WO2005084927A1

WO2005084927A1 - Process and installation for molding an optical lens

Info

Publication number: WO2005084927A1
Application number: PCT/EP2005/002104
Authority: WO
Inventors: Noémie Lesartre; Jérôme Dupuy; Abderrahim Maazouz; Jean-Pierre Pascault
Original assignee: Insa (Institut National Des Sciences Appliquees)
Priority date: 2004-02-27
Filing date: 2005-02-25
Publication date: 2005-09-15
Also published as: DE602004015240D1; ATE402006T1; US7950917B2; US20080230931A1; EP1720695A1; EP1568474A1; EP1568474B1

Abstract

The object of the invention is a process for molding an optical element such as a lens (2). According to the invention, the element is obtained by a reaction injection molding process comprising the steps of mixing at least two polymerizing reactants and forcing the obtained reacting mixture by an injection duct (5) for filling under pressure a sealed mold cavity (4) having an entry side (43) provided with a casting opening (42) and an evacuation side (44) and providing a laminated flow of mixture in a spout (6) having a progressive enlarging transversal section between the outlet opening (52) of the injection duct (5) and the casting opening (42) of the mold cavity (4), for avoiding any turbulent area in said laminated flow, said evacuation side (44) being provided with means (45) for evacuating air contained in the mixture during mold filling. The invention also covers the molding installation adapted for using such a process.

Description

PROCESS AND INSTALLATION FOR MOLDING AN OPTICAL LENS

The present invention relates to a process and an installation for molding an optical element by reaction injection molding. Optical elements such as a lens having a substantially circular shape and a substantially regular transversal thickness may be advantageously obtained by molding at least two polymerizing reactants forming a gel in a mold cavity. However, an optical element and particularly a lens must be homogeneous and it is necessary to avoid a partial solidification of the element. To this aim, the reactants have to remain liquid during the time necessary for filling the mold cavity. Therefore, until now, the reactants have been chosen for delaying the solidification until the mold cavity is completely filled. A first object of the present invention is, thus, to increase the productivity by shortening the time necessary for mixing the reactants and molding the optical element. Another object of the invention is to have broader possibilities of choosing the reactants to be molded. To this end, it has been discovered that a process known as

