WO2004014813A2 - Clear stable aqueous solution based upon waterglass for the production of fire resistant glazing - Google Patents
Clear stable aqueous solution based upon waterglass for the production of fire resistant glazing Download PDFInfo
- Publication number
- WO2004014813A2 WO2004014813A2 PCT/GB2003/003434 GB0303434W WO2004014813A2 WO 2004014813 A2 WO2004014813 A2 WO 2004014813A2 GB 0303434 W GB0303434 W GB 0303434W WO 2004014813 A2 WO2004014813 A2 WO 2004014813A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solution according
- solution
- aluminate
- acid
- interlayer
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10311—Intumescent layers for fire protection
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/069—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of intumescent material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
Definitions
- This invention relates to novel solutions useful in the production of fire resistant glazings comprising an alkali metal aluminate and a silicate waterglass, to methods for the preparation of those solutions and to the production of intumescent interlayers from those solutions which may be incorporated into fire resistant glazings.
- Glass laminates incorporating an intumescent inorganic silicate interlayer sandwiched between two opposed panes of glass are sold under the trade marks PYROSTOP and PYRODUR by the Pilkington group of companies. When such laminates are exposed to a fire the inorganic interlayer intumesces and expands to form a foam. The foam provides a thermally insulating layer which protects the pane of glass remote from the fire so that the structural integrity of the glass unit which acts as a barrier preventing the propagation of the fire is maintained for a longer period.
- Glass laminates incorporating such intumescent interlayers have been used successfully as fire resistant glass structures. These laminates may comprise more than two panes of glass sandwiching more than one intumescent interlayer. Laminates comprising up to eight intumescent interlayers have been employed. These multi layered laminates are relatively thick and correspondingly expensive.
- the intumescent inorganic layer is normally formed from a sodium silicate waterglass or a mixture thereof with a potassium silicate waterglass.
- the layer is commonly formed by preparing a solution of the waterglass (or waterglasses), spreading that solution on the surface of the glass and drying excess water from the solution so as to form the intumescent inorganic layer.
- USP 4190698 discloses fire resistant glazings comprising an intumescent inorganic layer obtained by drying a waterglass solution.
- the authors suggest the addition of various additives to the waterglass solution including urea, polyhydric alcohols, monosaccharides, polysaccharides, sodium phosphate, sodium aluminate, borax, boric acid and colloidal silica.
- urea polyhydric alcohols
- monosaccharides polysaccharides
- polysaccharides sodium phosphate
- sodium aluminate sodium aluminate
- borax boric acid
- colloidal silica There is no specific disclosure of the addition of an aluminate to a waterglass solution.
- this invention provides a clear stable solution useful in the production of fire resistant glazings comprising an alkali metal silicate waterglass and a water soluble aluminate which has been partially neutralised with a hydroxy carboxylic acid.
- the water soluble aluminate is preferably an alkali metal aluminate such as lithium aluminate, potassium aluminate, caesium aluminate and most preferably sodium aluminate.
- alkali metal aluminate such as lithium aluminate, potassium aluminate, caesium aluminate and most preferably sodium aluminate.
- Other water soluble aluminates notably ammonium aluminate and alkyl ammonium aluminates may also be employed.
- the carboxylic acid is preferably a hydroxy carboxylic acid and more preferably an of-hydroxy carboxylic acid.
- preferred carboxylic acids include tartaric acid, malic acid, gluconic acid, lactic acid, saccharic acid and most preferably citric acid.
- the waterglasses useful in the compositions of this invention are preferably sodium silicate waterglasses.
- the preferred sodium silicate waterglasses are those wherein the weight ratio of SiO 2 :Na 2 O is at least 1.6:1 e.g 2.0:1, more preferably at least 2.5:1 and most preferably at least 2.85:1.
- Sodium silicate waterglass solutions wherein the weight ratio of SiO 2 : Na O varies between 2.0:1 and 4.0:1 are available as articles of commerce. Specifically solutions wherein this ratio is 2.0:1, 2.5:1 and 2.85:1 3.0:1 and 3.3:1 are available as articles of commerce.
- Waterglasses having any particular weight ratio of SiO 2 : Na 2 O may be produced by blending these commercially available waterglass solutions.
