WO2008012314A1 - Dispenser for preparing a nutritional composition - Google Patents
Dispenser for preparing a nutritional composition Download PDFInfo
- Publication number
- WO2008012314A1 WO2008012314A1 PCT/EP2007/057636 EP2007057636W WO2008012314A1 WO 2008012314 A1 WO2008012314 A1 WO 2008012314A1 EP 2007057636 W EP2007057636 W EP 2007057636W WO 2008012314 A1 WO2008012314 A1 WO 2008012314A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- dispenser
- filter
- dispenser according
- discharge means
- Prior art date
Links
Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J31/00—Apparatus for making beverages
- A47J31/24—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure
- A47J31/34—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure
- A47J31/36—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means
- A47J31/3666—Coffee-making apparatus in which hot water is passed through the filter under pressure, i.e. in which the coffee grounds are extracted under pressure with hot water under liquid pressure with mechanical pressure-producing means whereby the loading of the brewing chamber with the brewing material is performed by the user
- A47J31/3676—Cartridges being employed
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
- C02F9/20—Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/022—Filtration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/004—Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
Definitions
- the present invention relates to a dispenser for preparing a ready to drink nutritional composition such as an infant formula.
- Powdered infant formulas are available in powder form, concentrated liquid form, or ready to feed liquid form. Powdered infant formulas are the most popular form; primarily due to their cost and nutritional quality. The key disadvantage with powdered infant formulas is the inconvenience of preparation. The powdered formula must be spooned into a sterilised drinking vessel such as a baby bottle, water which has been boiled and allowed to cool is poured into the drinking vessel to reconstitute the formula and the drinking vessel is then sealed and shaken to ensure the powder has been dissolved. It may be noted that milk- based nutritional compositions such as infant formula provide excellent substrates for bacterial growth. Therefore, to avoid any bacterial growth, the formula should be consumed immediately after reconstitution.
- powdered infant formulas provide a safe and nutritionally good substitute for mother's milk in the situations described above.
- the process needs to be repeated every time a feed is required. It may readily be seen that this may not always be convenient and, as a consequence, many parents and other caregivers do not prepare the formulas properly and hence expose the infant to the risk of infection.
- the water may not be boiled prior to use in which case any pathogens in the water are fed to the infant.
- any pathogens in the water are fed to the infant.
- batches of the infant formula may be prepared and then stored until needed. Unfortunately, if any pathogen has contaminated the formula, it then has time to replicate.
- Infant formulas in concentrated liquid form suffer substantially the same disadvantages as powdered infant formulas. Hence they do not provide a better solution.
- Infant formulas in ready to feed form should in theory provide a solution to the inconvenience of preparation. However, they have their own disadvantages; in particular they are much more costly and bulky. Further, it is often necessary to provide them in a size enabling multiple feeds. However once opened for the first feed, a contamination risk remains.
- WO 2004/107940 proposes a device having a first water chamber in which water to be used in the reconstitution of the composition is boiled then transferred to a second chamber in which it is held until required at which point it is reheated to the desired temperature of administration and dispensed into a baby bottle where it is mixed with powdered infant formula to prepare a single feed in the conventional way.
- the powdered infant formula and reheated water may be mixed together before being dispensed into the bottle.
- WO 03/084377 proposes a device comprising a sterilisation unit, a container and dispenser for the powdered infant formula, a water reservoir and a water pump all linked to a controller such as a microprocessor.
- This device would sterilise baby bottles, dispense the desired amount of infant formula into the sterilised bottle, pre-boil the water and then maintain it at a suitable temperature, and finally dispense the desired amount of water at the desired temperature into the bottle to reconstitute the infant formula.
- Dispensing equipment may provide a more convenient way to prepare single servings of nutritional compositions such as infant formula but its use brings new problems that are not encountered using traditional methods. This is not simply a question of sterilising the water which will be used to reconstitute the composition, attention must also be paid to such questions as the possibilities of bio-adhesion and build-up of biofilms within the equipment itself and the consequences of adhering bacteria or biofilms detaching and contaminating the previously sterilised water.
