WO2006133777A1 - Separation of metal values in zinc leaching residues - Google Patents
Separation of metal values in zinc leaching residues Download PDFInfo
- Publication number
- WO2006133777A1 WO2006133777A1 PCT/EP2006/004412 EP2006004412W WO2006133777A1 WO 2006133777 A1 WO2006133777 A1 WO 2006133777A1 EP 2006004412 W EP2006004412 W EP 2006004412W WO 2006133777 A1 WO2006133777 A1 WO 2006133777A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bearing
- agglomerates
- process according
- fuming
- residues
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/04—Obtaining zinc by distilling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/30—Obtaining zinc or zinc oxide from metallic residues or scraps
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/10—Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/16—Dry methods smelting of sulfides or formation of mattes with volatilisation or condensation of the metal being produced
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
- C22B7/002—Dry processes by treating with halogens, sulfur or compounds thereof; by carburising, by treating with hydrogen (hydriding)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- This invention relates to the separation of metals in Fe-bearing zinc leaching residues, in particular neutral and weak acid leach residues.
- Blende which is an impure ZnS ore, is the main starting material for the production of Zn.
- the typical industrial practice encompasses an oxidative roasting step, producing ZnO together with sulphates or oxides of the impurities.
- the ZnO in roasted blende is brought into solution by leaching in neutral conditions or in weak acidic conditions, thereby producing Zn-depleted residues, respectively referred to as neutral leach residue and as weak acid leach residue in this description.
- These residues typically contain from 2 to 10 wt . % S, up to 30 wt% Zn, 35 wt% Fe, 7 wt% Pb and 7 wt% SiO 2 .
- the leach residues therefore contain, besides lead sulphate, calcium sulphate and other impurities, a sizeable fraction of Zn in the form of ferrite.
- the recovery of the Zn from ferrite requires a specific hydro-metallurgical residue treatment using high acid concentrations of 50 to 200 g/1 H 2 SO 4 .
- a disadvantage of this acidic treatment is that besides Zn, almost all the Fe and also other impurities such as As, Cu, Cd, Ni, Co, Tl, Sb are dissolved.
- Waelz kilns which produce a slag and a Zn and Pb containing fume.
- Waelz kilns Such a process is described in 'Steelworks residues and the Waelz kiln treatment of electric arc furnace dust', G. Strohmeier and J. Bonestell, Iron and Steel Engineer vol. 73, N°4, pp. 87-90.
- zinc enters in the form of ferrites and sulphate, and is vaporized after being reduced by CO generated by burning cokes.
- the reaction zone of the kiln where iron is reduced to metal, the problem of overheating occurs frequently.
- the charge in the kiln melts and accretions are formed, mainly due to the formation of the eutectic 2FeCSiO 2 - FeO, which has a melting point of approximately 1180 °C.
- the dissolution of FeO further lowers the melting point and through combination with zinc sulphide, reduced from zinc sulphate in the earlier stages, solid crusts are formed.
- the furnace rotation is further hampered by the formation of large balls consisting of carbonized iron, which are formed as a molten metallic phase at approx. 1150 0 C. This again leads to a decreased reduction of ZnO and iron oxide, which are formed in the earlier stages of the furnace from reduced zinc ferrites.
- Overheating accelerates the wear of the brick lining of the kiln.
- the CaO/SiO 2 ratio in the feed has to be monitored closely by setting it to a value of 0.8 to 1.8.
- WO2005-005674 a process for the separation and recovery of non- ferrous metals from zinc-bearing residues was disclosed.
- the process comprises the steps of subjecting the residue to a direct reduction step, extracting Zn- and Pb-bearing fumes, and subjecting the resulting metallic Fe-bearing phase to an oxidising smelting step.
- the direct reduction is performed in a multiple hearth furnace operating at 1100 °C in the reduction zone.
- One disadvantage of the use of such a reduction furnace is that the reduction kinetics are limited by the temperature. Temperatures above 1100 0 C can however not be reached in a multiple hearth furnace.
- JP2004-107748 describes a process for the treatment of zinc leaching residues in a rotary hearth furnace, at a reduction temperature up to 1250 0 C.
- the burner air ratio is set within a limited range.
