WO2005054381A1 - Preparations colorantes a base de solvants pour impression par jet d'encre - Google Patents

Preparations colorantes a base de solvants pour impression par jet d'encre Download PDF

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Publication number
WO2005054381A1
WO2005054381A1 PCT/EP2004/013434 EP2004013434W WO2005054381A1 WO 2005054381 A1 WO2005054381 A1 WO 2005054381A1 EP 2004013434 W EP2004013434 W EP 2004013434W WO 2005054381 A1 WO2005054381 A1 WO 2005054381A1
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WO
WIPO (PCT)
Prior art keywords
pigment
weight
colorant
ink
pigment red
Prior art date
Application number
PCT/EP2004/013434
Other languages
English (en)
Inventor
Mike Husbands
Sarup Panesar
Heidemarie Menzel
Klaus Saitmacher
Original Assignee
Clariant Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Gmbh filed Critical Clariant Gmbh
Publication of WO2005054381A1 publication Critical patent/WO2005054381A1/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/16Writing inks
    • C09D11/17Writing inks characterised by colouring agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/023Emulsion inks
    • C09D11/0235Duplicating inks, e.g. for stencil printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/34Hot-melt inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/36Inkjet printing inks based on non-aqueous solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/40Ink-sets specially adapted for multi-colour inkjet printing