- biofilms may be formed within dispensing equipment even if the water dispensed therefrom has previously been boiled. It is thought that this may occur because it is very difficult to ensure that such previously boiled water remains sterile as this would entail a complete separation from the atmosphere. Once the water is again contaminated by bacteria at however low a level, it is possible that, over time, bio-adhesion will occur and biofilms will grow and adhere to surfaces with which the water is in contact, particularly in corners and crevices.
- the present invention provides a dispenser for a nutritional composition
- a dispenser for a nutritional composition comprising a water reservoir, water heating means, water discharge means, a bacterial filter between the water heating means and the water discharge means such that, in use, heated water passes though the filter prior to discharge from the dispenser, and means to heat surfaces of the dispenser which, in use, will come into contact with filtered water.
- the invention extends to a method of dispensing infant formula comprising heating water to a temperature between 25 and 45°C, passing the heated water through a bacterial filter, mixing the filtered water with the infant formula in the form of a powder or a concentrated liquid and dispensing the liquid infant formula.
- Figure 1 shows schematically one embodiment of a dispenser according to the invention.
- Figure 2 shows a cross-section through the water discharge means of the embodiment of Figure 1
- Figure 3 shows schematically another embodiment of a dispenser according to the invention.
- Figure 4 shows in perspective an embodiment of water discharge means for use in a dispenser according to the invention.
- Figure 5 compares the microbial count in infant formula dispensed from a dispenser according to the invention with that obtained from conventional dispensers.
- bio-adhesion means bacteria adhering to an inert surface
- biofilm means a structured community of bacterial cells enclosed in a self- produced polymeric matrix and adherent to an inert surface and is a specialised case of bio-adhesion (after Costerton et al, "Bacterial Biofilms: A Common Cause of Persistent Infections", Science, VoI 284, pages 1318-1322);
- bacterial filter means a filter which is capable of physically obstructing the passage of bacteria in water flowing through it.
- the present invention is primarily directed to minimising any hazard presented by bio-adhesion and/or the formation of biofilms within dispensing equipment to be used in the preparation of infant formula or other nutritional compositions intended for consumption by subjects with an immature or compromised immune system.
- a bacterial filter and means for heating surfaces of the dispenser that will come into contact with filtered water.
- the filter acts as a physical barrier to prevent the passage of any bacteria present in the water whether naturally (i.e. present in the mains water supply or mineral water) or as the result of detachment of a biofilm or other colony of adherent bacteria within the fluid system (the water reservoir or the pipes for example).
- the risk of contamination by biofilms is further reduced by separately providing heating means to reduce the adhesion and proliferation of bacteria and the formation of biofilms in regions of the water discharge means downstream of the filter.
- surfaces of the dispenser with which filtered water will be in contact may be provided with heating means operable to directly heat the surfaces as often as necessary to prevent bio-adhesion and/or formation of biofilms on these surfaces.
- means may be provided to regularly clean the bacterial filter and the water discharge means to discourage the adhesion and proliferation of bacteria and formation of biofilms in this area by the application of heat to these surfaces.
- a steam generator may be provided such that the interior of the water discharge means and preferably the bacterial filter as well may be cleaned by the passage of steam.
- the bacterial filter may have a nominal pore size of 0.45 microns or less. A particularly preferred nominal pore size is between 0.1 and 0.2 microns.
- the bacterial filter may be a conventional flat membrane filter or a shaped filter such as a hollow ceramic cylinder wherein the filtration layer is coated onto either the interior or exterior surface of the cylinder and water percolates from the inside the cylinder out or from outside the filter in, accordingly.
- a suitable material is the ceramic filter pipes (mono-channel and multi-channel) sold by atech innovations GmbH and ItN Nanovation AG.
- the filter may be composed of fibres which themselves have a structure which acts as a bacterial filter.
- One example of a suitable material is the hollow fibres manufactured by Gambro Dialysatoren GmbH for the Hemofilter 2X.
- the bacterial filter is located close to the water discharge means.
- heating means are provided to reduce the adhesion and proliferation of bacteria and the formation of biofilms in regions of the water discharge means downstream of the bacterial filter.
- heating means are provided by a steam generator arranged to deliver steam to at least those internal surfaces downstream of the bacterial filter that will be contacted by filtered water when the dispenser is in use. More preferably, steam is also delivered to the bacterial filter itself.
