WO2006087090A1 - Granules comprising sterol - Google Patents
Granules comprising sterol Download PDFInfo
- Publication number
- WO2006087090A1 WO2006087090A1 PCT/EP2006/000798 EP2006000798W WO2006087090A1 WO 2006087090 A1 WO2006087090 A1 WO 2006087090A1 EP 2006000798 W EP2006000798 W EP 2006000798W WO 2006087090 A1 WO2006087090 A1 WO 2006087090A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- particles
- fat
- lipid
- granule
- oil
- Prior art date
Links
- 239000008187 granular material Substances 0.000 title claims abstract description 41
- 229930182558 Sterol Natural products 0.000 title claims abstract description 23
- 235000003702 sterols Nutrition 0.000 title claims abstract description 23
- 150000003432 sterols Chemical class 0.000 title claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 31
- 150000002632 lipids Chemical class 0.000 claims abstract description 28
- 239000003921 oil Substances 0.000 claims description 20
- 235000019198 oils Nutrition 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- 239000004615 ingredient Substances 0.000 claims description 16
- 239000012071 phase Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000011163 secondary particle Substances 0.000 claims description 12
- 235000011194 food seasoning agent Nutrition 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 229920002472 Starch Polymers 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 235000002639 sodium chloride Nutrition 0.000 claims description 6
- 235000014347 soups Nutrition 0.000 claims description 6
- 235000010633 broth Nutrition 0.000 claims description 5
- 235000008216 herbs Nutrition 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 235000015067 sauces Nutrition 0.000 claims description 5
- 235000013599 spices Nutrition 0.000 claims description 5
- 235000000346 sugar Nutrition 0.000 claims description 5
- 239000007762 w/o emulsion Substances 0.000 claims description 5
- 238000005054 agglomeration Methods 0.000 claims description 4
- 230000002776 aggregation Effects 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000000796 flavoring agent Substances 0.000 claims description 4
- 235000019264 food flavour enhancer Nutrition 0.000 claims description 4
- 229920000881 Modified starch Polymers 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 235000019426 modified starch Nutrition 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 108010082495 Dietary Plant Proteins Proteins 0.000 claims description 2
- 229940041514 candida albicans extract Drugs 0.000 claims description 2
- 235000019634 flavors Nutrition 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 239000012138 yeast extract Substances 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 2
- 239000008158 vegetable oil Substances 0.000 claims 2
- 239000003925 fat Substances 0.000 description 31
- 235000019197 fats Nutrition 0.000 description 31
- 239000000047 product Substances 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 9
- 238000005469 granulation Methods 0.000 description 9
- 230000003179 granulation Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- LGJMUZUPVCAVPU-UHFFFAOYSA-N beta-Sitostanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 LGJMUZUPVCAVPU-UHFFFAOYSA-N 0.000 description 6
- -1 fatty acid esters Chemical class 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000011164 primary particle Substances 0.000 description 6
- 239000008157 edible vegetable oil Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004278 EU approved seasoning Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- ARYTXMNEANMLMU-UHFFFAOYSA-N 24alpha-methylcholestanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(C)C(C)C)C1(C)CC2 ARYTXMNEANMLMU-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 235000019486 Sunflower oil Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229940076810 beta sitosterol Drugs 0.000 description 3
- NJKOMDUNNDKEAI-UHFFFAOYSA-N beta-sitosterol Natural products CCC(CCC(C)C1CCC2(C)C3CC=C4CC(O)CCC4C3CCC12C)C(C)C NJKOMDUNNDKEAI-UHFFFAOYSA-N 0.000 description 3
- ARYTXMNEANMLMU-ATEDBJNTSA-N campestanol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]2(C)CC1 ARYTXMNEANMLMU-ATEDBJNTSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000013310 margarine Nutrition 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 235000013923 monosodium glutamate Nutrition 0.000 description 3
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 3
- 229950005143 sitosterol Drugs 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002600 sunflower oil Substances 0.000 description 3
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- SGNBVLSWZMBQTH-FGAXOLDCSA-N Campesterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@@](C)([C@H]([C@H](CC[C@H](C(C)C)C)C)CC4)CC3)CC=2)CC1 SGNBVLSWZMBQTH-FGAXOLDCSA-N 0.000 description 2