Definitions

  • a fine state of subdivision is a basic prerequisite for pigment preparations for use in ink jet printing, since the avoidance of nozzle clogging requires that the average pigment particle size not exceed 200 nm, ideally 150 nm, and that the particle size distribution be very narrow, so that even the maximum particle size does not exceed 500 nm.
  • it is particularly the flocculation resistance which is a very important quality criterion of an ink jet preparation, which is why crystal growth or agglomeration of the pigment particles has to be effectively prevented by means of suitable additives. This is usually accomplished by means of certain dispersing assistants.
  • the dispersing assistant used is of decisive importance, not only because it determines the physical properties, for example surface tension and viscosity, of the dispersions, but also because it shall stabilize the inks against flocculation in the course of storage and deterioration in the course of the printing operation.
  • the dispersant has much influence on the droplet formation during the printing process. A uniform droplet formation free of satellites is prerequisite for high performance ink-jet prints , e.g. in photoprinting.
  • WO 00/20519 discloses pigment dispersions of inorganic pigments for ink-jet printing containing several dispersants for inorganic pigments.
  • the stability problems of pigmented ink jet inks are closely related to 10 adequate stabilization of the pigment particles in the solvent based suspensions.
  • E 0 to 30% by weight and preferably 0.1 to 10% by weight of vinylchloride- vinylacetate copolymer
  • F 0 to 10% by weight and preferably 0.1 to 5% by weight of a polymeric dispersant having a molecular mass of from 1000 to 500,000 g/mol
  • G 0 to 10% by weight and preferably 0.1 to 5% by weight of further standard additives for ink-jet preparations, each percentage being based on the total weight of the colorant preparation (100% by weight).
  • Component (A) is a finely divided organic or inorganic pigment and/or organic dye or a mixture of various organic and/or inorganic pigments and/or organic dyes.
  • the pigments are preferably used in the form of dry powders.
  • Useful organic pigments include a monoazo, disazo, laked azo, ⁇ -naphthol, Naphtol AS, benzimidazolone, disazo condensation, azo metal complex pigment or a polycyclic pigment, such as for example a phthalocyanine, quinacridone, perylene, perinone, thiazineindigo, thioindigo, anthanthrone, anthraquinone, flavanthrone, indanthrone, isoviolanthrone, pyranthrone, dioxazine, quinophthalone, isoindolinone, isoindoline or diketopyrrolopyrrole pigment or carbon black.
  • a phthalocyanine quinacridone, perylene, perinone, thiazineindigo, thioindigo, anthanthrone, anthraquinone, flavanthrone, indanthrone, isoviolanthrone, pyr
  • Useful inorganic pigments include for example titanium dioxides, zinc sulfides, iron oxides, chromium oxides, ultramarine, nickel- or chromium antimony titanium oxides, cobalt oxides and bismuth vanadates.
  • Useful organic dyes include acid dyes, dispersion dyes, direct dyes, sulfur dyes, metalcomplex dyes or reactive dyes; in the case of reactive dyes, dyes which have been reacted with nucleophiles can be used as well.
  • the pigments used should have a light fastness higher than 5, preferably higher than 6 (determined by means of a blue scale).
  • the pigments used should be very finely divided, in that 95% (preferably 99%) of the pigment particles should have a particle size ⁇ 500 nm.
  • the average particle size is preferably ⁇ 150 nm.
  • the morphology of the pigment particles can vary widely, and accordingly the viscosity behavior of the pigment preparations can vary widely as a function of the particle shape. To obtain a favorable viscosity behavior for the preparations, the particles should preferably have a cuboid or spherical shape. Preferred are pure or, where necessary, purified pigments with very low organic or inorganic impurities.
  • a selection of particularly preferred organic pigments are carbon black pigments, for example lampblacks or furnace blacks; monoazo and disazo pigments, especially the Colour Index pigments Pigment Yellow 1 , Pigment Yellow 3, Pigment Yellow 12, Pigment Yellow 13, Pigment Yellow 14, Pigment Yellow 16, Pigment Yellow 17, Pigment Yellow 73, Pigment Yellow 74, Pigment Yellow 81 , Pigment Yellow 83, Pigment Yellow 87, Pigment Yellow 97, Pigment Yellow 111, Pigment Yellow 126, Pigment Yellow 127, Pigment Yellow 128, Pigment Yellow 155, Pigment Yellow 174, Pigment Yellow 176, Pigment Yellow 191, Pigment Yellow 213, Pigment Yellow 214, Pigment Red 38, Pigment Red 144, Pigment Red 214, Pigment Red 242, Pigment Red 262, Pigment Red 266, Pigment Red 269, Pigment Red 274, Pigment Orange 13, Pigment Orange 34 or Pigment Brown 41 ; ⁇ -naphthol- und Naphthol AS-pigments, especially the Colour Index Pigments Pigment Red 2, Pigment Red
  • Examples of especially preferred organic dyes are the Colour Index dyes Acid Yellow 17, Acid Yellow 23, Direct Yellow 86, Direct Yellow 98, Direct Yellow 132, Reactive Yellow 37, Acid Red 52, Acid Red 289, Reactive Red 23, Reactive Red 180, Acid Blue 9, Direct Blue 199 and reactive dyes reacted with nucleophiles.
  • Component (B) is preferably a compound of the formula wherein
  • R ⁇ , R 2 and R 3 independently of each other are a substituted or unsubstituted, branched or straight-chain CrC 2 o-alkyl- or C 3 -C 2 o-cycloalkyl or a substituted or unsubstituted, branched or straight-chain C 2 -C 2 o-alkenyl- or C 3 -C 2 o-cycloalkenyl, wherein the substituents are preferably 1 , 2, 3 or 4 substituents selected from the group consisting of halogen, aryl, aryl(CrC 2 o)alkyl, C 5 -C 6 -cycloalkyl, hetaryl, hetaryl(CrC 20 )alkyl or C ⁇ -C 2 o-alkoxy, and n is a number of from 1 to 100, especially 1 to 20.
  • R-i, R 2 and R 3 are C ⁇ 2 -C ⁇ 8 -alkyl (branched or straight-chain) or C-i2-Ci 8 -alkenyl (branched or straight-chain), which are substituted by 1 , 2, 3 or 4 substituents selected from the group consisting of halogen, aryl, aryl(C ⁇ -C4)alkyl, hetaryl, hetaryl(C ⁇ -C 4 )alkyl or CrC4-alkoxy.
  • R-i, R 2 and R 3 are C ⁇ 2 -C ⁇ 8 -alkyl (branched or straight-chain) or C-i2-Ci 8 -alkenyl (branched or straight-chain), which are substituted by 1 , 2, 3 or 4 substituents selected from the group consisting of halogen, aryl, aryl(C ⁇ -C4)alkyl, hetaryl, hetaryl(C ⁇ -C 4 )alkyl or CrC4-al
