WO2007082896A1 - Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream - Google Patents
Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream Download PDFInfo
- Publication number
- WO2007082896A1 WO2007082896A1 PCT/EP2007/050439 EP2007050439W WO2007082896A1 WO 2007082896 A1 WO2007082896 A1 WO 2007082896A1 EP 2007050439 W EP2007050439 W EP 2007050439W WO 2007082896 A1 WO2007082896 A1 WO 2007082896A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- synthesis gas
- gas stream
- process according
- cos
- solid adsorbent
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/308—Carbonoxysulfide COS
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07703937A EP1973841A1 (en) | 2006-01-18 | 2007-01-17 | Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream |
AU2007206964A AU2007206964A1 (en) | 2006-01-18 | 2007-01-17 | Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream |
US12/161,096 US8043589B2 (en) | 2006-01-18 | 2007-01-17 | Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream |
EA200801713A EA200801713A1 (en) | 2006-01-18 | 2007-01-17 | METHOD FOR REMOVING CARBONESULFIDE AND HYDROGEN FROM A SYNTHESIS GAS FLOW |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06100495.8 | 2006-01-18 | ||
EP06100495 | 2006-01-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007082896A1 true WO2007082896A1 (en) | 2007-07-26 |
Family
ID=36528833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/050439 WO2007082896A1 (en) | 2006-01-18 | 2007-01-17 | Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream |
Country Status (8)
Country | Link |
---|---|
US (1) | US8043589B2 (en) |
EP (1) | EP1973841A1 (en) |
CN (1) | CN101374759A (en) |
AU (1) | AU2007206964A1 (en) |
EA (1) | EA200801713A1 (en) |
MY (1) | MY149541A (en) |
WO (1) | WO2007082896A1 (en) |
ZA (1) | ZA200805501B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7951355B2 (en) | 2006-12-08 | 2011-05-31 | Shell Oil Company | Process for producing a purified synthesis gas stream |
US8258193B2 (en) | 2007-06-18 | 2012-09-04 | Shell Oil Company | Process for removal of hydrogen cyanide and ammonia from synthesis gas |
US8282707B2 (en) | 2010-06-30 | 2012-10-09 | Uop Llc | Natural gas purification system |
CN101676016B (en) * | 2008-08-13 | 2013-03-13 | 赫多特普索化工设备公司 | Process and system for the abatement of impurities from a gas stream |
US8889089B2 (en) | 2007-10-26 | 2014-11-18 | Haldor Topsoe A/S | Process for a reduction in the amount of sulphur compounds, hydrogen cyanide, and formic acid in synthesis gas |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102259835B (en) | 2011-06-20 | 2013-03-27 | 中国科学院广州能源研究所 | Method for purifying and upgrading crude synthesis gas based on molten salt characteristics |
CA2776369C (en) * | 2012-05-09 | 2014-01-21 | Steve Kresnyak | Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment |
US9394490B2 (en) | 2014-02-11 | 2016-07-19 | Uop Llc | Process for removing carbonyl sulfide from a hydrocarbon stream |
DE102014205955A1 (en) * | 2014-03-31 | 2015-10-01 | Siemens Aktiengesellschaft | Process and apparatus for purifying a synthesis gas stream of a crude fuel gasifier |
EP3871755A1 (en) * | 2014-10-24 | 2021-09-01 | Research Triangle Institute | Integrated method for removing acid gas from a gas stream |
US20170290358A1 (en) * | 2016-04-08 | 2017-10-12 | John Bean Technologies Corporation | System and method for automated, continuous high temperature sterilization and filling of food products |
JP6789777B2 (en) * | 2016-11-22 | 2020-11-25 | 三菱重工エンジニアリング株式会社 | Gas purification equipment and gas purification method |
CN112423860A (en) * | 2018-07-17 | 2021-02-26 | Sabic环球技术有限责任公司 | Process for removing sulphides from a carbon monoxide rich gas stream at ambient temperature |
CN111337425B (en) * | 2018-12-18 | 2022-07-12 | 山东华光光电子股份有限公司 | Semiconductor laser COS alloy strength detection device and detection method |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3441370A (en) * | 1966-04-25 | 1969-04-29 | Catalysts & Chem Inc | Method of removing sulfur compounds from gases |