"Reaction Injection Molding" (RIM) would be particularly advantageous for forming an optical element. Indeed, in the RIM process, mixing of the two reactants is obtained by jet impingement in a mixing head comprising a mixing chamber connected to the mold cavity by an injection duct associated with a piston forcing the required quantity of mixture to fill under pressure the mold cavity. Mixing and injecting being very rapid, fast-polymerizing reactants may be used. Therefore, if such a process is used for forming optical elements, a broader choice of reactants is allowed. Moreover, the productivity of this process is very high. However, air could be entrapped by the jet impingement mixing, thus forming bubbles in the mixture filling the mold cavity. The process according to the invention comprises the steps of mixing at least two polymerizing reactants in a mixing chamber for obtaining a reacting mixture and forcing said mixture to flow by an injection duct for filling under pressure a sealed mold cavity having an entry side provided with a casting opening and an evacuation side and providing a laminated flow of mixture in a spout having a progressive enlarging transversal section between an outlet opening of the injection duct and the casting opening of the mold cavity, the evacuation side of said mold cavity being provided with means for evacuating air eventually contained in the mixture during mold filling before solidification of the element. Thus, firstly using a laminated flow of mixture permits to avoid any turbulent area in said molding mixture and secondly, the air eventually entrapped by the mixing of the reactants only forms a bubble nucleation in the mixture and the bubbles growing during the polymerizing reaction may be evacuated before solidification. Thus, air entrappment and turbulence in the mixture filling the mold are avoided. In particular, for forming an optical element having a substantially circular shape and a substantially regular transversal thickness the sealed mold cavity has a substantially circular shape and a transversal thickness corresponding to those of the element and the spout provides a substantially flat space having an axis substantially passing by the center of the mold cavity and being limited by two flat faces and two diverging sides inclined on either side of said axis and tangentially connecting to the circular shape of the mold cavity. According to a preferred embodiment, the said casting opening of the mold cavity largely opens along a sector of the circular shape of the mold cavity and said flat faces of the spout each have a substantially trapezoidal shape with a large curvilinear base extending along said sector of the mold cavity and a short base connecting the outlet opening of the injection duct. Advantageously, the process comprises a compression step of the molding mixture after the mold cavity has been filled completely. According to another preferred characteristic of the invention, the process comprises the step of trapping a first part of the mixture upwards of the injection flow in a final part of the injection duct provided between the outlet opening and a closed end. The mold cavity is limited by two plates between which is inserted a circular seal comprising at least a vent for evacuating air during mold filling and the process advantageously comprises the steps of exerting an increased clamping force, at the end of mold filling, between the plates limiting the mold cavity, for compressing the circular seal and closing the vent, and then applying a post-injection pressure in the molded mixture. Moreover, the present invention covers a molding installation for forming an optical element having a substantially circular shape and a substantially regular transversal thickness, said installation comprising: - a mixing chamber for preparing a mixture to be molded, - a sealed mold cavity with a substantially circular shape having a center and a transversal thickness corresponding to those of the element to be obtained, said mold cavity being limited by two plates between which is inserted an elongated seal, and having an entry side provided with a casting opening and an evacuation side opposite to said entry side, - an injection duct connecting said mixing chamber to said mold cavity, said injection duct having an outlet opening, - a spout connecting said outlet opening of the injection duct to the casting opening of the mold cavity, - filling means for forcing said mixture to flow from the mixing chamber to the mold cavity via said injection duct and said spout for filling said mold cavity under pressure, - at least a vent provided on said evacuation side of the mold cavity and connected to air evacuation means, - said spout providing a substantially flat space having an axis substantially passing by the center of the mold cavity and being limited by two flat faces and two diverging sides inclined on either side of said axis and tangentially connecting to the circular shape of the mold cavity, - said casting opening of the mold cavity having a narrow rectangular section largely opening along a sector of the circular shape of the mold cavity and said flat faces of the spout each having a substantially trapezoidal shape with a large curvilinear base extending along said sector of the mold cavity and a short base connecting the outlet opening of the injection duct. According to a preferred embodiment, the injection duct extends downwards in the flow direction of the outlet opening until a closed end, which is separated from, said outlet opening by a space forming a reserve for trapping a first part of the mixture flowing upwards in said injection duct before entering in the enlarging spout. Each vent provided on the evacuation side of the mold cavity may be constituted by at least an aperture, which is small enough to avoid reactants containing the mixture to flow outside. According to another preferred embodiment, each vent provided on the evacuation side of the mold cavity is closed by a removable valve, said valve being open during mold filling and being closed after air evacuation, for applying a post-injection pressure in said mold cavity. Advantageously, a second cavity may be provided on the evacuation side of the mold cavity for trapping air contained in the mixture to be molded, said mold cavity and said second cavity being surrounded by a common continuous seal. According to another preferred embodiment, the mold cavity extends along an inclined median plane making an angle different from zero with the horizontal and comprises a lowest part and a highest part respectively constituting the entry side and the evacuation side of said mold cavity. Other advantageous characteristics of the process and of the installation are covered by the claims. The invention will be now described referring to a preferred embodiment illustrated by the hereattached drawings. Figure 1 is schematical view of a mixing head for RIM process. Figure 2 is a front view of a lens. Figure 3 is a side view of the lens. Figure 4 is a front view of a molding device according to the invention. Figure 5 is a cross-sectional view of the device of figure 4. Figure 6 is a schematical view of a molding device according to a first embodiment of the invention. Figure 7 shows schematically how the seal is compressed. Figure 8 is a partial schematical view of a vent for air evacuation according to a second embodiment. Figure 9 and figure 10 show schematically other embodiments for air evacuation. As above indicated, the object of the invention is to produce optical element by reaction injection molding, such a process being very rapid and allowing a larger choice of reactants. In the Reaction Injection Molding (RIM) process which is known since many years for producing polymer products, a reaction mixture is produced in a mixhead by jet impingement and immediately injected in a mold. Such mixheads may be of different types and are described, for example in the "Journal of Applied Polymer Science", vol. 37, 2295-2312 (1989). Thus a detailed description is not necessary. Only as an example, figure 1 shows schematically a mixhead 1 of the L type comprising two opposed nozzles 11 for injecting two polymerizing reactants in a mixing chamber 12 to obtain a reacting mixture by jet-to-jet impingement of the reactant streams, said mixture being forced by a plunger in a second chamber 13 associated with a second plunger 14 which moves along the chamber 13 for pressing the mixture into a mold via an injection duct. The RIM Process may be advantageously used for rapidly molding of polyurethane products as described in US 2002/0153623, the reactants being a polyisocyanate (NCO) compound and a polyhydroxyle

