WO2007083262A1 - Fabric treatment composition providing stain repellant coating - Google Patents
Fabric treatment composition providing stain repellant coating Download PDFInfo
- Publication number
- WO2007083262A1 WO2007083262A1 PCT/IB2007/050132 IB2007050132W WO2007083262A1 WO 2007083262 A1 WO2007083262 A1 WO 2007083262A1 IB 2007050132 W IB2007050132 W IB 2007050132W WO 2007083262 A1 WO2007083262 A1 WO 2007083262A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 101
- 239000004744 fabric Substances 0.000 title description 4
- 239000011248 coating agent Substances 0.000 title description 3
- 238000000576 coating method Methods 0.000 title description 3
- 239000004753 textile Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 19
- -1 alkyl quaternary ammonium compounds Chemical class 0.000 claims abstract description 18
- 239000002738 chelating agent Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 125000003118 aryl group Chemical class 0.000 claims abstract description 14
- 239000006174 pH buffer Substances 0.000 claims abstract description 11
- 229920000768 polyamine Polymers 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- 239000000375 suspending agent Substances 0.000 claims abstract description 9
- 125000002091 cationic group Chemical group 0.000 claims abstract description 8
- 235000005985 organic acids Nutrition 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 3
- 150000001412 amines Chemical class 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 7
- 229920006318 anionic polymer Polymers 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 1
- 238000009738 saturating Methods 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 125000000217 alkyl group Chemical group 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 18
- 125000002947 alkylene group Chemical group 0.000 description 15
- 150000002431 hydrogen Chemical class 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 125000001183 hydrocarbyl group Chemical group 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 125000005529 alkyleneoxy group Chemical group 0.000 description 3
- 150000001408 amides Chemical group 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 229920005573 silicon-containing polymer Polymers 0.000 description 3
- UXIDHQPACNSJJP-UHFFFAOYSA-M sodium;2-[2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC([O-])=O UXIDHQPACNSJJP-UHFFFAOYSA-M 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000004450 alkenylene group Chemical group 0.000 description 2
- 125000005275 alkylenearyl group Chemical group 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- 125000006755 (C2-C20) alkyl group Chemical group 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 description 1
- IJVRPNIWWODHHA-UHFFFAOYSA-N 2-cyanoprop-2-enoic acid Chemical compound OC(=O)C(=C)C#N IJVRPNIWWODHHA-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- GQWNPIKWYPQUPI-UHFFFAOYSA-N 2-methylbut-3-enoic acid Chemical compound C=CC(C)C(O)=O GQWNPIKWYPQUPI-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- JOCBASBOOFNAJA-UHFFFAOYSA-N N-tris(hydroxymethyl)methyl-2-aminoethanesulfonic acid Chemical compound OCC(CO)(CO)NCCS(O)(=O)=O JOCBASBOOFNAJA-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- FBYFHODQAUBIOO-UHFFFAOYSA-N carboxyethyl ether Natural products OC(=O)C(C)OC(C)C(O)=O FBYFHODQAUBIOO-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical group C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CXHHBNMLPJOKQD-UHFFFAOYSA-N methyl hydrogen carbonate Chemical compound COC(O)=O CXHHBNMLPJOKQD-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229940055076 parasympathomimetics choline ester Drugs 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
Definitions
- This invention relates to benefit compositions that can maintain or rejuvenate an article's stain repellency and processes for making and using such compositions.
- articles for example, articles that comprise fibers such as garments and linens are generally treated with compositions that provide such articles with a degree of stain repellency.
- compositions that provide such articles with a degree of stain repellency.
- effectiveness of such treatment compositions is fleeting and/or limited. Will not being bound by theory, Applicants believe that such loss in effectiveness is do to the adherence of materials that attract stains to the article's stain repellant coating.
- This invention relates to textile benefit compositions that can maintain or rejuvenate article's stain repellency and processes for making and using such compositions.
- Such article may be a textile product.
- textile products includes, unless otherwise indicated, fibers, yarns, fabrics and/or garments or articles comprising same.
- Applicants' benefit compositions may take any form, for example, a general treatment composition, a detergent, a wash additive or a rinse additive.
- a general treatment composition such composition may comprise from about 0.1% to about 60%, from about 0.5% to about 50%, or even from about 1% to about 40% of a chelating agent, from about 0.1% to about 50%, from about 0.5% to about 40%, or even from about 1% to about 30% of a stripping agent and a from about 0.01% to about 40%, from about 0.1% to about 35%, or even from about 0.5% to about 30% of a suspending agent and optionally a pH buffer and optionally one or more cleaning adjuncts.