- BTEISVKTSQLKST-UHFFFAOYSA-N Haliclonasterol Natural products CC(C=CC(C)C(C)(C)C)C1CCC2C3=CC=C4CC(O)CCC4(C)C3CCC12C BTEISVKTSQLKST-UHFFFAOYSA-N 0.000 description 2
- 239000005913 Maltodextrin Substances 0.000 description 2
- 229920002774 Maltodextrin Polymers 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- LGJMUZUPVCAVPU-JFBKYFIKSA-N Sitostanol Natural products O[C@@H]1C[C@H]2[C@@](C)([C@@H]3[C@@H]([C@H]4[C@@](C)([C@@H]([C@@H](CC[C@H](C(C)C)CC)C)CC4)CC3)CC2)CC1 LGJMUZUPVCAVPU-JFBKYFIKSA-N 0.000 description 2
- 235000000431 campesterol Nutrition 0.000 description 2
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229940035034 maltodextrin Drugs 0.000 description 2
- 239000003264 margarine Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229940068065 phytosterols Drugs 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- LGJMUZUPVCAVPU-HRJGVYIJSA-N stigmastanol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]2(C)CC1 LGJMUZUPVCAVPU-HRJGVYIJSA-N 0.000 description 2
- 235000016831 stigmasterol Nutrition 0.000 description 2
- 229940032091 stigmasterol Drugs 0.000 description 2
- BFDNMXAIBMJLBB-UHFFFAOYSA-N stigmasterol Natural products CCC(C=CC(C)C1CCCC2C3CC=C4CC(O)CCC4(C)C3CCC12C)C(C)C BFDNMXAIBMJLBB-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- VGSSUFQMXBFFTM-UHFFFAOYSA-N (24R)-24-ethyl-5alpha-cholestane-3beta,5,6beta-triol Natural products C1C(O)C2(O)CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 VGSSUFQMXBFFTM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BBTIMXAYZRWPNG-UHFFFAOYSA-N 3beta,Delta4-stigmasten-3-ol Natural products C1CC2=CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 BBTIMXAYZRWPNG-UHFFFAOYSA-N 0.000 description 1
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- OILXMJHPFNGGTO-NRHJOKMGSA-N Brassicasterol Natural products O[C@@H]1CC=2[C@@](C)([C@@H]3[C@H]([C@H]4[C@](C)([C@H]([C@@H](/C=C/[C@H](C(C)C)C)C)CC4)CC3)CC=2)CC1 OILXMJHPFNGGTO-NRHJOKMGSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 108010068370 Glutens Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- OILXMJHPFNGGTO-ZRUUVFCLSA-N UNPD197407 Natural products C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)C=C[C@H](C)C(C)C)[C@@]1(C)CC2 OILXMJHPFNGGTO-ZRUUVFCLSA-N 0.000 description 1
- HZYXFRGVBOPPNZ-UHFFFAOYSA-N UNPD88870 Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)=CCC(CC)C(C)C)C1(C)CC2 HZYXFRGVBOPPNZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- QADVIPISOOQJMJ-WLKYTNTRSA-N beta-stigmasterol Natural products CCC(CC)C=C[C@@H](C)[C@H]1CC[C@@H]2[C@@H]1CC[C@H]3[C@H]2CC=C4C[C@@H](O)CC[C@]34C QADVIPISOOQJMJ-WLKYTNTRSA-N 0.000 description 1
- 235000014448 bouillon/stock cubes Nutrition 0.000 description 1
- 235000004420 brassicasterol Nutrition 0.000 description 1
- OILXMJHPFNGGTO-ZAUYPBDWSA-N brassicasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@H](C)C(C)C)[C@@]1(C)CC2 OILXMJHPFNGGTO-ZAUYPBDWSA-N 0.000 description 1
- KJDZDTDNIULJBE-QXMHVHEDSA-N cetoleic acid Chemical compound CCCCCCCCCC\C=C/CCCCCCCCCC(O)=O KJDZDTDNIULJBE-QXMHVHEDSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 238000004581 coalescence Methods 0.000 description 1
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- 235000014541 cooking fats Nutrition 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 235000019625 fat content Nutrition 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000021312 gluten Nutrition 0.000 description 1
- 238000009884 interesterification Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000010198 maturation time Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
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- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- NLQLSVXGSXCXFE-UHFFFAOYSA-N sitosterol Natural products CC=C(/CCC(C)C1CC2C3=CCC4C(C)C(O)CCC4(C)C3CCC2(C)C1)C(C)C NLQLSVXGSXCXFE-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- HCXVJBMSMIARIN-PHZDYDNGSA-N stigmasterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)/C=C/[C@@H](CC)C(C)C)[C@@]1(C)CC2 HCXVJBMSMIARIN-PHZDYDNGSA-N 0.000 description 1
- HCXVJBMSMIARIN-UHFFFAOYSA-N stigmasterol Chemical compound C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(CC)C(C)C)C1(C)CC2 HCXVJBMSMIARIN-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/001—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
- A23D9/04—Working-up
- A23D9/05—Forming free-flowing pieces
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L23/00—Soups; Sauces; Preparation or treatment thereof
- A23L23/10—Soup concentrates, e.g. powders or cakes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- Granules comprising sterol
- the invention relates to granules comprising lipid powder.
