WO2005066027A1

WO2005066027A1 - Preform assembly, lightweight container and method of manufacture

Info

Publication number: WO2005066027A1
Application number: PCT/US2004/043304
Authority: WO
Inventors: Thomas E. Nahill
Original assignee: Graham Packaging Pet Technologies Inc.
Priority date: 2003-12-24
Filing date: 2004-12-23
Publication date: 2005-07-21
Also published as: EP1706327A1; US20050158495A1

Abstract

A hollow plastic container includes an open finish, a closed bottom and a sidewall connecting the finish to the bottom. The sidewall is ultra thin, having a radial wall thickness of not more than 0.008 inch, preferably in the range of about 0.003 to 0.004 inch. The container preferably is blow molded from a preform (12) having a wall thickness such that a stretch ratio of eight to ten is obtained during the blowing operation. The preform may be heated prior to blow molding to achieve sidewall crystallization at a level of 28 % to 35 %. A plastic finish ring (14) is formed separately from said preform and is externally secured to the neck (18) of said preform.

Description

PREFORM ASSEMBLY , LIGHTWEIGHT CONTAINER AND METHOD OF MANUFACTURE

The present invention relates to blow molded plastic containers, to preforms for blow molding such containers, and to methods of making such preforms and containers. Background and Summary of the Invention In the manufacture of plastic containers, it is conventional to injection mold or compression mold a container preform having a body and a finish with one or more external threads. The preform finish typically is molded to its final geometry, while the body of the

I preform subsequently is blow molded to the desired geometry of the container body. The preform may be of monolayer construction, or may be of multilayer construction in which one or more intermediate layers in the preform body may or may not extend into the finish area of the preform. U.S. Patents 4,609,516, 4,710,118 and 4,954,376 illustrate injection molding of multilayer container preforms.

5 Molding the finish portion of the container as part of the preform presents a number of problems . For example, when the preforms are formed by inj ection molding, the plastic material typically is injected into a mold cavity at the closed end of the preform body, so that the material must flow along the sides of the preform cavity into the area in which the finish is molded. The finish typically requires more accurate and stable dimensioning than the body of the preform,

) which may limit the cycle time of the molding process. Furthermore, the difficulty in forming the finish limits how thin the wall of the preform body can be. By the time a thick preform finish fills, the sidewall of the preform body can begin to cool if it is too thin. If the finish is made thin to limit the amount of time needed to fill the finish, the finish may not fill fully, and may not have the desired strength for securement of a container closure. It is a general object of the present invention to provide a method of making container preforms and containers, a preform and a container that address one or more of the noted problems in the art.

A hollow plastic container in accordance with a presently preferred aspect of the invention includes an open finish, a closed bottom and a sidewall connecting the finish to the

> bottom. The container sidewall is ultra thin, preferably having a radial wall thickness of not more than 0.008 inch, and more preferably in the range of about 0.003 to 0.004 inch thick. (All references to radial sidewall thickness refer to average radial wall thickness, and not to isolated thin or thick spots in the wall.) A method of making a container in accordance with another aspect of the present

3 invention includes molding a preform having a neck with an open end, a closed bottom and a sidewall with a thickness of not more than 0.08 inch, more preferably in the range of about 0.04 to 0.05 inch. The sidewall and bottom of the preform are blow molded to form a container having a wall thickness of not more than 0.008 inch, and more preferably in the range of about 0.003 to 0.004 inch. In the preferred embodiments in accordance with this aspect of the

5 invention, a separately formed finish ring is attached to the neck of the preform either prior to or subsequent to blow molding the preform body.

In accordance with another aspect of the present invention, a thin-wall container is provided that has particular utility for hot-fill applications - i.e., applications in which the container is filled with hot fluid product at a temperature of about 185° F. (Different packagers use different hot-fill temperatures, which typically are about 185 ° F.) The container sidewall has a thickness of not more than 0.008 inch, and a stretch ratio of about eight to ten as compared with the preform prior to blow molding. Brief Description of the Drawings

The invention, together with additional objects, features, advantages and aspects thereof,

will be best understood from the following description, the appended claims and the

accompanying drawings, in which: FIG. 1 is an elevational view of a preform assembly in accordance with one presently preferred embodiment of the invention;

FIGS. 1A is a fragmentary sectional view of the portion of FIG. 1 within the circle 1A; FIG. 2 is an exploded perspective view of the preform assembly illustrated in FIG. 1;

FIG. 3 is an elevational view of a package that includes a container blow molded from the preform assembly of FIG. 1; and

FIG. 3 A is a fragmentary sectional view of the portion of FIG. 3 within the circle 3 A.

