WO2005021698A1 - Liquid dish cleaning compositions - Google Patents
Liquid dish cleaning compositions Download PDFInfo
- Publication number
- WO2005021698A1 WO2005021698A1 PCT/US2004/028044 US2004028044W WO2005021698A1 WO 2005021698 A1 WO2005021698 A1 WO 2005021698A1 US 2004028044 W US2004028044 W US 2004028044W WO 2005021698 A1 WO2005021698 A1 WO 2005021698A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- acid
- surfactant
- alkyl
- surfactants
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- the present invention relates to novel light duty liquid detergent compositions with high foaming and good grease cutting properties as well as mildness properties.
- the prior art is replete with light duty liquid detergent compositions containing nonionic surfactants in combination with anionic and/or betaine surfactants wherein the nonionic detergent is not the major active surfactant.
- an anionic based shampoo contains a minor amount of a fatty acid alkanolamide.
- U.S. Patent No. 3,769,398 discloses a betaine-based shampoo containing minor amounts of nonionic surfactants.
- U.S. Patent No. 4,329,335 also discloses a shampoo containing a betaine surfactant as the major ingredient and minor amounts of a nonionic surfactant and of a fatty acid mono- or di- ethanolamide.
- U.S. Patent No. 4,259,204 discloses a shampoo comprising 0.8 to 20% by weight of an anionic phosphoric acid ester and one additional surfactant which may be either anionic, amphoteric, or nonionic.
- 4,329,334 discloses an anionic-amphoteric based shampoo containing a major amount of anionic surfactant and lesser amounts of a betaine and nonionic surfactants.
- U.S. Patent No. 3,935,129 discloses a liquid cleaning composition containing an alkali metal silicate, urea, glycerin, triethanolamine, an anionic detergent and a nonionic detergent. The silicate content determines the amount of anionic and/or nonionic detergent in the liquid cleaning composition. However, the foaming properties of these detergent compositions are not discussed therein.
- 4,595,526 describes a composition comprising a nonionic surfactant, a betaine surfactant, an anionic surfactant and a C-12-C14 fatty acid monoethanolamide foam stabilizer. Summary of the Invention It has now been found that a liquid dish cleaning composition can be formulated with three different anionic surfactants, an amine oxide surfactant, and water which has improved cleaning and foaming properties.
- An object of this invention is to provide a liquid dish cleaning composition which comprises a sulfate surfactant, two sulfonate anionic surfactants, an amine oxide surfactant, at least one solubilizing agent and water, wherein the composition does not contain any alkyl polyglucoside surfactants, zwitterionic surfactants, silicas, abrasives, acyl isoethionate, 2-hydroxy-4,2',4'-trichloridiphenyl ether, phosphoric acid, phosphonic acid, boric acid, alkali metal carbonates, alkaline earth metal carbonates, alkyl glycine surfactant, cyclic imidinium surfactant, or more than 3 wt.
- This invention relates to a liquid dish cleaning composition which comprises by weight: (a) 4% to 8% of a sodium salt of a C8-C16 linear alkyl benzene sulfonate surfactant; (b) 9% to 14% of a magnesium salt of a C8-C16 linear alkyl benzene sulfonate surfactant; (c) 9% to 14% of an ammonium or sodium salt of an ethoxylated C ⁇ -Ci ⁇ alkyl ether sulfate surfactant; (d) 5% to 10% of an amine oxide surfactant; (e) 0.1 % to 10%, more preferably 0.5 wt. % to 10 wt.
- the composition has a pH of 6 to 7.5 and has a viscosity of 100 to 1 ,000 cps, more preferably 200 to 600 cps at 25°C using a #21 spindle at 20 rpm as measured on a Brookfield RVTDV-II viscometer, wherein the composition does not contain any grease release agents such as choline, chloride or buffering system which is a nitrogenous buffer which is ammonium or alkaline earth carbonate, amine oxide surfactants, guanidine derivates, alkoxylalkyl amines and alkyleneamines C3-C7 alkyl and alkenyl monobasic and dibasic acids such as C4-C7 aliphatic carboxylic diacids which do not contain a hydroxy group, boric acid, phosphoric acid, ethoxylated nonionic surfactants, amino alkylene phosphonic acid, zwit
- the anionic sulfonate surfactants which may be used in the detergent of this invention are selected from the consisting of water soluble and include the sodium, potassium, ammonium, magnesium and ethanolammonium salts of linear C8-C16 alkyl benzene sulfonates; C10-C20 paraffin sulfonates, alpha olefin sulfonates containing 10- 24 carbon atoms and Cs-C-i ⁇ alkyl sulfates and mixtures thereof.
