WO2007102159A2 - Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof - Google Patents
Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof Download PDFInfo
- Publication number
- WO2007102159A2 WO2007102159A2 PCT/IL2007/000300 IL2007000300W WO2007102159A2 WO 2007102159 A2 WO2007102159 A2 WO 2007102159A2 IL 2007000300 W IL2007000300 W IL 2007000300W WO 2007102159 A2 WO2007102159 A2 WO 2007102159A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solid
- water
- fertilizer
- concentration
- solution
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/20—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
Definitions
- the invention relates to a solid free-flowing particulate fertilizer composition and to a method of manufacturing same, comprising phosphoric acid in mixture with monopotassium phosphate in a sub-equimolar ratio.
- the solid composition is used directly as a fertilizer or is used in the preparation of concentrated aqueous fertilizer compositions comprising otherwise scarcely soluble nutrients.
- US 5,395,418 describes fertilizer compositions containing urea phosphate with additional important nutrients such as calcium.
- the fertilizer compositions containing urea phosphate provide a sufficiently low pH to prevent the precipitation of solid materials and turbidity, but the use of urea or urea phosphate is not free of disadvantages. There are situations, e.g.
- compositions which can be stored without losing the aforesaid properties.
- This invention also aims at providing a method of manufacturing solid, free- flowing, non-caking particulate fertilizer compositions, which provide stable aqueous solutions, clear even in the presence of high concentrations of calcium or magnesium ions.
- the invention provides a solid particulate fertilizer composition containing from about 35 wt% to about 41 wt% of phosphoric acid (PA), and from about 59 wt% to about 65 wt% of monopotassium phosphate (MKP), which composition yields at the room temperature a clear aqueous solution at a concentration of up to 150 gram per liter of solution (g/1), in the presence of calcium or magnesium nitrate in a concentration of up to 150 g/1.
- Said solid particulate fertilizer composition contains water preferably in a concentration of from 0.1 to 0.6 wt%, more preferably from 0.2 to 0.5 wt%.
- the fertilizer composition of the invention yields a clear aqueous solution at a concentration of up to 150 g/1 also when calcium nitrate and magnesium nitrate are present simultaneously, each in a concentration of up to 150 gA.
- the above solubility values relate to the room temperature, which may comprise a temperature from 10 to 35°C, usually about 25°C.
- a solid particulate fertilizer composition according to the invention provides phosphorus and potassium, and is intended for uses either separately or together with other components, preferably in clear solutions containing said particulate solid composition and metal salts.
- the content of phosphorus in said solid composition is preferably in the range of 58.5-60.5 wt%, and the content of potassium in said solid composition, expressed as K2O moiety, is preferably in the range of 19.5-22.5 wt%.
- the solid particulate fertilizer composition according to the invention is a free- flowing material.
- the composition is preferably granular material with suitable hygroscopicity, for example from about 60 to about 65%, when expressed as C.R.U.
- the solid composition according to the invention may be mixed with calcium or magnesium nitrate and with water to produce a clear solution containing up to about 1.3 mol/1 phosphate ions beside up to about 1.0 mol/1 magnesium or calcium ions without the formation of precipitates.
- said solid composition in an amount of from 1 to 150 g/1 is dissolved in water together with from 1 to about 160 g/1 of calcium nitrate. In other preferred embodiment of the invention, said solid composition in an amount of from 1 to 150 g is dissolved in water together with from 1 to about 150 g of magnesium nitrate.
- the invention relates to the use of a solid particulate fertilizer containing from about 35 wt% to about 41 wt% of PA, and from about 59 wt% to about 65 wt% of MIQP, and further less than about 0.6 wt% water, in the preparation of a clear, stable, aqueous stock solution comprising from 1 to 150 g/1 of said solid composition and further nutrients selected from the group consisting of calcium nitrate, calcium phosphate, magnesium nitrate, and salts of magnesium, iron, manganese, copper, zinc, and molybdenum.
- the use of the invention comprises preparing stock solutions to be used as fertilizers later, either directly or after dilution.
- the use of the solid composition comprises preparing aqueous stock solutions to be used as components in the preparation of other fertilizers or fertilizer compositions, preferably said fertilizers or fertilizer compositions containing nutrients selected from calcium nitrate, calcium phosphate, magnesium nitrate, salts of magnesium, iron, manganese, copper, zinc, and molybdenum; said fertilizers or fertilizer compositions may, for various applications, as a skilled person will understand, necessitate the inclusion of other materials, such as other nutrients, micronutrients, color adjusting agents, etc.