Detailed Description of Preferred Embodiments

FIGS. 1-2 illustrate a preform assembly 10 in accordance with one exemplary aspect of

the invention as comprising a preform 12 and a separate finish ring 14 externally secured to the neck of preform 12. Preform 12 includes a body 16 having a closed lower end and a neck 18

integrally molded with body 16. (Directional words such as "upper" and "lower" are employed by way of description and not limitation with respect to the upright orientation of the preform

assembly, container and package illustrated in the drawings. Directional words such as "radial"

and "circumferential" are employed by way of description and not limitation with respect to the

axis of the preform neck or finish ring as appropriate.) Neck 18 typically is cylindrical. A flange

20 preferably extends radially outwardly from the open end of neck 18 remote from body 16.

Neck 18 and flange 20 surround the open mouth of preform 12. Finish ring 14 may be circumferentially continuous or circumferentially split to facilitate attachment to preform 12. Finish ring 14 includes an annular cylindrical wall 22 having one or more external threads or thread segments 24. A support flange 26 extends radially outwardly from the lower end of wall 22, giving finish ring 14 a generally L-shaped cross section in the

5 illustrated embodiment of the invention. Finish ring 14 may also include a bead for cooperating with tamper-indicating structure on the package closure. Finish ring 14 is externally secured to the surface of preform neck 18 by any suitable means, such as insert molding, press-fit, adhesive, ultrasonic welding, etc. Finish ringl 4 maybe secured to neck 18 either prior to or subsequent to blow molding container body 28 (FIG. 3). Techniques for attaching finish ring 14 to preform

j neck 18 are illustrated, for example, in U.S. applications 10/375,737, 10/375,736, 10/351,671, 10/375,758 and 10/403,415 assigned to the assignee of the present application.

Preform 12 maybe of monolayer construction as illustrated in FIG. 1A, or of multilayer construction. Preform 12 may be fabricated by injection or compression molding. Preform 12 may be of any suitable crystalizable polyester construction, such as polyethylene terephthalate

5 (PET), polyethylene naphthalate (PEN), blends or copolymers of PET and/or PEN, or process regrind that consists essentially of PET and/or PEN. Finish ring 14 may be of any suitable material construction, either the same as or more preferably different from the material construction of the preform. For example, finish ring 14 can be of PET, post consumer resin (PCR), process required (REG), polypropylene (PP), polyethylene (PE) or polyethylene) naphthlate (PEN) construction. When finish ring 14 is of polyester construction (e.g., PET or PEN), the finish ring may be wholly or partially crystalized.

In accordance with one aspect of the present invention, preform 12 has a wall thickness that is greatly reduced as compared with the prior art - i.e., an ultra thin wall thickness. Wall 16 has a radial thickness of not more than 0.08 inch, most preferably in the range of about 0.04 to 0.05 inch. Such ultra thin wall thicknesses can be employed in accordance with this aspect of the invention because finish ring 14 is separately formed and secured to the neck of the preform body, rather than being molded integrally with the preform body and thereby limiting the thinness

> of the preform body as previously discussed. When subsequently blow molded to form a container 28 (FIGS. 3 and 4), radial and axial stretching of the preform material reduces the thickness of the container wall 30, preferably to not more than about 0.008 inch, more preferably to not more than 0.008 inch for hot fill application and not more than 0.006 inch for cold fill applications, and most preferably to the range of about 0.003 to 0.004 inch for either application.

3 Containers having such a reduced wall thickness are sufficiently strong to retain the contents of the container when the container is filled and capped by a closure 32 (FIG. 3). The ultra thin container sidewall greatly reduces the amount of material and therefore the cost of the container. Furthermore, the container sidewalls can be substantially crushed when empty to reduce the shipping volume to the packager, and will reassume the blow-molded geometry when filled.

5 The preform and container geometries illustrated in the drawings are intended to be generic, with the principles of the present invention not being limited to any specific preform or container geometry. Provision of very thin-walled preforms in accordance with one aspect of the present invention has a number of advantages over the prior art. In the prior art, very small preforms of

3 normal wall thickness are used to blow mold thin-walled containers. However, the blow molding operation results in high levels of molecular orientation in the container wall, with the preform- to-container stretch ratio typically being on the order of about ten to twelve. These high stretch ratios result in severe shrinkage and distortion during hot fill applications. However, a larger preform having thin walls is used in accordance with the present invention, reducing the stretch

ratio to a range of about eight to ten, which will not shrink and distort during hot fill.

Furthermore, the use of a thin-wall preform yields more uniform stretch orientation levels across

the thickness of the container wall. Thin-wall preforms and containers have a further advantage in hot fill applications in that

vacuum panels molded into the container wall operate very efficiently because of the reduced

wall thickness. That is, the reduced thickness of the panels permits the panels readily to flex inwardly as the hot-filled package cools, reducing distortion to the remainder of the container.

