WO2005007904A1 - Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions - Google Patents
Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions Download PDFInfo
- Publication number
- WO2005007904A1 WO2005007904A1 PCT/IB2004/002285 IB2004002285W WO2005007904A1 WO 2005007904 A1 WO2005007904 A1 WO 2005007904A1 IB 2004002285 W IB2004002285 W IB 2004002285W WO 2005007904 A1 WO2005007904 A1 WO 2005007904A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lead
- desulphating
- carbonate
- sulphate
- process according
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
- C22B13/045—Recovery from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/008—Wet processes by an alkaline or ammoniacal leaching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Definitions
- Secondary lead is recovered from the electrode slime recovered from end-of-life lead-acid batteries using pyrometallurgical processes operating at high temperature and in the presence of iron to reduce the furnace operating temperature to approximately 1100 °C. These processes have a potentially high environmental impact, both as regards gaseous emissions and the large associated output of slag, which is classified as a hazardous material requiring disposal in special dumps . As far as gaseous emissions are concerned, the procedures adopted by lead recyclers make it possible to reduce and control these, although at a high cost, while the problem associated with the large output of associated slag persists. Conversion of the lead sulphate present in the electrode slime into carbonate through a "carbonatation" process is a technique which is well known among secondary lead producers.
- a method for virtually wholly desulphating the slime by reaction with an aqueous solution containing ammonium carbonate or alkali (sodium, ammonium, potassium) carbonates in addition to other substances which have the power to dissolve the insoluble lanarkite has now been found and is the subject of this invention.
- the treatment temperature may be between ambient temperature and the boiling point of the solution, preferably between 60 and 100°C.
- the ratio by weight between the water in the solution and the slime lies between 0.6 and 5, preferably between 0.7 and 1.2.
- the sodium carbonate present in the solution is the stoichiometric quantity appropriate for the sulphate levels present in the electrode slimes with an excess of between 0.01% and 10%.
- the sodium hydroxide is added in such a way that the carbonate/hydroxide ratio by weight lies between 6.4 and 5.5 so as to accelerate the desulphating reactions without plumbites being present in solution.
- the water/slime ratio may also be chosen in relation to the subsequent treatment separating the desulphated slime from the solution (normally by sedimentation, filtration and/or centrifuging) . This does not apply any constraint on desulphating.
- the water/slime/quantity of sodium carbonate ratio also depends on the subsequent treatment which it is intended to use to separate the sodium sulphate which forms as a result of the desulphating reaction described.
- the efficiency of lead recovery with reference to the weight of the non-desulphated dry slime was 71-72% in comparison with the maximum of 66% which can be obtained by known methods, while the maximum theoretical yield is 72-73%, depending on the composition of the slime.
- the amount of slag formed essentially depends on substances present in the slime
- lanarkite substances having the ability to dissolve lanarkite, such as : amines, amides, MEA (monoethanolamine) , DEA (diethanolamine) , TEA (triethanolamine) , tartaric acid and tartrates, citric acid and citrates, glycolic acid, gluconates, alkali and ammonium acetates, alkali and ammonium nitrates, ammonia, EDTA and other complexing agents, and with ammonium carbonate alone.
- amines, amides MEA (monoethanolamine) , DEA (diethanolamine) , TEA (triethanolamine) , tartaric acid and tartrates, citric acid and citrates, glycolic acid, gluconates, alkali and ammonium acetates, alkali and ammonium nitrates, ammonia, EDTA and other complexing agents, and with ammonium carbonate alone.
- 100 kg of electrode slimes were charged into a cylindrical mill reactor and suspended in a solution comprising 100 kg of water, 24 kg of 99% pure sodium carbonate and 3 kg of 99.5% pure sodium hydroxide.
- the suspension was heated to a temperature of 70 °C and held at that temperature for 90 minutes.
- the solid part of the suspension was subjected to a strong compression and shearing force through rotating brushes brushing against the inside walls of the reactor.
- the solid part of the suspension was separated out from the suspension and on analysis was found to have a total sulphur content of less than 0.06%.
- 100 kg of electrode slime was charged into a cylindrical reactor with a paddle stirrer and suspended in a solution comprising 100 kg of water, 24 kg of 99% pure sodium carbonate and 8 kg of 99.5% pure sodium hydroxide.
- the suspension was heated to a temperature of 70 °C and held at that temperature for 90 minutes. Again in this case the grinding action was applied throughout the duration of the test.
- the solid part of the suspension was separated out from the and on analysis was found to have a total sulphur content of less than 0.04%.