- aqueous stock solutions to be used as a fertilizer or as a component in the preparation of a fertilizer, are stable against the formation of precipitates, as well as against the growth of microorganisms. No chelating agents are needed for introducing the metal nutrients to the compositions of the invention.
- the invention is directed to the process of manufacturing a solid particulate fertilizer composition containing potassium and phosphorus, expressed as
- P 2 O 5 and K 2 O moieties in the ranges of 58.5-60.5 wt% and 19.5-22.5 wt%, respectively, which fertilizer dissolves in water at the room temperature at a concentration of up to 150 g/1, in the presence of magnesium or calcium nitrate in a concentration of up to 150 g/1, to yield a clear solution
- said method comprising i) providing technical or food grade phosphoric acid (PA), preferably containing at least 50 wt% of P2O5 moiety, most of the impurities being essentially water; ⁇ ) providing monopotassium phosphate (MKP); iii) mixing said PA and said MKP with water, in any order, and heating under stirring to a temperature of from about 65 to about 90 0 C until a clear solution is obtained, wherein the initial amount of water in the mixture, including water added as impurities with said PA and said MKP, preferably constitutes from 5 to 20 wt% of the mixture, and the weight ratios of said MKP to
- PA phosphoric acid
- MKP monopotassium phosphate
- Various fertilizers were described, comprising phosphoric acid (PA) and monopotassium phosphate (MKP).
- PA phosphoric acid
- MKP monopotassium phosphate
- WO 01/74740 having common inventors with the instant invention, provides a composition containing PA and MKP in the equimolar amounts, and a method of manufacturing it, comprising the formation of crystals of double salt KHs(PO ⁇ .
- the instant invention does not include crystallization and crystal separation, the manufacturing procedure being simpler in this invention, providing a product without inherent water component, such as crystal water, the product, comprising a sub-equimolar content of PA, being free-flowing and less hygroscopic, without tendency to caking.
- the invention provides a well soluble particulate solid, which is easily used as a potassium and phosphorus source, either directly used for fertilizing or used in preparing solid or liquid preparations, wherein the advantageous properties of the particulate solid are fully utilized when preparing aqueous solutions, because the solid of the invention dissolves completely and quickly, and provides aqueous solutions which have high capacity for dissolving further nutrients which may be added to the mixture in any order.
- Such nutrients are preferably selected from among calcium nitrate, calcium phosphate, magnesium nitrate, and additional salts of magnesium, and salts of iron, manganese, copper, zinc, and molybdenum.
- the particulate solid of the invention provides suitable pH values, usually between 2.2 and 2.8, when dissolved in water, enabling to include important metal nutrients without chelating agents.
- suitable pH values usually between 2.2 and 2.8
- the intention is not only to use such a mixture as a fertilizer, but, in one aspect, to demonstrate the high solubilizing capacity of the solid composition according to the invention, because combinations of phosphate and calcium, in other contexts incompatible, provide clear solutions in this invention.
- a skilled person will choose any composition, whether with cited high concentrations, or with any lower concentrations, according to the need.
- the particulate, free-flowing solid fertilizer of the invention provides an easy-to-use means for a variety of agricultural aims, including providing a solid source of quickly available PK, providing a concentrated liquid PK source with other nutrients, providing a solubilizing agent for making clear liquid nutrient mixtures, providing concentrated clear liquid NPK mixtures for urea-free applications, etc.
- An important aspect of the invention is the composition consistency, which, being a free-flowing powder with low tendency to caking, enables easy handling, even after prolonged storage.
- the invention provides a process for making solid particulate compositions comprising PA and MKP, the PA constituting from 35 to 41 wt% PA, which compositions are easily used and manipulated. Whether used directly, or together with other nutrients, they provide important components to the soil without forming precipitates in stock solutions, and without causing deposits in the soil.
- the particulate solid fertilizer is, in one aspect of the invention, used as a solubilizer of otherwise barely soluble or insoluble components.
- the process of the invention involves the stage of providing at a higher temperature a concentrated liquid phase containing PA and MKP, and the stage of removing the solvent from the mixture while homogenizing it at a higher temperature under vacuum.
- the process of the invention requires a device ensuring, beside the desired temperatures and pressures, continual stirring in liquid phase which continues also during the transition from liquid to solid phase and afterwards, wherein the parts of said device being in contact with the reaction mixture are resistant to the reactants and to the product.
- a technical PA is provided, and substantially dry monopotassium phosphate is provided, and the materials are mixed in any order with relatively small quantity of water, preferably not exceeding about 20 wt% of the total mixture weight.