- the invention further relates to use of these granules in the preparation of edible dispersions and/or tablets.
- Powdered lipids, lipid granules, lipid cubes and lipid tablets are known.
- these known products cannot be used to structure an oil phase in a food product comprising an oil phase, in the same way as such a product is structured by lipid crystallized from the melt, such as in a votator process for the preparation of margarine.
- Co-pending application PCT/EP2004/006544 describes edible dispersions, including water-in-oil emulsions, that comprise a structuring agent, specifically fat, having a microporous structure of submicron size particles.
- the water-in-oil emulsion may be a table spread.
- pourable emulsions and pourable dispersions were described.
- the edible dispersions may for instance be prepared by mixing an oil phase with structuring agent particles with a separately prepared water phase.
- One or more of the above problems are solved according to the invention which provides a granule comprising a liquid and lipid powder particles (herein described as secondary- particles) that have a microporous structure and which are agglomerates of primary particles of submicron size.
- micronised fat particles such as used in PCT/EP2004/006544 can become airborne and can be described as dusty. When using the micronised fat powder to produce food products, this dustiness influences the handling properties of the powder negatively. Additionally, we have found that micronised fat powder has a very low bulk density. This creates the problem that a certain mass of powder takes up a huge space if it is transported.
- the invention therefore ⁇ relates to a granule comprising:- a) solid micronised lipid powder particles that have a microporous structure; and, b) a liquid;
- the granule is an agglomeration of said lipid particles herein described as secondary particles; and wherein said secondary particles are agglomerates of primary lipid particles, said primary lipid particles are platelets having an average thickness of 0.01-0.5 ⁇ m and wherein the lipid comprises sterol.
- Granule is herein defined as an object prepared by size enlargement of secondary particles as described below.
- Such particles are herein referred to as granules, and they can be prepared by granulation, such granule- particles can also be prepared by other known techniques for size enlargement of particulate material, as long as the desired particle size of the granules is obtained, and particles with the proper rigidity.
- granules it does refer to all particles having a certain size (being larger than most components of the granules such as powdery material and/or crystalline material) , and such granules can be prepared by granulation, but also by other techniques.
- conventional ingredients for a range of conventional ingredients for e.g.
- a size enlarging technique is needed, that binds a plurality of such smaller particles (powdery materials such as flour and/or starch and/or cystalline materials such as salt, sugar, MSG) of the ingredients together to larger particles, herein referred to as granules.
- Suitable techniques for such size enlargement are known in the art and include granulation, agglomeration, pelletisation, sintering, briquetting or extruding followed by cutting the extrudates and other techniques as known in the art of size enlargement of particulate matter.
- the granules suitably have a diameter of between 0.5 and 10 mm (some fines may be allowed, at least 80 wt.% should have such size), preferably between 1 and 5 mm, more preferably 2-5 mm.
- the granules are agglomerates of solid micronised lipid powder particles, herein described as secondary particles.
- the solid structuring agent particles described herein as secondary particles, should have a microporous structure of submicron size particles, which are described herein as primary particles.
- the secondary particles are agglomerates of primary particles which have a microporous structure.
- the size of the primary particles is submicron (that is have a diameter below 1 ⁇ ) .
- Micronised fat may be prepared herein as described in PCT/EP2004/006544.
- the primary particles typically have the shape as shown -in figure 7, in which the platelets with submicron dimensions are the primary particles.
- the thickness of the platelets should be submicron, preferably the thickness is on average 0.01-0.5 ⁇ m, more preferably 0.03-0.2 ⁇ m, even more preferably 0.06-0.12 ⁇ m.
- the wall thickness of the bubbles should be submicron, for instance on average 0.01-0.5 ⁇ m, more preferably 0.03-0.2 ⁇ m, even more preferably 0.06-0.12 ⁇ m.