OH compound. The RIM Process is also known in the prior art as described in EP 0748 685 to prepare contact lenses from polyurethane products. According to the invention, the RIM Process will be used for molding an optical element such as a lens 2 having a substantially circular shape and a transversal thickness as shown on figures 2 and 3. Thus, the molding device 3 comprises, as represented on figures 4 and 5, two plates 31 , 31' limiting a mold cavity 4 having a circular shape and a transversal thickness corresponding to those of the element 2 to be obtained. As indicated on figures 4 and 5, the mold 3 comprises an injection duct 5 having an inlet opening 51 and an outlet opening 52 connected by a spout 6 to a casting opening 42 provided on an entry side 43 of the mold cavity 4. The injection duct 5, the spout 6 and the mold cavity 4 are constituted by opposed recesses provided in the two plates 31 , 31' of the mold 3 which are pressed together by screws 32. An elongated seal 41 is inserted between the two plates 31 , 31' along the side of the mold cavity 4, said seal 41 resisting to the pressure inside the cavity 4 during filling and curing. The spout 6 provides a substantially flat space 60 having an axis x'x passing by the center of the circular mold cavity 4 and the center of the outlet opening 52 of the injection duct 5. Said spout 6 is limited by two flat faces 61 , 61' and two diverging lateral sides 62, 62' which are symmetrically inclined on either side of the axis x'x and tangentially connect to the circular side 45 of the mold cavity 4. Thus, the spout has a narrow rectangular section progressively enlarging until the curvilinear casting opening 42 of the mold cavity 4 which widely opens along a sector A of the circular side 45, said sector being, for example of 90°. As represented on figure 4, the flat faces 61 , 61' of the spout 6 each have a substantially trapezoidal shape with a short base connecting to the outlet opening 52 of the injection duct 5 and a large curvilinear base extending along said sector A of the mold cavity. As indicated on figure 6, the outlet 15 of the pressing chamber 13 of the mixhead 1 is preferably directly connected to the inlet opening 51 of the injection duct 5, but this is not necessary. Thus, the reaction mixture forced by the plunger 14 flows successively in the injection duct 5, the outlet opening 52 and the spout 6 for filling the mold cavity 4. However, the mixture obtained by jet-impingement of the reactants injected in the mixing chamber 12 contains a small quantity of air producing a bubbles nucleation as pressure drops suddenly in the turbulent flow. Due to the pressure in the pressing chamber 13 and the injection duct 5, such bubbles are dissolved in the mixture but, during curing in the mold cavity, the exothermic polymerizing reaction produces a growing of the bubbles. According to the invention, these bubbles are evacuated before solidification of the mixture, for avoiding entrapment of air bubbles in the lens. To this end, air evacuation means are provided on the side 44 of the cavity 4 opposed to the entry side 43. For facilitating air evacuation, the mold cavity 4 extends along a median plane P which is preferably vertical or inclined by an angle different from zero, the evacuation side 44 being higher than the entry side 43. The flat space 60 of the spout 6 with a progressive enlarging transversal section produces a laminated flow of the mixture which emerges on the whole width of the cavity 4 and fills it without turbulence, thus avoiding air entrapment and permitting an immediate evacuation of the air bubbles which grow progressively in the liquid mixture. Indeed, the air contained in the mixture remains dissolved by the pressure applied until the outlet 52 of the injection duct 5 and then, the progressive enlarging section of the spout 6 provides, between the flat faces 61 , 61', a laminated flow with a progressively decreasing pressure. Thus, the bubbles appearing and growing progressively in this flow during filling the mold cavity 4 are regularly distributed in the mixture and may be immediately evacuated by the upper side 44 of the cavity 4 opposite to the spout 6. For this purpose, as represented on figure 6, air evacuation means are provided on the upper side 44 of the cavity 4, for example two small vents 45 provided in the seal 41 surrounding the cavity 4 opening directly in the air or in a space 46 connected to vacuum means. Figure 7 schematically represents the successive steps of the process. During mold filling, air is evacuated by the vents 45 provided in the seal 41 (figure 7a). At the end of mold filling, the mold clamping force is increased