US4088736A (en) * | 1974-12-27 | 1978-05-09 | Institut Francais Du Petrole | Process for purifying a gas containing hydrogen sulfide and contact masses usable therefor |
US4271133A (en) * | 1980-03-31 | 1981-06-02 | Union Carbide Corporation | Process for removing hydrogen cyanide from gaseous streams |
US4478800A (en) * | 1981-08-07 | 1984-10-23 | Veg Gasinstituut N.V. | Process for removal of sulfur compounds from gases |
US4994257A (en) * | 1986-04-24 | 1991-02-19 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for purifying high-temperature reducing gas |
US5169612A (en) * | 1989-05-29 | 1992-12-08 | Haldor Topsoe A/S | Purification of sulphide-containing gases |
US6322763B1 (en) | 1998-12-15 | 2001-11-27 | Teco, Inc. | Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing |
WO2003011436A1 (en) * | 2001-07-30 | 2003-02-13 | Johnson Matthey Plc | Desulphurisation |
DE10141193A1 (en) * | 2001-08-22 | 2003-03-13 | Daimler Chrysler Ag | Apparatus for desulfurizing gas streams comprises a heads-desulfurizing stage containing an adsorbent having a high potential for binding sulfur at higher operating temperatures |
US6551566B1 (en) * | 2000-10-12 | 2003-04-22 | Air Liquide Process And Construction, Inc. | Hydrodehalogenation process using a catalyst containing nickel |
US6692711B1 (en) * | 1998-01-23 | 2004-02-17 | Exxonmobil Research And Engineering Company | Production of low sulfur syngas from natural gas with C4+/C5+ hydrocarbon recovery |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3974256A (en) * | 1974-05-07 | 1976-08-10 | Exxon Research And Engineering Company | Sulfide removal process |
US4254094A (en) * | 1979-03-19 | 1981-03-03 | Air Products And Chemicals, Inc. | Process for producing hydrogen from synthesis gas containing COS |
US4299802A (en) * | 1980-03-31 | 1981-11-10 | Union Carbide Corporation | Process for removing carbonyl sulfide from gaseous streams |
GB8610196D0 (en) * | 1986-04-25 | 1986-05-29 | Ici Plc | Sulphur compounds removal |
US4888131A (en) * | 1988-03-28 | 1989-12-19 | Exxon Research And Engineering Company | Synthesis gas preparation and catalyst therefor |
US5104630A (en) * | 1990-11-13 | 1992-04-14 | Uop | Processes for removing carbonyl sulfide from hydrocarbon feedstreams |
NL9002661A (en) | 1990-12-04 | 1992-07-01 | Pacques Bv | PROCESS FOR THE REMOVAL OF H2S FROM GAS. |
DZ1708A1 (en) | 1992-08-18 | 2002-02-17 | Shell Int Research | Process for the preparation of hydrocarbon fuels. |
DE4321542C1 (en) | 1993-06-29 | 1994-09-01 | Bfi Entsorgungstech | Process for the separate removal of sulphur compounds and CO2 from gas |
GB9404191D0 (en) | 1994-03-04 | 1994-04-20 | Imperial College | Preparations and uses of polyferric sulphate |
US5463168A (en) * | 1994-08-17 | 1995-10-31 | Mobil Oil Corporation | Process for the removal of hydrogen cyanide from FCC hydrocarbon product gas streams |
DE4431788A1 (en) | 1994-09-07 | 1996-03-14 | Huels Chemische Werke Ag | Catalyst and process for the decomposition of HCN in gases |
DE69607423T2 (en) | 1995-08-08 | 2000-08-03 | Exxon Research Engineering Co | Process for removing hydrogen cyanide from synthesis gas |
FR2740704B1 (en) * | 1995-11-03 | 1997-12-26 | Elf Aquitaine | PROCESS FOR THE QUASI TOTAL ELIMINATION OF THE SULFUR H2S, SO2, COS AND / OR CS2 COMPOUNDS CONTAINED IN A RESIDUAL SULFUR PLANT GAS, WITH RECOVERY OF THE SAID COMPOUNDS IN THE FORM OF SULFUR |
KR100590415B1 (en) | 1997-12-30 | 2006-06-19 | 쉘 인터내셔날 리서치 마챠피즈 비.브이. | Cobalt based fischer-tropsch catalyst |
US5882614A (en) * | 1998-01-23 | 1999-03-16 | Exxon Research And Engineering Company | Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes |
US7588627B2 (en) * | 2003-04-17 | 2009-09-15 | Shell Oil Company | Process for the removal of H2S and mercaptans from a gas stream |
