WO2006038048A1 - Apparatus and method for decomposing water - Google Patents
Apparatus and method for decomposing water Download PDFInfo
- Publication number
- WO2006038048A1 WO2006038048A1 PCT/HU2005/000108 HU2005000108W WO2006038048A1 WO 2006038048 A1 WO2006038048 A1 WO 2006038048A1 HU 2005000108 W HU2005000108 W HU 2005000108W WO 2006038048 A1 WO2006038048 A1 WO 2006038048A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- chamber
- vessel
- dust
- decomposing
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000003054 catalyst Substances 0.000 claims abstract description 24
- 239000000428 dust Substances 0.000 claims abstract description 16
- 150000002500 ions Chemical class 0.000 claims abstract description 10
- 239000013078 crystal Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 13
- 239000000919 ceramic Substances 0.000 claims description 12
- 239000011148 porous material Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 238000002604 ultrasonography Methods 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- -1 oxygen ions Chemical class 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000000889 atomisation Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 claims description 4
- 230000007797 corrosion Effects 0.000 claims description 4
- 230000003301 hydrolyzing effect Effects 0.000 abstract description 5
- 230000005684 electric field Effects 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- 230000008569 process Effects 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 238000002144 chemical decomposition reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008713 feedback mechanism Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/80—Apparatus for specific applications
- H05B6/806—Apparatus for specific applications for laboratory use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/126—Microwaves
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0203—Preparation of oxygen from inorganic compounds
- C01B13/0207—Water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
- C01B3/045—Decomposition of water in gaseous phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
- B01J2219/0277—Metal based
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
- B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
- B01J2219/0809—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes employing two or more electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0873—Materials to be treated
- B01J2219/0877—Liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0873—Materials to be treated
- B01J2219/0892—Materials to be treated involving catalytically active material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- This invention relates to a method for decomposing water, consisting of feeding liquid water into a vessel and decomposing the molecules of water by means of electric energy, as well as to an apparatus for decomposing water, including a vessel and electrodes connected to the poles of a voltage source supplying direct current therein.
- Methods of water decomposition are for producing hydrogen from water.
- the simplest way to decompose water into hydrogen and oxygen is the so-called electrolysis. This process takes place between electrodes supplied by direct current and 2,8 kWh electric energy is necessary to produce 1 m 3 hydrogen gas of normal state.
- thermo-chemical decomposition of water steam by way of blue gas reaction as well as a generation process of hydrogen achieved by partial oxidation of methane.
- Patent application US 2 004 024 072 discloses a device for thermo- chemical decomposition of water steam, wherein a flow of water steam having temperature between 600 and 800 0 C is conducted into a reactor filled with a fluidized finely-ground mixture of CaO and coal powder.
- Patent application CA 2 289 666 discloses a method of direct thermal water decomposition, wherein a volume of water having a temperature of 80 0 C become transformed to steam in a steam generator, then carrying the steam into a reactor containing a complex compound of silicate-aluminate, preferably zeolit. The reactor should externally be heated to a temperature between 300 and 600 0 C.
- WO 2004002881 discloses a method for producing hydrogen gas by way of contacting steam with iron or iron oxide contaminated by earth metals, rare-earth metals, rare metals or noble metals on a relatively low temperature.
- the object of the present invention is to provide a hydrolysing or water decomposing method and apparatus, which are more effective and cheaper by far and produce hydrogen gas faster by orders of magnitude than existing methods and apparatuses forming the state of the art.
- the multistage resonator device developed by the inventor uses a resonator chamber the operation of which is optimized by a feed back mechanism.
- Basic difference between the hydrolysis according to the state of the art and the water decomposition achieved by a multistage resonator device is that the decomposition of water takes place in liquid state and one step in the case of known methods, but for the method and device of multistage resonator the process passes off by using pre-excited steam, exploiting the accelerating effect of high voltage.
- the above aim may easily be achieved by the method according to the invention for decomposing water, the method consisting steps of feeding liquid water into a vessel and decomposing the molecules of water by means of electric energy, and creating cold water-dust from said water by microwave atomization, introducing said water-dust into a chamber of a cavity resonator provided by a microwave energy source, exciting water dust by electric microwaves and creating water steam, introducing said steam consisting of high speed molecules into a high voltage catalyst chamber, decomposing said high speed molecules into hydrogen and oxygen ions, introducing said ions between accelerating electrodes connected to the poles of a controlled voltage source supplying direct current with alternate amplitude, trapping said hydrogen ions on the negatively polarized accelerating electrode (cathode) of said voltage source, and trapping said oxygen ions on the positively polarized accelerating electrode (anode) of said voltage source.
