WO2004078654A2 - Eau pour solution radicalaire - Google Patents
Eau pour solution radicalaire Download PDFInfo
- Publication number
- WO2004078654A2 WO2004078654A2 PCT/US2003/006600 US0306600W WO2004078654A2 WO 2004078654 A2 WO2004078654 A2 WO 2004078654A2 US 0306600 W US0306600 W US 0306600W WO 2004078654 A2 WO2004078654 A2 WO 2004078654A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- frs
- molecules
- electrolysis
- free radical
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/46195—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water characterised by the oxidation reduction potential [ORP]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/026—Treating water for medical or cosmetic purposes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/04—Oxidation reduction potential [ORP]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/23—O3
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/18—Removal of treatment agents after treatment
- C02F2303/185—The treatment agent being halogen or a halogenated compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
Definitions
- the present invention relates to water, and more particularly to Free Radical Solution (FRS) functional (electrolyzed) water.
- FFS Free Radical Solution
- Treaded water is water that has been processed through a variety of methods such as electrolytic ion separation or electrolysis to produce what are known as functional waters with unique physical characteristics.
- the processes that produce functional water systems restructure regular water into different types of functional (or utility) waters, including for example waters with alkaline concentrations or acidic concentrations. These waters may be used for sterilization in settings such as hospitals, medical clinics, or other industries such as food processing, or households, similar to chemical-based sterilizing solutions.
- Ultra Acidic Water is a typical example of a functional water used as an oxidizing agent (a bleaching product) for sterilization.
- the Ultra Acidic Water limits its use, and may be harmful for the environment.
- the Ultra Acidic Water and many other prior art functional waters may require a neutralization solution for their proper and safe disposal.
- the Ultra Acidic water is produced by the addition of chemical additives during various stages of water treatment, including electrolysis. Water is a weak electrolyte because it conducts very little amount of electric current. In order to electrolyze water efficiently, a small amount of additive such as salt or sulfate is added, making the resulting solution an electrolyte.
- the electrolyte is than placed in a tank (known as electrolytic tank) divided into two by a diaphragm (or a membrane).
- a tank known as electrolytic tank
- diaphragm or a membrane
- H + ions are deposited at cathode
- OH " ions are deposited at anode sections of diaphragm (or membrane), producing electrolyzed water.
- the resulting prior art electrolyzed waters generated are either acidic or alkaline with very high effective chlorine levels, further limiting their application.
- the present invention seeks to provide electrolyzed functional water that is pollution free and can be used as cleaning, deodorizing, and sterilizing solution.
- the present invention further seeks to provide electrolyzed functional water without the addition of any additives (chemical or otherwise).
- the present invention seeks to provide electrolyzed functional water with Oxidation-Reduction Potential level of 900mV to 1200mV, and with a stable Hydrogen Ion Concentration level of 6 - 8pH.
- unique functional (electrolyzed) water is presented that overcomes the short falls of the prior art functional waters.
- the Free Radical Solution (FRS) water of the present invention is functional (electrolyzed) water with no additives (chemical or otherwise).
- the FRS water is non-chemical and water based solution that has very strong cleansing, deodorizing and sterilizing capabilities.
- the original material used in the process of producing FRS water, and the FRS water itself, is simply water (H 2 O). Its difference with regular water has to do with its physical characteristics, making it distinctly different from water's more common well-known chemical features.
- water is transformed to Free Radical Solution water wherein the free radicals in the FRS water solution add the very unique characteristics and functions that makes this water different from regular water (physically).
- the transformation is not chemical, but a physical change of atoms or molecules in water, i.e. the H 2 O molecules of water are transformed into different types of free radicals.
- the transformations are random, continuous, and repeat.
- the water molecules are transformed into Free Radical mono-molecules, with the resulting FRS water having a stable Hydrogen Ion Concentration (HIC) level of 6 to 8 pH, with Oxidation Reduction Potential (ORP) of about 900mV to 1200mV.