- the paraffin sulfonates may be monosulfonates or di-sulfonates and usually are mixtures thereof, obtained by sulfonating paraffins of 10 to 20 carbon atoms.
- Preferred paraffin sulfonates are those of C-
- Suitable other sulfonated anionic detergents are the well known higher alkyl mononuclear aromatic sulfonates, such as the higher alkylbenzene sulfonates containing 9 to 18 or preferably 9 to 16 carbon atoms in the higher alkyl group in a straight or branched chain, or C ⁇ -15 alkyl toluene sulfonates.
- a preferred alkylbenzene sulfonate is a linear alkylbenzene sulfonate having a higher content of 3- phenyl (or higher) isomers and a correspondingly lower content (well below 50%) of 2- phenyl (or lower) isomers, such as those sulfonates wherein the benzene ring is attached mostly at the 3 or higher (for example 4, 5, 6 or 7) position of the alkyl group and the content of the isomers in which the benzene ring is attached in the 2 or 1 position is correspondingly low.
- Preferred materials are set forth in U.S. Patent
- the C ⁇ -18 ethoxylated alkyl ether sulfate surfactants have the structure - + R-(OCHCH2)nOS03M wherein n is 1 to 22 more preferably 1 to 3 and R is an alkyl group having 8 to 18 carbon atoms, more preferably 12 to 15 and natural cuts, for example, C12-14 or C-
- the ethoxylated alkyl ether sulfate may be made by sulfating the condensation product of ethylene oxide and C8-10 alkanol, and neutralizing the resultant product.
- the ethoxylated alkyl ether sulfates differ from one another in the number of carbon atoms in the alcohols and in the number of moles of ethylene oxide reacted with one mole of such alcohol.
- Preferred ethoxylated alkyl ether polyethenoxy sulfates contain 12 to 15 carbon atoms in the alcohols and in the alkyl groups thereof, e.g., sodium myristyl (3 EO) sulfate.
- Ethoxylated C8-18 alkylphenyl ether sulfates containing from 2 to 6 moles of ethylene oxide in the molecule are also suitable for use in the invention compositions.
- These detergents can be prepared by reacting an alkyl phenol with 2 to 6 moles of ethylene oxide and sulfating and neutralizing the resultant ethoxylated alkylphenol.
- concentration of the ethoxylated alkyl ether sulfate surfactant is 1 to 8 wt. %.
- Amine oxide semi-polar nonionic surfactants comprise compounds and mixtures of compounds having the formula: R 2 R ⁇ (C 2 H 4 ⁇ ) n N ⁇ O R 3 wherein R-j is an alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl, or 3-alkoxy-2-hydroxypropyl radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms, R2 and R3 are each methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, or
- n is from 0 to 10.
- Particularly preferred are amine oxides of the formula:
- is a C-12-I 6 alkyl and R2 and R3 are methyl or ethyl.
- the above ethylene oxide condensates, amides, and amine oxides are more fully described in U.S. Pat. No. 4,316,824 which is hereby incorporated herein by reference.
- the instant composition can optionally contain 0 to 10 wt. %, more preferably 0.5 wt. % to 8 wt. % of a C12-14 alkyl monoalkanol amide such as lauryl monoalkanol amide.
- the hydroxy containing organic acid which can be optionally used at a concentration of 0.5 wt. % to 5 wt.
- % are selected from the group consisting of ortho hydroxy benzoic acid or preferably a hydroxy aliphatic acid selected from the group consisting of lactic acid, citric acid, salicylic acid glycolic and mixtures thereof.
- Polyethylene glycol which can be optionally used at a concentration of 0.5 wt. % to 10 wt. % in the instant composition has a molecular weight of 200 to 1 ,000, wherein the polyethylene glycol has the structure HO(CH 2 CH 2 0) n H wherein n is 4 to 52.
- the instant light duty liquid compositions can contain 0 wt. % to 10 wt. %, more preferably 1 wt. % to 8 wt.
- solubilizing agent selected from the group consisting of a C2-5 mono, dihydroxy or polyhydroxy alkanols such as ethanol, isopropanol, glycerol ethylene glycol, diethylene glycol, propylene glycol, and hexylene glycol and mixtures thereof and alkali metal cumene, toluene and xylene sulfonates such as sodium cumene sulfonate and sodium xylene sulfonate.
- the solubilizing agents are included in order to control low temperature cloud clear properties.