- the aim of the present invention is to provide a process for the separation of the metals contained in Fe-bearing zinc leaching residues, which does not have the disadvantages described above. This process comprises the steps of:
- the Zn leaching residue should preferably be dried to a moisture content of less than 12 wt . % H 2 O, or even to less than 5 wt . % H 2 O, before preparing the agglomerates.
- a carbon content in the agglomerates of at least 15 wt . % is preferred, as is a CaO equivalent of at least 10 wt.%, or even at least 15 wt . % .
- the strength of the pellets should preferably be at least 5 kg, or even 10 kg. This way dust carry over is avoided and the fusion of the charge is better prevented at the high process temperatures.
- the fuming should advantageously be performed at a temperature of at least 1300 °C, in a carbon monoxide containing atmosphere
- the process is ideally suited for processing neutral or weak acid Zn leach residues.
- the invented process can be performed in a in a rotary hearth furnace; it can optionally be followed by a process whereby the reduced Fe- bearing phase is melted and oxidised.
- the high S content of the feed allows for a relatively high operating temperature without producing molten phases. There is thus no danger for the formation of accretions at the discharge port of the furnace.
- High temperatures guarantee fast reduction and fuming kinetics, which permit the use of a compact technology such as a static bed furnace. This type of furnace furthermore preserves the integrity of the agglomerates, avoiding to a large extent the production of dust and limiting the ensuing pollution of the fumes.
- the following example illustrates the separation of different non- ferrous metals contained in a roasted and subsequently leached blende.
- WAL Weak Acid Leaching
- ZnO-Fe 2 O 3 zinc ferrite
- PbSO 4 lead sulphate
- CaSO 4 calcium sulphate
- ZnSO 4 zinc sulphate
- impurities like CaO, SiO 2 , MgO, Al 2 O 3 , Cu 2 O, SnO
- This mixture was compacted in briquettes by pressing it between 2 hydraulic rolls at a pressure of 20 kN/cm 2 resulting in hard, shiny briquettes, having a Mass Pellet Strength of 20 kg.
- the fuming step was carried out in an induction furnace to simulate the process occurring in a rotating hearth furnace.
- An Indutherm MU-3000 furnace with a maximum power of 15 kW and a frequency of 2000 Hz was used.
- the internal furnace diameter was 180 mm, and the graphite crucible carrying the briquettes had an internal diameter of 140 mm.
- Approximately 40O g briquettes was placed on the bottom of the clean graphite crucible, in such a way that the crucible surface is covered with a single layer of material.
- the crucible was then placed in the induction furnace, and a monitoring thermocouple was mounted between the briquettes without touching the crucible bottom.
- the crucible was covered by a refractory plate.
- the fumed metals were post combusted above the crucible and captured in a filter under the form of flue dust.
- the reactor and the material were heated at to 1300 0 C, as measured with a Pt/PtRhl0 thermocouple mounted between the briquettes. Up to 600 0 C, heating was performed under a protective N 2 gas atmosphere at a gas flow rate of 200 1/h. From 600 °C to 1300 0 C, CO was injected into the crucible at a flow rate of 200 1/h.
- Example 2 This example illustrates the crucial role of S the briquettes, as it avoids the softening and melting of the material during the roasting process without loss in the selectivity.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Manufacture Of Iron (AREA)
