WO2004022493A1 - Dewatering of suspensions - Google Patents
Dewatering of suspensions Download PDFInfo
- Publication number
- WO2004022493A1 WO2004022493A1 PCT/EP2003/009381 EP0309381W WO2004022493A1 WO 2004022493 A1 WO2004022493 A1 WO 2004022493A1 EP 0309381 W EP0309381 W EP 0309381W WO 2004022493 A1 WO2004022493 A1 WO 2004022493A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coagulant
- flocculant
- suspension
- composition
- encapsulated
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/09—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/04—Surfactants, used as part of a formulation or alone
Definitions
- This invention relates to dewatering of suspensions and more particularly dewatering of suspensions using encapsulated material blended with a flocculant.
- the invention has been made with a view to dealing with this problem.
- a method for dewatering suspensions comprising adding to the suspension a high intrinsic viscosity (IV), water soluble, cationic polymer flocculant and a coagulant, the coagulant being encapsulated or entrapped whereby release of the coagulant into the suspension is delayed.
- IV intrinsic viscosity
- flocculation proceeds rapidly following addition of the high IV polymer flocculant to the suspension and is initially unaffected by the encapsulated or otherwise entrapped coagulant present also in the suspension but not having any effect.
- the coagulant is released into the suspension for example by rupturing of the capsules which enclose the coagulant or by migration from a matrix in which the coagulant is entrapped.
- no additional equipment is required for mixing the coagulant into the suspension at a later stage than the flocculant since it can be added at the same time as the flocculant.
- the coagulant is released into the suspension when flocculation and free drainage is substantially completed and any delay before the final dewatering stage can be kept to a minimum or eliminated completely.
- composition for use in dewatering suspensions comprising a high IV, water soluble, cationic polymer flocculant and a coagulant, the coagulant being encapsulated or otherwise entrapped.
- the coagulant may be any of the materials known for use as coagulants particularly low IV water soluble, cationic polymers and generally having an IV below 1.5 dl/g (measured using a suspended level viscometer on solutions of the coagulant polymer alone in 1 molar sodium chloride buffered to pH 7.5 at 25° and inorganic materials such as polyaluminium chloride.
- the cationic coagulant may comprise a polyamine coagulant polymer, such as a polymer made by condensation of an amine and/or a diamine or higher amine (e.g. ethylene diamine or tetraethylene pentamine) with epichlorohydrin or other epihalohydrin or with dichloroethane or other dihaloalkane.
- a polyamine coagulant polymer such as a polymer made by condensation of an amine and/or a diamine or higher amine (e.g. ethylene diamine or tetraethylene pentamine) with epichlorohydrin or other epihalohydrin or with dichloroethane or other dihaloalkane.
- suitable coagulants include polyethyleneimine, homopolymers of water soluble ethylenically unsaturated cationic monomer or a blend of one or more cationic ethylenically unsaturated monomers with one or more other ethylenically unsaturated monomers.
- the blend may be formed with acrylamide or other water soluble ethylenically unsaturated non- ionic monomer.
- the cationic monmer can be a diallyl quaternary monmer, generally diallyl dimethyl ammonium chloride (DADMAC) or dialkylaminoalkyl (meth) - acrylate or acrylamide wherein the alkyl groups generally contain 1 to 4 carbon atoms. Examples are dimethyl or diethyl aminoethyl or propyl (meth) - acrylate or acrylamideor dimethyl or diethyl aminomethyl (meth) - acrylamide.
- the monomer may be introduced as an acid addition salt or the polymer can be converted into such a salt after polymerisation.
- the quaternising group is usually methyl chloride or other aliphatic quaternising group.
- An acid such as adipic acid may advantageously be present when the coagulant is released into the thickened suspension.
- a preferred way of achieving this is to add encapsulated acid to the suspension at a suitable stage in the dewatering treatment, for example prior to flocculation.
- Encapsulation of the coagulant may be effected by known techniques utilising melamine /formaldehyde resin such as described for example in WO-A-98/28975
- Encapsulation using a polyamide can also be adopted, an example of such encapsulation being described in US Patent 6,225,372.
- the flocculant material preferably has an IV above 2.0 dl/g and desirably well above that, for example above 4.0 dl/g.
