WO2006062678A1 - Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings - Google Patents
Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings Download PDFInfo
- Publication number
- WO2006062678A1 WO2006062678A1 PCT/US2005/040821 US2005040821W WO2006062678A1 WO 2006062678 A1 WO2006062678 A1 WO 2006062678A1 US 2005040821 W US2005040821 W US 2005040821W WO 2006062678 A1 WO2006062678 A1 WO 2006062678A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aqueous dispersion
- pape
- aqueous
- present
- protective coating
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 72
- 239000011253 protective coating Substances 0.000 title claims abstract description 25
- 229920000570 polyether Polymers 0.000 title claims abstract description 23
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 69
- 239000004816 latex Substances 0.000 claims abstract description 17
- 229920000126 latex Polymers 0.000 claims abstract description 17
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 13
- 239000008199 coating composition Substances 0.000 claims abstract description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000002009 diols Chemical class 0.000 claims abstract description 4
- 150000001298 alcohols Chemical class 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 229920000642 polymer Polymers 0.000 claims description 35
- 238000004090 dissolution Methods 0.000 claims description 16
- 238000009472 formulation Methods 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 11
- -1 phosphate ester Chemical class 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 229940087810 eco-soft Drugs 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- MXVMODFDROLTFD-UHFFFAOYSA-N 2-[2-[2-(2-butoxyethoxy)ethoxy]ethoxy]ethanol Chemical compound CCCCOCCOCCOCCOCCO MXVMODFDROLTFD-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical group CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 claims description 3
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 239000004815 dispersion polymer Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 3
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 abstract description 52
- 238000010348 incorporation Methods 0.000 abstract description 12
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 50
- 239000004094 surface-active agent Substances 0.000 description 35
- 239000002904 solvent Substances 0.000 description 14
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 12
- 239000012855 volatile organic compound Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000000443 aerosol Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000008719 thickening Effects 0.000 description 5
- KFUSXMDYOPXKKT-UHFFFAOYSA-N 2-[(2-methylphenoxy)methyl]oxirane Chemical compound CC1=CC=CC=C1OCC1OC1 KFUSXMDYOPXKKT-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 125000001165 hydrophobic group Chemical group 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000006254 rheological additive Substances 0.000 description 3
- 238000000518 rheometry Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 238000010561 standard procedure Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NNARPPSIYMCXMB-UHFFFAOYSA-N 1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonic acid Chemical compound CC(C)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(C)C NNARPPSIYMCXMB-UHFFFAOYSA-N 0.000 description 2
- CBCQTCPKFYFJEU-UHFFFAOYSA-N 1,4-dioxo-1,4-dipentoxybutane-2-sulfonic acid Chemical compound CCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCC CBCQTCPKFYFJEU-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 2
- 229960000878 docusate sodium Drugs 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- SOSQXPIKTBUEKF-UHFFFAOYSA-N 1,4-dihexoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound CCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC SOSQXPIKTBUEKF-UHFFFAOYSA-N 0.000 description 1
- MPPPKRYCTPRNTB-UHFFFAOYSA-N 1-bromobutane Chemical compound CCCCBr MPPPKRYCTPRNTB-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920002257 Plurafac® Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- 229960002836 biphenylol Drugs 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940093470 ethylene Drugs 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J159/00—Adhesives based on polyacetals; Adhesives based on derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/50—Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C
Definitions
- aqueous solutions of associative thickeners exhibit high viscosities even at lower concentrations.
- viscosity suppressing aids such as propylene glycol, butyl carbitol, cyclodextrins and surfactants are used (see US 6,063,857; US 5,137,571 ; US 5,425,806; US 6,150,445; US 5,378,756; US 5,959,013; US 5574127; US 6162877).
- Typical useful viscosity ranges for these aqueous combinations of thickener and additive are about 1000 cps to 5000 cps.
- Typical desired polymer solid concentrations are in the range of about 15 to 30% by weight.