- HIC Hydrogen Ion Concentration
- ORP Oxidation Reduction Potential
- the FRS water service life time when exposed to air is at least two hours after production, where it gradually returns to regular water thereafter.
- the high ORP levels in FRS water allow it be used for generating electricity.
- Fig. 1 is a summary table showing the properties and the corresponding values for Free Radical Solution water, in accordance with the present invention
- Fig. 2 is a flow chart illustrating the process of producing the FRS water, in accordance with the present invention
- Fig. 3 is a graphical representation of the result of a sample spectrum transmittance test for FRS water and purified water by an optical spectrum analyzer, in accordance with the present invention
- Fig. 3A is a graphical representation of the result of a sample spectrum transmittance test for purified water
- Fig. 3B is a graphical representation of the result of a sample spectrum transmittance test for FRS water.
- Fig. 4 is a listing of Free Radicals and their transformation patterns in FRS water, in accordance with the present invention.
- Fig. 5 is a graphical representation of a sample Electron Spin Resonance (ESR) test result for capture of OH radicals in FRS water, in accordance with the present invention
- Fig. 6 is a graphical representation for the Oxidation Reduction Potential change pattern for FRS water, in accordance with the present invention.
- Fig. 7 is a graphical representation, illustrating power consumption during electrolysis for the production of FRS water, in accordance with the present invention.
- Fig. 8 is a comparison table illustrating the differences between the FRS water of the present invention and other existing prior art electrolysis water.
- FIG. 1 is a summary illustration of the various properties and the corresponding values of Free Radical Solution (FRS) water.
- FRS water comprises of H 2 O+ molecules, and contains Free Radicals therein.
- HIC Hydrogen Ion Concentration
- ORP Oxidation-Reduction Potential
- both ORP and HIC are used as a means to measure chemical characteristics of solutions, including water.
- the unit of measurement for HIC is "pH", which stands for “potential for Hydrogen” and represents the negative logarithm of the Hydrogen Ion Concentration, and is a value that indicates whether a substance is either acidic or alkaline according to the following scale: pH 1 - 3 Ultra Acidic pH 4 - 5 Acidic pH 6 - 8 Neutral pH 9 - 11 Alkaline pH 12 or more Ultra Alkaline
- the stated Hydrogen Ion Concentration (HIC) level of 6 - 8 pH is important in that it makes FRS water a safe neutral solution that does not require further processing for proper disposal.
- the range of 6 - 8 pH is also very important because it is not harmful for use, and hence has a wider application.
- the Oxidation-Reduction Potential defines the capability of a substance to either release or gain free electrons (the substance that gains electrons is termed the oxidizing agent).
- the unit of measurement for ORP is in general expressed in milli-volts (mV).
- Regular tap water for example has about 200mV to 600mV of ORP.
- the Dissolved Oxygen (DO) level of FRS water is greater than 10mg/L, with effective chlorine level of 0 ⁇ 1 mg/L (or PPM). Effective chlorine is a measure of the volume of chlorine in a solution. This low level enables the solution to be virtually free of chlorine, a chemical found in most water base products.
- Fig. 2 is a flow chart illustrating the typical production process of FRS water.
- regular water 2 Prior to electrolysis process, regular water 2 is pre-treated through processes 4 to 10 to eliminate most impurities and prepare the water for electrolysis process 12 to produce Free Radical solution 14.
- the Chlorine Removal Process 4 remove chlorine found in regular water.
- the removal of chlorine in the first step of pre-treatment of water 2 improves the overall electrolysis process in that no harmful chlorine gases will be generated when water is electrolyzed.
- the average volume of chlorine in regular water will depend on the water municipality and the jurisdictional regulations thereof. In general, regular water has around 20 - 30 mg/L of chlorine. After the Chlorine Removal Process 4, it will posses about 0 ⁇ 1 mg/L of chlorine.
