WO2006110515A1 - Film-forming compositions derived from acyclic carbonates and polyamines - Google Patents

Film-forming compositions derived from acyclic carbonates and polyamines Download PDF

Info

Publication number
WO2006110515A1
WO2006110515A1 PCT/US2006/012983 US2006012983W WO2006110515A1 WO 2006110515 A1 WO2006110515 A1 WO 2006110515A1 US 2006012983 W US2006012983 W US 2006012983W WO 2006110515 A1 WO2006110515 A1 WO 2006110515A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
film
polymer
carbonate
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/012983
Other languages
English (en)
French (fr)
Inventor
Eswarakrishnan Venkatachalam
Gregory J. Mccollum
Matthew Scott
Geoffrey R. Webster, Jr.
Judith A. Orzechowski
Kevin J. Dufford
David Robert Fenn
Alan J. Kaylo
Thomas C. Moriarity
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
PPG Industries Ohio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PPG Industries Ohio Inc filed Critical PPG Industries Ohio Inc
Priority to BRPI0612435-6A priority Critical patent/BRPI0612435A2/pt
Priority to AU2006235147A priority patent/AU2006235147B2/en
Priority to CN2006800114082A priority patent/CN101155884B/zh
Priority to EP06749483A priority patent/EP1907486B1/en
Priority to JP2008505562A priority patent/JP4742139B2/ja
Priority to DE200660003440 priority patent/DE602006003440D1/de
Priority to CA 2603307 priority patent/CA2603307C/en
Priority to MX2007012376A priority patent/MX2007012376A/es
Publication of WO2006110515A1 publication Critical patent/WO2006110515A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal

Definitions

  • the present invention provides a film-forming composition
  • a film-forming composition comprising a reaction product of: a) a polyamine containing a primary amino group and a secondary amino group; b) an acyclic carbonate; and c) a polyepoxide polymer.
  • compositions of the present invention may be curable compositions.
  • curable and “substantially cured” as used in connection with a curable composition means that any crosslinkable components of the composition are at least partially crosslinked after a curing process (e. g., heating).
  • the crosslink density (degree of crosslinking) of the crosslinkable components ranges from 5% to 100% of complete crosslinking.
  • DMTA dynamic mechanical thermal analysis
  • Polyamines suitable for use in the preparation of the reaction product used in the film-forming composition of the present invention contain a primary amino group and a secondary amino group. Any polyamines having these characteristics known to those skilled in the art may be used. In one embodiments, the polyamines contain at least two primary amino groups. Suitable polyamines include, for example, diethylenetriamine, dipropylenetriamine, and/or bis-hexamethylenetriamine. In an embodiment of the present invention, the polyamines used to prepare the reaction product comprising the film-forming compositions of the present invention are not intended to include polyfunctional amines containing at least one primary or secondary amino group and another functional group containing an active hydrogen such as a hydroxyl group.
  • the polymer contains cationic groups, such as cationic amine salt groups, quaternary ammonium groups, ternary sulfonium groups and/or quaternary phosphonium groups.
  • cationic groups such as cationic amine salt groups, quaternary ammonium groups, ternary sulfonium groups and/or quaternary phosphonium groups.
  • film-forming resins suitable for use in anionic coating compositions include base-solubilized, carboxylic acid group- containing polymers such as the reaction product or adduct of a drying oil or semi-drying fatty acid ester with a dicarboxylic acid or anhydride; and the reaction product of a fatty acid ester, unsaturated acid or anhydride and any additional unsaturated modifying materials which are further reacted with polyol.
  • the "substrate" upon which the coating composition is applied can comprise, for example any electroconductive substrates including those described above to which one or more pretreatment and/or primer coatings have been previously applied
  • a typical electrodeposition process involves immersing the electroconductive substrate into an electrodeposition bath of an aqueous electrodepositable composition, the substrate serving as a cathode in an electrical circuit comprising the cathode and an anode. Sufficient electrical current is applied between the electrodes to deposit a substantially continuous, adherent film of the electrodepositable coating composition onto at least a portion of the surface of the electroconductive substrate.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyamides (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
PCT/US2006/012983 2005-04-08 2006-04-05 Film-forming compositions derived from acyclic carbonates and polyamines Ceased WO2006110515A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
BRPI0612435-6A BRPI0612435A2 (pt) 2005-04-08 2006-04-05 composição formadora de pelìcula, método para preparar uma composição formadora de pelìcula e artigo revestido
AU2006235147A AU2006235147B2 (en) 2005-04-08 2006-04-05 Film-forming compositions derived from acyclic carbonates and polyamines
CN2006800114082A CN101155884B (zh) 2005-04-08 2006-04-05 衍生自无环碳酸酯和多元胺的成膜组合物
EP06749483A EP1907486B1 (en) 2005-04-08 2006-04-05 Film-forming compositions derived from acyclic carbonates and polyamines
JP2008505562A JP4742139B2 (ja) 2005-04-08 2006-04-05 非環式カーボネートおよびポリアミン由来のフィルム形成性組成物
DE200660003440 DE602006003440D1 (de) 2005-04-08 2006-04-05 Filmbildende zusammensetzungen aus acyclischen carbonaten und polyaminen
CA 2603307 CA2603307C (en) 2005-04-08 2006-04-05 Film-forming compositions derived from acyclic carbonates and polyamines
MX2007012376A MX2007012376A (es) 2005-04-08 2006-04-05 Composiciones formadoras de pelicula derivadas de carbonatos aciclicos y poliaminas.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/101,803 US7459504B2 (en) 2005-04-08 2005-04-08 Reaction product of polyamine and acyclic carbonate
US11/101,803 2005-04-08