- the secondary particles may, in the course of the preparation of the dispersion, for instance through the force of a mixer, be broken into submicron particles.
- the resulting submicron particles will form the structuring network of the dispersion.
- the structuring agent is edible lipid, more preferably it comprises edible fat.
- the granule comprises a liquid.
- the liquid content of the granule is 40- 60 wt. %.
- the liquid is edible oil or w/o- emulsions of edible oil.
- the lipid comprises sterol.
- the solid micronised lipid particles comprise from 25 to 100 wt.%, preferably 80 to 100 wt.% sterol on total weight of the lipid particles.
- sterol is used to indicate sterol, stanol, the fatty acid esters of sterol/stanol and mixtures of any of these.
- the products according to the invention comprise a sterol and/or stanol or a fatty acid ester thereof, or mixtures thereof.
- this also includes their saturated derivatives, the stanol esters, and combinations of sterol- and stanol esters.
- Sterols or phytosterols also known as plant sterols or vegetable sterols can be classified in three groups, 4- desmethylsterols, 4-monomethylsterols and 4,4'- dimethylsterols .
- oils they mainly exist as free sterols and sterol esters of fatty acids although sterol glucosides and acylated sterol glucosides are also present.
- There are three major phytosterols namely beta-sitosterol, stigmasterol and campesterol. Schematic drawings of the components meant are as given in "Influence of Processing on Sterols of Edible Vegetable Oils", S. P. Kochhar; Prog. Lipid Res. 22: pp. 161-188.
- stanols The respective 5 alpha- saturated derivatives such as sitostanol, campestanol and ergostanol and their derivatives are in this specification referred to as stanols .
- the (optionally esterified) sterol or stanol is selected from the group comprising fatty acid ester of ⁇ - sitosterol, ⁇ -sitostanol, campesterol, campestanol, stigmasterol, brassicasterol, brassicastanol or a mixture thereof.
- the sterols or stanols are optionally at least partly esterified with a fatty acid.
- the sterols or stanols are esterified with one or more C2-22 fatty acids.
- C2-22 fatty acid refers to any molecule comprising a C2-22 main chain and at least one acid group.
- the C 2 - 22 main chain may be partially substituted or side chains may be present.
- the C 2 - 22 fatty acids are linear molecules comprising one or two acid group (s) as end group (s). Most preferred are linear € 3 -22 fatty acids as these occur in natural oils.
- Suitable examples of any such fatty acids are acetic acid, propionic acid, butyric acid, caproic acid, caprylic acid, capric acid.
- Other suitable acids are for example citric acid, lactic acid, oxalic acid and maleic acid.
- Most preferred are myristic acid, lauric acid, palmitic acid, stearic acid, arachidic acid, behenic acid, oleic acid, cetoleic acid, erucic acid, elaidic acid, linoleic acid and linolenic acid.
- a mixture of fatty acids may be used for esterification of the sterols or stanols.
- a naturally occurring fat or oil as a source of the fatty acid and to carry out the esterification via an interesterification reaction.
- the lipid further optionally comprises edible fats.
- Edible fats consist predominantly of triglycerides.
- Such edible fats suitable as structuring agent are mixtures of triglycerides, some of which have a melting point higher than room or ambient temperature and therefore contain solids in the form of crystals.
- the solid structuring agent also denoted as hardstock, may- serve to structure the fat phase and may help to stabilise the dispersion.
- the crystals of the solid fat form a network throughout the liquid oil resulting into a structured fat phase.
- the aqueous phase droplets are fixed within the spaces of the lattice of solid fat crystals. In this way coalescence of the droplets and separation of the heavier aqueous phase from the fat phase is prevented.
- micronised lipid powder is subjected to agglomeration. This is done by spraying a sticky liquid on the micronised fat powder and gluing these secondary fat powder particles together to form granules.
- This sticky liquid should be a liquid that is able to wet the powder, but is strong enough to form a bridge between the secondary powder particles.
- the sticky liquid is edible oil or w/o-emulsions of edible oil.
- the granulation technique is not critical, for instance the primary micronised fat powder may be granulated in conventional granulation machines. Preferably the granulation is conducted as described above.
- the granules according to the invention may be used as intermediate for making several fat containing products, such as cooking fats, spreads and liquid margarines. Also it is possible to use the powders as such in an end product or as powder to press tablets.
