WO2007083213A3 - Process for the preparation of biodiesel - Google Patents

Process for the preparation of biodiesel Download PDF

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Publication number
WO2007083213A3
WO2007083213A3 PCT/IB2007/000104 IB2007000104W WO2007083213A3 WO 2007083213 A3 WO2007083213 A3 WO 2007083213A3 IB 2007000104 W IB2007000104 W IB 2007000104W WO 2007083213 A3 WO2007083213 A3 WO 2007083213A3
Authority
WO
WIPO (PCT)
Prior art keywords
biodiesel
preparation
component
esterification
triglyceride
Prior art date
Application number
PCT/IB2007/000104
Other languages
French (fr)
Other versions
WO2007083213A2 (en
Inventor
Maurizio Germani
Original Assignee
Merloni Progetti S P A
Maurizio Germani
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merloni Progetti S P A, Maurizio Germani filed Critical Merloni Progetti S P A
Priority to DK07700488T priority Critical patent/DK1976960T3/en
Priority to DE602007001580T priority patent/DE602007001580D1/de
Priority to EP07700488A priority patent/EP1976960B1/en
Priority to PL07700488T priority patent/PL1976960T3/en
Priority to BRPI0707134-5A priority patent/BRPI0707134A2/en
Publication of WO2007083213A2 publication Critical patent/WO2007083213A2/en
Publication of WO2007083213A3 publication Critical patent/WO2007083213A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00—Refining fats or fatty oils
    • C11B3/006—Refining fats or fatty oils by extraction
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B7/00—Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils
    • C11B7/0008—Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils by differences of solubilities, e.g. by extraction, by separation from a solution by means of anti-solvents
    • C11B7/0025—Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils by differences of solubilities, e.g. by extraction, by separation from a solution by means of anti-solvents in solvents containing oxygen in their molecule
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention relates to a process for the preparation of biodiesel, which comprises the separation of the triglyceride component from the free fatty acid one, both of which are contained in at least one biolipid, the esterification of said acid component, and the joint trans-esterification of the resulting esterifÊed acid component with said triglyceride component. The process according to the invention allows to use biolipids having any percentage of acidity as well as to prevent soap formation.
PCT/IB2007/000104 2006-01-19 2007-01-16 Process for the preparation of biodiesel WO2007083213A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DK07700488T DK1976960T3 (en) 2006-01-19 2007-01-16 Process for producing biodiesel
DE602007001580T DE602007001580D1 (en) 2006-01-19 2007-01-16
EP07700488A EP1976960B1 (en) 2006-01-19 2007-01-16 Process for the preparation of biodiesel
PL07700488T PL1976960T3 (en) 2006-01-19 2007-01-16 Process for the preparation of biodiesel
BRPI0707134-5A BRPI0707134A2 (en) 2006-01-19 2007-01-16 process for the preparation of biodiesel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2006A000082 2006-01-19
IT000082A ITMI20060082A1 (en) 2006-01-19 2006-01-19 PROCESS FOR THE PREPARATION OF BIODIESEL

Publications (2)

Publication Number Publication Date
WO2007083213A2 WO2007083213A2 (en) 2007-07-26
WO2007083213A3 true WO2007083213A3 (en) 2007-12-27

Family

ID=38287991

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2007/000104 WO2007083213A2 (en) 2006-01-19 2007-01-16 Process for the preparation of biodiesel

Country Status (13)

