WO2004045750A1 - Method for producing pores in a thin polyimide sheet - Google Patents
Method for producing pores in a thin polyimide sheet Download PDFInfo
- Publication number
- WO2004045750A1 WO2004045750A1 PCT/EP2003/012780 EP0312780W WO2004045750A1 WO 2004045750 A1 WO2004045750 A1 WO 2004045750A1 EP 0312780 W EP0312780 W EP 0312780W WO 2004045750 A1 WO2004045750 A1 WO 2004045750A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- une
- feuille
- est
- que
- dans
- Prior art date
Links
- 239000011148 porous material Substances 0.000 title claims abstract description 49
- 239000004642 Polyimide Substances 0.000 title claims abstract description 26
- 229920001721 polyimide Polymers 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000002500 ions Chemical class 0.000 claims description 12
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 claims description 5
- 238000012550 audit Methods 0.000 claims description 2
- 229910052724 xenon Inorganic materials 0.000 claims description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract 2
- 238000003486 chemical etching Methods 0.000 abstract 1
- 239000002071 nanotube Substances 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- -1 des ions Chemical class 0.000 description 4
- 238000000059 patterning Methods 0.000 description 4
- 229920000128 polypyrrole Polymers 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 241000861223 Issus Species 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 241000287107 Passer Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0032—Organic membrane manufacture by inducing porosity into non porous precursor membranes by elimination of segments of the precursor, e.g. nucleation-track membranes, lithography or laser methods
- B01D67/0034—Organic membrane manufacture by inducing porosity into non porous precursor membranes by elimination of segments of the precursor, e.g. nucleation-track membranes, lithography or laser methods by micromachining techniques, e.g. using masking and etching steps, photolithography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
- B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
- B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26F—PERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
- B26F1/00—Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
- B26F1/26—Perforating by non-mechanical means, e.g. by fluid jet
- B26F1/31—Perforating by non-mechanical means, e.g. by fluid jet by radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/021—Pore shapes
- B01D2325/0212—Symmetric or isoporous membranes
Definitions
- a cet effet, et selon un premier aspect, l'invention concerne un proceede de creation de pores de taille nanometrique a micrometrique dans une fiille mince de polyimide, dans lequel la fuseille estquee, dans cet ordre, a : - un bombardement ionique ;
- La fiille presente par example une epaisseur comprise entre 2 et 100 ⁇ m.
- Rhythm une hard realisation, la fuseille presente une epaisseur comprise entre 5 nm et 10 ⁇ m, et est deposee sur un support.
- par example comprise entre 2 et 100 ⁇ m ;
- La fille 1 est tout d'mergedCloude a un bombardement ionique 2.
- la densite d'ions bombardant la fuseille 1 etant comprise entrelO 4 et 10 13 ions/cm 2 .
- D' satisfying ions peuvent etre utilises pour le bombardement 2, tels que des ions issus de I'argon, du krypton, du cobalt, du plomb, de I'or, ou de I'uranium.
- L'energie de ces ions est comprise entre 1 et 10 MeV/amu (atomic mass unit, ou unite de masse atomique), I'intensite du severityceau patented varier entre 10 6 et 10 13 ions/s.
- La figure 2 represente, ceremonies au MEB, la surface d'une fiille 1 de polyimide deposee sur un support en silicium et presentant des pores 6 europas par le proceede de la figure 1. Les pores 6 thank sensiblement cylindriques, et presentent des diametres sensiblement identiques, de I' Arthur de 90 a 95 nm.
- Des nanotubes 7 de polypyrrole ont ete synthetises chimiquement dans les pores 6 crees dans la primaille 1. Les nanotubes 7 presentent une forme sensiblement cylindrique sur advocate leurholder, et des diametres sensiblement egaux, de I' Arthur de 40 nm.
