WO2006093756A1 - Support system for reactor vessel internals - Google Patents
Support system for reactor vessel internals Download PDFInfo
- Publication number
- WO2006093756A1 WO2006093756A1 PCT/US2006/006273 US2006006273W WO2006093756A1 WO 2006093756 A1 WO2006093756 A1 WO 2006093756A1 US 2006006273 W US2006006273 W US 2006006273W WO 2006093756 A1 WO2006093756 A1 WO 2006093756A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insert
- manway
- hanger
- support system
- support
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 239000012530 fluid Substances 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 238000009826 distribution Methods 0.000 description 6
- 238000003466 welding Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 238000005304 joining Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C13/00—Pressure vessels; Containment vessels; Containment in general
- G21C13/02—Details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Definitions
- the invention relates to a system for supporting certain reactor internals within a reactor vessel.
- Downflow reactor vessels are commonly used in the chemical and refining industries in catalytic processes such as hydrotreating, hydrocracking, hydrodesulfurization, hydrofinishing, and hydrodewaxing.
- the typical downflow reactor is a vessel that is equipped with a feed inlet and a reactor effluent outlet. Contained within the vessel is a bed of catalyst particles with which the feed that is introduced into the vessel is contacted.
- a feed distribution tray disposed between the point of feed introduction into the reactor vessel and the bed of catalyst particles for the purpose of distributing the feed fluid across the cross section of the catalyst bed.
- a typical manner by which the feed distribution tray is incorporated into the reactor vessel is by affixing or connecting the feed distribution tray or its supporting structure to the inside wall of the reactor vessel. This connection is often achieved by welding attachments to the inside wall of the reactor vessel. Affixing these reactor internals to the inside of a reactor wall, however, can be an unsuitable way of supporting the feed distribution system within the reactor vessel. For instance, welding to the inside wall of a hydroprocessing reactor vessel with a weld overlay material that is susceptible to hydrogen can result in cracking of the weld overlay metal and to other problems.
- the problems associated with affixing reactor internals to the inside wall of a reactor vessel may be resolved by a novel support system for supporting reactor internals inside a reactor vessel without the need to affix the support system to the reactor inside wall.
- an object of the invention is to provide a support system for supporting reactor internals within a reactor vessel without the need to affix the support system to the inside wall of the reactor.
- a support system for use with a reactor vessel having an inside wall that defines a reaction zone capable of containing a bed of catalyst particles and which includes an inlet manway providing an opening into the reaction zone.
- the support system includes a manway insert having an insert upper end and an insert lower end, wherein the manway insert is capable of extending through the opening into the reaction zone. It further includes a support hanger having a hanger upper end and a hanger lower end with the hanger upper end being fixedly connected to the insert lower end, and a support structure capable of supporting a fluid distributor tray and which is fixedly connected to the hanger lower end.
- FIG. 1 is a vertical cross section of a reactor vessel and support system of the invention.
- FIG. 2 is a detail sectional view showing the upper portion of the support system and the inlet manway of the reactor vessel shown in FIG. 1.
- FIG. 3 is a cross-sectional view of the reactor vessel and support system taken along line 3-3 of FIG. 1.
- FIG. 4 is a perspective view with the reactor vessel cut away to show the support system contained in the reactor vessel.
- the invention relates to apparatus for the support of certain internals of a downflow-type reactor without the need to affix the support apparatus to the inside wall of the reactor.
- FIG. 1 is presented a vertical cross section of a reactor vessel 10 that is equipped with the support system 12.
- the reactor vessel 10 may be any suitable type of vessel that defines a reaction zone 14 capable of containing a bed 16 of catalyst particles with which a feedstock is contacted.
- the reaction zone 14 includes both an inlet/fluid distribution zone 17 and the bed 16 that defines a zone in which, typically, the process reactions occur.
- Reactor vessel 10 has an inside wall 18 which defines the reaction zone 14 that contains the bed 16 of catalyst particles.
