WO2004047972A3 - New catalyst structure for olefin polymerization - Google Patents

New catalyst structure for olefin polymerization Download PDF

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Publication number
WO2004047972A3
WO2004047972A3 PCT/US2003/036049 US0336049W WO2004047972A3 WO 2004047972 A3 WO2004047972 A3 WO 2004047972A3 US 0336049 W US0336049 W US 0336049W WO 2004047972 A3 WO2004047972 A3 WO 2004047972A3
Authority
WO
WIPO (PCT)
Prior art keywords
olefin polymerization
ligand
catalyst structure
new catalyst
catalyst
Prior art date
Application number
PCT/US2003/036049
Other languages
French (fr)
Other versions
WO2004047972A2 (en
Inventor
Abbas Razavi
Margarito Lopez
Didier Baekelmans
Vladimir Marin
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/301,884 external-priority patent/US20040102311A1/en
Application filed by Fina Technology filed Critical Fina Technology
Priority to AU2003285202A priority Critical patent/AU2003285202A1/en
Priority to JP2004555427A priority patent/JP4977322B2/en
Priority to EP03779526A priority patent/EP1562705A4/en
Priority to CA002503986A priority patent/CA2503986A1/en
Publication of WO2004047972A2 publication Critical patent/WO2004047972A2/en
Publication of WO2004047972A3 publication Critical patent/WO2004047972A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms

Abstract

A catalyst comprising e.g. a pyridine bisimine ligand bonded to a transition metal by at least two heteroatoms of the ligand, the ligand having at least two aromatic groups or cyclopentadienyl groups on different heteroatoms of the ligand. The transition metal compound, its preparation, preparation and use of the catalyst in an olefin polymerization catalyst are also disclosed.
PCT/US2003/036049 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization WO2004047972A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2003285202A AU2003285202A1 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization
JP2004555427A JP4977322B2 (en) 2002-11-21 2003-11-12 A new catalyst structure for olefin polymerization.
EP03779526A EP1562705A4 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization
CA002503986A CA2503986A1 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/301,884 2002-11-21
US10/301,884 US20040102311A1 (en) 2002-11-21 2002-11-21 Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
US10/692,068 2003-10-23
US10/692,068 US6894180B2 (en) 2002-11-21 2003-10-23 Catalyst structure for olefin polymerization

Publications (2)

Publication Number Publication Date
WO2004047972A2 WO2004047972A2 (en) 2004-06-10
WO2004047972A3 true WO2004047972A3 (en) 2004-12-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/036049 WO2004047972A2 (en) 2002-11-21 2003-11-12 New catalyst structure for olefin polymerization

Country Status (6)

Country Link
EP (1) EP1562705A4 (en)
JP (1) JP4977322B2 (en)
KR (1) KR20050085108A (en)
AU (1) AU2003285202A1 (en)
CA (1) CA2503986A1 (en)
WO (1) WO2004047972A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
CA2594943A1 (en) * 2005-01-19 2006-07-27 Merck & Co., Inc. Aminomethyl beta-secretase inhibitors for the treatment of alzheimer's disease
EP1746111A1 (en) * 2005-07-19 2007-01-24 Total Petrochemicals Research Feluy Polymerisation catalyst system based on dioxime ligands
AR124328A1 (en) * 2020-12-15 2023-03-15 Shell Int Research AN OLIGOMERIZATION CATALYST, METHOD OF PREPARATION AND PROCESS FOR USING THE CATALYST
CN114874362B (en) * 2022-03-18 2023-05-23 中国科学院青岛生物能源与过程研究所 Pyridinimine oxime iron catalyst, preparation method thereof and application thereof in conjugated diene polymerization

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999065951A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
WO1999065952A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE234870T1 (en) * 1996-03-27 2003-04-15 Dow Global Technologies Inc SOLUTION POLYMERIZATION PROCESS WITH DISPERSED CATALYST ACTIVATORS
JP2001508107A (en) * 1997-01-13 2001-06-19 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー Propylene polymerization
CA2347385A1 (en) * 1999-09-02 2001-03-15 Haruhito Sato Transition metal compounds, catalysts for the production of .alpha.-olefins and process therefor
CN1164534C (en) * 2001-07-20 2004-09-01 中国科学院化学研究所 Iron catalyst and its prepn and application
ES2272770T3 (en) * 2001-08-01 2007-05-01 Shell Internationale Research Maatschappij B.V. LIGANDS AND CATALYTIC SYSTEMS DERIVED FROM THEM FOR OLIGOMERIZATION OF ETHYLENE TO LINEAR ALFA-OLEFINS.
JP2003206308A (en) * 2001-11-09 2003-07-22 Idemitsu Petrochem Co Ltd Polymerization catalyst for vinyl compound, polymer of vinyl compound and its manufacturing method, and composite resin comprising the polymer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999065951A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
WO1999065952A1 (en) * 1998-06-16 1999-12-23 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and method of polymerizing olefin
US6313243B1 (en) * 1998-06-16 2001-11-06 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin
US6369177B1 (en) * 1998-06-16 2002-04-09 Mitsui Chemicals Inc Catalyst for olefin polymerization and method of polymerizing olefin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1562705A4 *

Also Published As

Publication number Publication date
KR20050085108A (en) 2005-08-29
EP1562705A2 (en) 2005-08-17
WO2004047972A2 (en) 2004-06-10
AU2003285202A8 (en) 2004-06-18
CA2503986A1 (en) 2004-06-10
EP1562705A4 (en) 2007-04-25
AU2003285202A1 (en) 2004-06-18
JP4977322B2 (en) 2012-07-18
JP2006507345A (en) 2006-03-02

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