- the water contents of the raw materials are considered, so that the total water in the mixture will be between 5 and 20 wt%.
- the term technical PA in this invention is intended to include technical grades or food grades, and it relates to a material preferably comprising at least 60 wt% of H3PO4, for example materials comprising from 55-67 wt% P2O5, the rest being mainly water, wherein minor amounts of agriculturally acceptable impurities may be present.
- Said MKP preferably contains less than several wt% water, for example less than 1 wt%, to enable smooth material manipulations.
- the device for performing the process of the invention ensures the continual homogenization at any temperature in the range used in the process, comprising temperatures from the room temperature to about 125°C. Further, said device enables to cool the reaction mixture when necessary. Finally, a stable and sufficient vacuum must be ensured, providing at least 100 mbar.
- a flexible means is provided for preparing fertilizer compositions, either as water-soluble solids or as concentrated aqueous solutions, either for providing quickly- available PK or for solubilizing less soluble nutrients, either for direct use or as stock solutions, either for urea-free environment or for other purposes.
- PA Technical phosphoric acid
- MKP monopotassium phosphate
- the mixture was heated under continuous stirring, 25 rpm, to 90 0 C until a clear solution was obtained.
- the reactor was closed and connected with a vacuum pump, gradually decreasing the pressure to below 100 mbar, while heating the mixture up to a temperature of about 116-118°C, for about 5 hour.
- a solid with a water content below 0.5 wt% was cooled to about 40 0 C, and the material was unloaded.
- the yield was about 4.8 kg of particulate product; after sieving on 2 mm sieves, about 4.7 kg material was obtained, bigger particles being added to the next batch.
- the content of water was determined by thermogravimetric analysis, the content of P2O5 spectrophotometrically, the content of K2O by potentiometric titration with tetraphenylborate.
- the hygroscopicity was characterized as the critical relative humidity (C.R.U.), by determining a relative humidity of an environment in which water absorption by the sample causes a mass increase higher than 3%; hygroscopicity of the product was 60-65 %, when expressed as C.R.U.
- the flowability index was determined by i) filling a smooth funnel of stainless steel closed at the exit, with a top diameter of 100 mm and an exit diameter of 10 mm, with 300 grams of the examined substance, and ii) measuring the time t the substance takes to pass through the exit after its opening.
- the FI value of the product was higher than FI of the MKP used in the process.
- a free-flowing particulate material was obtained containing 59.5% of P2O5 moiety and 21.4% of K2O moiety.
- the particulate solid was dissolved in distilled water, 150 g/1, no precipitate was observed during 1 week period.
- the hygroscopicity of the product expressed as C.R.U., was 60-65 %.
- the pH of a 1 wt% solution was 2.4.
- Example 2 The product obtained in Example 2, was dissolved in water and various amounts of Ca(NO3)2, Mg(NOs)2, and metal sulfates were added to reach the required concentrations. The results are compared with compositions in which monoammonium phosphate (MAP) was used instead of the product. Table 1 shows the results. The values mean gram per liter of aqueous solutions, the product of the invention is denoted as Pr.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0707083A BRPI0707083B1 (en) | 2006-03-09 | 2007-03-08 | solid homogeneous particulate fertilizer composition, method of preparing a stable and transparent aqueous starter solution and manufacturing process of the solid homogeneous particulate fertilizer composition |
AP2008004607A AP2399A (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof. |
CN2007800082508A CN101400627B (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof |
MX2008011042A MX2008011042A (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof. |
