WO2005055357A1 - Membrane electrode assembly of fuel cell - Google Patents
Membrane electrode assembly of fuel cell Download PDFInfo
- Publication number
- WO2005055357A1 WO2005055357A1 PCT/KR2003/002663 KR0302663W WO2005055357A1 WO 2005055357 A1 WO2005055357 A1 WO 2005055357A1 KR 0302663 W KR0302663 W KR 0302663W WO 2005055357 A1 WO2005055357 A1 WO 2005055357A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fuel
- air
- mea
- open groove
- electrode
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 128
- 239000012528 membrane Substances 0.000 title claims abstract description 49
- 239000003054 catalyst Substances 0.000 claims abstract description 47
- 239000003792 electrolyte Substances 0.000 claims abstract description 40
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000008151 electrolyte solution Substances 0.000 claims description 4
- 229920001410 Microfiber Polymers 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000002657 fibrous material Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000003658 microfiber Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 238000006056 electrooxidation reaction Methods 0.000 abstract description 6
- 230000003213 activating effect Effects 0.000 abstract description 2
- 230000003197 catalytic effect Effects 0.000 description 14
- 239000010410 layer Substances 0.000 description 12
- -1 hydrogen ions Chemical class 0.000 description 11
- 238000006722 reduction reaction Methods 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8626—Porous electrodes characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
- H01M8/026—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant characterised by grooves, e.g. their pitch or depth
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
- H01M8/04216—Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a fuel cell, and in particular to a MEA
- membrane electrode assembly of a fuel cell capable of promoting
- Fuel cell has been presented as a substitute for fossil fuel. In the fuel
- Fuel cells can be classified into various kinds according to kinds of
- FIGS 1 and 2 illustrate an example of the fuel cell. As depicted in
- MEA membrane electrode assembly
- electrode (anode) 220 contacted to fuel is formed on a side of an electrolyte
- the fuel electrode 220 is arranged on the fuel side open
- FIG. 300 is a collector plate.
- Figure 3 illustrates a MEA of a fuel cell in accordance with the
- catalytic layer 221 , 231 is respectively coated on both sides of the electrolyte
- membrane 210 having a certain thickness and a rectangular area, and a
- coating layer 222, 232 is respectively coated onto the catalytic layer 221, 231.
- electrolyte membrane 210 construct a fuel electrode, and the catalytic layer
- membrane 210 construct the air electrode.
- reaction of fuel is
- LiAIH4, KH and NaH, etc. is dissolved in an alkali aqueous solution is used,
- coated catalytic layer 221 disturbs movement of hydrogen ions toward to the
- catalytic action is active only on a side of the catalytic layer 221, on the
- MEA membrane electrode assembly
- a MEA of a fuel cell in accordance with the present invention includes an electrolyte membrane
- Figure 1 is a sectional view illustrating a general fuel cell
- Figure 2 is an exploded-perspective view illustrating the general fuel
- FIG. 3 is a sectional view illustrating a MEA (membrane electrode
- Figure 4 is a sectional view illustrating a MEA of a fuel cell in
- Figure 5 is a perspective view illustrating a catalyst electrode of the MEA of the fuel cell in accordance with the present invention.
- Figures 6 and 7 are perspective views respectively illustrating
- Figure 8 is a sectional view illustrating an operation state of the MEA
- FIG. 4 is a front-sectional view illustrating a MEA (membrane
- the present invention includes an electrolyte membrane 500 as an ion
- an open fuel side open groove 410 having a
- the air side open groove 420 are formed on the plate 430.
- the bottom of the fuel side open groove 410 is plane.
- a straight path can be formed on the bottom of the fuel side
- the electrolyte membrane 500 is formed as a sheet metal having a
- the electrolyte membrane 500 is placed between the two bipolar
- a fuel path in which fuel flows is formed by the fuel side open groove
- the catalyst electrode 510 is formed so as to have a certain
- the catalyst electrode 510 is inserted into the fuel path
- the catalyst electrode 510 is formed as a corrugate shape having a certain
- the catalyst has a thickness and area so as to increase a contact area with fuel.
- electrode 510 has a certain thickness and a section in which hemispheres
- plural through holes (H) may be formed on both
- the catalyst electrode 510 is formed as a folded shape having a
- catalyst electrode 510 has a certain thickness, a section thereof is formed as
- plural through holes (H) may be formed on both ends or inside the
- plural through holes (H) may be formed on both ends or inside
- the catalyst electrode 510 is made of a fiber material, in more detail,
- the catalyst electrode 510 can be made of
- the fuel is an electrolyte solution having a
- the air electrode 520 on the air side open groove 420 is adhered to
- the air electrode 520 can be separately fabricated and inserted into
- the bottom of the fuel side open groove 410 is plane.