- such benefit composition is a detergent composition
- such composition may comprise from about 0.001% to about 30%, from about 0.05% to about 25%, or even from about 0.01% to about 20% of a chelating agent, from about 0.001% to about 25%, from about 0.05% to about 20%, or even from about 0.01% to about 15% of a stripping agent and a from about 0.01% to about 40%, from about 0.1% to about 35%, or even from about 0.5% to about 30% of a suspending agent and at least one detergent adjunct.
- such composition may comprise from about 0.1% to about 60%, from about 0.5% to about 50%, or even from about 1% to about 40% of a chelating agent, from about 0.1% to about 50%, from about 0.5% to about 40%, or even from about 1% to about 30% of a stripping agent and a from about 0.01% to about 40%, from about 0.1% to about 35%, or even from about 0.5% to about 30% of a suspending agent and a sufficient amount of pH buffer to provide a neat product pH of from about 1 to about 9, from about 1.5 to about 8, or even form about 2 to about 7.
- a chelating agent from about 0.1% to about 50%, from about 0.5% to about 40%, or even from about 1% to about 30% of a stripping agent and a from about 0.01% to about 40%, from about 0.1% to about 35%, or even from about 0.5% to about 30% of a suspending agent and a sufficient amount of pH buffer to provide a neat product pH of from about 1 to about 9, from about 1.5 to about 8, or even form about 2 to about 7.
- compositions may be a carrier.
- the pH buffer comprises citric acid.
- such benefit compositions are capable of maintaining or rejuvenating a textile product's stain repellency when said textile product is contacted with such textile benefit composition.
- such textile benefit compositions do not contain one or more adjuncts materials, for example, bleach activators, surfactants, builders, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, perfumes, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids and/or pigments.
- adjuncts materials for example, bleach activators, surfactants, builders, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, perfumes, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids and/or pigments.
- Useful chelating agents include chelating agents selected from the group consisting of aminocarboxylates, phosphonates, polyfunctionally-substituted aromatic chelating agents, and mixtures thereof.
- Useful aminocarboxylates include ethylenediaminetetracetates, N - h y d r o x y e t h y l e t h y l e n e d i a m i n e t r i a c e t a t e s , nitrilotriacetates, ethylenediamine tetraproprionates, triethylenetetraaminehexacetates, diethylenetriaminepentaacetates, and ethanoldiglycines, alkali metal, ammonium and substituted ammonium salts of such aminocarboxylates.
- Useful phosphonates include aminophosphonates.
- Useful polyfunctionally-substituted aromatic chelating agents include l-hydroxy-2,4-disulfo-6- carboxybenzene, l,3,5-trihydroxy-2-carboxybenzene, l,3,5-tris[carboxyethylether]-2- carboxybenzene, 2,4-disulfo-l,5-dihydrobenzene, l,4-bis[carboxymethylether]-2,5- dicarboxybenzene and mixtures thereof. Additional examples of polyfunctionally-substituted aromatic chelating agents can be found in U.S. Pat No. 3,812,044.
- Useful stripping agents include cationic materials selected from the group consisting of protonatable amines, alkyl quaternary ammonium compounds, cationic silicones, cationic polymers and mixtures thereof.
- Suitable protonatable amines include, protonatable amines having Formula I below:
- each R is independently selected from C 1 -C 22 alkyl, C 1 -C 22 hydroxyalkyl or a benzyl group; each RI is independently selected from Cn-C 22 linear alkyl, Cn-C 22 branched alkyl, Cn-C 22 linear alkenyl, or Cn-C 22 branched alkenyl; and each Q may comprise a carbonyl, carboxyl, or amide moiety.
- Suitable alkylated quaternary ammonium compounds include mono-alkyl quats, di-alkyl, tri-alkyl quats and tetra-alkyl quats and certain cationic surfactants.
- Suitable mono- alkyl quats, di-alkyl, tri-alkyl quats and tetra-alkyl quats typically have Formula II below:
- each R is independently selected from C 1 -C 22 alkyl, C 1 -C 22 hydroxyalkyl, or a benzyl group; each RI is independently selected from Cn-C 22 linear alkyl, Cn-C 22 branched alkyl, Cn-C 22 linear alkenyl, or Cn-C 22 branched alkenyl; X " is a water soluble anionic species such as chloride, bromide or methyl sulfate, and Q may comprise a carbonyl, carboxyl, or amide moiety.
- Suitable cationic silicones include silicones functionalized by amine derived compounds and cationic silicone polymers.
- Suitable silicones functionalized by amine derived compounds include amino silicones having Formula III below:
- R 1 , R 2 , R 3 , R 4 can be independently selected from:
- L and K can be independently selected from C 1 -C 22 linear or branched, substituted or unsubstituted hydrocarbyl moieties.
- L and K can be independently selected from Ci-Ci 2 linear or branched, substituted or unsubstituted hydrocarbyl moieties.