Landscapes
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Optics & Photonics (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Forests & Forestry (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60306679T DE60306679T2 (en) | 2002-11-19 | 2003-11-14 | PROCESS FOR PRODUCING PORES IN A THIN POLYIMIDE FILM |
AU2003289706A AU2003289706A1 (en) | 2002-11-19 | 2003-11-14 | Method for producing pores in a thin polyimide sheet |
EP03776906A EP1569742B1 (en) | 2002-11-19 | 2003-11-14 | Method for producing pores in a thin polyimide sheet |
US11/131,943 US7419612B2 (en) | 2002-11-19 | 2005-05-18 | Method of creating pores in a thin sheet of polyimide |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0214473A FR2847194B1 (en) | 2002-11-19 | 2002-11-19 | METHOD FOR CREATING PORES IN A POLYIMIDE THIN SHEET |
FR0214473 | 2002-11-19 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/131,943 Continuation US7419612B2 (en) | 2002-11-19 | 2005-05-18 | Method of creating pores in a thin sheet of polyimide |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004045750A1 true WO2004045750A1 (en) | 2004-06-03 |
Family
ID=32187737
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/012780 WO2004045750A1 (en) | 2002-11-19 | 2003-11-14 | Method for producing pores in a thin polyimide sheet |
Country Status (7)
Country | Link |
---|---|
US (1) | US7419612B2 (en) |
EP (1) | EP1569742B1 (en) |
AT (1) | ATE332184T1 (en) |
AU (1) | AU2003289706A1 (en) |
DE (1) | DE60306679T2 (en) |
FR (1) | FR2847194B1 (en) |
WO (1) | WO2004045750A1 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006036957A2 (en) * | 2004-09-28 | 2006-04-06 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising plasma etched porous support |
CN1293129C (en) * | 2004-10-14 | 2007-01-03 | 北京化工大学 | Method for preparing Nano film of multiporous polyimide in low dielectric constant |
CN101828114A (en) * | 2007-08-24 | 2010-09-08 | 国立大学法人东京工业大学 | Method for sending mbms and choosing device |
US7867669B2 (en) | 2004-09-28 | 2011-01-11 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising laser micromachined porous support |
US7947405B2 (en) | 2004-09-29 | 2011-05-24 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising porous ceramic support |
US8962132B2 (en) | 2004-09-28 | 2015-02-24 | Giner, Inc. | Solid polymer electrolyte composite membrane comprising a porous support and a solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide |
US9728802B2 (en) | 2013-05-14 | 2017-08-08 | Giner, Inc. | Micromold methods for fabricating perforated substrates and for preparing solid polymer electrolyte composite membranes |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080060995A1 (en) * | 2006-09-12 | 2008-03-13 | Sean Zhang | Semi-Permeable Membrane |
WO2013126885A1 (en) * | 2012-02-23 | 2013-08-29 | University Of Houston | Design and fabrication of multilayered nanosized porous membranes and their use for making novel nanostructures |
US10896804B2 (en) * | 2017-07-27 | 2021-01-19 | Lawrence Livermore National Security, Llc | Planarization, densification, and exfoliation of porous materials by high-energy ion beams |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3816078A1 (en) * | 1988-05-11 | 1989-11-23 | Brandt Reinhard | Process for producing heat-resistant and chemical-resistant ultrafinely pored microsieves (hole size d > 10 nano-m) from the polyimide film "Kapton" (tradename of Du Pont) |
WO2001049402A1 (en) * | 1999-12-29 | 2001-07-12 | Universite Catholique De Louvain | Method for creating pores in a polymer material |
WO2001049403A1 (en) * | 1999-12-29 | 2001-07-12 | Universite Catholique De Louvain | Method for creating pores and microporous film |
Family Cites Families (24)
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US3303085A (en) * | 1962-02-28 | 1967-02-07 | Gen Electric | Molecular sieves and methods for producing same |
US3493751A (en) * | 1966-06-17 | 1970-02-03 | Gen Electric | Track registration alpha autoradiography |
US3415993A (en) * | 1966-11-07 | 1968-12-10 | Gen Electric | Radiation detection sheet material having metal coating to facilitate read-out |
GB1271423A (en) * | 1968-06-27 | 1972-04-19 | Gen Electric | Improvements relating to the manufacture of sheets having holes therein by an etching process |
US3612871A (en) * | 1969-04-01 | 1971-10-12 | Gen Electric | Method for making visible radiation damage tracks in track registration materials |
US3852134A (en) * | 1969-05-05 | 1974-12-03 | Gen Electric | Method for forming selectively perforate bodies |
BE755122A (en) * | 1969-06-20 | 1971-02-01 | Albright & Wilson | COPPER ELECTROLYTIC DEPOSIT PROCESS |
US3677844A (en) * | 1970-11-19 | 1972-07-18 | Gen Electric | Process for making an elastic stretchy sheet containing apertures having a diameter of at least five angstroms and being suitable as a molecular sieve |
US3770532A (en) * | 1971-02-16 | 1973-11-06 | Gen Electric | Porous bodies and method of making |