- the Magnetic Field Process 6 is a well-known method for separating H 2 O water molecules, which are usually tied closely together in clusters, into single individual molecules of H 2 O (known as mono-molecules). H 2 O water molecules in water tend to cluster together, and with this process, H 2 O water molecule clusters are separated into individual H 2 O water molecules. This separation of H 2 O water molecules improves the efficiency of the electrolysis process because H 2 O water molecule clusters require a greater input of energy to be transformed into Free Radicals. This is because H 2 O water molecules clusters are less energetic. The individual H 2 O water mono- molecules on the other hand, tend to move randomly and more energetically in comparison with H 2 O water molecule clusters.
- the Rare Earth Ores Ceramic Filter Process 8 finally transforms any remaining H 2 O water molecule clusters remaining from the Magnetic Field Process 6, into single individual H 2 O mono-molecules.
- the rare earth ores are comprised of such elements as Nd, Ce, La, Zr, Y, U, Tr, Pd, Fe, Gd, Ti, Ca, K, P, Si, and Al. The natural radiation from these materials further help separate H 2 O water molecule clusters into individual H 2 O water mono-molecules, further facilitating efficient electrolysis of water to produce Free Radical Solution water.
- the Ion Exchange Filter Process 10 is used to remove "hardness" from water caused by materials such as calcium and Magnesium. These elements deteriorate the efficiency of the electrolysis process because they tend to combine with other molecules and create unwanted chemical reactions, hindering the electrolysis of water. This process can also be used to remove unwanted ions from polluted water streams. If regular water or pre-treated water is not available in service places such as remote disaster area, a supplemental filtration system is required before pretreatment processes 4 to 10.
- the pretreated water is electrolyzed using High Electric Field Electrolysis Process 12, with no chemicals added.
- the electrolysis of water produces the Free Radical Solution 14 of the present invention.
- the pretreatment processes 4 to 10 remove most chemical composite materials other than H 2 O such as for example, chlorine, magnesium, calcium, etc. In producing FRS water, all that is required is H 2 O.
- the pre-treated water before electrolysis 12 is therefore soft water, almost equal to purified water. Through pre-treatment processes, regular water is purified and most of the impurities are eliminated to improve the efficiency of electrolysis.
- the electrolysis of water enhances its ORP to more than 900mV while stabilizing its HIC within the range 6-8 pH.
- Fig. 3 is a sample of spectrum transmittance test result for FRS water and purified water.
- An optical spectrum analyzer measures the amount of spectrum absorbed (penetrated) and transmitted by a test material. Spectrum absorption and transmittance pattern for tested materials depend on the chemical composites contained therein. In this case, tested materials were FRS water and pure water. The result indicates that FRS water is almost identical to purified water because the transmittance patterns for both waters are almost identical as shown in Fig. 3A (purified water) and Fig. 3B (FRS water). The data proves that FRS water does not contain any chemical additives, and in fact, chemically is H 2 O.
- Fig. 4 is a listing of Free Radicals and their transformation patterns in FRS water. Transformation patterns illustrated in Fig. 4 occur repeatedly at random both during and after the electrolysis process. Each Free Radical is a result of the transformation of H 2 O water molecules in FRS water, illustrating the difference between FRS water and regular water (where no H 2 O molecule transformation occurs). Below is the same listing of transformation patterns and the resulting generated Free Radical:
- Free Radicals The generation of Free Radicals is random and is not necessarily in the sequence listed both above and in Fig. 4.
- the Free Radicals are transformed from one to another instantly and frequently in a random manner.
- Super oxide anion and hydroxyl radical float as free radicals in FRS water and are eventually stabilized by transforming to ozone or hydrogen peroxide.
- hydrogen peroxide and ozone also continue their transformations after electrolysis in the following manner: H 2 O 2 — > H + + HO 2 - (Transformation of hydrogen peroxide)
- Free Radicals generated are very unstable and tend to combine with other molecules or atoms surrounding them to stabilize. This phenomenon is used to sterilize various infective bacterial diseases such as for example, pathogenic bacilli.