  • HandHetaryl means herein an aromatic radical, having preferably 1 to 10 carbon atoms and 1 , 2, 3 or 4 heteroatoms selected from the group consisting of O, N, S or P.
  • Examples are pyrrolyl, furyl, thiophenyl, indolyl, isoindolyl, indolizinyl, benzofuryl, benzothiophenyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, triazolyl, tetrazolyl, pyridyl, quinolinyl, isoquinolinyl, pyridazinyl, pyrimidinyl, pyrazinyl and triazinyl.
  • organic solvents (component B) are: CH3-0-CH 2 -CH(CH 3 )-0-CO-CH3
  • Component C is preferably an urea/formaldehyde resin, wherein the aldehyde is preferably a C ⁇ -C 4 -aldehyde, especially formaldehyde, or an aliphatic dialdehyde, such as glyoxal.
  • Urea/formaldehyde resins are commercially available under the trade name ⁇ Laropal (BASF). These products are low-molecular condensation products of urea and aliphatic aldehydes, having a softening point between 70 and 110°C.
  • the colorant compositions according to the invention can be employed for the pigmenting of high-molecular-weight organic materials of natural or synthetic origin, for example of plastics, resins, surface coatings, paints, electrophotographic toners and developers, electret materials, colour filters and of writing and printing inks and seed.
  • High-molecular-weight organic materials which can be coloured with the colorant preparations according to the invention are, for example, cellulose compounds, such as, for example, cellulose ethers and esters, such as ethylcellulose, nitrocellulose, cellulose acetates or cellulose butyrates, natural binders, such as, for example, fatty acids, fatty oils, resins and conversion products thereof, or synthetic resins, such as polycondensates, polyadducts, polyaddition and copolyaddition products, such as, for example, amino plastics, in particular urea- and melamine-formaldehyde resins, alkyd resins, acrylic resins, phenolics and phenol resins, such as novolaks or resols, urea resins, polyvinyls, such as polyvinyl alcohols, polyvinyl acetals, polyvinyl acetates or polyvinyl ethers, polycarbonates, polyolefins, such
  • the colorant preparations according to the invention are also suitable as colorants in electrophotographic toners and developers, such as, for example, one- or two- component powder toners (also known as one- or two-component developers), magnetic toners, liquid toners, latex toners, polymerization toners and special toners.
  • electrophotographic toners and developers such as, for example, one- or two- component powder toners (also known as one- or two-component developers), magnetic toners, liquid toners, latex toners, polymerization toners and special toners.
  • Typical curing-agent components are, for example, acid anhydrides, imidazoles and dicyandiamide and derivatives thereof, blocked isocyanates, bisacylurethanes, phenol and melamine resins, triglycidyl isocyanurates, oxazolines and dicarboxylic acids.
  • the invention furthermore relates to the use of the colorant preparation described as colorant for printing inks, in particular for ink-jet inks.
  • ink-jet inks is taken to mean both water-based (including microemulsion inks) and solvent-based inks, UV-curable inks and inks which work by the hot-melt process.
  • UV-curable inks essentially comprise from 0.5 to 30% by weight of one or more of the colorant preparations according to the invention, from 0.5 to 95% by weight of water, from 0.5 to 95% by weight of an organic solvent or solvent mixture, from 0.5 to 50% by weight of a radiation-curable binder and, if desired, from 0 to 10% by weight of a photoinitiator.
  • the colorant preparations according to the invention facilitate low viscosities, which is of major importance, in particular, for applications in the ink-jet area, and rapid migration of the dispersant to the ink-droplet surface newly forming during the printing operation and thus stable and uniform droplet formation. In this way, ink-jet prints of high quality are possible.
  • a further problem which is frequently associated with the use of polymers in ink-jet inks is their tendency to solidify in the nozzles of the printing head, which results in nozzle clogging and thus in poor printing behaviour. This type of failure of the nozzles is not observed on use of the colorant preparation according to the invention, which facilitates streak-free and thus uniform printing.
  • the printing inks according to the invention are suitable for use in all conventional ink-jet printers, in particular for those based on the bubble-jet or piezo method.
  • the corresponding pigment is formed into a paste together with the other components and then homogenized using a dissolver ( ⁇ Pendraulik, model LD 50) or another suitable apparatus and pre-dispersed.
  • the subsequent microdispersion was carried out with the aid of a bead mill (VMA-Getzmann Dispermat model AE-6-C or a MiniZETA 03 from Netzsch), with the grinding being carried out with cooling to the desired particle- size distribution of the pigment particles.
  • the dispersion was subsequently adjusted to the desired final pigment concentration using solvent component (B).
  • the pigment preparations described in the following examples were prepared by the process described above, with the following constituents being used in the stated amounts so as to give 100 parts of the respective pigment preparation:
  • the composition of the test inks here was selected in such a way that the viscosity was in the range from 1.5 to 5 mPas.
  • the viscosity was determined using a Haake RS1 plate-and-cone viscometer at a temperature of 20°C, with the dependence of the viscosity on the shear rate being investigated in the range from 0 to 700 s "1 .
  • the viscosity values shown in Table 2 were measured at a shear rate of 400 s "1 .
  • the viscosity was measured directly after preparation and after storage at 60°C for four weeks.
  • the viscosities of the fresh samples are without exception between 3 and 9 mPas and are thus below 15 mPas.
  • the measurement results show that storage at 60°C causes only very slight changes in viscosity, i.e. the dispersions are stable on storage.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