- the granules may be used to stabilise an oil phase in a food product when used as an ingredient in ⁇ conventional processes for preparing the food products.
- an explanation could be that the granules, during the processing of the food product are broken-up by mechanical forces, and the fragments are able to stabilize an oil phase.
- the invention also relates to a process for the preparation of an edible dispersion comprising;
- an oil phase b) a structuring agent; and, c) an aqueous phase and optionally a solid phase, in which the dispersion is formed by mixing oil, structuring agent and the aqueous phase and optionally additionally a solid phase; wherein the structuring agent is a granule according to the present invention.
- the granules may be used in a process for preparing bouillon or seasoning cubes, the process comprising the steps of: a) mixing 2-99% of particulate ingredients, comprising one or more of salt, flavour enhancers, spices, herbs, flavourants, sugar, yeast extract, or hydrolysed vegetable protein, with 1-98% of fat solid at 20 0 C in particulate form, b) pressing to cubes; wherein the fat in particulate form comprises granules according to the present invention.
- the amount of ingredients are given.
- the actual amount depends e.g. on the intended use.
- the amount of fat is preferably 1-30%, more preferably 2-25%.
- the amount of fat is preferably 10-99%, more preferably 20-70%.
- Cubes e.g. for soups and sauces can have fat contents of 5- 60%, preferably 10-50%. All percentages are percentages by weight of the total cube.
- very low amounts of fat e.g. 1-5%
- the invention further relates to a particulate seasoning or concentrate for preparing a bouillon, broth, soup or sauce comprising 0.5-60 wt . % of fat and 40-99.5 wt.% of one or more of salt, flavour enhancers, starch, starch derivatives, sugar, herbs, spices, vegetable particulates, flavours, colourants, wherein the fat comprises granules according to the present invention.
- Benefits of this invention can be separated in what we can define as customer benefits and consumer benefits.
- Customer benefits are mainly present in intermediate products. These benefits reveal during storage and production of final products. Consumer benefits reveal in the final products. The benefits described here neglect the benefits of the use of micronised powders, which are numerous already.
- the bulk density is measured by determining the volume of 100 g of material in a measuring cylinder and is expressed as kg/1 and the gluten content is measured by AACC method 38-10 (9 th Ed, 1995) .
- the flow properties of the granular product are defined in terms of the dynamic flow rate (DFR) , in ml/s, measured by means of the following procedure.
- DFR dynamic flow rate
- a cylindrical glass tube of internal diameter of 35 mm and length of 600 mm is securely clamped with its longitudinal axis in the vertical position. Its lower end is terminated by a cone of polyvinyl chloride having an internal angle of 15' and a lower outlet orifice of diameter 22.5 mm.
- a first beam sensor is positioned 150 mm above the outlet, and a second beam sensor is positioned 250 mm above the first sensor.
- the outlet orifice is temporarily closed and the cylinder filled with the granular product to a point about 10 cm above the upper sensor.
- the outlet is opened and the flow time t (seconds) taken for the powder level to fall from the upper sensor to the lower sensor measured electronically. This is repeated 2 or 3 times and an average time taken. If V is the volume (ml) of the tube between the upper and lower sensors, the DFR is given by V/t .
- the unconfined compressibility test provides a measure of the cohesiveness or "stickiness" of a product and can provide a guide v to its storage properties in, for example, silos.
- the principle of the test is to compress the granular product into a compact and then measure the force required to break the compact. This is carried out using an apparatus comprising a cylinder of diameter 89 mm and height 114 mm (3.5 x 4.5 inches), a plunger and plastic discs and weights of predetermined weight as follows. The cylinder, positioned around a fixed locating disc and secured with a clamp, is filled with granular product and the surface leveled by drawing a straight edge across it.
- a 50 g plastic disc is placed on top of the granular product, the plunger lowered and a 10 kg weight placed slowly on top of the upper plunger disc. The weight is left in position for 2 minutes after which time the 10 kg weight is removed and plunger raised. The clamp is removed from the cylinder and the two halves of the cylinder carefully removed to leave a compact of granular product. If the compact is unbroken, a second 50 g plastic disc is placed on top of the first and left for approximately ten seconds. If the compact is still unbroken, a 100 g disc is placed on top to the plastic discs and left for ten seconds.
- the plunger is lowered very gently onto the discs and 250 g weights added at ten second intervals until the compact collapses.
- the total weight of plunger, plastic discs and weights at collapse is recorded.