- Processing Of Solid Wastes (AREA)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2007015812A MX2007015812A (es) | 2005-06-13 | 2006-05-11 | Separacion de valores de metal en residuos de lixiviacion de zinc. |
JP2008515071A JP2008545888A (ja) | 2005-06-13 | 2006-05-11 | 亜鉛浸出残渣中の金属有価物の分離 |
BRPI0612150A BRPI0612150A2 (pt) | 2005-06-13 | 2006-05-11 | processo para a separação de valores metálicos em um resíduo de zn contendo fe |
EP06753557A EP1893779A1 (en) | 2005-06-13 | 2006-05-11 | Separation of metal values in zinc leaching residues |
AU2006257458A AU2006257458A1 (en) | 2005-06-13 | 2006-05-11 | Separation of metal values in zinc leaching residues |
US11/917,278 US20080196551A1 (en) | 2005-06-13 | 2006-05-11 | Separation of Metal Values in Zinc Leaching Residues |
EA200800030A EA013690B1 (ru) | 2005-06-13 | 2006-05-11 | Извлечение ценных металлов из отходов выщелачивания цинка |
CA002611925A CA2611925A1 (en) | 2005-06-13 | 2006-05-11 | Separation of metal values in zinc leaching residues |
NO20080042A NO20080042L (no) | 2005-06-13 | 2008-01-03 | Separering av metallverdier i sinkutluftingsrester |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05076375 | 2005-06-13 | ||
EP05076375 | 2005-06-13 | ||
US75007705P | 2005-12-14 | 2005-12-14 | |
US60/750,077 | 2005-12-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006133777A1 true WO2006133777A1 (en) | 2006-12-21 |
Family
ID=35240857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2006/004412 WO2006133777A1 (en) | 2005-06-13 | 2006-05-11 | Separation of metal values in zinc leaching residues |
Country Status (14)
Country | Link |
---|---|
US (1) | US20080196551A1 (es) |
EP (1) | EP1893779A1 (es) |
JP (1) | JP2008545888A (es) |
KR (1) | KR20080022545A (es) |
CN (1) | CN101341265A (es) |
AU (1) | AU2006257458A1 (es) |
BR (1) | BRPI0612150A2 (es) |
CA (1) | CA2611925A1 (es) |
EA (1) | EA013690B1 (es) |
MX (1) | MX2007015812A (es) |
NO (1) | NO20080042L (es) |
PE (1) | PE20070088A1 (es) |
WO (1) | WO2006133777A1 (es) |
ZA (1) | ZA200710377B (es) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101979684A (zh) * | 2010-12-01 | 2011-02-23 | 中南大学 | 一种从热镀锌灰中回收锌的工艺 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103103344A (zh) * | 2013-03-01 | 2013-05-15 | 中南大学 | 一种含硫酸盐铅锌冶炼渣选冶联合处理方法 |
CN106119535A (zh) * | 2016-08-01 | 2016-11-16 | 江苏省冶金设计院有限公司 | 处理锌浸出渣的方法和系统 |
CN106148682A (zh) * | 2016-08-01 | 2016-11-23 | 江苏省冶金设计院有限公司 | 处理锌浸出渣的方法和系统 |
RU2626371C1 (ru) * | 2016-09-05 | 2017-07-26 | Общество с ограниченной ответственностью "Урал - рециклинг" | Способ переработки отходов металлургического производства |
CN106399702A (zh) * | 2016-09-27 | 2017-02-15 | 江苏省冶金设计院有限公司 | 一种转底炉处理铅锌渣回收有色金属的工艺 |
CN106929667A (zh) * | 2017-03-13 | 2017-07-07 | 江苏省冶金设计院有限公司 | 一种处理锌浸渣的方法 |
CN107254586B (zh) * | 2017-06-20 | 2019-05-14 | 西部矿业股份有限公司 | 一种氧压浸出尾矿渣的处理方法 |
CN114540628B (zh) * | 2022-01-20 | 2023-11-14 | 云南云铜锌业股份有限公司 | 一种处理浸锌渣、锌冶炼石膏渣和高炉瓦斯灰的方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4605435A (en) * | 1985-01-31 | 1986-08-12 | Amax Inc. | Recycling of steel plant dusts to steel furnaces |
WO1988001654A1 (en) * | 1986-08-27 | 1988-03-10 | Commonwealth Scientific And Industrial Research Or | Process for the treatment of lead-zinc ores, concentrates or residues |
US5667553A (en) * | 1995-03-02 | 1997-09-16 | Complete Recovery Process, Llc | Methods for recycling electric arc furnace dust |
US5906671A (en) * | 1996-10-25 | 1999-05-25 | Agglo Inc. | Method for extraction of metals and non-metals from minerals, industrial by-products and waste materials |
EP1199373A1 (fr) * | 2000-10-17 | 2002-04-24 | Universite Catholique De Louvain | Eléments agglomérés et procédé de traítement de poussières métallurgiques |
