WO2005051661A1 - A process for the manufacturing of decorative laminate - Google Patents

A process for the manufacturing of decorative laminate Download PDF

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Publication number
WO2005051661A1
WO2005051661A1 PCT/SE2004/001723 SE2004001723W WO2005051661A1 WO 2005051661 A1 WO2005051661 A1 WO 2005051661A1 SE 2004001723 W SE2004001723 W SE 2004001723W WO 2005051661 A1 WO2005051661 A1 WO 2005051661A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
process according
decor
wear layer
amino resin
Prior art date
Application number
PCT/SE2004/001723
Other languages
French (fr)
Inventor
Krister Hansson
Kent Lindgren
Original Assignee
Pergo (Europe) Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=29729162&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2005051661(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Pergo (Europe) Ab filed Critical Pergo (Europe) Ab
Priority to US10/580,219 priority Critical patent/US20070113970A1/en
Priority to EP04800384A priority patent/EP1697133B2/en
Priority to PL04800384T priority patent/PL1697133T5/en
Priority to DE602004013370T priority patent/DE602004013370T3/en
Priority to ES04800384T priority patent/ES2304632T5/en
Priority to DK04800384.2T priority patent/DK1697133T4/en
Publication of WO2005051661A1 publication Critical patent/WO2005051661A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/08—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • B44C5/0476—Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper with abrasion resistant properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine

Definitions

  • the present invention relates to a process for the manufacturing of a decorative laminate with increased laminar bond.
  • thermosetting laminate is common in many areas nowadays. They are mostly used where the demands on abrasion resistance are high, and furthermore where resistance to different chemicals and moisture is desired. As examples of such products floors, floor skirting, table tops, work tops and wall panels can be mentioned.
  • the thermosetting laminate most often consist of a number of base sheets with a decor sheet placed closest to the surface.
  • the decor sheet can be provided with a pattern by desire. Common patterns usually visualise different kinds of wood or mineral such as marble and granite.
  • the substrate carrying the decor often consist of a cellulose sheet on which the decor is printed. It is also known to use polymeric or polymer/cellulose blend materials as a decor carrier on which the decor is printed.
  • the decor sheet will need some protection and it is known to use one or more layers of cellulose impregnated with thermosetting resin arranged on top of the decor layer. It is known that the printing ink itself sometimes will cause problems with de-lamination, especially when certain pigments, solvents and amounts of ink is used. This is a problem which sometimes occur after some time of use.
  • the invention relates to a process for the manufacturing of a decorative laminate having a base layer, a decorative layer and a wear layer.
  • a decor is printed on a base layer wherein the decor printed comprises a printing ink.
  • the wear layer comprises a thermosetting resin selected from the group consisting of; melamine-formaldehyde resin, phenol-formaldehyde resin, urea formaldehyde resin and mixtures thereof.
  • the invention is characterised in that an amount of amino resin is mixed into the printing ink in order to increase the bond between the decorative layer and the wear layer.
  • the layers are then laminated together in a laminate press under increased temperature and pressure.
  • the printing ink is suitably an alkyde based ink or a polyester-acrylate based ink.
  • the amino resin added to the ink is preferably an etherified amino resin or a methylol amino resin.
  • the base layer may, according to one embodiment of the invention, be manufactured in the desired end user format and provided with edges intended for joining before applying decor and wear layer.
  • a main part of the base layer is suitably constituted by a particle board or a fibre board. It is advantageous to provide the base layer with a paper layer on which the decor is printed. This paper layer is suitably bonded to the base layer prior to the printing of the decor.
  • the wear layer is, according to one embodiment of the invention comprised of a high viscosity amino resin applied on top of the decorative layer prior to the lamination.
  • the wear layer is comprised of an amino resin / cellulose mixture.
  • the wear layer is comprised of one or more amino resin impregnated cellulose layer or layers. In order to increase the abrasion resistance it is advantageous to add hard particles with an average particle size in the range 50nm - 150 ⁇ m to the wear layer.
  • the wear layer is suitably provided with hard particles with an average particle size in the range 50nm - 30 ⁇ m while the inner portion of the wear layer is provided with hard particles with an average particle size in the range 31 ⁇ m - 150 ⁇ m.
  • the hard particles is preferably constituted by silicon oxide, silicon carbide, aluminium oxide or the like.
  • the wear layer is suitably provided with a surface structure that enhances the realistic impression of the decor during or after the lamination. This is suitably achieved by any known method of embossing.
  • the decor is achieved by digitisation of an actual archetype or by partly or completely being created in a digital media.
  • the digitised decor is stored digitally in order to be used as a control function and original, together with possible control programs, when printing the decor.
  • the decor may accordingly be obtained by making a high resolution or selected resolution digital picture of the desired decor. This is suitably made by means of a digital camera or scanner.
  • the most common decor will of course be different kinds of wood and minerals like marble, as these probably will continue to be preferred surface decoration in home and public environments. It is, however, possible to depict anything that is visible.
  • the digitised version of the decor is then edited to fit the size of the supporting core.
  • the digital decor is used together with guiding programs to control a printer.
  • the printer may be of an electrostatic type or an ink -jet type printer.
  • the colours yellow, magenta, cyan and black will be sufficient for the printing process, but in some cases it might be advantageous to add white.
  • Some colours are difficult to achieve using the colours yellow, magenta, cyan, black and white whereby the colours light magenta and light cyan may be added.
  • spot colours where specific colour tones are difficult to achieve or where only certain parts of the colour spectrum with intermixing shades is desired.
  • the resolution needed is much depending on the decor that is to be simulated, but resolutions of 10 - 1500 dots per inch (dpi) is the practical range in which most decors will be printed.
  • the translucent wear layer is suitably constituted of melamine-formaldehyde resin / cellulose blend, high viscosity melamine- formaldehyde or one or more sheets of cellulose which are impregnated with melamine-formaldehyde resin.
  • This wear layer is joined with the core and decor under heat and pressure whereby the resin cures. It is advantageous to add hard particles with an average particle size in the range 50 nm - 150 ⁇ m to the wear layer.
  • the particles in the range 10 ⁇ m - 150 ⁇ m, preferably 30 ⁇ m - 150 ⁇ m is foremost used to achieve abrasion resistance while the smaller of the particles, in the range 50 nm - 30 ⁇ m, preferably 50 nm - 10 ⁇ m, is used to achieve scratch resistance.
  • the smaller particles is hereby used on, or very close to, the top surface while the larger particles may be distributed in the wear layer.
  • the particles advantageously are constituted of silicon carbide, silicon oxide, aluminium oxide.
  • the wear layer is hereby suitably pressed together with the rest of the decorative laminate in a continuos belt press with two steel belts. It is also possible to utilise a discontinuous process where one or a number of surface elements can be pressed at the same time.