JP2008557899A JP5600242B2 (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing free-flowing solid fertilizer composition and its preparation |
US12/280,838 US7967889B2 (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof |
CA2644258A CA2644258C (en) | 2006-03-09 | 2007-03-08 | Soluble pk fertilizer compositions |
AU2007224319A AU2007224319B2 (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof |
EP07713321.3A EP2004574B1 (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof |
ES07713321T ES2572141T3 (en) | 2006-03-09 | 2007-03-08 | Solid, freely flowing, soluble and solubilizing fertilizer compositions, and the preparation thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL174212 | 2006-03-09 | ||
IL174212A IL174212A (en) | 2006-03-09 | 2006-03-09 | Soluble and solubilizing, free-flowing, solid fertilizer compositions and the preparation thereof |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2007102159A2 true WO2007102159A2 (en) | 2007-09-13 |
WO2007102159A3 WO2007102159A3 (en) | 2007-12-13 |
WO2007102159B1 WO2007102159B1 (en) | 2008-02-07 |
Family
ID=38475261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IL2007/000300 WO2007102159A2 (en) | 2006-03-09 | 2007-03-08 | Soluble and solubilizing, free-flowing, solid fertilizer compositions, and the preparation thereof |
Country Status (16)
Country | Link |
---|---|
US (1) | US7967889B2 (en) |
EP (1) | EP2004574B1 (en) |
JP (1) | JP5600242B2 (en) |
CN (1) | CN101400627B (en) |
AP (1) | AP2399A (en) |
AU (1) | AU2007224319B2 (en) |
BR (1) | BRPI0707083B1 (en) |
CA (1) | CA2644258C (en) |
ES (1) | ES2572141T3 (en) |
IL (1) | IL174212A (en) |
MX (1) | MX2008011042A (en) |
PL (1) | PL2004574T3 (en) |
RU (1) | RU2429213C2 (en) |
UA (1) | UA96591C2 (en) |
WO (1) | WO2007102159A2 (en) |
ZA (1) | ZA200808525B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011110212A1 (en) | 2010-03-08 | 2011-09-15 | Prayon S.A. | Composition including hemipotassium phosphate |
WO2014002098A1 (en) | 2012-06-28 | 2014-01-03 | Rotem Amfert Negev Ltd. | Continuous process for manufacturing freely flowing solid acidic p/k fertilizer |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL220685B (en) * | 2012-06-28 | 2018-02-28 | Rotem Amfert Negev Ltd | Continuous process for manufacturing a neutral granular p/k fertilizer |
Citations (4)
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US3832154A (en) * | 1972-10-10 | 1974-08-27 | Tennessee Valley Authority | Production of chloride-free potassium phosphates |
WO2001074740A2 (en) * | 2000-04-03 | 2001-10-11 | Rotem Amfert Negev Ltd. | Improved solubility fertilizer compounds and compositions |
US20020129632A1 (en) * | 2001-03-15 | 2002-09-19 | Colin Sheppardson | Concentrated phosphorus fertilizer |
US20050119124A1 (en) * | 1999-06-14 | 2005-06-02 | Alfred Alyeshmerni | Phosphorus and potassium fertilizer for all forms of perennial trees, vines and annual crops |
Family Cites Families (13)
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US1858230A (en) * | 1929-03-26 | 1932-05-10 | George P Walton | Fertilizer material and process for manufacturing the same |
IL75767A (en) * | 1985-07-10 | 1988-09-30 | Negev Phosphates Ltd | Process for the manufacture of pure monopotassium phosphate |
IL79020A0 (en) * | 1986-06-04 | 1986-09-30 | Haifa Chemicals Ltd | Process for the manufacture of monopotassium phosphate |
JP2540352B2 (en) * | 1988-03-11 | 1996-10-02 | フマキラー株式会社 | Aerosol fertilizer |
EP0852567A1 (en) * | 1995-09-08 | 1998-07-15 | Monsanto Company | Process for preparing hemipotassium phosphate |
US5707418A (en) | 1997-01-23 | 1998-01-13 | Safergro Laboratories, Inc. | Inorganic phosphorous fertilizer |
WO1998047814A1 (en) | 1997-04-23 | 1998-10-29 | Solutia Inc. | Solution crystallization process for the production of incongruently-soluble acid phosphates by incorporating a phosphate salt solution wash |
DE19735448B4 (en) | 1997-08-16 | 2007-02-01 | Chemische Fabrik Budenheim Kg | Use of anhydrous acidic alkali metal phosphate as a melt binder |
US20030029211A1 (en) * | 2001-03-15 | 2003-02-13 | Colin Sheppardson | Concentrated phosphorus fertilizer usable as a pesticide, fungicide, adjuvant, acidifier and phytophthora destroying agent |