L'invention concerne des préparations colorantes à base de solvants, comprenant (A) un colorant organique et/ou inorganique, (B) un solvant organique, (C) une résine aldéhyde, (D) un sel d'alkylammonium d'un polymère acide, (E) éventuellement un copolymère chlorure de vinyle-acétate de vinyle, (F) éventuellement un dispersant polymérique ayant un poids moléculaire compris entre 500 et 500'000 g/mol et (G) éventuellement d'autres additifs standard.
PCT/EP2004/013434 2003-12-06 2004-11-26 Preparations colorantes a base de solvants pour impression par jet d'encre WO2005054381A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0328340.5 2003-12-06
GB0328340A GB0328340D0 (en) 2003-12-06 2003-12-06 Solvent based colorant preparations for ink jet printing

Publications (1)

Publication Number Publication Date
WO2005054381A1 true WO2005054381A1 (fr) 2005-06-16

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008012848A1 (fr) * 2006-07-28 2008-01-31 Inxel Trademark & Patents Sagl Enrobage de pigments inorganiques effectué à l'aide d'un aldéhyde ou de résines de cétone
EP1911816A1 (fr) * 2006-10-11 2008-04-16 Agfa Graphics N.V. Encres non aqueuse et pigmentées pour jet d' encres
WO2010112427A1 (fr) 2009-03-31 2010-10-07 Solvay Sa Procédé de préparation du pigment violet facilement dispersible
US20110012072A1 (en) * 2008-01-10 2011-01-20 Clariant Finance (Bvi) Limited Use of Hydrophobic Solvent-Based Pigment Preparations in Electronic Displays
US8007906B2 (en) 2005-02-07 2011-08-30 Inxel Trademark & Patents Sagl Coating of organic and inorganic pigments with aldehyde or ketone resins
US8329781B2 (en) 2005-07-08 2012-12-11 INXEL Trademarks & Patents SAGL Thermosetting powder paints
US8575242B2 (en) 2006-01-16 2013-11-05 Ppg Industries Ohio, Inc. Coating of organic and inorganic pigments with acrylic resins
EP2670810A1 (fr) * 2011-01-31 2013-12-11 Hewlett-Packard Development Company, L.P. Encres pour jet d'encre thermique à base d'émulsion
CN105820661A (zh) * 2015-01-23 2016-08-03 佳能株式会社 水性墨、墨盒和喷墨记录方法
CN114080433A (zh) * 2019-06-25 2022-02-22 地板技术有限公司 用于制造至少一种设有印刷装饰的载体材料的方法
CN115537053A (zh) * 2022-10-10 2022-12-30 张垚 一种绝缘粉末涂料及其制备方法
CN116396636A (zh) * 2023-04-04 2023-07-07 佛山市三水区康立泰无机合成材料有限公司 一种陶瓷喷墨打印用黑色色料及其制备方法和应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047419A1 (fr) * 1999-02-09 2000-08-17 Source Technologies, Inc. Formulation d'encre a particules aciculaires pour systeme d'imprimante a jet d'encre
WO2000063305A1 (fr) * 1999-04-16 2000-10-26 Gem Gravure Company, Inc. Encre pigmentee opaque, stable et non sedimentable pour imprimante a jet d'encre
US20020055619A1 (en) * 2000-10-05 2002-05-09 Clariant Gmbh Process for preparing azo colorants
WO2002046322A2 (fr) * 2000-12-06 2002-06-13 Printar Ltd. Encre thermodurcissable pour imprimante a jet d'encre, utilisee pour l'impression de legendes sur des circuits imprimes
EP1327915A1 (fr) * 2002-01-08 2003-07-16 Samsung Electronics Co., Ltd. Encre liquide comprenant des organosols stabilisants
WO2003076520A2 (fr) * 2002-03-11 2003-09-18 Ciba Specialty Chemicals Holding Inc. Pigments brillants fortement satures