- Urea can be optionally used at a concentration of 0.5 wt. % to 7 wt. %.
- the instant compositions can contain 0 to 3 wt. %, more preferably 0.5 wt. % to 2 wt. % of an alkali metal halide such as sodium chloride.
- the instant formulas explicitly exclude alkali metal silicates and alkali metal builders such as alkali metal polyphosphates, alkali metal carbonates, alkali metal phosphonates and alkali metal citrates because these materials, if used in the instant composition, would cause the composition to have a high pH as well as leaving residue on the surface being cleaned.
- the final essential ingredient in the inventive compositions having improved interracial tension properties is water.
- the proportion of water in the compositions generally is in the range of 50% to 95%.
- the liquid cleaning composition of this invention may, if desired, also contain other components either to provide additional effect or to make the product more attractive to the consumer.
- Other components either to provide additional effect or to make the product more attractive to the consumer.
- Colors or dyes in amounts up to 0.5% by weight; bactericides in amounts up to 1 % by weight; in amounts up to 2% by weight; HEDTA for color improvement under stressed sun conditions, up to 1 % and pH adjusting agents, such as sulfuric acid or sodium hydroxide, as needed.
- pH adjusting agents such as sulfuric acid or sodium hydroxide, as needed.
- up to 4% by weight of an opacifier may be added.
- the instant compositions can contain 0 to 0.5 wt. %, more preferably 0.05 wt. % to 0.3 wt.
- the instant composition can also contain 0 to 10 wt. %, more preferably 0.1 wt. % to 9 wt. % of hydrogen peroxide. Preservatives which can be optionally used in the instant compositions at a concentration of 0 wt. % to 3 wt. %, more preferably 0.01 wt. % to 2.5 wt.
- % are: benzalkonium chloride; benzethonium chloride,5-bromo-5-nitro-1 ,3dioxane; 2-bromo-2- nitropropane-1 ,3-diol; alkyl trimethyl ammonium bromide; N-(hydroxymethyl)-N-(1 ,3- dihydroxy methyl-2,5-dioxo-4-imidaxolidinyl-N'-(hydroxy methyl) urea; 1-3-dimethyol- 5,5-dimethyl hydantoin; formaldehyde; iodopropynl butyl carbamate, butyl paraben; ethyl paraben; methyl paraben; propyl paraben, mixture of methyl isothiazolinone/methyl-chloroisothiazoline in a 1 :3 wt.
- compositions remain clear and stable in the range of 0°C to 50°C, especially 5°C to 43°C.
- Such compositions exhibit a pH of 6 to 7.5.
- the liquid microemulsion compositions are readily pourable and exhibit a viscosity in the range of 6 to 300 milliPascal . second (mPas.) as measured at 25°C. with a Brookfield RVTDV-II Viscometer using a #21 spindle rotating at 20 RPM.
- the viscosity is maintained in the range of 10 to 200 mPas.
- the following examples illustrate the liquid body cleaning compositions of the described invention. Unless otherwise specified, all percentages are by weight.
- the exemplified compositions are illustrative only and do not limit the scope of the invention.
- Example 1 The following compositions in wt. % were prepared by simple mixing procedure:
- the Cup test measures the grease removal under soaking conditions. 6 gr. of warm liquid beef tallow is applied on a 250 ml plastic cup. It is allowed to solidify for at least 3 hours. Warm solutions (115F) of LDL products at 0.267% concentration were poured on the plastic cups containing the grease. After 15 minutes they are emptied, and allowed to dry. The weight of the grease removed during soaking is measured.
- the foam volume test is an inverted cylinder test in which 100 ml of 0.0335 wt. % of the LDL composition in 150 ppm Mg/CaC03 hardened water is placed in a stoppered graduated cylinder (500 ml) and inverted 40 cycles at a rate of 30 cycles/minute.
- the foam height in the graduated cylinder is measured in mi's.
- the cylinder stopper is removed and 175 microliters of whole milk is added to the solution.
- the cylinder is then inverted for another 40 cycles and a foam volume with soil is measured.
- the values provided above include the 100 mi's of LDL solution inside the cylinder.
- the # of miniplates is measured using an automated miniplate test. The procedure is described in great detail in U.S. 4,556,509. Briefly, the test is used to determine the number of theoretical plates that can be washed in a detergent solution until the foam disappears. This test is used to demonstrate the improvement in cleaning efficiency as gauged by foam volume and foam stability.
- foam is generated in a detergent solution by the action of an agitating brush.