- 100 kg of electrode slime was charged into the same cylindrical reactor as in example no. 1 and suspended in a solution comprising 100 kg of water, 24 kg of 99% pure sodium carbonate and 6 kg of monoethanolamine.
- the suspension was heated to a temperature of 70 °C and held at that temperature for 90 minutes. Again in this case the grinding action was maintained throughout the duration of the test.
- the solid part of the suspension was separated out and on analysis was found to have a total sulphur content of less than 0.07%.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Secondary Cells (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20040743947 EP1656463A1 (en) | 2003-07-18 | 2004-07-12 | Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions |
US10/564,989 US20070028720A1 (en) | 2003-07-18 | 2004-07-12 | Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH12572003 | 2003-07-18 | ||
CH01257/03 | 2003-07-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005007904A1 true WO2005007904A1 (en) | 2005-01-27 |
Family
ID=34069956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2004/002285 WO2005007904A1 (en) | 2003-07-18 | 2004-07-12 | Process for the high yield recovery of lead from spent lead-acid batteries with reduced associated production of slag and gaseous emissions |
Country Status (4)
Country | Link |
---|---|
US (1) | US20070028720A1 (en) |
EP (1) | EP1656463A1 (en) |
CN (1) | CN1846005A (en) |
WO (1) | WO2005007904A1 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008056125A1 (en) * | 2006-11-08 | 2008-05-15 | Cambridge Enterprise Limited | Lead recycling |
CN100400683C (en) * | 2006-12-30 | 2008-07-09 | 同济大学 | Method for producing metallic lead and zinc by using lead-zinc containing waste slag or lead-zinc monoxide mine |
WO2008087684A1 (en) * | 2007-01-17 | 2008-07-24 | Millbrook Lead Recycling Technologies Limited | Recovery of lead in form of high purity lead carbonates from spent lead batteries incl. electrode paste |
WO2009068988A3 (en) * | 2007-11-30 | 2009-11-12 | Engitec Technologies S.P.A. | Process for producing metallic lead starting from desulfurized pastel |
EP2333895A1 (en) * | 2009-11-23 | 2011-06-15 | Instytut Metali Niezelaznych | Method for desulphurization of battery paste |
CN102102154A (en) * | 2010-12-22 | 2011-06-22 | 中南大学 | Low-temperature fused salt clean smelting method for tin |
US9533273B2 (en) | 2014-06-20 | 2017-01-03 | Johnson Controls Technology Company | Systems and methods for isolating a particulate product when recycling lead from spent lead-acid batteries |
US9670565B2 (en) | 2014-06-20 | 2017-06-06 | Johnson Controls Technology Company | Systems and methods for the hydrometallurgical recovery of lead from spent lead-acid batteries and the preparation of lead oxide for use in new lead-acid batteries |
US10062933B2 (en) | 2015-12-14 | 2018-08-28 | Johnson Controls Technology Company | Hydrometallurgical electrowinning of lead from spent lead-acid batteries |
WO2022018489A1 (en) * | 2020-07-22 | 2022-01-27 | Ecometales Limited | Procedure for leaching valuable elements from metallurgical residues. |
Families Citing this family (13)
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---|---|---|---|---|
CN100521364C (en) * | 2007-11-20 | 2009-07-29 | 浙江工业大学 | A crash selection method for thrown lead acid accumulator and special tower gravity selector |
CN102689921B (en) * | 2011-03-24 | 2017-08-08 | 杨春晓 | The preparation method for the Pb nm-class oxide powders for reclaiming and manufacturing for lead-acid accumulator |
WO2012167117A2 (en) * | 2011-06-03 | 2012-12-06 | Energ2 Technologies, Inc. | Carbon-lead blends for use in hybrid energy storage devices |
CN102275982A (en) * | 2011-06-07 | 2011-12-14 | 沈阳化工大学 | Mixed solvent for dissolving lead sulfate |
CA2930945C (en) | 2013-11-19 | 2018-03-20 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
CN103773972B (en) * | 2014-01-10 | 2016-06-15 | 张超 | A kind of processing method of raw material containing lead |