- L and K can be independently selected from Ci-C 4 linear or branched, substituted or unsubstituted hydrocarbyl moieties.
- L and K can be independently selected from methylene, ethylene, propylene, 2-methylpropylene, butylene, octadecylene or 3-(2,2',6,6'-tetramethyl-4-oxy-piperidyl)propyl.
- R 5 , R 6 , R 7 and R 8 can be independently selected from H, or C 1 -C 22 linear or branched, substituted or unsubstituted hydrocarbyl moieties.
- SiCW means the ratio of oxygen atoms to silicon atoms, i.e., SiO 1/2 means one oxygen atom is shared between two silicon atoms.
- Suitable cationic silicone polymers include cationic silicone polymers having Formula IV below:
- Formula IV wherein [CAP] can be a backbone termination or truncation unit; m can be an integer from 1 to 50 and each Z unit may have Formula V below: (R) x - W- (R) x
- Formula V wherein for Formula V: x can be 0 or 1 ; W can be a siloxane unit having Formula VI below:
- each R 1 unit can be a C 1 -C 22 linear or branched, substituted or unsubstituted hydrocarbyl moiety; wherein for Formula V above R can have Formula VII below:
- L can be a suitable carbon containing linking unit, suitable linking units include, but are not limited to, alkylene moieties, acrylate moieties, and amide containing moieties; each B can be a unit comprising at least one secondary, tertiary, or quaternary amino moiety; R 2 can be a coupling unit having the Formula VIII below:
- R 4 R 4 (R 3 O) Z — (C 1 H- CH- C ' H) — (OR 3 ) Z —
- each R 3 can be independently selected from a C 2 -C 12 linear or branched alkylene moiety, in one aspect each R 3 can be independently ethylene, 1,3 -propylene, or 1,2-propylene; each R 4 can be independently selected from hydrogen, or a C 1 -C 22 linear or branched, substituted or unsubstituted hydrocarbyl moiety, in one aspect each R 4 can be independently selected from hydrogen, a C 1 -C 22 linear or branched alkyl moiety; a C 1 -C 22 cycloalkyl moiety; a C 1 -C 22 linear or branched fluoroalkyl moiety; a C 2 -C 22 linear or branched alkenyl moiety; a C6-C 22 aryl moiety; or a C7-C 22 alkylenearyl moiety; in another aspect each R 4 can be hydrogen, or a C 1 -C 1 0 linear or branched alkyl moiety;
- Suitable cationic surfactants include quaternary ammonium surfactants selected from the group consisting of mono C ⁇ -Ci ⁇ , C ⁇ -Cio N-alkyl or alkenyl ammonium surfactants, wherein the remaining N positions are substituted by methyl, hydroxyehthyl or hydroxypropyl groups.
- the cationic surfactant may be C ⁇ -Cig alkyl or an alkenyl ester of an quaternary ammonium alcohol, such as quaternary choline esters.
- cationic surfactants have Formula IX below:
- R 1 is a Cg-Cig hydrocarbyl, C 8-I4 alkyl, or even Cg, Ci 0 or Ci 2 alkyl
- X " is a water soluble anionic species such as chloride, bromide or methyl sulfate.
- Useful suspending agents include anionic polymers, modified polyamine polymers and mixtures thereof.
- Suitable anionic polymers include random polymers, block polymers and mixtures thereof.
- Such polymers typically comprise first and second moieties in a ratio of from about 100:1 to about 1:5.
- Suitable first moieties include moieties derived from monoethylenically unsaturated C 3 -C 8 monomers comprising at least one carboxylic acid group, salts of such monomers, and mixtures thereof.
- suitable monomers include monoethylenically unsaturated C 3 -C 8 monocarboxylic acids and C 4 -C 8 dicarboxylic acids selected from the group consisting of acrylic acid, methacrylic acid, beta-acryloxypropionic acid, vinyl acetic acid, vinyl propionic acid, crotonic acid, ethacrylic acid, alpha-chloro acrylic acid, alpha-cyano acrylic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, methylenemalonic acid, their salts, and mixtures thereof.
- suitable first moieties comprise monomers that are entirely selected from the group consisting of: acrylic acid, methacrylic acid, maleic acid and mixtures thereof.
- Suitable second moieties include: 1.) Moieties derived from modified unsaturated monomers having the formulae R - Y - L and
- R a can be H or Ci-C 4 alkyl
- L can be selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium and amine bases, saturated Ci-C 20 alkyl, C 6 -Ci 2 aryl, and C 7 -C 20 alkylaryl
- Z can be selected from the group consisting of C 6 -Ci 2 aryl and C 7 -Ci 2 arylalkyl.