JP2004107748A (ja) * | 2002-09-19 | 2004-04-08 | Daido Steel Co Ltd | 亜鉛浸出残渣の処理方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW357193B (en) * | 1996-11-11 | 1999-05-01 | Sumitomo Metal Ind | Manufacturing method of reduced iron and the apparatus |
KR100530815B1 (ko) * | 2000-10-30 | 2005-11-25 | 신닛뽄세이테쯔 카부시키카이샤 | 환원로용 산화 금속 함유 미가공 팰릿, 그 제조 방법, 그환원 방법 및 환원 설비 |
KR101084927B1 (ko) * | 2003-07-04 | 2011-11-17 | 유미코르 | 아연 잔류물로부터 비철 금속을 회수하는 방법 |
-
2006
- 2006-05-11 BR BRPI0612150A patent/BRPI0612150A2/pt not_active IP Right Cessation
- 2006-05-11 KR KR20077028617A patent/KR20080022545A/ko not_active Application Discontinuation
- 2006-05-11 ZA ZA200710377A patent/ZA200710377B/xx unknown
- 2006-05-11 WO PCT/EP2006/004412 patent/WO2006133777A1/en active Application Filing
- 2006-05-11 CA CA002611925A patent/CA2611925A1/en not_active Abandoned
- 2006-05-11 EA EA200800030A patent/EA013690B1/ru not_active IP Right Cessation
- 2006-05-11 JP JP2008515071A patent/JP2008545888A/ja not_active Withdrawn
- 2006-05-11 AU AU2006257458A patent/AU2006257458A1/en not_active Abandoned
- 2006-05-11 MX MX2007015812A patent/MX2007015812A/es unknown
- 2006-05-11 EP EP06753557A patent/EP1893779A1/en not_active Withdrawn
- 2006-05-11 CN CNA2006800209006A patent/CN101341265A/zh active Pending
- 2006-05-11 US US11/917,278 patent/US20080196551A1/en not_active Abandoned
- 2006-06-08 PE PE2006000634A patent/PE20070088A1/es not_active Application Discontinuation
-
2008
- 2008-01-03 NO NO20080042A patent/NO20080042L/no not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4605435A (en) * | 1985-01-31 | 1986-08-12 | Amax Inc. | Recycling of steel plant dusts to steel furnaces |
WO1988001654A1 (en) * | 1986-08-27 | 1988-03-10 | Commonwealth Scientific And Industrial Research Or | Process for the treatment of lead-zinc ores, concentrates or residues |
US5667553A (en) * | 1995-03-02 | 1997-09-16 | Complete Recovery Process, Llc | Methods for recycling electric arc furnace dust |
US5906671A (en) * | 1996-10-25 | 1999-05-25 | Agglo Inc. | Method for extraction of metals and non-metals from minerals, industrial by-products and waste materials |
EP1199373A1 (fr) * | 2000-10-17 | 2002-04-24 | Universite Catholique De Louvain | Eléments agglomérés et procédé de traítement de poussières métallurgiques |
JP2004107748A (ja) * | 2002-09-19 | 2004-04-08 | Daido Steel Co Ltd | 亜鉛浸出残渣の処理方法 |
Non-Patent Citations (3)
Title |
---|
"Zinc leach residues - A mine on the doorstep", METAL BULLETIN MONTHLY, April 1971 (1971-04-01), pages 6 - 10, XP009056015 * |
PATENT ABSTRACTS OF JAPAN vol. 2003, no. 12 5 December 2003 (2003-12-05) * |
STROHMEIER G ET AL: "STEELWORKS RESIDUES AND THE WAELZ KILN TREATMENT OF ELECTRIC ARC FURNACE DUST", IRON AND STEEL ENGINEER, ASSOCIATION OF IRON AND STEEL ENGINEERS. PITTSBURGH, US, vol. 73, no. 4, 1 April 1996 (1996-04-01), pages 87 - 90, XP000595696, ISSN: 0021-1559 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101979684A (zh) * | 2010-12-01 | 2011-02-23 | 中南大学 | 一种从热镀锌灰中回收锌的工艺 |
Also Published As
Publication number | Publication date |
---|---|
NO20080042L (no) | 2008-01-03 |
US20080196551A1 (en) | 2008-08-21 |
KR20080022545A (ko) | 2008-03-11 |
EA013690B1 (ru) | 2010-06-30 |
AU2006257458A1 (en) | 2006-12-21 |
EP1893779A1 (en) | 2008-03-05 |
JP2008545888A (ja) | 2008-12-18 |
BRPI0612150A2 (pt) | 2016-09-06 |
MX2007015812A (es) | 2008-04-29 |
CA2611925A1 (en) | 2006-12-21 |
ZA200710377B (en) | 2009-03-25 |
EA200800030A1 (ru) | 2008-12-30 |
PE20070088A1 (es) | 2007-02-02 |
CN101341265A (zh) | 2009-01-07 |
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