- Sodium silicate waterglasses having a weight ratio of SiO 2 : Na 2 O of 2.0:1, 2.5:1 and 2.85:1 may incorporate a higher proportion of aluminate and produce a glass which combines good fire resistance properties with good impact resistant properties.
- Sodium silicate waterglasses having a higher weight ratio of SiO 2 to Na 2 O e.g 3.0 :1 ; 3.3:1 or 3.9:1 are able to incorporate a smaller proprtion of aluminate and produce fire resistant glasses with relatively superior fire resistant properties and relatively inferior impact resistant properties.
- the fire resistant glazings of the present invention are produced from a sodium silicate waterglass having a weight ratio of SiO 2 : Na 2 O of from 2.5:1 to 3.0:1.
- Potassium silicate and lithium silicate waterglasses may also be used in the compositions of this invention.
- these waterglasses will be used as a partial replacement for the sodium silicate waterglasses.
- the molar ratio of sodium to potassium and/or lithium in the waterglass solution will be at least 2:1.
- the waterglass solution used in the present invention comprise a mixture of sodium silicate waterglass and a potassium silicate waterglass.
- the molar ratio of sodium ions to potassium ions in these mixtures in preferably at least 4:1.
- a potassium silicate waterglass is employed it is preferably one where the weight ratio SiO 2 : K 2 O is in the range 1.43:1 to 2.05:1.
- the solutions of this invention may further comprise one or more polyhydric compounds which are known to be useful in existing intumescent interlayers.
- Polyhydric compounds which have been proposed for this use include glycerol, glycerine or a derivative of glycerine or a sugar.
- the most commonly used polyhydric compound and the preferred polyhydric compound for present use is glycerol.
- the solution of this invention should preferably be clear, stable and capable of being dried to form a useful intumescent interlayer.
- the stability of the solution is affected by the composition of the solution and the methods used in its preparation. The utility of any particular solution maybe determined by experiment.
- the stability of the solutions decreases as the amount of aluminate present increases.
- the fire resistance of the interlayer increases in proportion to the amount of aluminate present.
- the amount of aluminate which is incorporated into the solution will preferably represent a compromise between these two properties.
- the molar ratio of silicon to aluminium may vary from as much as 100:1 to 20:1 but preferably is in the range 20:1 to 35:1 and more preferably in the range 25:1 to 32:1.
- a second significant factor which affects the utility of the solutions of this invention is the weight ratio of silica to alkali metal oxide.
- Increasing the proportion of silica reduces the stability of the solution and is undesirable.
- the higher ratios of silicon to alkali metal are preferred since this increases the flow point of the dried interlayer which is an important factor influencing the performance of a glazing incorporating such an interlayer in fire testing.
- the weight ratio of silica to alkali metal oxide is in the range 2:1 to 4:1; more preferably 2.5:1 to 4:1
- the solutions of the present invention must be clear. They are prepared by mixing the various components in a manner which produces a clear stable solution which may then be dried to form a clear stable intumescent layer.
- the solutions are prepared using a process which comprises as a first step partially neutralising the aluminate with the hydroxy carboxylic acid.
- This neutralisation may be carried out by adding a hydroxycarboxylic acid solution to an aqueous solution of the aluminate.
- a hydroxycarboxylic acid solution may be added to an aqueous solution of the aluminate.
- the partially neutralised aluminate solution may typically comprise from 20 to 45% by weight of solids.
- the hydroxy carboxylic acid solution may be added to the aluminate as a solid but more usually it will be added as a solution.
- the solution may be an aqueous solution.
- the solutions of this invention comprise a polyhydroxy compound which is preferably glycerol the hydroxy carboxylic acid may be dissolved in the polyhydroxy compound and the resulting solution used to partially neutralise the aluminate.
- the addition of the acid solution to the aluminate solution is preferably continued until the solution has a pH in the range 9.0 to 11.0 and more preferably in the range 9.5 to 10.0.
- the neutralisation should be carried out with thorough mixing and in a manner such that the temperature of the reaction mixture is not allowed to rise excessively and is preferably maintained below 50°C.
- Solutions which comprise a water soluble aluminate, a hydroxy carboxylic acid and a polyhydric compound which is preferably glycerol are believed to be novel and comprise a further aspect of the invention.
- the partially neutralised aluminate solution may be added to a solution comprising an alkali metal silicate waterglass to form a solution according to the present invention.