- R 1 can be H and (ii) X can be H, or CO 2 H; b.) Y can be -CO 2 -; c.) L can be selected from the group consisting of hydrogen, alkali metals, C 6 -Ci 2 aryl, and C 7 -C 20 alkylaryl; and d.) Z can be selected from the group consisting of C 6 -Ci 2 aryl and C 7 -Ci 2 arylalkyl.
- the variables R, R 1 , Y, L and Z can be as described immediately above and the variable X can be H.
- Suitable anionic polymers comprising such first and second moieties typically have weight- average molecular weights of from about 1000 Da to about 100,000 Da..
- Another class of suitable second moiety includes moieties derived from ethylenically unsaturated monomers containing from 1 to 100 repeat units selected from the group consisting of Ci-C 4 carbon alkoxides and mixtures thereof.
- An example of such an unsaturated monomer is represented by the formula J-G-D wherein:
- G can be selected from the group consisting of Ci-C 4 alkyl, -O-, -CH 2 O-, -CO 2 -.
- D can be selected from the group consisting of a.) -CH 2 CH(OH)CH 2 O(R 3 O) d R 4 ; b.) -CH 2 CH[O(R 3 O) d R 4 ]CH 2 OH; c.) -CH 2 CH(OH)CH 2 NR 5 (R 3 O) d R 4 ; d.) -CH 2 CH[NR 5 (R 3 O) d R 4 ]CH 2 OH, and mixtures thereof; wherein R 3 can be selected from the group consisting of ethylene, 1,2-propylene, 1,3-propylene, 1,2- butylene, 1,4-butylene, and mixtures thereof;
- R 4 can be a capping unit selected from the group consisting of H, C 1 -C 4 alkyl, C O -C I2 aryl and C 7 -C 20 alkylaryl;
- R 5 can be selected from the group consisting of H, Ci-C 4 alkyl C 6 -Ci 2 aryl and C 7 -C 20 alkylaryl; and subscript index d can be an integer from 1 to 100.
- G can be selected from the group consisting of -O-, -CH 2 O-, -CO 2 -.
- D can be selected from the group consisting of a.) -CH 2 CH(OH)CH 2 O(R 3 O) d R 4 ; b.) -CH 2 CH[O(R 3 O) d R 4 ]CH 2 OH, and mixtures thereof; wherein R 3 can be ethylene;
- R 4 can be a capping unit selected from the group consisting of H, and Ci-C 4 alkyl; and d can be an integer from 1 to 100.
- variables J, D, R 3 and d can be as described immediately above and the variables Ri and X can be H, G can be -CO 2 -. and R 4 can be Ci-C 4 alkyl. Suitable anionic polymers comprising such first and second moieties typically have weight- average molecular weights of from about 2000 Da to about 100,000 Da.
- Suitable anionic polymers include graft co-polymers that comprise the first moieties previously described herein, and typically have weight- average molecular weights of from about 1000 Da to about 50,000 Da. In such polymers, the aforementioned first moieties are typically grafted onto a Ci- C 4 carbon polyalkylene oxide.
- Suitable modified polyamine polymers include modified polyamines having the formulae:
- V units can be terminal units having the formula:
- W units can be backbone units having the formula:
- Y and Y' units can be branching units having the formula:
- Z units can be terminal units having the formula:
- R units can be selected from the group consisting of C 2 -Ci 2 alkylene, C 4 -Ci 2 alkenylene, C 3 -Ci 2 hydroxyalkylene, C 4 -C n dihydroxy-alkylene, C 8 -Ci 2 dialkylarylene, -(R 1 O) x R 1 -, ⁇ (R 1 O) x R 5 (OR ⁇ x -, -(CH 2 CH(OR 2 )CH 2 O) z -(R 1 O) y R 1 (OCH 2 CH(OR 2 )CH 2 ) w -, -C(O)(R 4 ) r C(O)-, -CH 2 CH(OR 2 )CH 2 -, and mixtures thereof; wherein R 1 can be C 2 -C 3 alkylene and mixtures thereof;
- R 2 can be hydrogen, -(R 1 O) X B, and mixtures thereof; wherein at least one B can be selected from the group consisting of - (CH 2 ) q -SO 3 M, -(CH 2 ) p CO 2 M, -(CH 2 ) ,(CHSO 3 M)CH 2 SO 3 M, -(CH 2 ),- (CHSO 2 M)CH 2 SO 3 M, -(CH 2 ) P PO 3 M, -PO 3 M, and mixtures thereof, and any remaining B moieties can be selected from the group consisting of hydrogen, C 1 -C 6 alkyl, -(CH 2 ) q -SO 3 M, -(CH 2 ) P CO 2 M, -(CH 2 ) ,(CHSO 3 M)CH 2 SO 3 M, -(CH 2 ) q -(CHSO 2 M)CH 2 SO 3 M, -(CH 2 ) P PO 3 M, - PO 3 M, and mixtures thereof; R 4 can