Abstract

A process for the manufacturing of a decorative laminate having a base layer, a decorative layer and a wear layer wherein a decor is printed on a base layer. The decor printed comprises a printing ink and the wear layer comprises a thermosetting resin selected from the group consisting of; melamine-formaldehyde resin, phenol-formaldehyde resin, urea formaldehyde resin and mixtures thereof. An amount of amino resin is mixed into the printing ink in order to increase the bond between the decorative layer and the wear layer. The layers are laminated together in a laminate press under increased temperature and pressure.

Description

A process for the manufacturing of decorative laminate.
The present invention relates to a process for the manufacturing of a decorative laminate with increased laminar bond.
Products clad with thermosetting laminate is common in many areas nowadays. They are mostly used where the demands on abrasion resistance are high, and furthermore where resistance to different chemicals and moisture is desired. As examples of such products floors, floor skirting, table tops, work tops and wall panels can be mentioned. The thermosetting laminate most often consist of a number of base sheets with a decor sheet placed closest to the surface. The decor sheet can be provided with a pattern by desire. Common patterns usually visualise different kinds of wood or mineral such as marble and granite. The substrate carrying the decor often consist of a cellulose sheet on which the decor is printed. It is also known to use polymeric or polymer/cellulose blend materials as a decor carrier on which the decor is printed. The decor sheet will need some protection and it is known to use one or more layers of cellulose impregnated with thermosetting resin arranged on top of the decor layer. It is known that the printing ink itself sometimes will cause problems with de-lamination, especially when certain pigments, solvents and amounts of ink is used. This is a problem which sometimes occur after some time of use.
It has, through the present invention, been made possible to overcome the above mentioned problems and a decorative laminate where the bond between decor layer and supporting layers is increased has been obtained. The invention relates to a process for the manufacturing of a decorative laminate having a base layer, a decorative layer and a wear layer. A decor is printed on a base layer wherein the decor printed comprises a printing ink. The wear layer comprises a thermosetting resin selected from the group consisting of; melamine-formaldehyde resin, phenol-formaldehyde resin, urea formaldehyde resin and mixtures thereof. The invention is characterised in that an amount of amino resin is mixed into the printing ink in order to increase the bond between the decorative layer and the wear layer. The layers are then laminated together in a laminate press under increased temperature and pressure. The printing ink is suitably an alkyde based ink or a polyester-acrylate based ink. The amino resin added to the ink is preferably an etherified amino resin or a methylol amino resin. The base layer may, according to one embodiment of the invention, be manufactured in the desired end user format and provided with edges intended for joining before applying decor and wear layer. A main part of the base layer is suitably constituted by a particle board or a fibre board. It is advantageous to provide the base layer with a paper layer on which the decor is printed. This paper layer is suitably bonded to the base layer prior to the printing of the decor.
The wear layer is, according to one embodiment of the invention comprised of a high viscosity amino resin applied on top of the decorative layer prior to the lamination. According to another embodiment of the invention the wear layer is comprised of an amino resin / cellulose mixture. According to yet another embodiment of the invention the wear layer is comprised of one or more amino resin impregnated cellulose layer or layers. In order to increase the abrasion resistance it is advantageous to add hard particles with an average particle size in the range 50nm - 150μm to the wear layer. In order to increase both scratch resistance and wear resistance the wear layer is suitably provided with hard particles with an average particle size in the range 50nm - 30μm while the inner portion of the wear layer is provided with hard particles with an average particle size in the range 31 μm - 150 μm. The hard particles is preferably constituted by silicon oxide, silicon carbide, aluminium oxide or the like. The wear layer is suitably provided with a surface structure that enhances the realistic impression of the decor during or after the lamination. This is suitably achieved by any known method of embossing.