(figure 7b) and the seal 41 is compressed in order to close the vents 45. Flow of reactants by the vents is avoided and a post-injection pressure can be applied by the plunger 14 which, for example, may penetrate in the inlet opening 51 of the injection duct 5. Thus, the air still contained in the mixture remains dissolved and no bubble appears until solidification of the molded lens. During curing, the clamping force is one more time increased

(figure 7c) in order to compensate for shrinkage at the surface of the lens 2. After solidification, the molded piece may be withdrawn from the mold 3 and the part corresponding to the spout 6 may be broken, a rounded lens 2 without bubbles being obtained. It has been observed that the front part of the mixture flowing from the chamber 13 of the mixhead 1 in the injection duct 5 and being in contact with air, is more subjected to bubbles nucleation. Therefore, as represented on figure 4, the injection duct 5 is advantageous prolongated by a part 53 extending in the flow direction from the outlet opening 52 until a closed end 54, said part 53 forming a reserve for trapping the first part of the mixture flowing upwards in said injection duct 5 before entering in the enlarging spout 6. Besides, the vent 45 may open in a second cavity 46 provided in the two plates 31 , 31' and connected, for example, with vacuum means. As indicated on figure 7, each vent 45 is constituted by at least an aperture which is small enough to avoid the molded mixture to flow outside, said aperture being provided in the seal 41 and closed by compression of the seal as indicated on figure 7b. However, as indicated on figure 8, the mold may be provided with a larger aperture forming a unique vent which may be closed by a removable valve 7, said valve 7 being open during mold filling and being closed after air evacuation, for applying a post injection pressure in the mold cavity 4. Thus, the invention allows using of the R.I.M. process for obtaining optical lens from polymerized reactants with a high productivity. It should be noted that such a process allows a very broad choice of reactants. According to another embodiment shown on figure 9, the aperture 47 may be closed by a plug 71 which is, at the ambient temperature, smaller than the aperture 47 for providing a slight play 72 allowing air evacuation during filling of the mold cavity by the injected mixture, said plug 71 expanding and closing said play 72 by increasing of its temperature when the mold cavity 4 is completely filled by the liquid mixture. Moreover, the invention is not limited to the details of the various embodiments described hereabove only as examples, other variants and other improvements being conceivable without departing from the protective scope defined by the claims. Indeed, as represented on figure 10, the air evacuation means could be constituted by a space 73 largely opening on the evacuation side 44 of the mold cavity 4 for trapping air contained in the molded mixture, said mold cavity 4 and said space 73 being surrounded by a common continuous seal 41. In this case, a part of the mixture eventually penetrating in said space 73 could be eliminated after solidification and withdrawing the lens from the mold. Moreover, as indicated on figures 4 and 5, the mold cavity 4 is advantageously vertical or inclined during filling and thus comprises the lowest part 43 constituting the entry side of the mixture and a highest part 44 constituting the air evacuation side. However, in some cases, it could be possible to use an horizontal mold cavity 4. Besides, as indicated on figure 5, the flat trapezoidal faces 61, 61' of the enlarging spout 6 may be symmetrically inclined by a slide angle on either side of the median plane P of the mold cavity 4, said faces 61 , 61' slightly converging from the outlet opening 52 of the injection duct 55 to the inlet opening 42 of the mold cavity 4. Thus, the progressive decreasing of the pressure in the enlarging spout 6 may be controlled for having a better distribution of the mixture on the whole width of the mold cavity 4. The reference signs inserted after the technical characteristics mentioned in the claims are intended only to facilitate the understanding of said claims and in no way limit their scope.