- Said microwave atomization advantageously takes place by means of piezoelectric crystals, and said cold water-dust is filtered by a ceramic filter having a pore size of at most 5 ⁇ m.
- the pressure of said cold water-dust is measured by pressure sensors, and the chamber of the cavity resonator is formed of a corrosion-resistant metal.
- a ceramic filter having a pore size of at most 5 ⁇ m preferably filters the steam consisting of high speed molecules.
- the piezoelectric crystals, the pressure sensors, the microwave energy source and the accelerating electrodes are each connected to a control unit and operated periodically.
- an apparatus for decomposing water, the device includes a vessel and electrodes connected to the poles of a voltage source supplying direct current therein, and an atomizing chamber is arranged in the vessel, and a conduit entering the vessel from a water source outside the vessel, and sources of ultrasound are placed in the atomizing chamber, and further, a cavity resonator chamber having at least one magnetron is provided in the vessel, and a filter means is arranged between the atomizing chamber and the cavity resonator chamber, and the apparatus is further provided with a catalyst chamber having an opening receiving a catalyst rod, and a second filter means is arranged between the catalyst chamber and the cavity resonator chamber, and the electrodes are placed in open bottomed gas collecting receivers arranged about the catalyst rod adjacent the opening of the catalyst chamber.
- Said sources of ultrasound are piezoelectric crystals
- said atomizing chamber is a metal cylinder and the piezoelectric crystals are arranged spaced apart evenly and symmetrically on the cylindrical shell.
- the atomizing chamber is provided with pressure sensors, and said filter means is a ceramic filter having a pore size of at most 5 ⁇ m.
- the cavity resonator chamber is made of a corrosion-resistant metal and both its opposite sides are covered by screen grids, and said second filter means is a ceramic filter having a pore size of at most 5 ⁇ m.
- Said gas collecting receivers are open bottomed glass cylinders connected to gas-issue openings formed on a cover plate of the vessel, and an electrode coating is formed on the inner surfaces thereof.
- a preferred embodiment of apparatus according to the invention is arranged in a closed vessel 1 having a cylindrical shell showed in the Figure 1.
- a close-bottomed cylinder 2 made of metal is arranged in the space beneath the lower screen grid 2a.
- the conduit 5 is further connected to a water injection device operating discontinuously (not shown) and placed outside the vessel 1.
- a ceramic filter 6 having a pore diameter between 1 and 5 ⁇ m covers the cylinder 2 from above.
- a baffle means 7 having a form of a conical frustum is arranged between the ceramic filter 6 and the screen grid 2a.
- a cavity resonator chamber 8 is arranged in the space between the two screen grids 2a, 2b.
- two pieces of oppositely displaced magnetrons 9 are attached to the shell of the vessel 1.
- the resonator chamber 8 is blocked up above by the second screen grid 2b.
- a baffle means 10 having the form of a conical frustum is attached to the screen grid 2b from above.
- a ceramic filter 11 is arranged, the pore diameter of which is preferably between 0,1 and 0,5 ⁇ m.
- a catalyst cylinder forming a catalyst chamber 12 having a catalytic coating on its inner surface is fixed on the top of the filter 11 and supported by spacers 13 secured to the shell of the vessel 1.
- a catalyst rod 15 is immersed into the inner space of the catalyst chamber 12 from the direction of the cover plate 14 of the vessel 1 and it is supported by spacers 16.
- Spacers 16 are preferably attached to open-bottomed gas collecting receivers 17a, 17b being advantageously glass cylinders fitted to the cover plate 14. In the inside of each glass receivers 17a, 17b unlikely charged accelerating electrodes 18a, 18b are placed, respectively, i.e. electrode 18a is positively charged (anode), the other electrode 18b (cathode) shall be negatively charged.
- Gas delivery openings 19a, 19b are formed on the cover plate 14 above the respective glass receivers 17a, 17b.
- the distance between the electrodes 18a, 18b and the catalyst rod 15 as well as the distance between the catalyst rod 15 and the catalyst cylinder 12 is adjustable externally by means of a threaded device (not shown in the Figure).
- distilled or ion exchanged liquid water may be injected through the conduit 5 in a pulse-type manner into the metal cylinder 2 forming a close-bottomed atomizing chamber 21 arranged in the space beneath the lower screen grid 2a inside the vessel 1. Injection of water takes place discontinuously and pressure sensors 4 will measure the actual pressure created in the atomizing chamber 21.