Publications (1)

Publication Number Publication Date
WO2006110515A1 true WO2006110515A1 (en) 2006-10-19

Family

ID=36749065

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/012983 Ceased WO2006110515A1 (en) 2005-04-08 2006-04-05 Film-forming compositions derived from acyclic carbonates and polyamines

Country Status (13)

Country Link
US (2) US7459504B2 (https=)
EP (1) EP1907486B1 (https=)
JP (2) JP4742139B2 (https=)
KR (1) KR100943557B1 (https=)
CN (1) CN101155884B (https=)
AU (1) AU2006235147B2 (https=)
BR (1) BRPI0612435A2 (https=)
CA (1) CA2603307C (https=)
DE (1) DE602006003440D1 (https=)
ES (1) ES2314910T3 (https=)
MX (1) MX2007012376A (https=)
RU (1) RU2406742C2 (https=)
WO (1) WO2006110515A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7842762B2 (en) 2007-08-08 2010-11-30 Ppg Industries Ohio, Inc. Electrodepositable coating composition containing a cyclic guanidine
US20110045725A1 (en) 2009-08-24 2011-02-24 Ppg Industries Ohio, Inc. Film-forming compositions, related processes and coated substrates
WO2011149736A1 (en) * 2010-05-28 2011-12-01 3M Innovative Properties Company Roofing repair system and method
US9068089B2 (en) 2013-03-15 2015-06-30 Ppg Industries Ohio, Inc. Phenolic admix for electrodepositable coating composition containing a cyclic guanidine
FR3005958B1 (fr) * 2013-05-24 2015-06-05 Arkema France Oligomere urethane acryle ou methacryle sans isocyanate.
US9688874B2 (en) 2013-10-25 2017-06-27 Ppg Industries Ohio, Inc. Method of making a bicyclic guanidine-cured acrylic coating
EP2942374A1 (en) * 2014-05-09 2015-11-11 PPG Coatings Europe B.V. A Coating Composition
EP3243857A1 (en) * 2016-05-13 2017-11-15 Centre National de la Recherche Scientifique - CNRS - Uniform sequence-defined polyurethanes and uses thereof as molecular labels
CN107177035B (zh) * 2017-07-20 2019-10-15 广东工业大学 一种聚氨酯预聚体及其制备方法和紫外光固化聚氨酯预聚体组合物
US20200078288A1 (en) * 2018-09-07 2020-03-12 Eastern Michigan University Biobased, uv-curable nail polish compositions and related methods