Claims

CLAIMS 1. Process for forming an optical element by molding at least two polymerizing reactants characterized by the fact that the molded element is obtained by a reaction injection molding process comprising the steps of mixing at least two polymerizing reactants in a mixing chamber (12) for obtaining a reacting mixture, forcing said mixture to flow by an injection duct (5) for filling under pressure a sealed mold cavity (4) having an entry side (43) provided with a casting opening (42) and an evacuation side (44), and providing a laminated flow of mixture in a spout (6) having a progressive enlarging transversal section between an outlet opening (52) of the injection duct (5) and the casting opening (42)of the mold cavity (4), for avoiding any turbulent area in said laminated flow, the evacuation side (44) of said mold cavity (4) being provided with means (45) for evacuating air eventually contained in the mixture during mold filling before solidification of the element.

2. Process according to claim 1 for forming an optical element having a substantially circular shape and a substantially regular transversal thickness wherein the sealed mold cavity (4) has a substantially circular shape and a transversal thickness corresponding to those of the element and wherein the spout (6) provides a substantially flat space (60) having an axis (x'x) substantially passing by the center of the mold cavity (4) and being limited by two flat faces (61 , 61') and two diverging sides (62, 62') inclined on either side of said axis (x'x) and tangentially connecting to the circular shape (45) of the mold cavity (4),

3. Process according to claim 2 wherein the casting opening (42) of the mold cavity (4) largely opens along a sector (A) of the circular shape (45) of the mold cavity (4), said flat faces (61 , 61') of the spout (6) each having a substantially trapezoidal shape with a large curvilinear base extending along said sector (A) of the mold cavity (4) and a short base connecting the outlet opening (52) of the injection duct (5).

4. Process according to one of claims 1 to 3 wherein said mold cavity (4) and said spout (6) are inclined as regards the horizontal, said mold cavity (4) having a lowest entry side and a highest evacuation side.

5. Process according to one of the preceding claims, comprising a compression step of the molded mixture after the mold cavity (4) has been filled completely.

6. Process according to one of the preceding claims comprising the step of trapping a first part of the mixture upwards of the injection flow, in a final part (53) of the injection duct provided between the outlet opening (52) and a closed end (54).

7. Process according to one of the preceding claims, wherein said mold cavity is limited by two plates (31 , 31') between which is inserted a circular seal (41) comprising at least a vent (45) for evacuating air during mold filling, the process comprising the steps of exerting an increased clamping force between the plates (31 , 31') limiting the mold cavity (4), at the end of mold filling, for compressing the circular seal and closing the vent (45), and then applying a post-injection pressure in the molded mixture.

8. Process according to claim 7, wherein the clamping force compressing the circular seal (41) is increased during curing of the reactants in order to compensate for shrinkage.

9. Process according to one of the preceding claims, comprising the steps of accumulating the evacuated air in a space (73) provided on the evacuation side (44).