According to one embodiment of the invention the decor is achieved by digitisation of an actual archetype or by partly or completely being created in a digital media. The digitised decor is stored digitally in order to be used as a control function and original, together with possible control programs, when printing the decor. The decor may accordingly be obtained by making a high resolution or selected resolution digital picture of the desired decor. This is suitably made by means of a digital camera or scanner. The most common decor will of course be different kinds of wood and minerals like marble, as these probably will continue to be preferred surface decoration in home and public environments. It is, however, possible to depict anything that is visible. The digitised version of the decor is then edited to fit the size of the supporting core. It is also possible to rearrange the decor in many different ways, like changing colour tones, contrast, dividing the decor into smaller segments and adding other decorative elements. It is also possible to completely create the decor in a computer equipped for graphic design. It is possible to create a simulated decor so realistic that even a professional will have great problems in visually separating it from genuine material. This makes it possible to make for example floor boards with an almost perfect illusion of a rare kind of wood, like ebony or rose wood and still preserving trees under threat of extermination. The digital decor is used together with guiding programs to control a printer. The printer may be of an electrostatic type or an ink -jet type printer. Most often the colours yellow, magenta, cyan and black will be sufficient for the printing process, but in some cases it might be advantageous to add white. Some colours are difficult to achieve using the colours yellow, magenta, cyan, black and white whereby the colours light magenta and light cyan may be added. It is also possible to add so called spot colours where specific colour tones are difficult to achieve or where only certain parts of the colour spectrum with intermixing shades is desired. The resolution needed is much depending on the decor that is to be simulated, but resolutions of 10 - 1500 dots per inch (dpi) is the practical range in which most decors will be printed. Under normal conditions a resolution of 300 - 800 dpi is sufficient when creating simulations of even very complex decorative patterns and still achieve a result that visually is very difficult to separate from the archetype without close and thorough inspection. It is advantageous to manufacture the supporting core in the desired end user format and to provide it with edges suited for joining before applying the decor and wear layer, since the amount of waste thereby is radically reduced. The decor matching tolerances will also be improved further by this procedure.
As mentioned above the translucent wear layer is suitably constituted of melamine-formaldehyde resin / cellulose blend, high viscosity melamine- formaldehyde or one or more sheets of cellulose which are impregnated with melamine-formaldehyde resin. This wear layer is joined with the core and decor under heat and pressure whereby the resin cures. It is advantageous to add hard particles with an average particle size in the range 50 nm - 150 μm to the wear layer. Larger particles, in the range 10 μm - 150 μm, preferably 30 μm - 150 μm is foremost used to achieve abrasion resistance while the smaller of the particles, in the range 50 nm - 30 μm, preferably 50 nm - 10 μm, is used to achieve scratch resistance. The smaller particles is hereby used on, or very close to, the top surface while the larger particles may be distributed in the wear layer. Also here the particles advantageously are constituted of silicon carbide, silicon oxide, aluminium oxide. The wear layer is hereby suitably pressed together with the rest of the decorative laminate in a continuos belt press with two steel belts. It is also possible to utilise a discontinuous process where one or a number of surface elements can be pressed at the same time.