- the mixing of the aluminate with the waterglass must be carried out in a controlled manner so as to avoid the formation of any precipitate. We prefer to add the aluminate to the waterglass at a controlled rate with thorough mixing.
- the resulting solutions may be used in the production of five resistant glazings using known techniques.
- the solutions may be spread upon the surface of a glass sheet which is provided with an edge barrier which retains the solution on the surface of the glass.
- the quantity of solution employed will vary with the desired thickness of the dried interlayer. The quantity needed to produce an interlayer of any particular thickness may be determined by routine experiment.
- the solution is then dried under carefully controlled conditions of temperature and humidity so as to ensure the production of a clear transparent interlayer which is free from bubbles and other optical imperfections.
- the dried interlayers generally comprise form 10 to 35% by weight of water.
- the aluminium content of the dried interlayer is generally in the range 0.1 % to 5.0% by weight preferably from 0.1 % to 1.0% by weight. We have discovered that the presence of the aluminium improves the performance of glazings into which the interlayer is incorporated in terms of their fire resistance and their mechanical impact resistance properties.
- the thickness of the dried interlayer will generally be in the range 0.1 to 2.0 mm preferably from 0.5 to 2.0 mm.
- the formations of thicker interlayers requires a longer drying time and is thereby disadvantageous. Thinner interlayers can be produced using shorter drying times.
- a glass laminate having a thicker interlayer may be produced by bringing two sheets of glass each having a relatively thin interlayer having say a thickness of from 0.5 mm to 1.0 mm into face to face contact so as to form a laminate having an intumescent interlayer which is from 1.0mm to 2.0 mm thick.
- Flat glass sheets of various thickness may be used in the laminates of the present invention. Typically sheets of soda lime float glass having a thickness of from 2.0 mm to 4.0 mm are employed.
- An edge barrier formed from a suitable material such as a clay may be provided at the edges of the glass so as to retain the waterglass solution on the surface of the glass.
- a laminate may be formed by placing a second glass sheet on top of the interlayer.
- the second glass sheet may itself be one having an intumescent interlayer on one surface thereof. Mounting this second sheet on top of the first sheet so that the two fire resistant interlayers are in contact with each other produces a laminate having a relatively thick interlayer. Mounting the second sheet so that the interlayer is on its upper surface and subsequently providing a third glass sheet on top of that second interlayer produces a laminate having two interlayers mounted between three panes of glass. Laminates having as many as eight interlayers may be produced.
- the solutions of this invention may be poured onto the surface of the substrate and dried to form an intumescent fire resistant interlayer which is sufficiently strong to be removed from the substrate in the form of a transparent film.
- the film may then be placed between two sheets of glass to form a fire resistant glass laminate.
- substrates may be employed in processes of this type examples being glass sheets, metal sheets and polymeric materials such as PTFE and polyolefins such as polypropylene.
- the substrate is clear and transparent, e.g when the substrate is a clear polymeric film , having a dried interlayer on one surface thereof the substrate may be incorporated into a glass laminate and thereby produce a fire resistant laminate without the need to separate the dried interlayer from the substrate.
- the invention is illustrated by the following example
- a solution comprising a sodium aluminate, a sodium silicate waterglass, a potassium silicate waterglass and citric acid was made up using the following components:- A solution of a sodium silicate waterglass having a weight ration SiO 2 :Na 2 O of 2.85:1 and comprising 40% by weight of solids, sold by INEOS as Crystal 96.
- a partially neutralised aluminate solution wase made up as follows :-
- a waterglass solution comprising a sodium silicate , a potassium silicate and glycerol was made up by mixing 151.7 parts by weight of Crystal 96 with 44.3 parts by weight of Crystal K120 and 10.5 parts by weight of glycerol.
- the partially neutralised aluminate solution was then added to the waterglass solution.
- the addition was carried out by slowly adding the aluminate solution with thorough mixing using a Silverson high shear mixer.
- the resulting solution was clear and was stable on storage at room temperature.
- This solution was then applied to the surface of a sheet of float glass having an edge barrier around its perimeter in a quantity of 4 kilograms of solution per square metre of glass.
- the glass sheet was placed in an oven and dried over a prolonged period in a controlled atmosphere until the water content of the solution had reduced to 26% by weight.
- a clear interlayer having a depth of approximately 1.3mm had formed on the surface of the glass.