- the water fed in the chamber 21 becomes steam in a few ⁇ s due to the action of the ultrasound energy created by piezoelectric crystals 3 arranged spaced apart evenly and symmetrically, oppositely in pairs around the cylindrical shell of the chamber 21.
- the oscillation of the piezoelectric crystals 3 and the cycles of the water injection may be harmonized by means of a computer (not shown) taking into account the pressure values measured by the pressure sensors 4, too.
- a ratio between the chordal distance of the crystals 3 and the wave length of the ultrasound created by the crystals 3 is determined in such a manner, that the ultrasound waves interfering in the space of the chamber 21 will be maximally amplified in predetermined points, preferably in the axis of the chamber 21, consequently the acoustical power of the ultrasound will be concentrated in these points or region.
- the operation of the crystals 3 may be modified by the computer on the base of the pressure values measured by the sensors 4 in such a way, that the ultrasounds created by the crystals 3 will be amplified exactly in the region mentioned above in despite of change of the pressure prevailing in the chamber 21.
- the cold water dust resulted in this manner may pass through the filter 6 which is a barrier in relation to liquid water on the other hand. Molecules of water become steam in the region of amplification and passing through a filter 6 and the baffle means 7 as well as the screen grid 2a enter the resonator chamber 8.
- Oppositely displaced magnetrons 9 attached to the periphery of the chamber 8 radiate microwave electromagnetic energy into the inner space of the chamber 8 in a pulsed manner, which is determined by the computer, resulting in an extremely increased speed of the molecules of water.
- Molecules of water passed through the screen grid 2b covering the resonator chamber 8 may enter the baffle means 10 having a form of conical frustum and the ceramic filter 11 with a pore diameter of 0,1-0,5 ⁇ m, then they reach the cylindrical catalyst chamber 12.
- the catalyst rod 15 hanging into the catalyst chamber 12 from above and an inner coating of the chamber 12 are connected to the respective poles of a high voltage source of some kVs.
- the main advantage of the apparatus and method according to the invention is that the speed of the gas generation will be in a range of fifty times higher than that of the conventional hydrolysing methods according to the state of the art, moreover, its efficiency exceeds extremely the efficiency of the conventional hydrolysis accomplished nowadays in industrial scale.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Clinical Laboratory Science (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU0402015A HUP0402015A2 (en) | 2004-10-06 | 2004-10-06 | Method and installation for decompozition of water |
HUP0402015 | 2004-10-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006038048A1 true WO2006038048A1 (en) | 2006-04-13 |
Family
ID=89985529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/HU2005/000108 WO2006038048A1 (en) | 2004-10-06 | 2005-10-06 | Apparatus and method for decomposing water |
Country Status (2)
Country | Link |
---|---|
HU (1) | HUP0402015A2 (en) |
WO (1) | WO2006038048A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008148504A2 (en) | 2007-06-04 | 2008-12-11 | Conpower Energieanlagen Gmbh & Co Kg | Method for the isolation of hydrogen by means of a dissociation process, and dissociating apparatus |
ES2317728A1 (en) * | 2006-04-19 | 2009-04-16 | Antonio Victor De La Vega Montero | Method of obtaining hydrogen by water dissociation (Machine-translation by Google Translate, not legally binding) |
WO2008064002A3 (en) * | 2006-11-13 | 2009-09-24 | Kc Energy Llc | Rf systems and methods for processing salt water |
ITMI20091249A1 (en) * | 2009-07-14 | 2011-01-15 | Maurizio Egidio Brioschi | APPARATUS FOR THE PRODUCTION OF HYDROGEN GASEOUS AND ENERGY GENERATION SYSTEM USING THE APPARATUS |
EP2907787A1 (en) * | 2014-02-17 | 2015-08-19 | Ewald Rautenberg | Device for large scale production of hydrogen |
CN106586953A (en) * | 2016-11-28 | 2017-04-26 | 武汉武钢工程技术生产力促进中心有限责任公司 | Device for decomposition of water with addition of ironmaking hot-blast stove thermal force with microwaves |