- the internal surfaces downstream of the water filter may be made from a material which discourages adhesion and/or proliferation of bacteria such as Teflon ®, a bacteriostatic material or stainless steel.
- a complete cycle of operation of the dispenser may comprise the following steps:-
- the desired quantity of water passes from the water reservoir to the water heating means where it is heated to the desired discharge temperature (preferably between 25 and 45°C);
- the heated water passes through the bacterial filter to the sanitised water discharge means and is dispensed as required.
- two heating means may be required, one to generate steam and one to heat the water to be dispensed.
- the steam-cleaning could be performed at the end of the operating cycle in which case the sequence would be as follows :
- the desired quantity of water passes from the water reservoir to the water heating means where it is heated to the desired discharge temperature
- the heated water passes through the bacterial filter to the water discharge means and is dispensed as required; 3. Steam is supplied from the steam generator to the water discharge means for a period of 20 seconds to sanitise the internal surfaces of the water discharge means downstream of the bacterial filter.
- the same heating means could be used to heat the water to be dispensed and to generate the steam.
- two heating means are provided as outlined above.
- a dispenser according to the invention may also be equipped with other features to make the process of preparing individual servings of nutritional compositions even more convenient.
- the dispenser may include a steriliser for baby bottles or the like containers and/or a water pump if it is desired to operate the dispenser under pressure.
- a dispenser according to the invention is particularly suitable for use with individually packaged unit doses of the nutritional composition to be prepared. Such a concept is described in more detail in our co-pending patent application published under International Publication Number WO 2006/077259, the contents of which are incorporated herein by reference.
- the water discharge means is adapted to receive a sealed disposable capsule containing a unit dose of the composition in concentrated form.
- the capsule has an outlet which opens in response to pressure of water within the capsule so that when the dispenser is operated to introduce water into the capsule and the required pressure is attained within the capsule it opens to allow the nutritional composition to flow directly from the capsule outlet into a drinking vessel without contacting the dispenser.
- the nutritional composition is preferably present in the capsule in powder form but may alternatively be in the form of a concentrated liquid.
- the dispenser may further be provided with means to flush the capsule with a gas after introduction of the water to empty the capsule of liquid and to restrict any flow back of the nutritional composition into the dispenser.
- a suitable gas is air at a pressure of between 200 mbar and 2 bar, for example 300 mbar.
- the capsule may be configured to suit the dispenser provided always that the configuration is such as to enable opening of the capsule in such a way as to allow liquid to drain directly from the capsule into the receiving vessel and that the means for opening the capsule to allow liquid to drain from it is located within the capsule itself and is operable in response to conditions generated in the capsule by the introduction of water into the capsule.
- Various suitable capsule configurations of this type are disclosed in our co-pending patent application published under International Publication Number WO 03/059778, the contents of which are incorporated herein by reference.
- the dispenser will also include control means and appropriate circuitry to enable it to be operated as desired.
- the delivery of the water is preferably arranged such that the temperature of the final product in the receiving vessel is at a suitable temperature for the infant to drink immediately, for example between 25 and 45°C.
- a suitable temperature for the infant to drink immediately for example between 25 and 45°C.
- This may be achieved by simply programming the water heating means to heat the water to the desired temperature as selected by the consumer.
- 30 to 50% of the water may be discharged at a temperature of between 70 and 80 0 C and then the remaining amount at or about room temperature or the water at room temperature may be discharged first followed by the hot water. In both cases the mixture of hot water with water at room temperature will ensure that the resulting ready to drink infant formula is at a temperature suitable for immediate consumption
- control means preferably includes means to regulate the amount of water to be discharged. This may be selected manually by the operator. Alternatively, if unit dose capsules are to be used, the capsules may be provided with a bar code which is read by a sensor provided on the dispenser and adapted to pass a signal to the control means to trigger the heating and discharge of the correct amount of water.
- FIG. 1 shows schematically one embodiment of a dispenser according to the invention.