- the reactor vessel 10 is equipped with an inlet manway 20 and an outlet manway or, alternatively, a reactor effluent outlet 22.
- the inlet manway 20 has a manway inside wall 24 that defines an opening or conduit allowing for the entry or passage from outside to within the reaction zone 14.
- inlet manway 24 provides means for communication between the outside and inside of the reactor vessel 10.
- the reactor effluent outlet 22 provides means for removing a reactor effluent from the reaction zone 14 within the reactor vessel 10.
- the support system 12 includes a manway insert 26, support hangers 28 and support structure 30.
- the support hangers 28 include a hanger upper end 32 and a hanger lower end 34.
- the support hangers 28 provide means by which the load from the support structure 30 and the objects that are supported upon such support structure 30 is transmitted to the manway insert 26.
- the support hangers 28 will be, in most instances, in tension.
- the hanger lower end 34 is fixedly connected to the support structure 30 by any suitable connection means for connecting the hanger lower end 34 to the support structure 30 and can include welding or connecting using bolts or any other known means for connecting metal parts.
- connection means In order to permit the off-site fabrication and the separate assembly of the support system 12 within the reactor vessel 10, it is preferred for the connection means to be a plate 36 that is affixed, preferably by welding, to the support structure 30 and which plate 36 includes a hole through which a bolt may be inserted.
- the hanger lower end 34 further includes a hole that is matched with the hole of plate 36 through which a bolt may pass to thereby provide for the connecting means for fixedly connecting the hanger lower end 34 to the support structure 30. It is, however, recognized that any other suitable means for fixedly connecting the hanger lower end 34 to the support structure 30 may be used.
- FIG. 2 presents an enlarged view of the sectional detail 40 as indicated in FIG. 1.
- the enlarged sectional detail 40 shows the inlet manway 20 and portions of the support system 12 (entire support system 12 is shown in FIG. 1) that include the manway insert 26, the hanger upper end 32 of the support hangers 28, and clamp 42.
- the hanger upper end 32 is fixedly connected to the manway insert 26 by clamp 42.
- the manway insert 26 has an insert outside wall 43, an insert inside wall 44, an insert upper end 45 and an insert lower end 46. While what is depicted is clamp 42 used to fasten the hanger upper end 32 to the manway insert 26, it is understood that any suitable connection means for fastening the hanger upper end 32 to the manway insert 26 may be used. Such connecting means can include welding or connecting using bolts or any other suitable means for connecting metal parts. Affixed to the clamp 42 is a plate 48 having a hole through which a bolt may be inserted. The hanger upper end 32 further may include a hole 50 that may be matched with the hole of plate 48 through which a bolt may pass to thereby provide for connecting means for fixedly connecting the hanger upper end 32 to the clamp 42. The clamp 42 may be detachable or removable so as to permit its fabrication off-site with it being separately assembled and installed within the reactor vessel 10.
- the clamp 42 or any other connecting means for affixing the hanger upper end 32 to the manway insert 26, to be positioned at the insert lower end 46.
- a groove 52 to be machined into the outer surface of the insert lower end 46 and for the clamp 42 to have a matching or corresponding protrusion 54, which may be fitted together to form a joint for joining the clamp 42 to the insert lower end 46.
- the inlet manway 20 has a manway inside wall 24 that defines a conduit or an opening into the reaction zone 12.
- the manway insert 26 is, thus, capable of extending through the manway conduit and into the reaction zone 14 wherein the insert lower end 46 terminates.
- the insert upper end 45 may further include a flange 56 extending horizontally and outwardly from the insert outside wall 43 and providing for its seating upon a face 58 of the inlet manway flange 60.
- the face 58 of the inlet manway flange 60 provides a bearing upon which the flange 56 may rest.
- the flange 56 thus, provides means for transferring the load from the support structure 30, and the objects supported thereon, through the support system 12 and onto the inlet manway 20.
- the face 58 is provided with means for forming a ring joint with an opposing manway cover flange (not shown).