CN110343862A (en) | 2015-05-13 | 2019-10-18 | 艾库伊金属有限公司 | The method of lead is recycled from the lead plaster of lead-acid battery |
SI3294929T1 (en) | 2015-05-13 | 2021-11-30 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
CN107923057B (en) | 2015-05-13 | 2020-07-14 | 艾库伊金属有限公司 | Electrodeposited lead compositions, methods of production and uses |
US10316420B2 (en) * | 2015-12-02 | 2019-06-11 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
CN106637298A (en) * | 2016-11-16 | 2017-05-10 | 昆明冶金研究院 | Electrical lead deposition method of lead-containing multi-metal material |
IT201800005267A1 (en) * | 2018-05-11 | 2019-11-11 | PROCEDURE FOR THE DESULPHURATION OF MATERIALS AND / OR RESIDUES CONTAINING LEAD SULFATE BY MEANS OF AN AMINE COMPOUND | |
US10968144B2 (en) | 2018-10-08 | 2021-04-06 | Marsulex Environmental Technologies Corporation | Systems and methods for producing potassium sulfate |
Citations (4)
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US3883348A (en) * | 1973-09-06 | 1975-05-13 | R S R Corp | Process for the removal of sulfur from battery wrecker material using ammonium carbonate solution |
US4018567A (en) * | 1973-05-14 | 1977-04-19 | James P. La Point, Jr. | Apparatus for separating the constituents of lead-acid storage batteries |
GB2073725A (en) * | 1980-04-11 | 1981-10-21 | Ass Lead Mfg Ltd | A Method of Recovering Lead Values from Scrap Batteries |
US5690718A (en) * | 1995-10-06 | 1997-11-25 | Global Aener/Cology Corp. | Battery paste recycling process |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3689253A (en) * | 1970-08-27 | 1972-09-05 | Minerals Technology Corp | Reclaiming lead from storage batteries |
US4269810A (en) * | 1978-10-10 | 1981-05-26 | Nl Industries, Inc. | Method for desulfation of battery mud |
ITMI20041456A1 (en) * | 2004-07-20 | 2004-10-20 | Engitec S R L | PASTEL DESULFORATION PROCESS AND LEAD STORAGE GRIDS + |
-
2004
- 2004-07-12 EP EP20040743947 patent/EP1656463A1/en not_active Withdrawn
- 2004-07-12 CN CNA2004800250660A patent/CN1846005A/en active Pending
- 2004-07-12 US US10/564,989 patent/US20070028720A1/en not_active Abandoned
- 2004-07-12 WO PCT/IB2004/002285 patent/WO2005007904A1/en not_active Application Discontinuation
Patent Citations (4)
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US4018567A (en) * | 1973-05-14 | 1977-04-19 | James P. La Point, Jr. | Apparatus for separating the constituents of lead-acid storage batteries |
US3883348A (en) * | 1973-09-06 | 1975-05-13 | R S R Corp | Process for the removal of sulfur from battery wrecker material using ammonium carbonate solution |
GB2073725A (en) * | 1980-04-11 | 1981-10-21 | Ass Lead Mfg Ltd | A Method of Recovering Lead Values from Scrap Batteries |
US5690718A (en) * | 1995-10-06 | 1997-11-25 | Global Aener/Cology Corp. | Battery paste recycling process |
Non-Patent Citations (2)
Title |
---|
BEGUM D A ET AL: "A STUDY ON THE DISSOLUTION OF LEAD SULPHATE FROM WASTE BATTERIES WITH ETHANOLAMINES", HYDROMETALLURGY, ELSEVIER SCIENTIFIC PUBLISHING CY. AMSTERDAM, NL, vol. 22, no. 1/2, 1 June 1989 (1989-06-01), pages 259 - 266, XP000050290, ISSN: 0304-386X * |
FERRACIN L C ET AL: "Lead recovery from a typical Brazilian sludge of exhausted lead-acid batteries using an electrohydrometallurgical process", HYDROMETALLURGY, ELSEVIER SCIENTIFIC PUBLISHING CY. AMSTERDAM, NL, vol. 65, no. 2-3, September 2002 (2002-09-01), pages 137 - 144, XP004377792, ISSN: 0304-386X * |
Cited By (26)
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RU2486266C2 (en) * | 2006-11-08 | 2013-06-27 | Кембридж Энтерпрайз Лимитед | Lead wastes processing |
US20100040938A1 (en) * | 2006-11-08 | 2010-02-18 | Cambridge Enterprise Limited | Lead recycling |
WO2008056125A1 (en) * | 2006-11-08 | 2008-05-15 | Cambridge Enterprise Limited | Lead recycling |
US8323376B2 (en) | 2006-11-08 | 2012-12-04 | Cambridge Enterprise Limited | Lead recycling |
CN100400683C (en) * | 2006-12-30 | 2008-07-09 | 同济大学 | Method for producing metallic lead and zinc by using lead-zinc containing waste slag or lead-zinc monoxide mine |