- edge barrier was cut away and a second sheet of float glass having a thickness of 3mm was placed on top of the interlayer to produce a glass laminate.
- Pieces of this laminate were tested for Fire Resistance according to B.S. 476 Part 20/2 and mechanical impact performance according to B.S 6206 Class C. Two pieces were subject to the fire test and both passed with times of 33 minutes and 30 minutes. Four pieces were tested for impact performance and all were rated at least a safe pass.
- a partially neutralised aluminate solution was prepared in the same manner as in Example 1.
- the aluminate solution was added to a solution of a sodium silicate waterglass having a weight ratio Si0 2 :Na 2 O of 3.3:1 and comprising 37% by weight solids.
- the quantity added was such as to provide 2 parts by weight of sodium aluminate to 100 parts of sodium silicate.
- the atomic ratio of silicon to aluminium in the solution was approximately 56:1.
- the solution was poured onto a sheet of float glass,dried,laminated and tested for Fire Resistance in the same manner as is recited in Example 1.
- the fire resistance time was 66 minutes.
- Example 2 was repeated with the exception that a higher proportion of aluminate was used to provide 3 parts of sodium aluminate to 100 parts of sodium silicate.
- the atomic ratio of silicon to aluminium was 38:1.
- the resulting solution was clear and stable over a period of weeks.
- Example 4 Example 1 was repeated using a sodium silicate waterglass having a weight ratio of SiO 2 :Na 2 O of 3.9:1 in form form of an aqueous solution comprising 28% by weight of solid material.
- the amount of partially neutralised aluminate solution added was sufficient to provide an atomic ratio of silicon to aluminium of 96:1.
- the solution was clear and stable over an extended period. It could be dried on glass to form a clear interlayer. It was noted that if the proportion of aluminate was increased so that the atomic ratio of silicon to aluminium was 64:1 the resulting solution was unstable and was not tested further.
- Example 1 was repeated using a sodium silicate waterglass having a weight ratio of SiO 2 :Na 2 O of 2.5:1 in the form of an aqueous solution comprising 41% by weight of solid material.
- the amount of aluminate added was sufficient to provide an atomic ratio of silicon to aluminium of 33:1.
- the solution was clear and remained clear after storage at 70°C for two weeks.
- the solution was poured onto a sheet of 3m float glass and dried to form a clear interlayer which was approximately 1.4mm thick.
- This glass was laminated with a second sheet of float glass and the laminate tersted for fire and impact resistance using the procedures described in example 1.
- the fire resistance time was 39 minutes.
- the laminate safely passed the impact test described in B.S 6206 class C.
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- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
- Fireproofing Substances (AREA)
- Surface Treatment Of Glass (AREA)
- Medicinal Preparation (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004527028A JP4445857B2 (en) | 2002-08-10 | 2003-08-06 | A clear and stable aqueous solution based on water glass for the production of flame resistant glazing |
AU2003249079A AU2003249079A1 (en) | 2002-08-10 | 2003-08-06 | Clear stable aqueous solution based upon waterglass for the production of fire resistant glazing |
US10/523,540 US20050255323A1 (en) | 2002-08-10 | 2003-08-06 | Fire resistant glazing |
EP03784262.2A EP1558536B1 (en) | 2002-08-10 | 2003-08-06 | Clear stable aqueous solution based upon waterglass for the production of fire resistant glazing |
CA002494194A CA2494194A1 (en) | 2002-08-10 | 2003-08-06 | Fire resistant glazing |
US12/552,097 US9789667B2 (en) | 2002-08-10 | 2009-09-01 | Fire resistant glazing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0218672.4 | 2002-08-10 | ||