- the flocculant can be any of the polymers discussed above for the low IV polymer particularly preferred being a mixture of 80% dimethylaminoethylacrylate methyl chloride quaternary and 20% acrylamide with an IV of 8.0 dl/g.
- the coagulant in encapsulated form or otherwise entrapped and the flocculant may be added to the suspension together or separately.
- the flocculant and coagulant are premixed and then added to the suspension as a homogeneous blend. If desired a wetting agent can be added to the mixture followed by ageing to improve homogeneity.
- the ratio of coagulant to flocculant is preferably selected from the range 0.2 : 1.0 to 2.0 : 1.0 by weight, the selection being made having regard to the suspension to be dewatered.
- a concentrated mixture of flocculant and coagulant is prepared which is diluted appropriately before addition to a suspension.
- the encapsulated or otherwise entrapped coagulant can be one coagulant type or a mixture of two or more coagulants.
- the flocculant and encapsulated or otherwise entrapped coagulant are mixed with the suspension so that they are distributed throughout the suspension, preferably as evenly as possible.
- the flocculated suspension is initially drained - so called 'free drainage'.
- the encapsulated or otherwise entrapped coagulant is preferably not released into the suspension and takes no part in the dewatering.
- the thickened substrate is subjected to pressure dewatering whereby a solid cake is produced.
- the coagulant capsules become ruptured or the entrapment broken down so that the coagulant diffuses into the thickened suspension. This leads to an improvement in the dryness of the cake compared to the conventional dewatering methods.
- the invention is applicable to dewatering of suspensions generally, some examples of which are described in WO 02/12213.
- the invention can be used for dewatering aqueous suspensions or mixtures of organic and inorganic materials or suspensions made entirely of organic material.
- aqueous suspensions include industrial waste from dairies, canneries, chemical manufacturing waste, distillery waste, fermentation waste, waste from paper manufacturing plants, waste from dyeing plants, sewage suspensions such as any type of sludge derived from a sewage treatment plant including digested sludge, activated sludge, raw or primary sludge or mixtures thereof.
- the aqueous suspensions may also contain detergents and polymeric materials which can hinder precipitation. Modified methods for treatment in view of these factors are known to those familiar with the art.
- the dosage of flocculant and encapsulated or otherwise entrapped coagulant will depend upon the content of the suspension. Optimum results require accurate dosing. If the dose is too low or too high flocculation may be inferior. In addition the degree of agitation of the suspension during flocculation can also affect performance. The floes are very sensitive to agitation especially if the dosage is not at an optimum when there is a possibility that solids will be redispersed as discrete solids.
- the invention can also be used to aid retention and/or drainage in the production of paper in which the suspensions to be treated contain cellulosic fibres and optional fillers.
- Paper as used herein includes not only paper but also other cellulosic fibre- containing sheet or web-like products such as board and paperboard).
- the flocculated suspension is dewatered on a wire to form a wet web containing cellulosic fibres, whereafter the encapsulated or otherwise entrapped coagulant is released into the wet web.
- Improved drainage and/or retention can be obtained with papermaking stocks having high contents of salt and thus having high conductivity levels, and colloidal materials.
- the invention makes it possible to increase the speed of the paper machine and to use lower dosages of additives to give a corresponding drainage and/or retention effect thereby leading to an improved papermaking process and economic benefits.
- the invention can also be applied to papermaking processes using wood-containing fibre stocks and so called dirty or difficult stocks, for example those prepared from certain grades of recycled fibres and/or processes with extensive white water recirculation and limited fresh water supply and/or processes using fresh water having high salt contents, in particular salts of di-and multivalent cations such as calcium.
- the dosages of flocculant and encapsulated or otherwise entrapped coagulant to be added to the stock can vary within wide limits depending on, inter alia type of stock, salt content, type of salt or salts, filler content, type of filler etc.
- the stock to be treated can contain additives such as anionic microparticulate materials, for example anionic organic particles and anionic inorganic particles, water soluble anionic-vinyl addition polymers, low molecular weight cationic organic polymers, aluminium compounds and combinations thereof.
- anionic microparticulate materials for example anionic organic particles and anionic inorganic particles, water soluble anionic-vinyl addition polymers, low molecular weight cationic organic polymers, aluminium compounds and combinations thereof.