- R 5 can be Ci-Ci 2 alkylene, C 3 -C 12 hydroxy-alkylene, C 4 -Ci 2 dihydroxyalkylene, C 8 -Ci 2 dialkylarylene, -C(O)-, -C(O)NHR 6 NHC(O)-, -R ⁇ OR 1 )-, - C(O)(R 4 ) r C(O)-, -CH 2 CH(OH)CH 2 -, -CH 2 CH(OH)CH 2 O(R 1 O) x R 1 - OCH 2 CH(OH)CH 2 -, and mixtures thereof;
- R 6 is C 2 -Ci 2 alkylene or C 6 -Ci 2 arylene
- X can be a water soluble anion; provided at least one backbone nitrogen is quaternized or oxidized
- E units can be selected from the group consisting of hydrogen, Ci-C 22 alkyl, C 3 -C 22 alkenyl, C 7 -C 22 arylalkyl, C 2 -C 22 hydroxyalkyl, -(CH 2 ) p CO 2 M, -(CH 2 ) q SO 3 M, -
- R 1 can be C 2 -C 3 alkylene and mixtures thereof;
- R 3 can be C r Ci 8 alkyl, C 7 -Ci 2 arylalkyl, C 7 -Ci 2 alkyl substituted aryl, C 6 -Ci 2 aryl, and mixtures thereof;
- at least one B can be selected from the group consisting of -(CH 2 ) q -SO 3 M, - (CH 2 ) p CO 2 M, -(CH 2 ) q (CHSO 3 M)CH 2 SO 3 M, -(CH 2 ) q -(CHSO 2 M)CH 2 SO 3 M, - (CH 2 ) p PO 3 M, -PO 3 M, and mixtures thereof, and any remaining B moieties can be selected from the group consisting of hydrogen, Ci-C 6 alkyl, -(CH 2 ) q -SO 3 M, -
- M can be hydrogen or a water soluble cation in sufficient amount to satisfy charge balance; and wherein the values for the following indices are as follows: subscript index p can be an integer from 1 to 6; subscript index q can be an integer from O to 6; subscript index r can have the value of 0 or 1 ; subscript index w can have the value 0 or 1 ; subscript index x can be an integer from 1 to 100; subscript index y can be an integer from 0 to 100; and subscript index z can have the value 0 or 1.
- R units can be selected from the group consisting of C 2 -Ci 2 alkylene, -(R 1 O) x R 1 -, and mixtures thereof; wherein R 1 can be C 2 -C 3 alkylene and mixtures thereof;
- X can be a water soluble anion; provided at least one backbone nitrogen is quaternized or oxidized
- E units can be -(R 1 O) x B wherein R 1 can be C 2 -C 3 alkylene and mixtures thereof; and
- B can be hydrogen, -(CH 2 ) q -SO 3 M, -(CH 2 ) P CO 2 M, and mixtures thereof;
- M can be hydrogen or a water soluble cation in sufficient amount to satisfy charge balance; and subscript p can be an integer from 1 to 6; subscript q can be 0 ; subscript r can have the value of 0 or 1 ; subscript w can have the value 0 or 1 ; subscript x can be an integer from
- subscript y can be an integer from 0 to 100; and subscript z can have the value 0 or 1.
- R can be C O -C 2O linear or branched alkylene, and mixtures thereof;
- X in Formula (X) can be an anion present in sufficient amount to provide electronic neutrality;
- n and subscript index n in Formula (X) can have equal values and can be integers from 0 to 4;
- R 1 in Formula (X) can be a capped polyalkyleneoxy unit having Formula (IX):
- R 2 in Formula (IX) can be C 2 -C 4 linear or branched alkylene, and mixtures thereof; subscript index x in Formula (IX) describes the average number of alkyleneoxy units attached to the backbone nitrogen, such index can have a value from about 1 to about 50, in another aspect of Applicants' invention such index can have a value from about 15 to about 25; at least one R 3 moiety in Formula (IX) can be an anionic capping unit, with the remaining R moieties in Formula (IX) selected from the group comprising hydrogen, C 1 -C 2I alkylenearyl, an anionic capping unit, a neutral capping unit, and mixtures thereof; at least one Q moiety, in Formula (X) can be a hydrophobic quaternizing unit selected from the group comprising C 7 -C 30 substituted or unsubstituted alkylenearyl, and mixtures thereof, any remaining Q moieties in Formula (X) can be selected from the group comprising lone pairs of
- modified polyamines include modified polyamines having the following structures. As with all polymers containing alkyleneoxy units it is understood that only an average number or statistical distribution of alkyleneoxy units will be known. Therefore, depending upon how
- Suitable modified polyamines may be produced in accordance with the processes and methods disclosed in Applicants examples.