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000047419A1 (fr) * 1999-02-09 2000-08-17 Source Technologies, Inc. Formulation d'encre a particules aciculaires pour systeme d'imprimante a jet d'encre
WO2000063305A1 (fr) * 1999-04-16 2000-10-26 Gem Gravure Company, Inc. Encre pigmentee opaque, stable et non sedimentable pour imprimante a jet d'encre
US20020055619A1 (en) * 2000-10-05 2002-05-09 Clariant Gmbh Process for preparing azo colorants
WO2002046322A2 (fr) * 2000-12-06 2002-06-13 Printar Ltd. Encre thermodurcissable pour imprimante a jet d'encre, utilisee pour l'impression de legendes sur des circuits imprimes
EP1327915A1 (fr) * 2002-01-08 2003-07-16 Samsung Electronics Co., Ltd. Encre liquide comprenant des organosols stabilisants
WO2003076520A2 (fr) * 2002-03-11 2003-09-18 Ciba Specialty Chemicals Holding Inc. Pigments brillants fortement satures

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8007906B2 (en) 2005-02-07 2011-08-30 Inxel Trademark & Patents Sagl Coating of organic and inorganic pigments with aldehyde or ketone resins
EP2597122A1 (fr) * 2005-02-07 2013-05-29 Inxel Trademark & Patents SAGL Enrobage de pigments organiques et inorganiques avec résines d'aldéhyde ou de cétone
US8329781B2 (en) 2005-07-08 2012-12-11 INXEL Trademarks & Patents SAGL Thermosetting powder paints
US8575242B2 (en) 2006-01-16 2013-11-05 Ppg Industries Ohio, Inc. Coating of organic and inorganic pigments with acrylic resins
JP2009544792A (ja) * 2006-07-28 2009-12-17 インクセル トレードマーク アンド パテンツ エスエージーエル アルデヒド樹脂又はケトン樹脂を有する無機顔料のコーティング
JP2013241616A (ja) * 2006-07-28 2013-12-05 Inxel Trademark & Patents Sagl アルデヒド樹脂又はケトン樹脂を有する無機顔料のコーティング
WO2008012848A1 (fr) * 2006-07-28 2008-01-31 Inxel Trademark & Patents Sagl Enrobage de pigments inorganiques effectué à l'aide d'un aldéhyde ou de résines de cétone
CN101501146B (zh) * 2006-07-28 2012-01-25 因艾克斯塞尔商标专利公司 用醛或酮树脂涂覆无机颜料
AU2006346657B2 (en) * 2006-07-28 2012-12-06 Ppg Industries Ohio, Inc. Coating of inorganic pigments with aldehyde or ketone resins
EP1911816A1 (fr) * 2006-10-11 2008-04-16 Agfa Graphics N.V. Encres non aqueuse et pigmentées pour jet d' encres
WO2008043681A1 (fr) * 2006-10-11 2008-04-17 Agfa Graphics Nv Encres pigmentées non aqueuses pour l'impression par jet d'encre
US8093312B2 (en) 2006-10-11 2012-01-10 Agfa Graphics Nv Non-aqueous pigmented inkjet inks
US20110012072A1 (en) * 2008-01-10 2011-01-20 Clariant Finance (Bvi) Limited Use of Hydrophobic Solvent-Based Pigment Preparations in Electronic Displays
WO2010112427A1 (fr) 2009-03-31 2010-10-07 Solvay Sa Procédé de préparation du pigment violet facilement dispersible
EP2670810A1 (fr) * 2011-01-31 2013-12-11 Hewlett-Packard Development Company, L.P. Encres pour jet d'encre thermique à base d'émulsion
EP2670810A4 (fr) * 2011-01-31 2014-04-16 Hewlett Packard Development Co Encres pour jet d'encre thermique à base d'émulsion
US8894761B2 (en) 2011-01-31 2014-11-25 Hewlett-Packard Development Company, L.P. Emulsion-based thermal inkjet inks
CN105820661A (zh) * 2015-01-23 2016-08-03 佳能株式会社 水性墨、墨盒和喷墨记录方法
CN105820661B (zh) * 2015-01-23 2019-04-19 佳能株式会社 水性墨、墨盒和喷墨记录方法
CN114080433A (zh) * 2019-06-25 2022-02-22 地板技术有限公司 用于制造至少一种设有印刷装饰的载体材料的方法
CN115537053A (zh) * 2022-10-10 2022-12-30 张垚 一种绝缘粉末涂料及其制备方法
CN116396636A (zh) * 2023-04-04 2023-07-07 佛山市三水区康立泰无机合成材料有限公司 一种陶瓷喷墨打印用黑色色料及其制备方法和应用
CN116396636B (zh) * 2023-04-04 2023-11-14 佛山市三水区康立泰无机合成材料有限公司 一种陶瓷喷墨打印用黑色色料及其制备方法和应用

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