- the cohesiveness of the powder is classified by the weight required to break the compact as follows. The greater the weight required, the higher the UCT value and the more cohesive ("sticky") the powder.
- fines refers to particles with a diameter of less than 180 microns.
- coarse material means particles with a diameter greater than 1400 microns. Levels of fine and coarse particles can be measured using sieve analysis.
- Stevens values give an indication about the firmness of a product. The firmness of all products stored at 5°C for 24 hours was measured at room temperature using a Stevens Texture Analyser (1 mm/sec, 25 mm depth, 4.4. mm probe) and is quoted herein as the Stevens value (in g) .
- the water phase was made by mixing the salt in distilled water and holding the mixture at room temperature.
- the fat phase was produced by adding the granulated fat powder to liquid oil using a spatula.
- the water phase and the oil phase were mixed using a home kitchen mixer.
- a stable spread without emulsifier and thickener It was possible to prepare a stable spread without emulsifier and thickener.
- the long term stability and/or consistency of the spread without emulsifier may be improved by adding a thickener to the water phase, e.g. 1 wt .% starch, a suitable starch type is Resistamyl 310.
- the solid ingredients i.e. all ingredients except water and oil
- these ingredients may be mixed with oil and water.
- Table 2 Composition of instant spreads of examples 2-4
- beta sitosterol mixed with 50 wt% beta sitosterol was micronised as in example 1 of PCT/EP2004/006544, and granulated as in example 1 with sunflower oil in ratio 1:1 (w/w) .
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Edible Oils And Fats (AREA)
- Seasonings (AREA)
- Fats And Perfumes (AREA)
- Medicinal Preparation (AREA)
- Colloid Chemistry (AREA)
- General Preparation And Processing Of Foods (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0606341-1A BRPI0606341A2 (en) | 2005-02-17 | 2006-01-25 | granule, process for the preparation of an edible dispersion, cube or tablet, process for the preparation of cubes or tablets and particulate or concentrated seasoning |
AU2006215828A AU2006215828B2 (en) | 2005-02-17 | 2006-01-25 | Granules comprising sterol |
CA002597478A CA2597478A1 (en) | 2005-02-17 | 2006-01-25 | Granules comprising sterol |
US11/884,289 US20090136645A1 (en) | 2005-02-17 | 2006-01-25 | Granules Comprising Sterol |
EP06701226A EP1850676A1 (en) | 2005-02-17 | 2006-01-25 | Granules comprising sterol |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
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EP05075391.2 | 2005-02-17 | ||
EP05075384.7 | 2005-02-17 | ||
EP05075392.0 | 2005-02-17 | ||
EP05075392 | 2005-02-17 | ||
EP05075391 | 2005-02-17 | ||
EP05075393 | 2005-02-17 | ||
EP05075393.8 | 2005-02-17 | ||
EP05075384 | 2005-02-17 |
Publications (1)
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WO2006087090A1 true WO2006087090A1 (en) | 2006-08-24 |
Family
ID=36694463
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Application Number | Title | Priority Date | Filing Date |
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PCT/EP2006/000800 WO2006087091A2 (en) | 2005-02-17 | 2006-01-25 | Process for the preparation of a spreadable dispersion |
PCT/EP2006/000802 WO2006087093A1 (en) | 2005-02-17 | 2006-01-25 | Process for the preparation of a spreadable dispersion comprising sterol |
PCT/EP2006/000798 WO2006087090A1 (en) | 2005-02-17 | 2006-01-25 | Granules comprising sterol |
PCT/EP2006/000801 WO2006087092A2 (en) | 2005-02-17 | 2006-01-25 | Fat granules |
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PCT/EP2006/000800 WO2006087091A2 (en) | 2005-02-17 | 2006-01-25 | Process for the preparation of a spreadable dispersion |
PCT/EP2006/000802 WO2006087093A1 (en) | 2005-02-17 | 2006-01-25 | Process for the preparation of a spreadable dispersion comprising sterol |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2006/000801 WO2006087092A2 (en) | 2005-02-17 | 2006-01-25 | Fat granules |
Country Status (8)
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US (6) | US20080193628A1 (en) |
EP (4) | EP1885192B8 (en) |
AT (1) | ATE535152T1 (en) |
AU (4) | AU2006215831B2 (en) |
BR (4) | BRPI0606341A2 (en) |
CA (4) | CA2597478A1 (en) |
PL (2) | PL1885192T3 (en) |
WO (4) | WO2006087091A2 (en) |
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