Citations (3)

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Publication number Priority date Publication date Assignee Title
EP0149156A2 (en) * 1983-12-16 1985-07-24 Ppg Industries, Inc. A novel process of curing compositions with the reaction product of polyprimary amines and organic carbonates
EP0889101A2 (en) * 1997-06-30 1999-01-07 Basf Corporation Cathodic electrodeposition coating with carbamate-functional crosslinking agents
EP1156085A1 (en) * 2000-05-16 2001-11-21 E.I. Du Pont De Nemours And Company Binders for use in cathodic electrodeposition coatings, process for their preparation and cathodic electrodeposition coating compositions containing same

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US4167499A (en) * 1978-05-09 1979-09-11 E. I. Du Pont De Nemours And Company Graft copolymer useful in electrodeposition
US4335028A (en) * 1980-09-22 1982-06-15 Scm Corporation Cathodic electrocoating compositions containing base-functional graft polymers having epoxy resin backbones, and substrates coated therewith
DE3123536A1 (de) * 1981-06-13 1982-12-30 Basf Farben + Fasern Ag, 2000 Hamburg Bindemittel fuer kathodisch abscheidbare ueberzugsmassen, verfahren zu ihrer herstellung und ihre verwendung
DE3246812A1 (de) 1982-12-17 1984-06-20 Hoechst Ag, 6230 Frankfurt Haertbare, kationische modifizierungsprodukte von epoxidharzen, verfahren zu ihrer herstellung und ihre verwendung
DE3311518A1 (de) * 1983-03-30 1984-10-04 Basf Farben + Fasern Ag, 2000 Hamburg Hitzehaertbare ueberzugsmittel und deren verwendung
US4459400A (en) * 1983-12-12 1984-07-10 Eastman Kodak Company Poly(ester-amide) compositions
JPS60168762A (ja) * 1983-12-16 1985-09-02 ピ−ピ−ジ−・インダストリ−ズ・インコ−ポレイテツド 活性水素含有組成物の硬化方法
US4484994A (en) * 1984-02-17 1984-11-27 American Cyanamid Company Hydroxyalkyl carbamate-containing resins for cathodic electrodeposition and method of making the same
GB8714873D0 (en) 1987-06-25 1987-07-29 Bp Chemicals Additives Additives
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Publication number Priority date Publication date Assignee Title
EP0149156A2 (en) * 1983-12-16 1985-07-24 Ppg Industries, Inc. A novel process of curing compositions with the reaction product of polyprimary amines and organic carbonates
EP0889101A2 (en) * 1997-06-30 1999-01-07 Basf Corporation Cathodic electrodeposition coating with carbamate-functional crosslinking agents
EP1156085A1 (en) * 2000-05-16 2001-11-21 E.I. Du Pont De Nemours And Company Binders for use in cathodic electrodeposition coatings, process for their preparation and cathodic electrodeposition coating compositions containing same

Also Published As

Publication number Publication date
JP4742139B2 (ja) 2011-08-10
US20090042033A1 (en) 2009-02-12
EP1907486A1 (en) 2008-04-09
BRPI0612435A2 (pt) 2010-11-09
ES2314910T3 (es) 2009-03-16
EP1907486B1 (en) 2008-10-29
KR100943557B1 (ko) 2010-02-22
US7670500B2 (en) 2010-03-02
MX2007012376A (es) 2007-11-09
CA2603307A1 (en) 2006-10-19
KR20070110420A (ko) 2007-11-16
AU2006235147B2 (en) 2009-06-25
RU2007141382A (ru) 2009-05-20
CN101155884B (zh) 2012-09-05
US7459504B2 (en) 2008-12-02
DE602006003440D1 (de) 2008-12-11
US20060229419A1 (en) 2006-10-12
JP2008534773A (ja) 2008-08-28
CA2603307C (en) 2009-11-03
RU2406742C2 (ru) 2010-12-20
AU2006235147A1 (en) 2006-10-19
JP2011068896A (ja) 2011-04-07
CN101155884A (zh) 2008-04-02

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