- Useful pH buffers include a material selected from the group consisting of organic acids, inorganic acids and mixtures there of.
- Useful organic acids include organic acids selected from the group consisting of an organic carboxylic acid, a polycarboxylic acid and mixtures thereof. Typically, the organic acids preferably have equivalent weights that are less than or equal to about 80 Daltons.
- suitable organic acids include: adipic, aspartic, carboxymethyloxymalonic, carboxymethyloxysuccinic, citric, glutaric, hydroxyethyliminodiacetic, iminodiacetic, maleic, malic, malonic, oxydiacetic, oxydisuccinic, succinic, sulfamic, tartaric, tartaric-disuccinic, tartaric-monosuccinic and mixtures thereof.
- Useful inorganic acids include inorganic acids selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid and mixtures hereof. Typically the inorganic is used in conjunction with an organic acid.
- Useful carriers may comprise water.
- a useful carrier is water.
- the aforementioned useful materials may be obtained as follows: useful chelating agents Aldrich, P.O. Box 2060, Milwaukee, WI 53201, USA; useful stripping agents may be obtained from Akzo Nobel, Velperweg 76, 6824 BM Arnhem
- useful suspending agents include, Alcosperse® 725 and Alcosperse® 747 available from Alco Chemical of Chattanooga, Tennessee U.S.A. and
- adjuncts While certain embodiments of Applicants textile benefit compositions do not contain one or more of the adjunct materials listed herein as such adjuncts are not essential for the purposes of the present invention, other embodiments may contain one or more adjuncts illustrated hereinafter. Such adjuncts may be incorporated in the textile benefit compositions disclosed herein, for example to assist or enhance cleaning performance, or to modify the aesthetics of such compositions as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the textile benefit composition and the nature of the operation for which it is to be used and applied.
- Useful adjunct materials may include, but are not limited to, bleach activators, surfactants, builders, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, clay and soil removal/anti- redeposition agents, brighteners, suds suppressors, dyes, perfumes, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids and/or pigments.
- Such textile benefit compositions can be made using a variety of reaction vessels and processes including batch, semi-batch and continuous processes.
- Such equipment may be obtained from a variety of sources such as Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Kentucky, U.S.A.), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex (Minneapolis, Minnesota, USA).
- an article comprising a stain repellant treatment is contacted with the benefit composition in neat form or during a cleaning or washing process.
- Contact methods include padding wiping, spraying and washing.
- Useful equipment for practicing the method disclosed herein includes sponges, cloths, spray bottles and washing units and containers such as washing machines. Treatment methods may comprise contacting the article before during or after a washing step that may optionally include rinsing and/or a drying step.
- Textile products having enhanced and/or durable stain repellency properties may be made by treating said textile products with Applicants' benefit compositions.
- Treatment methods include the methods disclosed in the present specification.
- compositions of Examples 1-3 are used to treat a situs in the following manner in accordance with the methods described in the present specification.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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JP2008549972A JP2009523852A (en) | 2006-01-19 | 2007-01-16 | Fabric treatment composition providing antifouling coating |
BRPI0706667-8A BRPI0706667A2 (en) | 2006-01-19 | 2007-01-16 | fabric treatment composition providing a stain-repellent coating |
EP07700599A EP1974004A1 (en) | 2006-01-19 | 2007-01-16 | Fabric treatment composition providing stain repellant coating |
CA002634099A CA2634099A1 (en) | 2006-01-19 | 2007-01-16 | Fabric treatment composition providing stain repellant coating |
CN2007800026194A CN101370919B (en) | 2006-01-19 | 2007-01-16 | Fabric treatment composition providing stain repellant coating |
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US76022406P | 2006-01-19 | 2006-01-19 | |
US60/760,224 | 2006-01-19 |