JP2004051434A (en) * | 2002-07-19 | 2004-02-19 | Sumika Takeda Engei Kk | Calcium-containing liquid fertilizer composition |
IL150910A0 (en) | 2002-07-25 | 2003-02-12 | Rotem Amfert Negev Ltd | Agrochemical composition containing phosphite and process for the preparation thereof |
IL154007A (en) | 2003-01-16 | 2007-09-20 | Rotem Amfert Negev Ltd | Soluble fertilizer compositions comprising calcium and/or magnesium phosphates |
JP4482344B2 (en) * | 2004-02-09 | 2010-06-16 | サンアグロ株式会社 | Foliar spray |
-
2006
- 2006-03-09 IL IL174212A patent/IL174212A/en active IP Right Grant
-
2007
- 2007-03-08 CA CA2644258A patent/CA2644258C/en active Active
- 2007-03-08 RU RU2008135930/21A patent/RU2429213C2/en active
- 2007-03-08 PL PL07713321.3T patent/PL2004574T3/en unknown
- 2007-03-08 US US12/280,838 patent/US7967889B2/en active Active
- 2007-03-08 BR BRPI0707083A patent/BRPI0707083B1/en active IP Right Grant
- 2007-03-08 MX MX2008011042A patent/MX2008011042A/en active IP Right Grant
- 2007-03-08 JP JP2008557899A patent/JP5600242B2/en not_active Expired - Fee Related
- 2007-03-08 EP EP07713321.3A patent/EP2004574B1/en active Active
- 2007-03-08 CN CN2007800082508A patent/CN101400627B/en active Active
- 2007-03-08 UA UAA200811262A patent/UA96591C2/en unknown
- 2007-03-08 AU AU2007224319A patent/AU2007224319B2/en not_active Ceased
- 2007-03-08 WO PCT/IL2007/000300 patent/WO2007102159A2/en active Application Filing
- 2007-03-08 AP AP2008004607A patent/AP2399A/en active
- 2007-03-08 ES ES07713321T patent/ES2572141T3/en active Active
-
2008
- 2008-10-07 ZA ZA200808525A patent/ZA200808525B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US3832154A (en) * | 1972-10-10 | 1974-08-27 | Tennessee Valley Authority | Production of chloride-free potassium phosphates |
US20050119124A1 (en) * | 1999-06-14 | 2005-06-02 | Alfred Alyeshmerni | Phosphorus and potassium fertilizer for all forms of perennial trees, vines and annual crops |
WO2001074740A2 (en) * | 2000-04-03 | 2001-10-11 | Rotem Amfert Negev Ltd. | Improved solubility fertilizer compounds and compositions |
US20020129632A1 (en) * | 2001-03-15 | 2002-09-19 | Colin Sheppardson | Concentrated phosphorus fertilizer |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011110212A1 (en) | 2010-03-08 | 2011-09-15 | Prayon S.A. | Composition including hemipotassium phosphate |
WO2014002098A1 (en) | 2012-06-28 | 2014-01-03 | Rotem Amfert Negev Ltd. | Continuous process for manufacturing freely flowing solid acidic p/k fertilizer |
US9278890B2 (en) | 2012-06-28 | 2016-03-08 | Rotem Amfert Negev Ltd. | Continuous process for manufacturing freely flowing solid acidic P/K fertilizer |
AP4024A (en) * | 2012-06-28 | 2017-02-03 | Rotem Amfert Negev Ltd | Continuous process for manufacturing freely flowing solid acidic p/k fertilizer |
AU2013282720B2 (en) * | 2012-06-28 | 2017-11-30 | Rotem Amfert Negev Ltd. | Continuous process for manufacturing freely flowing solid acidic P/K fertilizer |
RU2643042C2 (en) * | 2012-06-28 | 2018-01-30 | Ротем Амферт Негев Лтд. | Continuous method for production of liquid solid acid phosphoro-potassium (p/p) fertilizer |
Also Published As
Publication number | Publication date |
---|---|
WO2007102159B1 (en) | 2008-02-07 |
PL2004574T3 (en) | 2016-10-31 |
EP2004574B1 (en) | 2016-03-02 |
US20090071212A1 (en) | 2009-03-19 |
RU2008135930A (en) | 2010-03-10 |
AU2007224319A1 (en) | 2007-09-13 |
IL174212A (en) | 2011-09-27 |
ES2572141T3 (en) | 2016-05-30 |
JP5600242B2 (en) | 2014-10-01 |
RU2429213C2 (en) | 2011-09-20 |
MX2008011042A (en) | 2009-03-16 |
WO2007102159A3 (en) | 2007-12-13 |
JP2009529484A (en) | 2009-08-20 |
BRPI0707083A2 (en) | 2011-04-19 |
AP2008004607A0 (en) | 2008-10-31 |
ZA200808525B (en) | 2009-08-26 |
CA2644258A1 (en) | 2007-09-13 |
AU2007224319B2 (en) | 2012-07-05 |
AP2399A (en) | 2012-04-30 |
BRPI0707083B1 (en) | 2018-12-26 |
IL174212A0 (en) | 2006-08-01 |
CA2644258C (en) | 2014-08-05 |
EP2004574A2 (en) | 2008-12-24 |
US7967889B2 (en) | 2011-06-28 |
CN101400627B (en) | 2012-10-03 |
CN101400627A (en) | 2009-04-01 |
UA96591C2 (en) | 2011-11-25 |
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