- the dispenser consists of a water reservoir 1 provided with a water pump 2 to pass water to heater 3 which comprises a coiled stainless-steel pipe in a die cast aluminium thermoblock (not shown). Power is supplied to the thermoblock sufficient to heat the water to the desired temperature as it passes though the pipe. From heater 3, water is supplied to a discharge head 4 provided with a bacterial filter 5 comprising two superposed hydrophilic PES
- the heating means is first operated to heat the internal surfaces of the discharge head downstream of the filter to sanitise them. Then, the desired quantity of water is pumped at a pressure of about 0.2 bar from reservoir 1 to heater 3 where it is heated to a temperature between 25 and 40 0 C. The heated water is passed through bacterial filter 5 to discharge head 4 at a pressure of between 2 and 7 bar and dispensed from there into a capsule 7 which contains a unit dose of a nutritional composition such as an infant formula. When the pressure in capsule 7 reaches a predetermined value, the capsule opens and the reconstituted infant formula is dispensed directly from the capsule into a suitable receptacle such as a baby bottle (not shown). Air pump 6 is then operated to flush any remaining liquid out of the capsule and into the receptacle.
- FIG 2 shows a cross section through an embodiment of discharge head 4 in which the filter 5 is incorporated in the discharge head. Heated water is supplied from heater 3 and enters the top of the discharge head through inlet 41. The heated water then passes through the filter 5 and into chamber 42 before passing to capsule 7. It may be seen that chamber 42 is also connected to air pump 6 (not shown in Figure 2) via inlet 43.
- FIG 3 shows schematically another embodiment of a dispenser according to the invention. As may be seen from Figure 3, this is similar to the embodiment of Figure 1 but is provided with a steam generator 8 connected to the discharge head 4 in place of the heating means. In operation, the interior of discharge head, the filter and, in particular chamber 42 ( Figure 2) may be sterilised as often as desired by passing steam from the steam generator through the discharge head.
- FIG 4 shows an alternative embodiment of the discharge head 4 of the embodiment of Figure 3.
- the discharge head in addition to the water inlet 43 and a steam inlet 44, the discharge head is provided with electrical heating elements 45 whereby the discharge head may be heated during operation of the dispenser to further discourage the adhesion and proliferation of bacteria in chamber 42.
- Figure 5 compares the bacterial contamination in infant formula discharged from a dispenser according to the invention (Figure 5a) with the bacterial contamination in infant formula discharged from a similar dispenser without a bacterial filter ( Figure 5b) and with the bacterial contamination in infant formula discharged from a dispenser such as that disclosed in WO 03/084377 in which the water is pre -boiled and the dispenser is flushed with 45 ml of boiling water every two days ( Figure 5c). In each case, the test period was two weeks.
- the machines were operated as they would be in a family having one infant i.e. six servings per day were prepared using each dispenser with the servings being prepared at spaced intervals.
- the sample analysed was the first serving to be discharged by the dispenser on the day in question as this is likely to be the worst sample because water has been stagnating in the machine overnight.
- the total aerobic mesophilic content (AMC) was then determined for each sample and the results are shown in Figure 5a for a dispenser according to the invention, Figure 5b for the conventional dispenser and Figure 5c for the prior art dispenser.
- AMC was determined by incubating each sample at ambient temperature and exposed to the air until the bacterial colonies were large enough to be measured.