WO2008087684A1 (en) * | 2007-01-17 | 2008-07-24 | Millbrook Lead Recycling Technologies Limited | Recovery of lead in form of high purity lead carbonates from spent lead batteries incl. electrode paste |
US7998440B2 (en) | 2007-01-17 | 2011-08-16 | Millbrook Lead Recycling Technologies Limited | Reclaiming of lead in form of high purity lead compound from recovered electrode paste slime of dismissed lead batteries and/or of lead minerals |
US8147780B2 (en) | 2007-01-17 | 2012-04-03 | Millbrook Lead Recycling Technologies Limited | Recovery of lead in form of high purity lead carbonates from spent lead batteries incl. electrode paste |
WO2009068988A3 (en) * | 2007-11-30 | 2009-11-12 | Engitec Technologies S.P.A. | Process for producing metallic lead starting from desulfurized pastel |
RU2467084C2 (en) * | 2007-11-30 | 2012-11-20 | Энджитек Текнолоджиз С.п.А. | Method of producing metallic lead from sweet paste making active part of lead-acid accumulator |
US8409421B2 (en) | 2007-11-30 | 2013-04-02 | Engitec Technologies S.P.A. | Process for producing metallic lead starting from desulfurized pastel |
EP2333895A1 (en) * | 2009-11-23 | 2011-06-15 | Instytut Metali Niezelaznych | Method for desulphurization of battery paste |
CN102102154A (en) * | 2010-12-22 | 2011-06-22 | 中南大学 | Low-temperature fused salt clean smelting method for tin |
US10122052B2 (en) | 2014-06-20 | 2018-11-06 | Johnson Controls Technology Company | Systems and methods for purifying and recycling lead from spent lead-acid batteries |
US9555386B2 (en) | 2014-06-20 | 2017-01-31 | Johnson Controls Technology Company | Systems and methods for closed-loop recycling of a liquid component of a leaching mixture when recycling lead from spent lead-acid batteries |
US9670565B2 (en) | 2014-06-20 | 2017-06-06 | Johnson Controls Technology Company | Systems and methods for the hydrometallurgical recovery of lead from spent lead-acid batteries and the preparation of lead oxide for use in new lead-acid batteries |
US9751067B2 (en) | 2014-06-20 | 2017-09-05 | Johnson Controls Technology Company | Methods for purifying and recycling lead from spent lead-acid batteries |
US9757702B2 (en) | 2014-06-20 | 2017-09-12 | Johnson Controls Technology Company | Systems and methods for purifying and recycling lead from spent lead-acid batteries |
US9533273B2 (en) | 2014-06-20 | 2017-01-03 | Johnson Controls Technology Company | Systems and methods for isolating a particulate product when recycling lead from spent lead-acid batteries |
US10403940B2 (en) | 2014-06-20 | 2019-09-03 | Cps Technology Holdings Llc | Systems and methods for closed-loop recycling of a liquid component of a leaching mixture when recycling lead from spent lead-acid batteries |
US10777858B2 (en) | 2014-06-20 | 2020-09-15 | Cps Technology Holdings Llc | Methods for purifying and recycling lead from spent lead-acid batteries |
US11005129B2 (en) | 2014-06-20 | 2021-05-11 | Clarios Germany Gmbh & Co. Kgaa | Systems and methods for closed-loop recycling of a liquid component of a leaching mixture when recycling lead from spent lead-acid batteries |
US11791505B2 (en) | 2014-06-20 | 2023-10-17 | Cps Technology Holdings Llc | Methods for purifying and recycling lead from spent lead-acid batteries |
US11923518B2 (en) | 2014-06-20 | 2024-03-05 | Clarios Advanced Germany Gmbh & Co. KG | Systems and methods for closed-loop recycling of a liquid component of a leaching mixture when recycling lead from spent lead-acid batteries |
US10062933B2 (en) | 2015-12-14 | 2018-08-28 | Johnson Controls Technology Company | Hydrometallurgical electrowinning of lead from spent lead-acid batteries |
WO2022018489A1 (en) * | 2020-07-22 | 2022-01-27 | Ecometales Limited | Procedure for leaching valuable elements from metallurgical residues. |
Also Published As
Publication number | Publication date |
---|---|
EP1656463A1 (en) | 2006-05-17 |
CN1846005A (en) | 2006-10-11 |
US20070028720A1 (en) | 2007-02-08 |
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