- the bipolar plates 400 and the electrolyte membrane 500 are
- plates 400 can be two (pair) or not less than two. When there is a pair of
- outflow path 450 are formed on a side of the bipolar plate 400, and the air
- KBH4, LiAIH4, KH and NaH, etc. is dissolved in an alkali aqueous solution
- the fuel flowing into the inflow path 440 flows through the fuel path
- the electrons are moved to the air electrode 520, and the hydrogen ions are
- oxygen occurs on the air electrode 520 of the electrolyte membrane 500.
- the fuel passing the fuel path flows out through the outflow path 450,
- ions generated by the catalyst electrode 510 can be moved to the air
- the catalyst electrode 510 is formed as a
- electrochemical oxidation reaction occurs, ion generation can be activated, a region in which hydrogen ions are moved to an air electrode, namely, a
- reaction on the air electrode can be activated more
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Materials Engineering (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/KR2003/002663 WO2005055357A1 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
AU2003304597A AU2003304597A1 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
EP03819100A EP1702382A1 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
US10/483,812 US7318975B2 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
CNB2003801107928A CN100442589C (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/KR2003/002663 WO2005055357A1 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005055357A1 true WO2005055357A1 (en) | 2005-06-16 |
Family
ID=34631997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2003/002663 WO2005055357A1 (en) | 2003-12-05 | 2003-12-05 | Membrane electrode assembly of fuel cell |
Country Status (5)
Country | Link |
---|---|
US (1) | US7318975B2 (en) |
EP (1) | EP1702382A1 (en) |
CN (1) | CN100442589C (en) |
AU (1) | AU2003304597A1 (en) |
WO (1) | WO2005055357A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101290998B (en) * | 2007-04-17 | 2012-05-23 | 上海清能燃料电池技术有限公司 | Self-humidifying electrochemical device |
US11374242B2 (en) * | 2019-04-06 | 2022-06-28 | Mark Minto | Methods and apparatus for decoupling reactant activation and reaction completion |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001059865A1 (en) * | 2000-02-08 | 2001-08-16 | Honeywell International Inc. | Wicking strands for a polymer electrolyte membrane fuel cell |
EP1286408A2 (en) * | 2001-08-16 | 2003-02-26 | Asia Pacific Fuel Cell Technologies, Ltd. | Modular single cell and assembled cell stack of a proton exchange membrane fuel cell |
US20030175577A1 (en) * | 2002-03-18 | 2003-09-18 | Rock Jeffrey Allan | Converging/diverging flow channels for fuel cell |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1141601A (en) * | 1965-02-24 | 1969-01-29 | Hovercraft Dev Ltd | Improvements relating to gas-cushion vehicles |
FR2302600A1 (en) * | 1975-02-25 | 1976-09-24 | Inst Francais Du Petrole | NEW IMPROVEMENT IN FUEL CELLS |
NL7502842A (en) * | 1975-03-11 | 1976-09-14 | Stamicarbon | POROUS ELECTRODE. |
KR0124985B1 (en) * | 1994-08-17 | 1997-12-15 | 심상철 | Akaline fuel cell |
US5879828A (en) * | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
-
2003
- 2003-12-05 US US10/483,812 patent/US7318975B2/en not_active Expired - Fee Related
- 2003-12-05 EP EP03819100A patent/EP1702382A1/en not_active Withdrawn
- 2003-12-05 WO PCT/KR2003/002663 patent/WO2005055357A1/en active Application Filing
- 2003-12-05 CN CNB2003801107928A patent/CN100442589C/en not_active Expired - Fee Related
- 2003-12-05 AU AU2003304597A patent/AU2003304597A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001059865A1 (en) * | 2000-02-08 | 2001-08-16 | Honeywell International Inc. | Wicking strands for a polymer electrolyte membrane fuel cell |
US6555262B1 (en) * | 2000-02-08 | 2003-04-29 | Hybrid Power Generation Systems, Llc | Wicking strands for a polymer electrolyte membrane |
EP1286408A2 (en) * | 2001-08-16 | 2003-02-26 | Asia Pacific Fuel Cell Technologies, Ltd. | Modular single cell and assembled cell stack of a proton exchange membrane fuel cell |
US20030175577A1 (en) * | 2002-03-18 | 2003-09-18 | Rock Jeffrey Allan | Converging/diverging flow channels for fuel cell |
Also Published As
Publication number | Publication date |
---|---|
EP1702382A1 (en) | 2006-09-20 |
US20050123820A1 (en) | 2005-06-09 |
AU2003304597A1 (en) | 2005-06-24 |
US7318975B2 (en) | 2008-01-15 |
CN100442589C (en) | 2008-12-10 |
CN1879245A (en) | 2006-12-13 |
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