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- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Mechanical Engineering (AREA)
- Epidemiology (AREA)
- Clinical Laboratory Science (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Food Science & Technology (AREA)
- Devices For Dispensing Beverages (AREA)
- Dairy Products (AREA)
- Medicines Containing Plant Substances (AREA)
- Apparatus For Making Beverages (AREA)
- General Preparation And Processing Of Foods (AREA)
- Formation And Processing Of Food Products (AREA)
- Jellies, Jams, And Syrups (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2009000961A MX2009000961A (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition. |
BRPI0715483-6A BRPI0715483B1 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition and dispensing method for baby |
CA002658776A CA2658776A1 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
AU2007278255A AU2007278255B2 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
US12/375,084 US8696899B2 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
PL07787866T PL2046398T3 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
CN2007800354057A CN101516409B (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
AT07787866T ATE512675T1 (en) | 2006-07-25 | 2007-07-25 | DISPENSER FOR PRODUCING A NUTRITIONAL COMPOSITION |
EP07787866A EP2046398B1 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
HK09109530.9A HK1133603A1 (en) | 2006-07-25 | 2009-10-15 | Dispenser for preparing a nutritional composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06117801.8 | 2006-07-25 | ||
EP06117801 | 2006-07-25 |
Publications (1)
Publication Number | Publication Date |
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WO2008012314A1 true WO2008012314A1 (en) | 2008-01-31 |
Family
ID=37684443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/057636 WO2008012314A1 (en) | 2006-07-25 | 2007-07-25 | Dispenser for preparing a nutritional composition |
Country Status (16)
Country | Link |
---|---|
US (1) | US8696899B2 (en) |
EP (1) | EP2046398B1 (en) |
CN (1) | CN101516409B (en) |
AT (1) | ATE512675T1 (en) |
AU (1) | AU2007278255B2 (en) |
BR (1) | BRPI0715483B1 (en) |
CA (1) | CA2658776A1 (en) |
CL (1) | CL2007002183A1 (en) |
ES (1) | ES2367716T3 (en) |
HK (1) | HK1133603A1 (en) |
MX (1) | MX2009000961A (en) |
PL (1) | PL2046398T3 (en) |
PT (1) | PT2046398E (en) |
RU (1) | RU2440145C2 (en) |
TW (1) | TWI417057B (en) |
WO (1) | WO2008012314A1 (en) |
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WO2010128028A1 (en) | 2009-05-05 | 2010-11-11 | Nestec S.A. | Capsule, method and device for preparing a nutritional product |
WO2011042489A1 (en) | 2009-10-08 | 2011-04-14 | Nestec S.A. | Portioned system for preparing a nutritional product |
WO2011070365A1 (en) * | 2009-12-09 | 2011-06-16 | Strix Limited | Steam generating appliances |
WO2012034819A1 (en) | 2010-09-15 | 2012-03-22 | Nestec S.A. | Capsule with enhanced product delivery system |
WO2012049052A1 (en) | 2010-10-12 | 2012-04-19 | Nestec S.A. | Capsule opening kit |
WO2013127694A1 (en) * | 2012-02-29 | 2013-09-06 | Nestec S.A. | Filtration unit for use in machine for preparing ready-to-drink nutritional liquids |
WO2013127696A1 (en) * | 2012-02-29 | 2013-09-06 | Nestec S.A. | Container holder with filtration unit for use in a nutritional preparation machine |
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US8696899B2 (en) | 2006-07-25 | 2014-04-15 | Nestec S.A. | Dispenser for preparing a nutritional composition |
US8703219B2 (en) | 2009-05-05 | 2014-04-22 | Nestec S.A. | Capsule for preparing a nutritional product including a filter |
WO2014082924A1 (en) | 2012-11-29 | 2014-06-05 | Nestec S.A. | Capsule for preparing a beverage or nutritional product |
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Also Published As
Publication number | Publication date |
---|---|
AU2007278255B2 (en) | 2014-01-09 |
BRPI0715483A2 (en) | 2014-05-06 |
US20100021604A1 (en) | 2010-01-28 |
PL2046398T3 (en) | 2011-11-30 |
CN101516409B (en) | 2013-03-20 |
ES2367716T3 (en) | 2011-11-07 |
US8696899B2 (en) | 2014-04-15 |
HK1133603A1 (en) | 2010-04-01 |
RU2440145C2 (en) | 2012-01-20 |
EP2046398A1 (en) | 2009-04-15 |
PT2046398E (en) | 2011-09-07 |
EP2046398B1 (en) | 2011-06-15 |
RU2009106467A (en) | 2010-08-27 |
ATE512675T1 (en) | 2011-07-15 |
CA2658776A1 (en) | 2008-01-31 |
MX2009000961A (en) | 2009-02-20 |
TW200816939A (en) | 2008-04-16 |
TWI417057B (en) | 2013-12-01 |
BRPI0715483B1 (en) | 2015-06-30 |
AU2007278255A1 (en) | 2008-01-31 |
CL2007002183A1 (en) | 2008-06-13 |
CN101516409A (en) | 2009-08-26 |
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