- Table 2 below shows viscosity data for 20% NLS-200 (Ci 6 -PAPE; commercial lot# F-05178-AT 02, see below) in low EPB - Water solvent mixture, in Strodex LFK-70 - Water mixture, in EPB - Strodex LFK-70 -Water, in EPB - lconol DA-6 - Water mixtures as well as for 20% NHS-300 just in Water and in Strodex LFK-70 - Water mixture.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0515808A BRPI0515808B1 (en) | 2004-12-09 | 2005-11-09 | aqueous poly (acetal-polyether) dispersion, aqueous backing composition and method of incorporating said polymer into backing formulation |
CA2589486A CA2589486C (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings |
DE602005026455T DE602005026455D1 (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly (acetyl-polyether) and its use in protective coatings |
AT05848872T ATE498656T1 (en) | 2004-12-09 | 2005-11-09 | AQUEOUS DISPERSION OF POLY(ACETYL-POLYETHER) AND THEREOF USE IN PROTECTIVE COVERS |
MX2007006681A MX2007006681A (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings. |
CN2005800421866A CN101094893B (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings |
EP05848872A EP1838782B1 (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings |
PL05848872T PL1838782T3 (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings |
JP2007545487A JP5137582B2 (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersions of poly (acetal-polyethers) and their use in protective coatings |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63450004P | 2004-12-09 | 2004-12-09 | |
US60/634,500 | 2004-12-09 | ||
US63626804P | 2004-12-15 | 2004-12-15 | |
US60/636,268 | 2004-12-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006062678A1 true WO2006062678A1 (en) | 2006-06-15 |
Family
ID=36130036
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/040821 WO2006062678A1 (en) | 2004-12-09 | 2005-11-09 | Aqueous dispersion of poly(acetal-polyether) and its use in protective coatings |
Country Status (12)
Country | Link |
---|---|
US (1) | US7531591B2 (en) |
EP (1) | EP1838782B1 (en) |
JP (1) | JP5137582B2 (en) |
AR (1) | AR053793A1 (en) |
AT (1) | ATE498656T1 (en) |
BR (1) | BRPI0515808B1 (en) |
CA (1) | CA2589486C (en) |
DE (1) | DE602005026455D1 (en) |
MX (1) | MX2007006681A (en) |
PL (1) | PL1838782T3 (en) |
RU (1) | RU2403271C2 (en) |
WO (1) | WO2006062678A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2730836A1 (en) | 2008-07-17 | 2010-01-21 | Hercules Incorporated | Process for tailoring water-borne coating compositions |
JP5712145B2 (en) * | 2009-02-12 | 2015-05-07 | ハーキュリーズ・インコーポレーテッドHercules Incorporated | Rheology modifiers for formulations based on aqueous surfactants |
EP2510064B1 (en) * | 2009-12-11 | 2016-06-15 | Rhodia Operations | Methods and systems for improving open time and drying time of latex binders and aqueous coatings |
CA2839474C (en) * | 2011-07-28 | 2016-11-01 | Hercules Incorporated | Readily dissolvable solid nonionic synthetic associative thickener with dissolution promotion water soluble additive |
AU2013230911B2 (en) * | 2012-03-08 | 2016-02-25 | Hercules Incorporated | Viscosity suppression of associative thickeners using organophosphates |
EP2870193B1 (en) | 2012-07-03 | 2018-01-03 | Hercules LLC | Water soluble polymer powders with improved dispersibility |
FR3004458A1 (en) * | 2013-04-11 | 2014-10-17 | Rhodia Operations | FRACTURING FLUIDS BASED ON ASSOCIATIVE POLYMERS AND SURFACTANTS LABILES |
JP6113695B2 (en) | 2014-10-31 | 2017-04-12 | 株式会社 資生堂 | Elastic gel composition |
KR102517608B1 (en) | 2015-12-24 | 2023-04-05 | 롯데정밀화학 주식회사 | Associative thickener composition and aqueous paint composition including the same |
PL3478663T3 (en) | 2016-07-01 | 2021-05-04 | Hercules Llc | Lactam-functionalized polymer, compositions and applications thereof |
US10358574B2 (en) | 2016-07-01 | 2019-07-23 | Hercules Llc | Coating compositions containing lactam-functionalized polymer |
WO2019125455A1 (en) * | 2017-12-21 | 2019-06-27 | Hercules Llc | Coating compositions containing lactam-functionalized polymer |
PL3807388T3 (en) | 2018-06-15 | 2024-03-11 | Hercules Llc | Coarse particle solid nonionic synthetic associative thickeners for paint formulations and methods for producing the same |
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- 2005-11-08 US US11/269,329 patent/US7531591B2/en active Active
- 2005-11-09 PL PL05848872T patent/PL1838782T3/en unknown
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- 2005-11-09 RU RU2007125771/02A patent/RU2403271C2/en active
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- 2005-11-09 AT AT05848872T patent/ATE498656T1/en not_active IP Right Cessation
- 2005-11-09 CA CA2589486A patent/CA2589486C/en active Active
- 2005-11-09 JP JP2007545487A patent/JP5137582B2/en active Active
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- 2005-11-09 WO PCT/US2005/040821 patent/WO2006062678A1/en active Application Filing
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EP0682094A1 (en) * | 1994-05-12 | 1995-11-15 | Rheox International, Inc. | A pourable water dispersible thickening composition for aqueous systems and a method of thickening said aqueous systems |
US5574127A (en) * | 1995-04-05 | 1996-11-12 | Aqualon | Hydrophobically modified poly(acetal-polyethers) |
US20030171459A1 (en) * | 2001-10-29 | 2003-09-11 | Sau Arjun C. | Suppression of aqueous viscosity of associating polyacetal-polyethers |
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Also Published As
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JP5137582B2 (en) | 2013-02-06 |
EP1838782B1 (en) | 2011-02-16 |
RU2403271C2 (en) | 2010-11-10 |
US7531591B2 (en) | 2009-05-12 |
PL1838782T3 (en) | 2011-06-30 |
CA2589486C (en) | 2013-01-29 |
RU2007125771A (en) | 2009-01-20 |
EP1838782A1 (en) | 2007-10-03 |
AR053793A1 (en) | 2007-05-23 |
DE602005026455D1 (en) | 2011-03-31 |
CA2589486A1 (en) | 2006-06-15 |
MX2007006681A (en) | 2007-12-07 |
BRPI0515808A (en) | 2008-08-05 |
JP2008523206A (en) | 2008-07-03 |
BRPI0515808B1 (en) | 2017-05-02 |
US20060128846A1 (en) | 2006-06-15 |
ATE498656T1 (en) | 2011-03-15 |
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