- An example of such means includes a groove or a bevel that is machined or formed into the face 58. This groove or bevel is capable of being matched with a matching and opposing groove or bevel that is machined or formed into the face of the opposing manway cover flange.
- a ring joint gasket may be placed within the groove or bevel of the face 58 and the opposing groove or bevel of the face of the opposing manway cover flange so that when the two flanges are joined together the ring joint is formed.
- a wider ring joint gasket may be used, or, alternatively, a chamber may be formed in the face of the opposing manway cover flange so as to allow for the placement of the flange 56 upon the face 58 and the joining of the flange 60 with the opposing manway cover flange in a manner so as to provide a desirable ring joint.
- the manway inside wall 24 has a cylindrical geometry that can be characterized by a diameter, and it is further preferred for the insert outside wall 43 to extend to within close proximity to and along the manway inside wall 24 and, more preferably, with the insert outside wall 43 being substantially flush against the manway inside wall 24. It is also preferred for the insert inside wall 44 to define a conduit through which a fluid may be introduced into the reaction zone 14 or through which a feed inlet pipe may extend to provide means for introducing a fluid from outside to within the reaction zone 14.
- FIG. 3 is a cross-sectional view of the reactor vessel 10 taken along line 3-3 of FIG. 1.
- Shown is the clamp 42 onto which are affixed plates 48.
- the plates 48 provide means for fixedly connecting the hanger upper ends 32 of the support hangers 28 to the manway insert 26.
- the plates 48 and the hanger upper end 32 will have holes that are matching through which a bolt may be passed to form a connection.
- This type of connection permits the fabrication of the individual parts of the support system 12 off-site from the location of the reactor vessel 10 and the later and separate assembly of the individual parts of the support system 12 within the reaction zone 14 of the reactor vessel 10.
- the clamp 42 is affixed to the manway insert 26 using a hole-and-bolt connection
- the support hangers 28 extend from manway insert 26 downwardly to a skirt 64 of the support structure 30 (not shown in FIG. 3).
- the skirt 64 may be a structural element that extends to within close proximity to and along the inside wall 18 of the reactor vessel 10.
- the skirt 64 provides means for attaching additional elements that make up the support structure 30 and means for supporting various types of reactor internal equipment, such as, for example, a fluid distributor tray (not shown) for distributing a reactor feed fluid across the surface and cross section of the bed 16 of catalyst particles.
- the skirt 64 may be a flat plate of a structural element having a flat face 66 that may be placed flush against the inside wall 18, and, further, it may include one or more flanges.
- sealing means (not shown) for sealing the space between the inside wall 18 of the reactor vessel 10 and the flat face 66 of skirt 64 to thereby prevent the excessive flow of fluid through the space that is formed between the inside wall 18 and flat face 66. Any suitable material or means may be used to form this seal.
- the skirt 64 may also be any other suitable structural element that can provide support means for supporting a load such as the aforementioned distribution tray system.
- the hanger lower end 34 of support hanger 28 extends downwardly and away from the manway insert 26, and it is fixedly connected to the skirt 64.
- FIG. 4 presents a perspective view of the reactor vessel 10 that is cut away to show the support system 12 associated with the reactor vessel 10.
- the reactor vessel 10 is equipped with the inlet manway 20 providing for an opening into the inside of the reactor vessel 10.
- the manway insert 26 is supported by the inlet manway 20 at the flange face 58, and the manway insert 20 extends through the opening that is defined by the inlet manway 20 into the inside of the reactor vessel 10 where the insert lower end 46 of the manway insert 26 terminates.
- Fastened to the insert lower end 46 is clamp 42, which provides means for connecting support hanger 28 to the manway insert 20 and means for transferring the load from the support hanger 28 to the manway insert 20.
- Each support hanger 28 has a hanger upper end 32 and a hanger lower end 34.
- the hanger upper end 32 is fixedly attached to the clamp 42 and the hanger lower end 34 is fixedly attached to a skirt 64, which is part of the support structure 30 (See FIG. 1).