10. Process according to one of claims 1 to 8, comprising the steps of evacuating air by an aperture (47) provided on the evacuation side (44) of the mold cavity (4) and closing said aperture (47) when said mold cavity (4) is completely filled by the injected mixture.

11. Molding installation for forming an optical lens (2) having a substantially circular shape and a substantially regular transversal thickness, said installation comprising: - a mixing chamber (12) for preparing a mixture to be molded, - a sealed mold cavity (4) with a substantially circular shape having a center and a transversal thickness corresponding to those of the lens to be obtained, said mold cavity (4) being limited by two plates (31 , 31') between which is inserted an elongated seal, and having an entry side (43) provided with a casting opening (42) and an evacuation side (44) opposite to said entry side (43), - an injection duct (5) connecting said mixing chamber (12) to said mold cavity (4), said injection duct having an outlet opening (52), - a spout (6) connecting said outlet opening (52') of the injection duct (5) to the casting opening of the mold cavity (4), - filling means (14) for forcing said mixture to flow from the mixing chamber (12) to the mold cavity (4) via said injection duct (5) and said spout (6) for filling said mold cavity (4) under pressure, - at least a vent (45) provided on said evacuation side (44) of the mold cavity (4) and connected to air evacuation means (7), - said spout (6) providing a substantially flat space (60) having an axis (x'x) substantially passing by the center of the mold cavity (4) and being limited by two flat faces (61 , 61') and two diverging sides (62, 62') inclined on either side of said axis (x'x) and tangentially connecting to the circular shape (45) of the mold cavity (4).

12. Molding installation according to claim 11 , wherein the injection duct is prolongated by a part (53) extending in the flow direction from the outlet opening (52) until a closed end (54), said part (53) forming a reserve for trapping a first part of the mixture flowing upwards in said injection duct (5).

13. Molding installation according to one of claims 11 and 12, wherein each vent (45) provided on the evacuation side (44) of the mold cavity (4) is constituted by at least an aperture which is small enough to avoid reactants contained in the mixture to flow outside.

14. Molding installation according to one of claims 11 and 12, wherein each vent (45) provided on the evacuation side of the mold cavity (4) is closed by a removable valve (7), said valve (7) being open during mold filling and being closed after air evacuation for applying a post-injection pressure in said mold cavity (4).

15. Molding installation according to one of claims 11 to 14, comprising a space (73) opening on the evacuation side (44) of the mold cavity (4) for trapping air contained in the mixture to be molded, said mold cavity (4) and said space (73) being surrounded by a common continuous seal.

16. Molding installation according to one of claims 11 to 14, wherein each vent comprises an aperture (45) provided in the seal (41) on the evacuation side (44) of the mold cavity (4) and connected with air evacuation means.

17. Molding installation according to claim 16, wherein a post- injection pressure is applied in the mold cavity (4) after completely filling and air evacuation, said pressure compressing the seal (41) and closing the vents (45).

18. Molding installation according to claim 17, wherein said aperture is closed by a plug (71) having a slight play (72) for allowing air evacuation during filling of the mold cavity (4) by the injected mixture, said plug (71) expanding and closing said play (72) by increasing of its temperature when the mold cavity (4) is completely filled.

19. Molding installation according to one of claims 11 to 18, wherein the mold cavity (4) extends along an inclined median plane making an angle different from zero with the horizontal and comprises a lowest part and a highest part respectively constituting the entry side (43) and the evacuation side (44) of said mold cavity (4).

20. Molding installation according to claim 19, wherein the flat trapezoidal faces (61 , 61') of the enlarging spout (6) are substantially parallel to the median plane (P) of the mold cavity (4).

21. Molding installation according to claim 19, wherein the flat trapezoidal faces (61 , 61') of the enlarging spout (6) are symmetrically inclined by a slight angle on either side of the median plane (P) of the mold cavity (4), said flat faces slightly converging from the outlet opening (52) of the injection duct (5) to the inlet opening (42) of the mold cavity (4).