GBGB0218672.4A GB0218672D0 (en) | 2002-08-10 | 2002-08-10 | Fire resistant glazings |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10523540 A-371-Of-International | 2003-08-06 | ||
US12/552,097 Division US9789667B2 (en) | 2002-08-10 | 2009-09-01 | Fire resistant glazing |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004014813A2 true WO2004014813A2 (en) | 2004-02-19 |
WO2004014813A3 WO2004014813A3 (en) | 2004-03-25 |
Family
ID=9942120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2003/003434 WO2004014813A2 (en) | 2002-08-10 | 2003-08-06 | Clear stable aqueous solution based upon waterglass for the production of fire resistant glazing |
Country Status (10)
Country | Link |
---|---|
US (2) | US20050255323A1 (en) |
EP (1) | EP1558536B1 (en) |
JP (1) | JP4445857B2 (en) |
KR (1) | KR101076211B1 (en) |
CN (1) | CN100455531C (en) |
AU (1) | AU2003249079A1 (en) |
CA (1) | CA2494194A1 (en) |
GB (1) | GB0218672D0 (en) |
RU (1) | RU2292375C2 (en) |
WO (1) | WO2004014813A2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007002867B3 (en) * | 2007-01-15 | 2008-03-27 | Pilkington Deutschland Ag | Fire retarding window pane mounting has thermally activated foam strip located around edge of pane and secured by trim strips |
WO2008053248A1 (en) * | 2006-10-31 | 2008-05-08 | Pilkington Group Limited | Fire glazing |
JP2009507940A (en) * | 2005-07-26 | 2009-02-26 | イネオス シリカス リミテッド | Aqueous composition and pioneer system and application system thereof |
WO2011027163A2 (en) | 2009-09-03 | 2011-03-10 | Pilkington Group Limited | Fire resistant glazings |
EP2305603A1 (en) | 2009-10-05 | 2011-04-06 | Cognis IP Management GmbH | Soluble glass solutions containing aluminium |
WO2013034921A1 (en) | 2011-09-08 | 2013-03-14 | Pilkington Group Limited | Fire resistant glazings |
US9080063B2 (en) | 2009-12-23 | 2015-07-14 | Pilkington Group Limited | Fire resistant glazings |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0023020D0 (en) * | 2000-09-20 | 2000-11-01 | Pilkington Plc | Production of fire resistant laminates |
EP1960317B1 (en) * | 2005-11-25 | 2018-01-31 | AGC Glass Europe | Fire-resistant glazing |
GB0621568D0 (en) * | 2006-10-31 | 2006-12-06 | Pilkington Group Ltd | Method for the production of fire resistant glazings |
CH704939B1 (en) * | 2008-03-10 | 2012-11-15 | Akzo Nobel Chemicals Int Bv | Translucent heat protection element with aluminate or boratmodifiziertem silica. |
EP2111977A1 (en) * | 2008-04-25 | 2009-10-28 | AGC Flat Glass Europe SA | Fireproof glazing |
Citations (6)
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US4190698A (en) * | 1977-08-03 | 1980-02-26 | Bfg Glassgroup | Light-transmitting fire screening panel |
GB2226024A (en) * | 1988-12-16 | 1990-06-20 | Tioxide Group Plc | Zirconium salts with carboxylic acids and polyols |
US5216100A (en) * | 1989-12-18 | 1993-06-01 | Coatex S.A. | Non-toxic stabilizing agent for aqueous suspensions of sodium silico-aluminates |
WO2001010638A1 (en) * | 1999-08-04 | 2001-02-15 | Pilkington Plc | Fire resistant glazings |
WO2001070495A1 (en) * | 2000-03-18 | 2001-09-27 | Pilkington Plc | Fire resistant glazings |
WO2002024445A1 (en) * | 2000-09-20 | 2002-03-28 | Pilkington Plc | Production of fire resistant laminates |
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JP2987885B2 (en) | 1990-06-19 | 1999-12-06 | 三菱化学株式会社 | Method for producing flaky graphite fine particles |
DE69233756D1 (en) * | 1991-07-18 | 2009-04-02 | Mitsui Chemicals Inc | Curable compositions, aqueous gels, and methods for their preparation and use |
US6816988B2 (en) | 2001-08-31 | 2004-11-09 | Agilent Technologies, Inc. | Method and system for minimal-time bit-error-rate testing |
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2002
- 2002-08-10 GB GBGB0218672.4A patent/GB0218672D0/en not_active Ceased
-
2003