- Figure I is a graph showing the effect of the invention on free drainage
- Figure2 is a graph showing the effect of the invention on the cake solids
- Figures 3 and 4 are repeats of the procedures shown in Figures 1 and 2 respectively as a check on the results;
- Figures 5 and 6 are graphs showing the effect on free drainage and cake solids respectively with a different coagulant
- Figures 7 and 8 are graphs showing the effect on free drainage and cake solids respectively when polyamide capsules are used.
- Figure 9 is a graph showing the effect of including acid capsules.
- Example 1 In the Examples all ratios and percentages are by weight. In the Figures the x axis indicates the dose of flocculant. Example 1
- the thickened substrate collected in the filter was transferred to a piston head pressure cylinder with a filter-clothed head on one side. Pressure was applied to remove more water. The pressure was applied at 10 psi ( 0.69 bar) and increased to 100 psi (6.9 bar) over 10 minutes. The cake solids were removed, weighed and then placed in an oven overnight at 110°C. After reweighing the dry solids of the cake was calculated. The results are shown in Figure 2. This shows an increase in dryness. The average increase of dosages at 150 and 200 ppm in dryness with solutions containing 0.25:1 and 0.5:1 capsules ( containing active material) to flocculant was about 16%.
- Example 1 The procedure of Example 1 was repeated but with only three solutions containing capsules and flocculant in the ratio 1 :0.25 as follows:
- Example 2 The same procedure was followed as in Example 1 but using as coagulant, in the capsules, poly aluminium chloride in three solutions at ratios of 0.3:1 , 0.6:1 and 0.9:1 , capsules to flocculant.
- Example 2 The same procedure was followed as in Example 1 except that the capsules were of polyamide. Two solutions were used having ratios of capsules to flocculant of 1 :1 and 2:1 , these higher ratios than before being chosen because the capsules were supplied as an emulsion.
- Example 9 The same procedure was followed as in Example 1 except that capsules of citric acid were blended with the flocculant in the ratio 1 :1 by weight. The effect on the cake solids is shown in Figure 9 indicating an improvement in dryness compared to the use of flocculant without acid.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/526,176 US20060016761A1 (en) | 2002-09-05 | 2003-08-25 | Dewatering of suspensions |
EP03757763A EP1534636A1 (en) | 2002-09-05 | 2003-08-25 | Dewatering of suspensions |
AU2003273802A AU2003273802A1 (en) | 2002-09-05 | 2003-08-25 | Dewatering of suspensions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0220714.0 | 2002-09-05 | ||
GBGB0220714.0A GB0220714D0 (en) | 2002-09-05 | 2002-09-05 | Dewatering of suspensions |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004022493A1 true WO2004022493A1 (en) | 2004-03-18 |
Family
ID=9943595
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/009381 WO2004022493A1 (en) | 2002-09-05 | 2003-08-25 | Dewatering of suspensions |
Country Status (5)
Country | Link |
---|---|
US (1) | US20060016761A1 (en) |
EP (1) | EP1534636A1 (en) |
AU (1) | AU2003273802A1 (en) |
GB (1) | GB0220714D0 (en) |
WO (1) | WO2004022493A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7749392B2 (en) | 2004-03-12 | 2010-07-06 | Ciba Specialty Chemicals Water Treatments Ltd | Dewatering process |
US7754087B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments, LTD | Dewatering process |
US7754088B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments Ltd. | Process for the dewatering of aqueous suspensions |
US7754086B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments Ltd. | Dewatering process |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112013015920B1 (en) | 2010-12-24 | 2020-02-11 | Unilever N.V. | WATER PURIFICATION PROCESS, WASH WATER PURIFICATION PROCESS AND KIT |
AU2011347796B2 (en) | 2010-12-24 | 2015-03-26 | Unilever Global Ip Limited | Water clarification composition and process |