US3713921A (en) * | 1971-04-01 | 1973-01-30 | Gen Electric | Geometry control of etched nuclear particle tracks |
GB1375204A (en) | 1971-04-05 | 1974-11-27 | ||
US3742182A (en) * | 1971-12-27 | 1973-06-26 | Coherent Radiation | Method for scanning mask forming holes with a laser beam |
US4115303A (en) * | 1972-04-21 | 1978-09-19 | Commissariat A L'energie Atomique | Method of fabrication of porous macromolecular materials having an internal lining and materials obtained by means of said method |
EP0109147A3 (en) | 1982-10-19 | 1986-04-16 | Varian Associates, Inc. | Charged particle beam lithography machine incorporating localized vacuum envelope |
US4652412A (en) * | 1985-06-14 | 1987-03-24 | Polaroid Corporation | Method for forming microporous filter |
FR2597391B1 (en) * | 1986-03-25 | 1989-02-24 | Univ Catholique Louvain | PROCESS FOR PERFORMING PERFORATIONS IN SOLID SHEET MATERIAL, IRRADIATION DEVICE FOR IMPLEMENTING THE PROCESS AND PERFORATED MATERIAL THUS OBTAINED |
FR2607022B1 (en) * | 1986-11-20 | 1991-02-22 | Commissariat Energie Atomique | PRODUCTION OF ASYMMETRIC MICROPOROUS MEMBRANES BY DOUBLE IRRADIATION, AND MEMBRANES THUS OBTAINED |
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-
2002
- 2002-11-19 FR FR0214473A patent/FR2847194B1/en not_active Expired - Fee Related
-
2003
- 2003-11-14 WO PCT/EP2003/012780 patent/WO2004045750A1/en not_active Application Discontinuation
- 2003-11-14 AU AU2003289706A patent/AU2003289706A1/en not_active Abandoned
- 2003-11-14 AT AT03776906T patent/ATE332184T1/en not_active IP Right Cessation
- 2003-11-14 DE DE60306679T patent/DE60306679T2/en not_active Expired - Lifetime
- 2003-11-14 EP EP03776906A patent/EP1569742B1/en not_active Expired - Lifetime
-
2005
- 2005-05-18 US US11/131,943 patent/US7419612B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3816078A1 (en) * | 1988-05-11 | 1989-11-23 | Brandt Reinhard | Process for producing heat-resistant and chemical-resistant ultrafinely pored microsieves (hole size d > 10 nano-m) from the polyimide film "Kapton" (tradename of Du Pont) |
WO2001049402A1 (en) * | 1999-12-29 | 2001-07-12 | Universite Catholique De Louvain | Method for creating pores in a polymer material |
WO2001049403A1 (en) * | 1999-12-29 | 2001-07-12 | Universite Catholique De Louvain | Method for creating pores and microporous film |
Non-Patent Citations (3)
Title |
---|
A.I.VILENSKY ET AL: "Polyimide Track Membranes for Ultrafiltration and Microfiltration", POLYMER SCIENCE, vol. 36, no. 3, 1994, Birmingham,AL,US, pages 391-400, XP000434424 * |
L.KLINTBERG ET AL: "Sodium hypochlorite as a developer for heavy ion tracks in polyimide", NUCLEAR INSTRUMENTS AND METHODS IN PHYSICS RESEARCH B, vol. 184, 2001, Amsterdam,NL, pages 536-543, XP004313112 * |
P.YU.APEL ET AL: "Morphology of latent and etched heavy ion tracks in radiation resistant polymers polyimide and poly(ethylene naphthalate)", NUCLEAR INSTRUMENTS AND METHODS IN PHYSICS RESEARCH B, vol. 185, 2001, Amsterdam,NL, pages 216-221, XP004326838 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006036957A2 (en) * | 2004-09-28 | 2006-04-06 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising plasma etched porous support |
WO2006036957A3 (en) * | 2004-09-28 | 2007-12-13 | Giner Electrochemical Systems | Solid polymer electrolyte composite membrane comprising plasma etched porous support |
US7807063B2 (en) | 2004-09-28 | 2010-10-05 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising plasma etched porous support |
US7867669B2 (en) | 2004-09-28 | 2011-01-11 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising laser micromachined porous support |
US8962132B2 (en) | 2004-09-28 | 2015-02-24 | Giner, Inc. | Solid polymer electrolyte composite membrane comprising a porous support and a solid polymer electrolyte including a dispersed reduced noble metal or noble metal oxide |
US7947405B2 (en) | 2004-09-29 | 2011-05-24 | Giner Electrochemical Systems, Llc | Solid polymer electrolyte composite membrane comprising porous ceramic support |
CN1293129C (en) * | 2004-10-14 | 2007-01-03 | 北京化工大学 | Method for preparing Nano film of multiporous polyimide in low dielectric constant |
CN101828114A (en) * | 2007-08-24 | 2010-09-08 | 国立大学法人东京工业大学 | Method for sending mbms and choosing device |
CN101828114B (en) * | 2007-08-24 | 2015-03-11 | Lsip基金运营联合公司 | Method for detecting gynecological cancer |
US9728802B2 (en) | 2013-05-14 | 2017-08-08 | Giner, Inc. | Micromold methods for fabricating perforated substrates and for preparing solid polymer electrolyte composite membranes |
Also Published As
Publication number | Publication date |
---|---|
FR2847194A1 (en) | 2004-05-21 |
FR2847194B1 (en) | 2005-02-04 |
EP1569742A1 (en) | 2005-09-07 |
US7419612B2 (en) | 2008-09-02 |
DE60306679D1 (en) | 2006-08-17 |
ATE332184T1 (en) | 2006-07-15 |
US20060000798A1 (en) | 2006-01-05 |
EP1569742B1 (en) | 2006-07-05 |
DE60306679T2 (en) | 2007-06-28 |
AU2003289706A1 (en) | 2004-06-15 |
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