FR3132296A1 (en) * | 2022-01-28 | 2023-08-04 | Pierre Lecanu | Hydrogen generator by excitation of micro-droplets of water |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5617902A (en) * | 1979-07-20 | 1981-02-20 | Akiyama Morio | Water dissociating method utilizing microwave plasma phenomenon |
DE4238952A1 (en) * | 1992-11-16 | 1994-05-05 | Klaus Rasbach | Hydrogen and oxygen generation from water using resonance frequency - from hypersonic generator in efficient, environmentally friendly technique, giving hydrogen useful e.g. as fuel |
JP2002220201A (en) * | 2001-01-19 | 2002-08-09 | Tsutomu Sakurai | Method of manufacturing hydrogen from steam by microwave discharge |
US20030183505A1 (en) * | 2001-06-18 | 2003-10-02 | Austin Gary N. | Methods for affecting the ultra-fast photodissociation of water molecules |
-
2004
- 2004-10-06 HU HU0402015A patent/HUP0402015A2/en unknown
-
2005
- 2005-10-06 WO PCT/HU2005/000108 patent/WO2006038048A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5617902A (en) * | 1979-07-20 | 1981-02-20 | Akiyama Morio | Water dissociating method utilizing microwave plasma phenomenon |
DE4238952A1 (en) * | 1992-11-16 | 1994-05-05 | Klaus Rasbach | Hydrogen and oxygen generation from water using resonance frequency - from hypersonic generator in efficient, environmentally friendly technique, giving hydrogen useful e.g. as fuel |
JP2002220201A (en) * | 2001-01-19 | 2002-08-09 | Tsutomu Sakurai | Method of manufacturing hydrogen from steam by microwave discharge |
US20030183505A1 (en) * | 2001-06-18 | 2003-10-02 | Austin Gary N. | Methods for affecting the ultra-fast photodissociation of water molecules |
Non-Patent Citations (4)
Title |
---|
LIPOVETSKY V: "Gaseous hydrogen production by water dissociation method", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, ELSEVIER SCIENCE PUBLISHERS B.V., BARKING, GB, vol. 28, no. 4, April 2003 (2003-04-01), pages 377 - 379, XP004401393, ISSN: 0360-3199 * |
PATENT ABSTRACTS OF JAPAN vol. 005, no. 067 (C - 053) 7 May 1981 (1981-05-07) * |
PATENT ABSTRACTS OF JAPAN vol. 2002, no. 12 12 December 2002 (2002-12-12) * |
PROTASEVICH E T: "ON THE FEASIBILITY OF A PLASMA-CHEMICAL REACTOR FOR HYDROGEN PRODUCTION", TECHNICAL PHYSICS, PLEIADES PUBLISHING / AIP, MELVILLE, NY, US, vol. 48, no. 6, June 2003 (2003-06-01), pages 795 - 796, XP001198981, ISSN: 1063-7842 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2317728A1 (en) * | 2006-04-19 | 2009-04-16 | Antonio Victor De La Vega Montero | Method of obtaining hydrogen by water dissociation (Machine-translation by Google Translate, not legally binding) |
WO2008064002A3 (en) * | 2006-11-13 | 2009-09-24 | Kc Energy Llc | Rf systems and methods for processing salt water |
AU2007323906B2 (en) * | 2006-11-13 | 2012-06-28 | Kc Energy Llc | RF systems and methods for processing salt water |
WO2008148504A2 (en) | 2007-06-04 | 2008-12-11 | Conpower Energieanlagen Gmbh & Co Kg | Method for the isolation of hydrogen by means of a dissociation process, and dissociating apparatus |
WO2008148504A3 (en) * | 2007-06-04 | 2009-03-12 | Conpower Energieanlagen Gmbh & | Method for the isolation of hydrogen by means of a dissociation process, and dissociating apparatus |
ITMI20091249A1 (en) * | 2009-07-14 | 2011-01-15 | Maurizio Egidio Brioschi | APPARATUS FOR THE PRODUCTION OF HYDROGEN GASEOUS AND ENERGY GENERATION SYSTEM USING THE APPARATUS |
WO2011006749A1 (en) * | 2009-07-14 | 2011-01-20 | Sonolis S.R.L. | Apparatus for producing gaseous hydrogen and energy generation system utilising such apparatus |
EP2907787A1 (en) * | 2014-02-17 | 2015-08-19 | Ewald Rautenberg | Device for large scale production of hydrogen |
CN106586953A (en) * | 2016-11-28 | 2017-04-26 | 武汉武钢工程技术生产力促进中心有限责任公司 | Device for decomposition of water with addition of ironmaking hot-blast stove thermal force with microwaves |
FR3132296A1 (en) * | 2022-01-28 | 2023-08-04 | Pierre Lecanu | Hydrogen generator by excitation of micro-droplets of water |
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HU0402015D0 (en) | 2004-12-28 |
HUP0402015A2 (en) | 2007-11-28 |
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