- the foam is electronically measured by reflectance of the solution surface as Crisco (vegetable shortening) soil is added to the detergent solution at a steady rate. The disappearance of the foam determines the endpoint of the test, and the number of miniplates is then calculated based on foam duration and the rate of soil addition.
- Crisco vegetable shortening soil
- the detergent solution was made at 3.333 wt. % with 150 ppm Mg/CaC03 hardness, and was initially heated to 47C (116.6F) at the start of soil addition.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MXPA06001794A MXPA06001794A (en) | 2003-08-28 | 2004-08-27 | Liquid dish cleaning compositions. |
AU2004269386A AU2004269386A1 (en) | 2003-08-28 | 2004-08-27 | Liquid dish cleaning compositions |
EP04782509A EP1658361A1 (en) | 2003-08-28 | 2004-08-27 | Liquid dish cleaning compositions |
CA002534841A CA2534841A1 (en) | 2003-08-28 | 2004-08-27 | Liquid dish cleaning compositions |
US11/010,815 US20050096240A1 (en) | 2003-08-28 | 2004-12-13 | Liquid dish cleaning compositions |
IL173464A IL173464A0 (en) | 2003-08-28 | 2006-01-31 | Liquid dish cleaning compositions |
NO20061365A NO20061365L (en) | 2003-08-28 | 2006-03-24 | Liquid detergent |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/650,418 US20050049161A1 (en) | 2003-08-28 | 2003-08-28 | Liquid dish cleaning compositions |
US10/650,418 | 2003-08-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005021698A1 true WO2005021698A1 (en) | 2005-03-10 |
Family
ID=34217154
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2004/028044 WO2005021698A1 (en) | 2003-08-28 | 2004-08-27 | Liquid dish cleaning compositions |
Country Status (9)
Country | Link |
---|---|
US (1) | US20050049161A1 (en) |
EP (1) | EP1658361A1 (en) |
AU (1) | AU2004269386A1 (en) |
CA (1) | CA2534841A1 (en) |
EC (1) | ECSP066451A (en) |
IL (1) | IL173464A0 (en) |
MX (1) | MXPA06001794A (en) |
NO (1) | NO20061365L (en) |
WO (1) | WO2005021698A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007057839A2 (en) * | 2005-11-15 | 2007-05-24 | The Procter & Gamble Company | Liquid laundry detergent composition with naturally derived alkyl or hydroxyalkyl sulphate or sulphonate surfactant and mid-chain branched amine oxide surfactants |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1874914B1 (en) | 2005-04-21 | 2012-09-26 | Colgate-Palmolive Company | Liquid detergent composition |
US7470653B2 (en) * | 2006-04-07 | 2008-12-30 | Colgate-Palmolive Company | Liquid cleaning composition comprising an anionic/betaine surfactant mixture having low viscosity |
US8022028B2 (en) * | 2008-06-17 | 2011-09-20 | Colgate-Palmolive Company | Light duty liquid cleaning compositions and methods of manufacture and use thereof comprising organic acids |
US8247362B2 (en) | 2008-06-17 | 2012-08-21 | Colgate-Palmolive Company | Light duty liquid cleaning compositions and methods of manufacture and use thereof |
US20090312226A1 (en) * | 2008-06-17 | 2009-12-17 | Colgate-Palmolive Company | Light Duty Liquid Cleaning Compositions And Methods Of Manufacture And Use Thereof |
US7718595B2 (en) * | 2008-06-17 | 2010-05-18 | Colgate Palmolive Company | Light duty liquid cleaning compositions and methods of manufacture and use thereof comprising organic acids |
AU2010365415B2 (en) | 2010-12-13 | 2014-06-26 | Colgate-Palmolive Company | Dilutable concentrated cleaning composition |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995007971A1 (en) * | 1993-09-14 | 1995-03-23 | The Procter & Gamble Company | Light duty liquid or gel dishwashing detergent compositions containing protease |
US6010992A (en) * | 1999-06-01 | 2000-01-04 | Colgate-Palmolive Co. | Liquid detergent composition containing amine oxide and citric acid |
US6048834A (en) * | 1994-12-15 | 2000-04-11 | Colgate-Palmolive Co. | Microemulsion light duty liquid cleaning compositions |
US6475967B1 (en) * | 2002-03-05 | 2002-11-05 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing a peroxide source |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6627589B1 (en) * | 2001-05-11 | 2003-09-30 | Colgate-Palmolive Company | Mild antibacterial liquid dish cleaning compositions containing peroxide having improved stability and stain removal benefits |
US6605579B1 (en) * | 2001-05-11 | 2003-08-12 | Colgate- Palmolive Company | Antibacterial liquid dish cleaning compositions |