- Application of FRS water to an infected area causes the Free Radicals in FRS water to combine with bacteria and other molecules, sterilizing the infected region.
- oxygen is forcefully removed from H 2 O water molecules, and is transformed into one of unstable Free Radical atoms that tends to combine with other atoms or molecules surrounding it.
- the combinations of Free Radicals such as oxygen with other molecules, such as pathogenic bacilli oxidize and sterilize the bacteria. It is important to note that all the transformation patterns of Free Radicals shown in Fig. 4 are random, continuous and repeat at almost the same level for at least two -(2) hours after electrolysis.
- FIG. 5 is a sample Electron Spin Resonance (ESR) test result for capturing OH radicals in FRS water detected immediately after production, one- (1) hour after production, and two- (2) hours after production. ESR spectrum patterns of all three are almost identical and show the capture of OH radicals, which indicates that FRS water maintains the same level and transformations of Free Radicals consistently for at least two- (2) hours after production.
- the high ORP level of more than 900mV generated in FRS water helps the self-perpetuation of continued generation of Free Radicals and their transformations after electrolysis. In other words, FRS water continues the electrolysis process itself for as long as the ORP levels are high.
- FRS water can be used as a sterilizing solution for at least two- (2) hours after it is produced, which is a substantial practical benefit for use in comparison with the existing electrolysis water such as for example, Ultra Acidic Water.
- the ORP levels for Ultra Acidic Water is reduced immediately after production, which means a loss in sterilizing'capability.
- the Ultra Acidic Water can maintain a 900mV ORP for only 10 - 15 minutes after production.
- the ORP level of the FRS water of the present invention will reach its peak ORP usually 10 ⁇ 15 minutes after production and maintain more than 900mV level at least 2 hours thereafter, including the very high free radical reactions.
- Fig. 6 is a graphical representation for the Oxidation-Reduction Potential change vs. time for FRS water.
- a peak of ORP is indicated at approximately 10 to 15 minutes after production, maintaining the same for about 40 minutes.
- the level of ORP gradually decreases with time.
- very high level of ORP at about 900mV
- ORP levels at about 900mV
- the FRS water maintains the high levels of ORP with a stabilized level of Hydrogen Ion Concentrate (HIC) of 6 - 8 pH.
- HIC Hydrogen Ion Concentrate
- FRS water While FRS water gradually returns to regular water, Free Radicals continue to combine with other Free Radicals like oxygen found in FRS water and in the air.
- DO Dissolved Oxygen
- FRS water has more than 10mg/L of DO.
- the production of Free Radicals eventually stop as the ORP levels in FRS water is decreased from about 1000mV down to approximately 200mV to 600mV.
- Fig. 7 is a graphical representation, illustrating power consumption during electrolysis for the production of FRS water.
- the Oxidation-Reduction Potential in FRS water increases as the electrolysis voltage is increased.
- This increase in ORP reduces the need for an ever-increasing application of power for continued electrolysis to generate FRS water, minimizing the power consumption during production.
- the amount of power applied to electrolyze water may be controlled either manually by a power supply and an amplifier, or automatically through a central processing unit.
- the relationship between the ORP level in FRS water and the application of power to produce the FRS water is dependent on many factors, including for example, the size of electrolysis cell, quality of water, water temperature, etc.
- the Oxidation- Reduction Potential in FRS water may be adjusted by controlling the electric power to the electrolysis cell and/or the time-duration of electrolysis.
- FRS water with highest ORP levels such as 1100mV may be produced.
- 900mV of ORP in FRS water may be sufficient. Since FRS water maintains ORP levels at more than 900mV for at least two hours, the FRS water itself may be used as a source of electricity, for example, a battery.
- Fig. 8 is a comparison table illustrating the differences between the FRS water of the present invention and other existing prior art electrolysis water according to ORP, HIC, and Effective Chlorine levels.