ES2532478T3 (en) | 2012-06-26 | 2015-03-27 | Unilever N.V. | Composition and water clarification process |
CA2812271A1 (en) * | 2013-04-10 | 2014-10-10 | Imperial Oil Resources Limited | Systems and methods for dewatering mine tailings with water-absorbing polymers |
US11760665B2 (en) * | 2016-10-12 | 2023-09-19 | Rkm Ip Holding Llc | Effluent treatment mixture |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0479616A1 (en) * | 1990-10-04 | 1992-04-08 | Ciba Specialty Chemicals Water Treatments Limited | Dewatering compositions and processes |
US5611934A (en) * | 1995-12-18 | 1997-03-18 | Hoechst Celanese Corporation | Process for dye removal |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA926532A (en) * | 1970-05-25 | 1973-05-15 | S. Jolly Colin | Compositions and a process for preparing water dispersible polymers |
FR2516397B1 (en) * | 1981-11-16 | 1988-01-15 | Rhone Poulenc Spec Chim | FLOCCULATION ADDITIVE AND PROCESS FOR THE PURIFICATION OF WATER |
GB2167400B (en) * | 1984-04-24 | 1988-07-06 | Sanyo Chemical Ind Ltd | Auxiliary and method for dewatering of sludge |
US4668747A (en) * | 1984-09-24 | 1987-05-26 | Allied Corporation | Preparation of water soluble cationic acrylamide polymer and product using weak acid to adjust pH |
US4668715A (en) * | 1985-03-25 | 1987-05-26 | Nalco Chemical Company | Rapid solubilization of dry polymers |
US5073272A (en) * | 1988-11-15 | 1991-12-17 | Aluminum Company Of America | Method for using a flocculant powder |
US5008319A (en) * | 1990-02-01 | 1991-04-16 | Polypure, Inc. | Homogeneous mixtures of solid organic acids and solid cationic ester-based polymer flocculants |
US5698109A (en) * | 1990-06-29 | 1997-12-16 | Allied Colloids Limited | Purification of aqueous liquor |
JP2960261B2 (en) * | 1992-07-04 | 1999-10-06 | 三洋化成工業株式会社 | Sludge dewatering agent |
GB9402717D0 (en) * | 1994-02-11 | 1994-04-06 | Allied Colloids Ltd | Solid polymeric products and their use |
AU716712B2 (en) * | 1995-12-29 | 2000-03-02 | Ciba Specialty Chemicals Water Treatments Limited | Particles having a polymeric shell and their production |
MY118538A (en) * | 1997-01-20 | 2004-12-31 | Ciba Spec Chem Water Treat Ltd | Polymeric compositions and their production and uses |
US6881346B2 (en) * | 2002-05-16 | 2005-04-19 | Halliburton Energy Services, Inc. | Methods of treating phosphate in a body of water |
-
2002
- 2002-09-05 GB GBGB0220714.0A patent/GB0220714D0/en not_active Ceased
-
2003
- 2003-08-25 US US10/526,176 patent/US20060016761A1/en not_active Abandoned
- 2003-08-25 EP EP03757763A patent/EP1534636A1/en not_active Withdrawn
- 2003-08-25 WO PCT/EP2003/009381 patent/WO2004022493A1/en not_active Application Discontinuation
- 2003-08-25 AU AU2003273802A patent/AU2003273802A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0479616A1 (en) * | 1990-10-04 | 1992-04-08 | Ciba Specialty Chemicals Water Treatments Limited | Dewatering compositions and processes |
US5611934A (en) * | 1995-12-18 | 1997-03-18 | Hoechst Celanese Corporation | Process for dye removal |
US5750035A (en) * | 1995-12-18 | 1998-05-12 | Hoechst Celanese Corporation | Process for dye removal |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7749392B2 (en) | 2004-03-12 | 2010-07-06 | Ciba Specialty Chemicals Water Treatments Ltd | Dewatering process |
US7754087B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments, LTD | Dewatering process |
US7754088B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments Ltd. | Process for the dewatering of aqueous suspensions |
US7754086B2 (en) | 2004-03-12 | 2010-07-13 | Ciba Specialty Chemicals Water Treatments Ltd. | Dewatering process |
US8088288B2 (en) | 2004-03-12 | 2012-01-03 | Ciba Specialty Chemicals Water Treatments Ltd. | Dewatering process |
Also Published As
Publication number | Publication date |
---|---|
GB0220714D0 (en) | 2002-10-16 |
EP1534636A1 (en) | 2005-06-01 |
AU2003273802A1 (en) | 2004-03-29 |
US20060016761A1 (en) | 2006-01-26 |
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