- Support structure 30 provides means for supporting a load resulting from reactor internal device such as, preferably, a fluid distributor tray.
- the skirt 64 extends along the circumference of the inside wall 18 of the reactor vessel 10.
- the support structure 30 may further include additional support members such as one or more beams 68, which extend horizontally and are affixed at each of their ends to the inside circumference of the skirt 64.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Load-Engaging Elements For Cranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2007010225A MX2007010225A (en) | 2005-02-25 | 2006-02-22 | Support system for reactor vessel internals. |
EP06735784A EP1855790A1 (en) | 2005-02-25 | 2006-02-22 | Support system for reactor vessel internals |
JP2007557122A JP5647386B2 (en) | 2005-02-25 | 2006-02-22 | Support device for internal structure of reaction vessel |
KR1020077021864A KR101292599B1 (en) | 2005-02-25 | 2006-02-22 | Support system for reactor vessel internals |
CA2598654A CA2598654C (en) | 2005-02-25 | 2006-02-22 | Support system for reactor vessel internals |
BRPI0606917-7A BRPI0606917A2 (en) | 2005-02-25 | 2006-02-22 | support system for use with a reactor vessel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65652605P | 2005-02-25 | 2005-02-25 | |
US60/656,526 | 2005-02-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006093756A1 true WO2006093756A1 (en) | 2006-09-08 |
Family
ID=36603519
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/006273 WO2006093756A1 (en) | 2005-02-25 | 2006-02-22 | Support system for reactor vessel internals |
Country Status (9)
Country | Link |
---|---|
US (1) | US7470410B2 (en) |
EP (1) | EP1855790A1 (en) |
JP (1) | JP5647386B2 (en) |
KR (1) | KR101292599B1 (en) |
CN (1) | CN100548460C (en) |
BR (1) | BRPI0606917A2 (en) |
CA (1) | CA2598654C (en) |
MX (1) | MX2007010225A (en) |
WO (1) | WO2006093756A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8202498B2 (en) | 2010-07-19 | 2012-06-19 | Chevron U.S.A. Inc. | Multiphase contact and distribution apparatus for hydroprocessing |
US8372354B2 (en) | 2010-07-19 | 2013-02-12 | Chevron U.S.A. Inc. | Multiphase contact and distribution apparatus for hydroprocessing |
NL2008694C2 (en) | 2012-04-24 | 2013-10-28 | Ihc Holland Ie Bv | Vessel comprising a spud. |
FR3096904B1 (en) * | 2019-06-07 | 2021-05-07 | Air Liquide | Device for delivering gas to a gas processing vessel comprising particulate material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2292716A (en) * | 1938-10-20 | 1942-08-11 | Universal Oil Prod Co | Treating chamber |
US2767066A (en) * | 1953-08-17 | 1956-10-16 | Standard Oil Co | Impact baffle |
US3363843A (en) * | 1965-04-26 | 1968-01-16 | Union Oil Co | Fluid inlet distributor |
US3479748A (en) * | 1967-09-22 | 1969-11-25 | Vernon H Sietmann | Apparatus for and process of drying grain |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7002A (en) * | 1850-01-08 | Obe-washek | ||
JPS5335865B1 (en) * | 1967-11-11 | 1978-09-29 | ||
JPS478202B1 (en) * | 1968-04-15 | 1972-03-09 | ||
US3824080A (en) | 1972-04-27 | 1974-07-16 | Texaco Inc | Vertical reactor |
DE2359954A1 (en) * | 1973-10-06 | 1975-06-05 | Hermann Dipl Chem Dr Stage | Distributor tray for packed column - contg. expanded metal downpipes and peripheral skirt in widened out dia of column |