- Prior art functional waters such as Ultra Acidic water use the chlorine contained in tap water to increase Oxidation Reduction Potential in the water solution.
- other additives including various chemicals are also added to improve the electrolytic character of water, which may cause the production of various chlorine gases harmful to human health.
- the FRS water production process of the present invention removes most of the chlorine at the first processing stage of water. Therefore, FRS water is generated as a result of transformation of water molecules, whereas all the other existing electrolysis waters are produced as a result of chemical reaction among water molecules and chemical electrolysis additives.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Physical Water Treatments (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA038260689A CN1784238A (zh) | 2003-03-04 | 2003-03-04 | 自由基溶液水 |
EP03719352A EP1617851A4 (fr) | 2003-03-04 | 2003-03-04 | Eau pour solution radicalaire |
PCT/US2003/006600 WO2004078654A2 (fr) | 2003-03-04 | 2003-03-04 | Eau pour solution radicalaire |
AU2003223222A AU2003223222A1 (en) | 2003-03-04 | 2003-03-04 | Free radical solution water |
JP2004569169A JP2006513849A (ja) | 2003-03-04 | 2003-03-04 | フリーラジカル溶液である水 |
US10/547,722 US20060263441A1 (en) | 2003-03-04 | 2003-03-04 | Free radical solution water |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2003/006600 WO2004078654A2 (fr) | 2003-03-04 | 2003-03-04 | Eau pour solution radicalaire |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004078654A2 true WO2004078654A2 (fr) | 2004-09-16 |
WO2004078654A3 WO2004078654A3 (fr) | 2005-09-15 |
Family
ID=32961108
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/006600 WO2004078654A2 (fr) | 2003-03-04 | 2003-03-04 | Eau pour solution radicalaire |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1617851A4 (fr) |
JP (1) | JP2006513849A (fr) |
CN (1) | CN1784238A (fr) |
AU (1) | AU2003223222A1 (fr) |
WO (1) | WO2004078654A2 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008131936A2 (fr) * | 2007-04-25 | 2008-11-06 | Akuatech S.R.L. | Eau électrolytique extrêmement stable à largeur de raie à mi-hauteur de rmn réduite |
US8062500B2 (en) | 2001-12-05 | 2011-11-22 | Oculus Innovative Sciences, Inc. | Method and apparatus for producing negative and positive oxidative reductive potential (ORP) water |
US8147444B2 (en) | 2006-01-20 | 2012-04-03 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing peritonitis with oxidative reductive potential water solution |
US8277634B2 (en) | 2005-10-28 | 2012-10-02 | Apr Nanotechnologies S.A. | Electrolytic water treatment device having sintered nanoparticle coated electrode and method for making acid or basic water therewith |
US8323252B2 (en) | 2005-03-23 | 2012-12-04 | Oculus Innovative Sciences, Inc. | Method of treating skin ulcers using oxidative reductive potential water solution |
US8691289B2 (en) | 2009-06-17 | 2014-04-08 | Apr Nanotechnologies S.A. | Methods of treating outer eye disorders using high ORP acid water and compositions thereof |
US9168318B2 (en) | 2003-12-30 | 2015-10-27 | Oculus Innovative Sciences, Inc. | Oxidative reductive potential water solution and methods of using the same |
US9498548B2 (en) | 2005-05-02 | 2016-11-22 | Oculus Innovative Sciences, Inc. | Method of using oxidative reductive potential water solution in dental applications |
US10342825B2 (en) | 2009-06-15 | 2019-07-09 | Sonoma Pharmaceuticals, Inc. | Solution containing hypochlorous acid and methods of using same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101662961B (zh) * | 2007-05-10 | 2013-09-11 | 仓敷纺织株式会社 | 清洗方法和其中使用的设备 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5833831A (en) * | 1994-03-25 | 1998-11-10 | Nec Corporation | Method and system for generating electrolyzed water |