ES2308194T3 (en) * | 2003-05-29 | 2008-12-01 | Shell Internationale Research Maatschappij B.V. | A PROCESS FOR THE REMOVAL OF SO2 HCN AND H2S AND OPTIONALLY COS, CS2 AND NH3 FROM A GAS CURRENT. |
US7056487B2 (en) * | 2003-06-06 | 2006-06-06 | Siemens Power Generation, Inc. | Gas cleaning system and method |
MY140997A (en) * | 2004-07-22 | 2010-02-12 | Shell Int Research | Process for the removal of cos from a synthesis gas stream comprising h2s and cos |
MY145821A (en) * | 2005-05-23 | 2012-04-30 | Shell Int Research | Process for the removal of contaminants |
-
2007
- 2007-01-17 EA EA200801713A patent/EA200801713A1/en unknown
- 2007-01-17 AU AU2007206964A patent/AU2007206964A1/en not_active Abandoned
- 2007-01-17 EP EP07703937A patent/EP1973841A1/en not_active Withdrawn
- 2007-01-17 CN CNA2007800032284A patent/CN101374759A/en active Pending
- 2007-01-17 MY MYPI20082546A patent/MY149541A/en unknown
- 2007-01-17 WO PCT/EP2007/050439 patent/WO2007082896A1/en active Application Filing
- 2007-01-17 US US12/161,096 patent/US8043589B2/en not_active Expired - Fee Related
-
2008
- 2008-06-24 ZA ZA200805501A patent/ZA200805501B/en unknown
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3441370A (en) * | 1966-04-25 | 1969-04-29 | Catalysts & Chem Inc | Method of removing sulfur compounds from gases |
US4088736A (en) * | 1974-12-27 | 1978-05-09 | Institut Francais Du Petrole | Process for purifying a gas containing hydrogen sulfide and contact masses usable therefor |
US4271133A (en) * | 1980-03-31 | 1981-06-02 | Union Carbide Corporation | Process for removing hydrogen cyanide from gaseous streams |
US4478800A (en) * | 1981-08-07 | 1984-10-23 | Veg Gasinstituut N.V. | Process for removal of sulfur compounds from gases |
US4994257A (en) * | 1986-04-24 | 1991-02-19 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for purifying high-temperature reducing gas |
US5169612A (en) * | 1989-05-29 | 1992-12-08 | Haldor Topsoe A/S | Purification of sulphide-containing gases |
US6692711B1 (en) * | 1998-01-23 | 2004-02-17 | Exxonmobil Research And Engineering Company | Production of low sulfur syngas from natural gas with C4+/C5+ hydrocarbon recovery |
US6322763B1 (en) | 1998-12-15 | 2001-11-27 | Teco, Inc. | Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing |
US6551566B1 (en) * | 2000-10-12 | 2003-04-22 | Air Liquide Process And Construction, Inc. | Hydrodehalogenation process using a catalyst containing nickel |
WO2003011436A1 (en) * | 2001-07-30 | 2003-02-13 | Johnson Matthey Plc | Desulphurisation |
DE10141193A1 (en) * | 2001-08-22 | 2003-03-13 | Daimler Chrysler Ag | Apparatus for desulfurizing gas streams comprises a heads-desulfurizing stage containing an adsorbent having a high potential for binding sulfur at higher operating temperatures |
Non-Patent Citations (1)
Title |
---|
MAARTEN VAN DER BURGT ET AL., THE SHELL MIDDLE DISTILLATE SYNTHESIS PROCESS, PETROLEUM REVIEW, April 1990 (1990-04-01), pages 204 - 209 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7951355B2 (en) | 2006-12-08 | 2011-05-31 | Shell Oil Company | Process for producing a purified synthesis gas stream |
US8258193B2 (en) | 2007-06-18 | 2012-09-04 | Shell Oil Company | Process for removal of hydrogen cyanide and ammonia from synthesis gas |
US8889089B2 (en) | 2007-10-26 | 2014-11-18 | Haldor Topsoe A/S | Process for a reduction in the amount of sulphur compounds, hydrogen cyanide, and formic acid in synthesis gas |
CN101676016B (en) * | 2008-08-13 | 2013-03-13 | 赫多特普索化工设备公司 | Process and system for the abatement of impurities from a gas stream |
US8282707B2 (en) | 2010-06-30 | 2012-10-09 | Uop Llc | Natural gas purification system |
Also Published As
Publication number | Publication date |
---|---|
US20100197984A1 (en) | 2010-08-05 |
AU2007206964A1 (en) | 2007-07-26 |
CN101374759A (en) | 2009-02-25 |
EA200801713A1 (en) | 2008-12-30 |
MY149541A (en) | 2013-09-13 |
US8043589B2 (en) | 2011-10-25 |
EP1973841A1 (en) | 2008-10-01 |
ZA200805501B (en) | 2009-02-25 |
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