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PCT/IB2007/050132 WO2007083262A1 (en) | 2006-01-19 | 2007-01-16 | Fabric treatment composition providing stain repellant coating |
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US (1) | US20070163054A1 (en) |
EP (1) | EP1974004A1 (en) |
JP (1) | JP2009523852A (en) |
CN (1) | CN101370919B (en) |
BR (1) | BRPI0706667A2 (en) |
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WO2009153184A1 (en) * | 2008-06-16 | 2009-12-23 | Unilever Plc | Improvements relating to fabric cleaning |
WO2011047987A1 (en) | 2009-10-23 | 2011-04-28 | Unilever Plc | Dye polymers |
WO2012119859A1 (en) | 2011-03-10 | 2012-09-13 | Unilever Plc | Dye polymer |
CN102171323B (en) * | 2008-06-16 | 2013-06-12 | 荷兰联合利华有限公司 | Improvements relating to fabric cleaning |
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US11525211B2 (en) | 2016-08-24 | 2022-12-13 | Organoclick Ab | Bio-based polyelectrolyte complex compositions comprising non-water soluble particles |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4949480B2 (en) * | 2006-11-22 | 2012-06-06 | ザ プロクター アンド ギャンブル カンパニー | Beneficial compositions and methods |
US20090014034A1 (en) * | 2006-11-22 | 2009-01-15 | The Procter & Gamble Company | Benefit compositions and formaldehyde scavengers for same |
ES2572079T3 (en) | 2012-07-19 | 2016-05-30 | Basf Se | Hydrophobically Modified Cationic Polymer |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996011248A1 (en) * | 1994-10-07 | 1996-04-18 | The Procter & Gamble Company | Fabric softening composition containing chlorine scavengers |
EP0971027A1 (en) * | 1998-07-10 | 2000-01-12 | The Procter & Gamble Company | Amine reaction compounds comprising one or more active ingredient |
DE20010121U1 (en) * | 2000-06-06 | 2000-12-28 | Procter & Gamble | Kit for treating a carpet with a composition containing a non-irritating surfactant |
GB2355015A (en) * | 1999-08-02 | 2001-04-11 | Procter & Gamble | Structured liquid detergents with selected perfume fragrance materials |
DE10027634A1 (en) * | 2000-06-06 | 2001-12-13 | Basf Ag | Use of hydrophobic polymer particles, cationically modified by coating with cationic polymer, as additives in washing or care materials for textiles and as additives in detergents |
US20030224964A1 (en) * | 1999-11-09 | 2003-12-04 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3812044A (en) * | 1970-12-28 | 1974-05-21 | Procter & Gamble | Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent |
JP3212173B2 (en) * | 1993-01-30 | 2001-09-25 | ライオン株式会社 | Softener composition |
US6004922A (en) * | 1996-05-03 | 1999-12-21 | The Procter & Gamble Company | Laundry detergent compositions comprising cationic surfactants and modified polyamine soil dispersents |
MA25183A1 (en) * | 1996-05-17 | 2001-07-02 | Arthur Jacques Kami Christiaan | DETERGENT COMPOSITIONS |
CN1161451C (en) * | 1997-07-29 | 2004-08-11 | 普罗格特-甘布尔公司 | Aqueous gel laundry detergent composition |
TR200100733T2 (en) * | 1998-09-15 | 2001-10-22 | The Procter & Gamble Company | Fabric protection compositions added during rinsing containing low molecular weight linear and cyclic polyamines |
EP1151078A1 (en) * | 1999-02-10 | 2001-11-07 | The Procter & Gamble Company | Stable non-aqueous detergents comprising low density particles |
US6677289B1 (en) * | 1999-07-16 | 2004-01-13 | The Procter & Gamble Company | Laundry detergent compositions comprising polyamines and mid-chain branched surfactants |
EP1228176A1 (en) * | 1999-11-10 | 2002-08-07 | Unilever Plc | Automatic dishwashing compositions containing water soluble cationic surfactants |
US6844309B1 (en) * | 1999-12-08 | 2005-01-18 | The Procter & Gamble Company | Ether-capped poly(oxyalkylated) alcohol surfactants |
WO2001062885A1 (en) * | 2000-02-23 | 2001-08-30 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines and xyloglucanase |
BR0113807A (en) * | 2000-09-11 | 2003-07-29 | Procter & Gamble | Laundry articles and methods for tissue protection or for combined cleaning and protection of fabrics |
US7056880B2 (en) * | 2002-02-28 | 2006-06-06 | The Procter & Gamble Company | Using cationic celluloses to enhance delivery of fabric care benefit agents |
US7056879B2 (en) * | 2002-02-28 | 2006-06-06 | The Procter & Gamble Company | Using cationic celluloses to enhance delivery of fabric care benefit agents |
US20030226212A1 (en) * | 2002-04-16 | 2003-12-11 | Jiping Wang | Textile mill applications of cellulosic based polymers to provide appearance and integrity benefits to fabrics during laundering and in-wear |
JP2004044056A (en) * | 2002-07-11 | 2004-02-12 | Matsumoto Yushi Seiyaku Co Ltd | Soil-resisting agent for cotton (blended) fabric |