Country Link
EP (1) EP1976960B1 (en)
CN (1) CN101370910A (en)
BR (1) BRPI0707134A2 (en)
CY (1) CY1109469T1 (en)
DE (1) DE602007001580D1 (en)
DK (1) DK1976960T3 (en)
ES (1) ES2329949T3 (en)
IT (1) ITMI20060082A1 (en)
PL (1) PL1976960T3 (en)
PT (1) PT1976960E (en)
RU (1) RU2008134001A (en)
SI (1) SI1976960T1 (en)
WO (1) WO2007083213A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016473B (en) * 2007-03-02 2012-04-18 安徽省粮油科学研究所 Method of producing biological fuel oil from poor oil
US20100205853A1 (en) * 2007-10-09 2010-08-19 Council Of Scientific & Industrial Research Process for the Preparation of Biodiesel from Vegetable Oils Containing High FFA
MX2010004637A (en) * 2007-10-30 2010-05-14 Bayer Technology Services Gmbh Method for the heterogenically catalyzed esterification of fatty acids.
DE102007052065A1 (en) * 2007-10-30 2009-05-07 Bayer Technology Services Gmbh Continuous process for heterogeneously catalyzed esterification of fatty acids
PH12010501172A1 (en) * 2007-12-19 2009-06-25 Bayer Technology Services Gmbh Method for producing fatty acid alkyl esters
DE102008060902A1 (en) 2008-12-09 2010-06-10 Grace Gmbh & Co. Kg Preparing fatty acid alkyl ester from feed stock containing e.g. free fatty acids and fatty acid triglycerides, comprises esterifying feedstock with alkyl alcohol in presence of catalyst and transesterifying the free fatty acid feedstock
CN101531915B (en) * 2009-04-09 2012-10-24 江苏卡特新能源有限公司 Method for preparing biodiesel
CN101781610A (en) * 2010-03-16 2010-07-21 刘宽 Continuous esterification and ester exchange process used for producing biodiesel
CN103074165A (en) * 2013-01-18 2013-05-01 天津大学 Continuous ester interchange reaction method and reactor in production process of natural vitamin E and phytosterin
BR102021016123A2 (en) * 2021-08-16 2023-02-23 Petróleo Brasileiro S.A. - Petrobras PROCESS FOR BIODIESEL PRODUCTION FROM ACID CARDS
CN115322838A (en) * 2022-08-29 2022-11-11 浙江工业大学 Method for preparing fatty acid methyl ester by using waste oil

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164506A (en) * 1977-03-17 1979-08-14 Kao Soap Co., Ltd. Process for producing lower alcohol esters of fatty acids
DE3015277A1 (en) * 1979-05-09 1981-01-22 Kao Corp METHOD FOR CONTINUOUSLY REFINING OILS AND FATS
EP0194165A1 (en) * 1985-02-15 1986-09-10 Institut Français du Pétrole Process for manufacturing a fatty-acid ester composition for use as a diesel oil fuel substitute with hydrated ethyl alcohol, and ester composition so formed
WO2001012581A1 (en) * 1999-08-18 2001-02-22 David Gavin Brooke Boocock Single-phase process for production of fatty acid methyl esters from mixtures of triglycerides and fatty acids
WO2004029016A1 (en) * 2002-09-20 2004-04-08 Oelmühle Leer Connemann Gmbh & Co. Method and device for producing biodiesel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164506A (en) * 1977-03-17 1979-08-14 Kao Soap Co., Ltd. Process for producing lower alcohol esters of fatty acids
DE3015277A1 (en) * 1979-05-09 1981-01-22 Kao Corp METHOD FOR CONTINUOUSLY REFINING OILS AND FATS
EP0194165A1 (en) * 1985-02-15 1986-09-10 Institut Français du Pétrole Process for manufacturing a fatty-acid ester composition for use as a diesel oil fuel substitute with hydrated ethyl alcohol, and ester composition so formed
WO2001012581A1 (en) * 1999-08-18 2001-02-22 David Gavin Brooke Boocock Single-phase process for production of fatty acid methyl esters from mixtures of triglycerides and fatty acids
WO2004029016A1 (en) * 2002-09-20 2004-04-08 Oelmühle Leer Connemann Gmbh & Co. Method and device for producing biodiesel

Also Published As

Publication number Publication date
EP1976960A2 (en) 2008-10-08
ITMI20060082A1 (en) 2007-07-20
BRPI0707134A2 (en) 2011-04-19
PT1976960E (en) 2009-10-09
DK1976960T3 (en) 2009-11-16
WO2007083213A2 (en) 2007-07-26
CY1109469T1 (en) 2014-08-13
EP1976960B1 (en) 2009-07-15
SI1976960T1 (en) 2009-12-31
RU2008134001A (en) 2010-02-27
CN101370910A (en) 2009-02-18
ES2329949T3 (en) 2009-12-02
PL1976960T3 (en) 2010-01-29
DE602007001580D1 (en) 2009-08-27

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