WO2007049287A3 - Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof - Google Patents

Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof Download PDF

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Publication number
WO2007049287A3
WO2007049287A3 PCT/IN2005/000355 IN2005000355W WO2007049287A3 WO 2007049287 A3 WO2007049287 A3 WO 2007049287A3 IN 2005000355 W IN2005000355 W IN 2005000355W WO 2007049287 A3 WO2007049287 A3 WO 2007049287A3
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WO
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Patent type
Prior art keywords
method
product
bio
liquid hydrocarbon
hydrocarbon fuels
Prior art date
Application number
PCT/IN2005/000355
Other languages
French (fr)
Other versions
WO2007049287A2 (en )
Inventor
Brij Mohan Bansal
Wadhava Ram Kalsi
Manoj Kumar
Ravinder Kumar Malhotra
Alex Cheru Pulikottil
Rakesh Sarin
Mahendra Pratap Singh
Deepak Kumar Tuli
Ram Prakash Verma
Original Assignee
Brij Mohan Bansal
Indian Oil Corp Ltd
Wadhava Ram Kalsi
Manoj Kumar
Ravinder Kumar Malhotra
Alex Cheru Pulikottil
Rakesh Sarin
Mahendra Pratap Singh
Deepak Kumar Tuli
Ram Prakash Verma
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00Refining of hydrocarbons oils by electric or magnetic means, by irradiation or by using microorganisms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06Refining of hydrocarbon oils in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12Organic compounds only
    • C10G21/16Oxygen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes
    • C10G53/02Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/04Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one extraction step
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes
    • C10G53/02Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14Treatment of hydrocarbon oils in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06Gasoil

Abstract

Disclosed herein is a method for producing ultra-low-sulfur content hydrocarbon fuel and product thereof. The method comprises selective biocatalytic oxidation of sulfur containing compounds present in the fuels employing enzyme lipase as biocatalyst in presence of controlled and incremental amount of hydrogen peroxide and carboxylic acid without using water or any co-factor for the reactivity of said enzymes.
PCT/IN2005/000355 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof WO2007049287A3 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/IN2005/000355 WO2007049287A3 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
PCT/IN2005/000355 WO2007049287A3 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof
DK05823611T DK1957118T3 (en) 2005-10-28 2005-10-28 A process for bio-oxidative desulfurization of liquid hydrocarbon fuels and products thereof
US12091913 US20090217571A1 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof
EP20050823611 EP1957118B1 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Publications (2)

Publication Number Publication Date
WO2007049287A2 true WO2007049287A2 (en) 2007-05-03
WO2007049287A3 true true WO2007049287A3 (en) 2007-11-08

Family

ID=37968221

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2005/000355 WO2007049287A3 (en) 2005-10-28 2005-10-28 Method for bio-oxidative desulfurization of liquid hydrocarbon fuels and product thereof

Country Status (4)

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US (1) US20090217571A1 (en)
EP (1) EP1957118B1 (en)
DK (1) DK1957118T3 (en)
WO (1) WO2007049287A3 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010008750A3 (en) * 2008-06-24 2010-06-03 Novozymes A/S Recovery of liquid hydrocarbons
US9023120B2 (en) * 2009-06-19 2015-05-05 Cyuba Enzyme Ltd. Fuel production method, fuel production apparatus, and fuel oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5876990A (en) * 1996-10-22 1999-03-02 Reddy; Malireddy S. Biochemical media system for reducing pollution
US5980733A (en) * 1994-04-15 1999-11-09 United Laboratories International Method of removing sulfur compounds from hydrocarbon streams
US6398707B1 (en) * 2001-05-31 2002-06-04 Wen-Teng Wu Method of preparing lower alkyl fatty acids esters and in particular biodiesel

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3551328A (en) * 1968-11-26 1970-12-29 Texaco Inc Desulfurization of a heavy hydrocarbon fraction
JP3227521B2 (en) * 1992-04-06 2001-11-12 哲夫 相田 Process for recovering organic sulfur compounds from liquid oil
US6071738A (en) * 1997-09-19 2000-06-06 Energy Biosystems Corporation Conversion of organosulfur compounds to oxyorganosulfur compounds for desulfurization of fossil fuels
US6160193A (en) * 1997-11-20 2000-12-12 Gore; Walter Method of desulfurization of hydrocarbons
US6171478B1 (en) * 1998-07-15 2001-01-09 Uop Llc Process for the desulfurization of a hydrocarbonaceous oil
US5958224A (en) * 1998-08-14 1999-09-28 Exxon Research And Engineering Co Process for deep desulfurization using combined hydrotreating-oxidation
FR2793256B1 (en) * 1999-05-05 2001-07-27 Total Raffinage Distrib Method for obtaining petroleum products has low sulfur content by desulfurization of extracts
US6251289B1 (en) * 1999-06-03 2001-06-26 Grt, Inc. Treatment of contaminated liquids with oxidizing gases and liquids
US6461859B1 (en) * 1999-09-09 2002-10-08 Instituto Mexicano Del Petroleo Enzymatic oxidation process for desulfurization of fossil fuels
CA2387870C (en) * 1999-10-15 2012-02-14 Avatar Medical, Llc Stabilized proteins
US6596914B2 (en) * 2000-08-01 2003-07-22 Walter Gore Method of desulfurization and dearomatization of petroleum liquids by oxidation and solvent extraction

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5980733A (en) * 1994-04-15 1999-11-09 United Laboratories International Method of removing sulfur compounds from hydrocarbon streams
US5876990A (en) * 1996-10-22 1999-03-02 Reddy; Malireddy S. Biochemical media system for reducing pollution
US6398707B1 (en) * 2001-05-31 2002-06-04 Wen-Teng Wu Method of preparing lower alkyl fatty acids esters and in particular biodiesel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1957118A2 *

Also Published As

Publication number Publication date Type
WO2007049287A2 (en) 2007-05-03 application
DK1957118T3 (en) 2013-09-08 grant
EP1957118A4 (en) 2009-12-23 application
US20090217571A1 (en) 2009-09-03 application
EP1957118A2 (en) 2008-08-20 application
EP1957118B1 (en) 2013-06-19 grant

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