubes
CN113164931A (en) * 2018-10-23 2021-07-23 卡本科技有限公司 Enriched synthesis of semiconducting nanotubes
CN112707385A (en) * 2021-01-15 2021-04-27 北海惠科光电技术有限公司 Method for preparing carbon nano tube

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6730284B2 (en) * 2000-06-16 2004-05-04 Honda Giken Kogyo Kabushiki Kaisha Method for producing carbonaceous articles
US20050123467A1 (en) * 2003-12-03 2005-06-09 Avetik Harutyunyan Systems and methods for production of carbon nanostructures

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5424054A (en) * 1993-05-21 1995-06-13 International Business Machines Corporation Carbon fibers and method for their production
US6333016B1 (en) * 1999-06-02 2001-12-25 The Board Of Regents Of The University Of Oklahoma Method of producing carbon nanotubes
US6401526B1 (en) * 1999-12-10 2002-06-11 The Board Of Trustees Of The Leland Stanford Junior University Carbon nanotubes and methods of fabrication thereof using a liquid phase catalyst precursor
US7338648B2 (en) * 2001-12-28 2008-03-04 The Penn State Research Foundation Method for low temperature synthesis of single wall carbon nanotubes
US20040038251A1 (en) * 2002-03-04 2004-02-26 Smalley Richard E. Single-wall carbon nanotubes of precisely defined type and use thereof
US7744816B2 (en) * 2002-05-01 2010-06-29 Intel Corporation Methods and device for biomolecule characterization
US20040005269A1 (en) * 2002-06-06 2004-01-08 Houjin Huang Method for selectively producing carbon nanostructures
US6841003B2 (en) * 2002-11-22 2005-01-11 Cdream Display Corporation Method for forming carbon nanotubes with intermediate purification steps
US6764874B1 (en) * 2003-01-30 2004-07-20 Motorola, Inc. Method for chemical vapor deposition of single walled carbon nanotubes
KR20060133974A (en) * 2003-10-16 2006-12-27 더 유니버시티 오브 아크론 Carbon nanotubes on carbon nanofiber substrate
EP1709213A4 (en) * 2004-01-15 2012-09-05 Nanocomp Technologies Inc Systems and methods for synthesis of extended length nanostructures
JP4457227B2 (en) * 2004-06-11 2010-04-28 独立行政法人物質・材料研究機構 Carbon-coated ferromagnetic metal spherical particles and method for producing the same
JP3935479B2 (en) * 2004-06-23 2007-06-20 キヤノン株式会社 Carbon fiber manufacturing method, electron-emitting device manufacturing method using the same, electronic device manufacturing method, image display device manufacturing method, and information display / reproducing apparatus using the image display device
US20060025515A1 (en) * 2004-07-27 2006-02-02 Mainstream Engineering Corp. Nanotube composites and methods for producing
US7871591B2 (en) * 2005-01-11 2011-01-18 Honda Motor Co., Ltd. Methods for growing long carbon single-walled nanotubes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6730284B2 (en) * 2000-06-16 2004-05-04 Honda Giken Kogyo Kabushiki Kaisha Method for producing carbonaceous articles
US20050123467A1 (en) * 2003-12-03 2005-06-09 Avetik Harutyunyan Systems and methods for production of carbon nanostructures

Also Published As

Publication number Publication date
JP2009528969A (en) 2009-08-13
WO2008016388A2 (en) 2008-02-07
US20080279753A1 (en) 2008-11-13
JP5550833B2 (en) 2014-07-16

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