US6143163A (en) * | 1997-08-06 | 2000-11-07 | Permelec Electrode Ltd. | Method of water electrolysis |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6426066B1 (en) * | 2000-01-12 | 2002-07-30 | California Pacific Labs, Inc. | Use of physiologically balanced, ionized, acidic solution in wound healing |
-
2003
- 2003-03-04 CN CNA038260689A patent/CN1784238A/zh active Pending
- 2003-03-04 JP JP2004569169A patent/JP2006513849A/ja active Pending
- 2003-03-04 AU AU2003223222A patent/AU2003223222A1/en not_active Abandoned
- 2003-03-04 WO PCT/US2003/006600 patent/WO2004078654A2/fr active Application Filing
- 2003-03-04 EP EP03719352A patent/EP1617851A4/fr not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5833831A (en) * | 1994-03-25 | 1998-11-10 | Nec Corporation | Method and system for generating electrolyzed water |
US6143163A (en) * | 1997-08-06 | 2000-11-07 | Permelec Electrode Ltd. | Method of water electrolysis |
Non-Patent Citations (1)
Title |
---|
See also references of EP1617851A2 * |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8062500B2 (en) | 2001-12-05 | 2011-11-22 | Oculus Innovative Sciences, Inc. | Method and apparatus for producing negative and positive oxidative reductive potential (ORP) water |
US10016455B2 (en) | 2003-12-30 | 2018-07-10 | Sonoma Pharmaceuticals, Inc. | Method of preventing or treating influenza with oxidative reductive potential water solution |
US9642876B2 (en) | 2003-12-30 | 2017-05-09 | Sonoma Pharmaceuticals, Inc. | Method of preventing or treating sinusitis with oxidative reductive potential water solution |
US9168318B2 (en) | 2003-12-30 | 2015-10-27 | Oculus Innovative Sciences, Inc. | Oxidative reductive potential water solution and methods of using the same |
US8840873B2 (en) | 2005-03-23 | 2014-09-23 | Oculus Innovative Sciences, Inc. | Method of treating second and third degree burns using oxidative reductive potential water solution |
US8323252B2 (en) | 2005-03-23 | 2012-12-04 | Oculus Innovative Sciences, Inc. | Method of treating skin ulcers using oxidative reductive potential water solution |
US9498548B2 (en) | 2005-05-02 | 2016-11-22 | Oculus Innovative Sciences, Inc. | Method of using oxidative reductive potential water solution in dental applications |
US8277634B2 (en) | 2005-10-28 | 2012-10-02 | Apr Nanotechnologies S.A. | Electrolytic water treatment device having sintered nanoparticle coated electrode and method for making acid or basic water therewith |
US8834445B2 (en) | 2006-01-20 | 2014-09-16 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing peritonitis with oxidative reductive potential water solution |
US9072726B2 (en) | 2006-01-20 | 2015-07-07 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution |
US8147444B2 (en) | 2006-01-20 | 2012-04-03 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing peritonitis with oxidative reductive potential water solution |
US9782434B2 (en) | 2006-01-20 | 2017-10-10 | Sonoma Pharmaceuticals, Inc. | Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution |
US8709495B2 (en) | 2007-04-25 | 2014-04-29 | Apr Nanotechnologies S.A. | Highly stable electrolytic water with reduced NMR half line width |
AU2008243353B2 (en) * | 2007-04-25 | 2014-02-06 | Akuatech S.R.L. | Highly stable electrolytic water with reduced NMR half line width |
EP2594276A1 (fr) * | 2007-04-25 | 2013-05-22 | APR Nanotechnologies S.A. | Eau electrolytique extremement stable a largeur de raie a mi-hauteur de RMN Reduite |
US9404192B2 (en) | 2007-04-25 | 2016-08-02 | Apr Nanotechnologies S.A. | Highly stable electrolytic water with reduced NMR half line width |