Whereas containers for hot fill applications normally have a wall thickness of about 0.012 to

0.015 inch and are blown from a preform having a wall thickness of about 0.15 to 0.18 inch, the

present invention provides a container for hot fill applications having a wall thickness of not

more than 0.008 inch blown from a preform having a wall thickness of about 0.08 inch.

The thin- wall preforms of the present invention possess the further advantage that they are

less sensitive to moisture than are preforms having thicker walls. For example, it has been found

that preforms having a moisture content of 2000 to 3000 ppm can be blow molded satisfactorily.

Thin- wall preforms also possess the advantage that they can be blow molded around tighter radii on the mold face, providing additional flexibility in container design.

It has been found that the thin-wall preforms of the present invention possess an

unexpected additional advantage. During reheat of the preforms prior to blow molding, thermal

crystallization occurs in the preform wall, followed by strain crystahzation during blow molding. During tests, up to 28% to 35% total sidewall crystallization was obtained, which improved hot-

fill performance of the resulting container without affecting the clarity of the container wall. Total sidewall crystalinity can be measured employing any suitable technique, such as the ASTM 1505 density gradient column technique.

There have thus been disclosed a container, a preform assembly, and methods of making

the container and preform assembly that fully satisfy all of the objects and aims previously set

forth. The invention has been disclosed in conjunction with a presently preferred embodiment

thereof, and modifications and variations have been discussed. Other modifications and

variations will readily suggest themselves to persons of ordinary skill in the art. The invention is intended to embrace all such modifications and variations as fall within the spirit and broad scope

of the appended claims.

Claims

1. A hollow plastic container for hot fill applications having an open finish, a closed bottom and a sidewall connecting said finish to said bottom, said container being blow molded from a preform, said sidewall having a stretch ratio of eight to ten as compared with said preform and having a wall thickness of not more than 0.008 inch.

2. The container set forth in claim 1 wherein said sidewall has a crystallization level in the range of 28% to 35%.

3. A method of making a container for hot fill applications, which includes the steps of:

(a) providing a preform having a sidewall with a first radial thickness, and

(b) blow molding said preform into a container having a second radial wall thickness i of not more than 0.008 inch, and in such a way that said second wall thickness has a stretch ratio of eight to ten as compared with said first wall thickness.

4. The method set forth in claim 3 that includes the step, between said steps (a) and (b), of: (c) crystallizing said sidewall of said preform to a crystallization level in the range of 28%

) to 35%.

5. The method set forth in claim 3 that includes the step, prior to said step (b), of: (c) hot filling said container with a fluid product at a temperature of about 185° F.

6. A hollow plastic container that includes an open finish, a closed bottom and a

sidewall connecting said finish to said bottom, said sidewall having a radial wall thickness of not

more than 0.008 inch.

7. The container set forth in claim 6 wherein said sidewall has a thickness of not

more than about 0.004 inch.

8. The container set forth in claim 7 wherein said sidewall has a thickness in the

range of about 0.003 to 0.004 inch.

9. A preform assembly for blow molding a plastic container, which includes: a molded plastic preform having a body and a neck, said body having a wall thickness of

not more than about 0.08 inch, and a plastic finish ring formed separately from said preform and externally secured to said neck.

10. The preform assembly set forth in claim 9 wherein said wall thickness is in the range of about 0.04 to 0.05 inch.

11. A preform for blow molding a plastic container, which includes a neck and a body

with a closed bottom, said body having a wall thickness of not more than about 0.08 inch.

12. The preform set forth in claim 11 wherein said wall thickness is in the range of about 0.04 to 0.05 inch.

13. The preform set forth in claim 11 wherein said body is crystallized to a level of 5 28% to 35%.

14. A method of making a hollow plastic container that includes the steps of:

(a) molding a preform having a neck with an open end, a closed bottom and a sidewall with a thickness of not more than 0.08 inch, and

L0 (b) blow molding said sidewall and bottom to form a container having a wall thickness less than 0.008 inch.

15. The method set forth in claim 14 wherein said preform in said step (a) has a wall thickness in the range of 0.04 to 0.05 inch, and said container in said step (b) has a thickness in

15 the range of 0.003 to 0.004 inch.

16. The method set forth in claim 14 including the additional step, prior to or subsequent to said step (b), of: (c) attaching a finish ring to said neck.

0 17. The method set forth in claim 14 that includes the additional step, between said steps (a) and (b), of: (c) crystallizing said sidewall of said preform to a crystallization level in the range of28% to 35%.

18. The method set forth in claim 14 that includes the additional step, following sai

step (b), of: (c) hot filling said container with a liquid product at a temperature of about 185° F.