-
2003
- 2003-08-28 US US10/650,418 patent/US20050049161A1/en not_active Abandoned
-
2004
- 2004-08-27 AU AU2004269386A patent/AU2004269386A1/en not_active Abandoned
- 2004-08-27 CA CA002534841A patent/CA2534841A1/en not_active Abandoned
- 2004-08-27 EP EP04782509A patent/EP1658361A1/en not_active Withdrawn
- 2004-08-27 WO PCT/US2004/028044 patent/WO2005021698A1/en not_active Application Discontinuation
- 2004-08-27 MX MXPA06001794A patent/MXPA06001794A/en unknown
-
2006
- 2006-01-31 IL IL173464A patent/IL173464A0/en unknown
- 2006-03-23 EC EC2006006451A patent/ECSP066451A/en unknown
- 2006-03-24 NO NO20061365A patent/NO20061365L/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995007971A1 (en) * | 1993-09-14 | 1995-03-23 | The Procter & Gamble Company | Light duty liquid or gel dishwashing detergent compositions containing protease |
US6048834A (en) * | 1994-12-15 | 2000-04-11 | Colgate-Palmolive Co. | Microemulsion light duty liquid cleaning compositions |
US6010992A (en) * | 1999-06-01 | 2000-01-04 | Colgate-Palmolive Co. | Liquid detergent composition containing amine oxide and citric acid |
US6475967B1 (en) * | 2002-03-05 | 2002-11-05 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing a peroxide source |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007057839A2 (en) * | 2005-11-15 | 2007-05-24 | The Procter & Gamble Company | Liquid laundry detergent composition with naturally derived alkyl or hydroxyalkyl sulphate or sulphonate surfactant and mid-chain branched amine oxide surfactants |
WO2007057839A3 (en) * | 2005-11-15 | 2007-10-11 | Procter & Gamble | Liquid laundry detergent composition with naturally derived alkyl or hydroxyalkyl sulphate or sulphonate surfactant and mid-chain branched amine oxide surfactants |
Also Published As
Publication number | Publication date |
---|---|
EP1658361A1 (en) | 2006-05-24 |
US20050049161A1 (en) | 2005-03-03 |
MXPA06001794A (en) | 2006-05-04 |
NO20061365L (en) | 2006-03-24 |
IL173464A0 (en) | 2006-06-11 |
AU2004269386A1 (en) | 2005-03-10 |
ECSP066451A (en) | 2006-09-18 |
CA2534841A1 (en) | 2005-03-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7115550B2 (en) | Liquid dish cleaning compositions | |
US6475967B1 (en) | Liquid dish cleaning compositions containing a peroxide source | |
US6605579B1 (en) | Antibacterial liquid dish cleaning compositions | |
US6444636B1 (en) | Liquid dish cleaning compositions containing hydrogen peroxide | |
US6482788B1 (en) | Light duty liquid composition containing an acid and zinc chloride | |
US20010009893A1 (en) | Light duty liquid cleaning compositions comprise an alpha hydroxy fatty acid | |
US6441037B1 (en) | Antibacterial liquid dish cleaning compositions | |
US6815406B1 (en) | Liquid dish cleaning compositions | |
WO2002092743A1 (en) | Antibacterial liquid dish cleaning compositions having improved viscosity | |
US6884764B2 (en) | Liquid dish cleaning compositions | |
US6593284B2 (en) | Antibacterial liquid dish cleaning compositions | |
EP1658361A1 (en) | Liquid dish cleaning compositions | |
US20020197293A1 (en) | Antibacterial liquid dish cleaning compositions having improved viscosity | |
US6586014B2 (en) | Liquid dish cleaning compositions containing hydrogen peroxide | |
US20050096240A1 (en) | Liquid dish cleaning compositions | |
AU2002309641A1 (en) | Antibacterial liquid dish cleaning compositions having improved viscosity |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2004269386 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref document number: 2534841 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004782509 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 545272 Country of ref document: NZ |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2006/001794 Country of ref document: MX Ref document number: 12006500340 Country of ref document: PH |
|
ENP | Entry into the national phase |
Ref document number: 2004269386 Country of ref document: AU Date of ref document: 20040827 Kind code of ref document: A |
|
WWP | Wipo information: published in national office |
Ref document number: 2004269386 Country of ref document: AU |
|
WWP | Wipo information: published in national office |
Ref document number: 2004782509 Country of ref document: EP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2004782509 Country of ref document: EP |