Claims

1. A process for the manufacturing of a decorative laminate having a base layer, a decorative layer and a wear layer wherein a decor is printed on a base layer wherein the decor printed comprises a printing ink and wherein the wear layer comprises a thermosetting resin selected from the group consisting of; melamine-formaldehyde resin, phenol-formaldehyde resin, urea formaldehyde resin and mixtures thereof, whereby an amount of amino resin is mixed into the printing ink in order to increase the bond between the decorative layer and the wear layer whereby the layers are laminated together in a laminate press under increased temperature and pressure.
2. A process according to claim 1 wherein the printing ink is an alkyde based ink.
3. A process according to claim 1 wherein the printing ink is a polyester-acrylate based ink.
4. A process according to claim 2 or 3 wherein the amino resin is a etherified amino resin.
5. A process according to claim 2 or 3 wherein the amino resin is a methylol amino resin.
6. A process according to claim 1 wherein the base layer is manufactured in the desired end user format and provided with edges intended for joining before applying decor and wear layer.
7. A process according to claim 6 wherein the main part of the base layer is constituted by a particle board or a fibre board.
8. A process according to claim 6 or 7 wherein the base layer is provided with a paper layer on which the decor is printed.
9. A process according to claim 8 wherein the paper layer is bonded to the base layer prior to the printing of the decor.
10. A process according to claim 1 wherein the wear layer is comprised of a high viscosity amino resin applied on top of the decorative layer prior to the lamination.
11. A process according to claim 1 wherein the wear layer is comprised of an amino resin / cellulose mixture.
12. A process according to claim 1 wherein the wear layer is comprised of one or more amino resin impregnated cellulose layer or layers.
13. A process according to any of the claims 10 - 12 wherein the wear layer also comprises hard particles with an average particle size in the range 50nm - 150μm.
14. A process according to claim 13 wherein the upper portion of the wear layer is provided with hard particles with an average particle size in the range 50nm - 30μm while the inner portion of the wear layer is provided with hard particles with an average particle size in the range 31 μm - 150 μm.
15. A process according to claim 13 wherein the hard particles is constituted by silicon oxide, silicon carbide, aluminium oxide or the like.
16. A process according to claim 1 wherein the wear layer is provided with a surface structure that enhances the realistic impression of the decor during or after the lamination.
PCT/SE2004/001723 2003-11-25 2004-11-24 A process for the manufacturing of decorative laminate WO2005051661A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US10/580,219 US20070113970A1 (en) 2003-11-25 2004-11-24 Process for the manufacturing of decorative laminate
EP04800384A EP1697133B2 (en) 2003-11-25 2004-11-24 A process for manufacturing a decorative laminate
PL04800384T PL1697133T5 (en) 2003-11-25 2004-11-24 A process for manufacturing a decorative laminate
DE602004013370T DE602004013370T3 (en) 2003-11-25 2004-11-24 METHOD FOR PRODUCING A DECORATIVE LAMINATE
ES04800384T ES2304632T5 (en) 2003-11-25 2004-11-24 Procedure for manufacturing a decorative laminate
DK04800384.2T DK1697133T4 (en) 2003-11-25 2004-11-24 Process for making a decorative laminate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0303148-1 2003-11-25
SE0303148A SE526467C2 (en) 2003-11-25 2003-11-25 Process for making decorative surface elements with a surface structure

Publications (1)

Publication Number Publication Date
WO2005051661A1 true WO2005051661A1 (en) 2005-06-09

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ID=29729162

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE2004/001723 WO2005051661A1 (en) 2003-11-25 2004-11-24 A process for the manufacturing of decorative laminate

Country Status (10)

Country Link
US (1) US20070113970A1 (en)
EP (1) EP1697133B2 (en)
AT (1) ATE393018T1 (en)
DE (1) DE602004013370T3 (en)
DK (1) DK1697133T4 (en)
ES (1) ES2304632T5 (en)
PL (1) PL1697133T5 (en)
PT (1) PT1697133E (en)
SE (1) SE526467C2 (en)
WO (1) WO2005051661A1 (en)

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WO2009080772A1 (en) * 2007-12-21 2009-07-02 Akzenta Paneele + Profile Gmbh Method for producing a decorative laminate
US20110287237A1 (en) * 2008-03-24 2011-11-24 Biovation, Llc Wear Resistant Biolaminate Composite Assembly and Related Methods
WO2012022006A1 (en) * 2010-08-19 2012-02-23 Bienzobas Saffie Fernando Andres System and method for two dimensional printing on a three dimensional printing support
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US8652617B2 (en) 2008-03-24 2014-02-18 Biovation, Llc Biolaminate composite assembly including polylactic acid and natural wax laminate layer, and related methods
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CN104314272B (en) * 2014-11-06 2017-02-15 湖南圣保罗木业有限公司 Laminate wood flooring and manufacturing method thereof
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