- 2003-08-06 CN CNB03819063XA patent/CN100455531C/en not_active Expired - Lifetime
- 2003-08-06 WO PCT/GB2003/003434 patent/WO2004014813A2/en active Application Filing
- 2003-08-06 RU RU2005106365/03A patent/RU2292375C2/en active
- 2003-08-06 JP JP2004527028A patent/JP4445857B2/en not_active Expired - Fee Related
- 2003-08-06 CA CA002494194A patent/CA2494194A1/en not_active Abandoned
- 2003-08-06 EP EP03784262.2A patent/EP1558536B1/en not_active Expired - Lifetime
- 2003-08-06 KR KR1020057002161A patent/KR101076211B1/en active IP Right Grant
- 2003-08-06 AU AU2003249079A patent/AU2003249079A1/en not_active Abandoned
- 2003-08-06 US US10/523,540 patent/US20050255323A1/en not_active Abandoned
-
2009
- 2009-09-01 US US12/552,097 patent/US9789667B2/en not_active Expired - Lifetime
Patent Citations (6)
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US4190698A (en) * | 1977-08-03 | 1980-02-26 | Bfg Glassgroup | Light-transmitting fire screening panel |
GB2226024A (en) * | 1988-12-16 | 1990-06-20 | Tioxide Group Plc | Zirconium salts with carboxylic acids and polyols |
US5216100A (en) * | 1989-12-18 | 1993-06-01 | Coatex S.A. | Non-toxic stabilizing agent for aqueous suspensions of sodium silico-aluminates |
WO2001010638A1 (en) * | 1999-08-04 | 2001-02-15 | Pilkington Plc | Fire resistant glazings |
WO2001070495A1 (en) * | 2000-03-18 | 2001-09-27 | Pilkington Plc | Fire resistant glazings |
WO2002024445A1 (en) * | 2000-09-20 | 2002-03-28 | Pilkington Plc | Production of fire resistant laminates |
Non-Patent Citations (1)
Title |
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SAIDEN CHEM KK: "WPI WORLD PATENT INFORMATION DERWENT, DERWENT, GB" , WPI WORLD PATENT INFORMATION DERWENT, DERWENT, GB, VOL. 1976, NR. 31 XP002151356 abstract * |
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JP2009507940A (en) * | 2005-07-26 | 2009-02-26 | イネオス シリカス リミテッド | Aqueous composition and pioneer system and application system thereof |
WO2008053248A1 (en) * | 2006-10-31 | 2008-05-08 | Pilkington Group Limited | Fire glazing |
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DE102007002867B8 (en) * | 2007-01-15 | 2008-06-26 | Pilkington Deutschland Ag | Fire-resistant glazing |
DE102007002867B3 (en) * | 2007-01-15 | 2008-03-27 | Pilkington Deutschland Ag | Fire retarding window pane mounting has thermally activated foam strip located around edge of pane and secured by trim strips |
WO2011027163A3 (en) * | 2009-09-03 | 2011-04-28 | Pilkington Group Limited | Fire resistant glazings |
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WO2011042132A1 (en) * | 2009-10-05 | 2011-04-14 | Cognis Ip Management Gmbh | Aluminium-containing waterglass solutions |
US8460453B2 (en) | 2009-10-05 | 2013-06-11 | Cognis Ip Management Gmbh | Aluminum-containing waterglass solutions |
AU2010305075B2 (en) * | 2009-10-05 | 2014-11-27 | Cognis Ip Management Gmbh | Aluminium-containing waterglass solutions |
EP2305603A1 (en) | 2009-10-05 | 2011-04-06 | Cognis IP Management GmbH | Soluble glass solutions containing aluminium |
US9080063B2 (en) | 2009-12-23 | 2015-07-14 | Pilkington Group Limited | Fire resistant glazings |
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Also Published As
Publication number | Publication date |
---|---|
WO2004014813A3 (en) | 2004-03-25 |
EP1558536B1 (en) | 2015-03-18 |
AU2003249079A1 (en) | 2004-02-25 |
GB0218672D0 (en) | 2002-09-18 |
US20050255323A1 (en) | 2005-11-17 |
CN100455531C (en) | 2009-01-28 |
EP1558536A2 (en) | 2005-08-03 |
CN1675138A (en) | 2005-09-28 |
JP2005538015A (en) | 2005-12-15 |
CA2494194A1 (en) | 2004-02-19 |
JP4445857B2 (en) | 2010-04-07 |
KR101076211B1 (en) | 2011-10-25 |
US9789667B2 (en) | 2017-10-17 |
KR20050084801A (en) | 2005-08-29 |
RU2292375C2 (en) | 2007-01-27 |
RU2005106365A (en) | 2005-09-10 |
US20090317618A1 (en) | 2009-12-24 |
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