WO2008131936A2 (fr) * | 2007-04-25 | 2008-11-06 | Akuatech S.R.L. | Eau électrolytique extrêmement stable à largeur de raie à mi-hauteur de rmn réduite |
US9889153B2 (en) | 2007-04-25 | 2018-02-13 | Apr Nanotechnologies S.A. | Highly stable electrolytic water with reduced NMR half line width |
WO2008131936A3 (fr) * | 2007-04-25 | 2009-10-01 | Akuatech S.R.L. | Eau électrolytique extrêmement stable à largeur de raie à mi-hauteur de rmn réduite |
US10342825B2 (en) | 2009-06-15 | 2019-07-09 | Sonoma Pharmaceuticals, Inc. | Solution containing hypochlorous acid and methods of using same |
US8691289B2 (en) | 2009-06-17 | 2014-04-08 | Apr Nanotechnologies S.A. | Methods of treating outer eye disorders using high ORP acid water and compositions thereof |
Also Published As
Publication number | Publication date |
---|---|
AU2003223222A1 (en) | 2004-09-28 |
AU2003223222A8 (en) | 2004-09-28 |
WO2004078654A3 (fr) | 2005-09-15 |
CN1784238A (zh) | 2006-06-07 |
EP1617851A4 (fr) | 2011-09-21 |
EP1617851A2 (fr) | 2006-01-25 |
JP2006513849A (ja) | 2006-04-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Drogui et al. | Oxidising and disinfecting by hydrogen peroxide produced in a two-electrode cell | |
Ghernaout et al. | From chemical disinfection to electrodisinfection: The obligatory itinerary? | |
TW450945B (en) | Electrolyzed functional water, and production process and production apparatus thereof | |
RU2064440C1 (ru) | Способ обработки воды | |
US20090266706A1 (en) | High electric field electrolysis cell | |
Li et al. | Electrochemical wastewater disinfection: Identification of its principal germicidal actions | |
CN105540761B (zh) | 一种水体消毒设备及利用其进行水体消毒的方法 | |
EP1617851A2 (fr) | Eau pour solution radicalaire | |
US20060263441A1 (en) | Free radical solution water | |
JP2006198499A (ja) | 水の殺菌方法および殺菌装置 | |
Suresh et al. | Experimental analysis on the synergistic effect of combined use of ozone and UV radiation for the treatment of dairy industry wastewater | |
Venczel et al. | Inactivation of enteric microbes in water by electro-chemical oxidant from brine (NaCl) and free chlorine | |
CN108358298A (zh) | 一种利用臭氧控制亚硝胺类物质生成的方法 | |
Selvakumar et al. | Use of Fenton's reagent as a disinfectant | |
WO2022050838A1 (fr) | Traitement à l'ozone d'eaux usées | |
KR20060004911A (ko) | 자유 라디칼 용해수 | |
JPH1133561A (ja) | 凝集沈澱処理設備 | |
JP2007234459A (ja) | 燃料電池システムの制菌方法 | |
Ganizadeh et al. | Elimination of pathogenic bacteria using electrochemical process containing steel mesh electrode | |
RU2220109C2 (ru) | Способ дезинфекции с помощью активированного водного препарата | |
Rogers et al. | Water purification, microbiological control, sterilization and organic waste decomposition using an electrochemical advanced ozonation process | |
Chang et al. | Study on the efficacy of sterilization in tap water by electrocatalytic technique | |
RU2188169C1 (ru) | Способ получения питьевой воды | |
RU2804982C1 (ru) | Устройство для обеззараживания сточных вод холодной атмосферной воздушной плазмой и способ его использования | |
JP2002153873A (ja) | 殺菌方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1020057016272 Country of ref document: KR Ref document number: 20038260689 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004569169 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2003719352 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020057016272 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2003719352 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2006263441 Country of ref document: US Ref document number: 10547722 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 10547722 Country of ref document: US |