DE2436456A1 (en) * | 1974-07-29 | 1976-02-12 | Siemens Ag | DISTRIBUTOR FOR STREAMING MEDIA |
JPS5221269A (en) * | 1975-08-12 | 1977-02-17 | Jgc Corp | Reaction vessel having fluid distribution system |
JPS5222571A (en) * | 1975-08-14 | 1977-02-19 | Jgc Corp | Reactor having a fluid distributor |
US4161963A (en) * | 1975-09-22 | 1979-07-24 | Techni-Chem, Inc. | Liquid treatment apparatus |
KR830002469B1 (en) * | 1980-04-02 | 1983-10-26 | 도오요 엥지니어링 가부시끼가이샤 | Exothermic reaction method of gaseous raw material in contact with granular catalyst layer |
US4743433A (en) * | 1982-10-15 | 1988-05-10 | Mobil Oil Corporation | Catalytic reactor system |
KR900005191B1 (en) * | 1985-02-13 | 1990-07-21 | 현대중공업 주식회사 | Corrugating sheet for the diaphragm of ships |
US4904456A (en) * | 1985-06-20 | 1990-02-27 | Phillips Petroleum Company | Apparatus for treating fluids in a bed of particulate material |
GB2201964B (en) | 1987-03-05 | 1991-05-22 | Shell Int Research | Process and apparatus for the catalytic treatment of hydrocarbon oils |
US4836989A (en) | 1987-07-02 | 1989-06-06 | Mobil Oil Corporation | Distribution system for downflow reactors |
JP3431216B2 (en) * | 1993-06-18 | 2003-07-28 | 千代田化工建設株式会社 | Catalyst layer support structure |
US5484578A (en) | 1994-06-20 | 1996-01-16 | Mobil Oil Corporation | Two-phase distributor system for downflow reactors |
US6669915B1 (en) | 1999-07-13 | 2003-12-30 | Exxonmobil Research And Engineering Company | Gas-liquid inlet nozzle for cocurrent downflow reactors |
JP2001232183A (en) * | 2000-02-23 | 2001-08-28 | Sumitomo Heavy Ind Ltd | Liquid dispersion supplying unit and vacuum liquid treating device |
-
2006
- 2006-02-22 KR KR1020077021864A patent/KR101292599B1/en not_active IP Right Cessation
- 2006-02-22 EP EP06735784A patent/EP1855790A1/en not_active Withdrawn
- 2006-02-22 BR BRPI0606917-7A patent/BRPI0606917A2/en active Search and Examination
- 2006-02-22 CA CA2598654A patent/CA2598654C/en not_active Expired - Fee Related
- 2006-02-22 CN CNB2006800053958A patent/CN100548460C/en not_active Expired - Fee Related
- 2006-02-22 MX MX2007010225A patent/MX2007010225A/en unknown
- 2006-02-22 US US11/359,321 patent/US7470410B2/en not_active Expired - Fee Related
- 2006-02-22 WO PCT/US2006/006273 patent/WO2006093756A1/en active Application Filing
- 2006-02-22 JP JP2007557122A patent/JP5647386B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2292716A (en) * | 1938-10-20 | 1942-08-11 | Universal Oil Prod Co | Treating chamber |
US2767066A (en) * | 1953-08-17 | 1956-10-16 | Standard Oil Co | Impact baffle |
US3363843A (en) * | 1965-04-26 | 1968-01-16 | Union Oil Co | Fluid inlet distributor |
US3479748A (en) * | 1967-09-22 | 1969-11-25 | Vernon H Sietmann | Apparatus for and process of drying grain |
Also Published As
Publication number | Publication date |
---|---|
CN100548460C (en) | 2009-10-14 |
JP2008531259A (en) | 2008-08-14 |
KR20070107153A (en) | 2007-11-06 |
KR101292599B1 (en) | 2013-08-05 |
EP1855790A1 (en) | 2007-11-21 |
US20070025495A1 (en) | 2007-02-01 |
BRPI0606917A2 (en) | 2009-12-01 |
CA2598654A1 (en) | 2006-09-08 |
US7470410B2 (en) | 2008-12-30 |
CN101124037A (en) | 2008-02-13 |
MX2007010225A (en) | 2007-09-04 |
CA2598654C (en) | 2013-11-26 |
JP5647386B2 (en) | 2014-12-24 |
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