BR0315924A (en) * | 2002-11-04 | 2005-09-20 | Procter & Gamble | Liquid laundry detergent composition, use thereof, method for softening fabrics, method for treating a substrate, as well as processes for preparing said composition |
EP1431383B1 (en) * | 2002-12-19 | 2006-03-22 | The Procter & Gamble Company | Single compartment unit dose fabric treatment product comprising pouched compositions with cationic fabric softener actives |
US20070056119A1 (en) * | 2003-06-27 | 2007-03-15 | Gardner Robb R | Method for treating hydrophilic stains in a lipophlic fluid system |
JP4191015B2 (en) * | 2003-11-21 | 2008-12-03 | 花王株式会社 | Cleaning composition |
US20060248657A1 (en) * | 2004-05-05 | 2006-11-09 | Jiping Wang | Textile benefit compositions |
US20050246841A1 (en) * | 2004-05-05 | 2005-11-10 | The Procter & Gamble Company | Textile benefit compositions |
US20060003913A1 (en) * | 2004-06-30 | 2006-01-05 | The Procter & Gamble Company | Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents |
EP1851298B1 (en) * | 2005-02-17 | 2010-03-24 | The Procter and Gamble Company | Fabric care composition |
WO2007034447A2 (en) * | 2005-09-22 | 2007-03-29 | The Procter & Gamble Company | Multiple use fabric softening composition with reduced fabric staining |
-
2007
- 2007-01-16 EP EP07700599A patent/EP1974004A1/en not_active Withdrawn
- 2007-01-16 JP JP2008549972A patent/JP2009523852A/en active Pending
- 2007-01-16 WO PCT/IB2007/050132 patent/WO2007083262A1/en active Application Filing
- 2007-01-16 CN CN2007800026194A patent/CN101370919B/en not_active Expired - Fee Related
- 2007-01-16 CA CA002634099A patent/CA2634099A1/en not_active Abandoned
- 2007-01-16 BR BRPI0706667-8A patent/BRPI0706667A2/en not_active IP Right Cessation
- 2007-01-18 US US11/654,714 patent/US20070163054A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996011248A1 (en) * | 1994-10-07 | 1996-04-18 | The Procter & Gamble Company | Fabric softening composition containing chlorine scavengers |
EP0971027A1 (en) * | 1998-07-10 | 2000-01-12 | The Procter & Gamble Company | Amine reaction compounds comprising one or more active ingredient |
GB2355015A (en) * | 1999-08-02 | 2001-04-11 | Procter & Gamble | Structured liquid detergents with selected perfume fragrance materials |
US20030224964A1 (en) * | 1999-11-09 | 2003-12-04 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines |
DE20010121U1 (en) * | 2000-06-06 | 2000-12-28 | Procter & Gamble | Kit for treating a carpet with a composition containing a non-irritating surfactant |
DE10027634A1 (en) * | 2000-06-06 | 2001-12-13 | Basf Ag | Use of hydrophobic polymer particles, cationically modified by coating with cationic polymer, as additives in washing or care materials for textiles and as additives in detergents |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009153184A1 (en) * | 2008-06-16 | 2009-12-23 | Unilever Plc | Improvements relating to fabric cleaning |
CN102171323B (en) * | 2008-06-16 | 2013-06-12 | 荷兰联合利华有限公司 | Improvements relating to fabric cleaning |
US9150993B2 (en) | 2008-06-16 | 2015-10-06 | Conopco, Inc. | Methods and compositions for fabric cleaning |
WO2011047987A1 (en) | 2009-10-23 | 2011-04-28 | Unilever Plc | Dye polymers |
WO2012119859A1 (en) | 2011-03-10 | 2012-09-13 | Unilever Plc | Dye polymer |
WO2014114570A1 (en) | 2013-01-23 | 2014-07-31 | Unilever Plc | An uncoloured laundry additive material for promotion of anti redeposition of particulate soil |
US11319673B2 (en) | 2016-08-24 | 2022-05-03 | Organoclick Ab | Bio-based PEC compositions as binders for fiber based materials, textiles, woven and nonwoven materials |
US11525211B2 (en) | 2016-08-24 | 2022-12-13 | Organoclick Ab | Bio-based polyelectrolyte complex compositions comprising non-water soluble particles |
US11685820B2 (en) | 2016-08-24 | 2023-06-27 | Organoclick Ab | Bio-based polyelectrolyte complex compositions with increased hydrophobicity comprising fatty compounds |
WO2018085386A1 (en) | 2016-11-01 | 2018-05-11 | Milliken & Company | Leuco polymers as bluing agents in laundry care compositions |
WO2018085306A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
Also Published As
Publication number | Publication date |
---|---|
CA2634099A1 (en) | 2007-07-26 |
US20070163054A1 (en) | 2007-07-19 |
JP2009523852A (en) | 2009-06-25 |
CN101370919B (en) | 2013-07-17 |
BRPI0706667A2 (en) | 2011-04-05 |
EP1974004A1 (en) | 2008-10-01 |
CN101370919A (en) | 2009-02-18 |
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