WO2004011717A1 - Method of deinking - Google Patents
Method of deinking Download PDFInfo
- Publication number
- WO2004011717A1 WO2004011717A1 PCT/EP2003/008166 EP0308166W WO2004011717A1 WO 2004011717 A1 WO2004011717 A1 WO 2004011717A1 EP 0308166 W EP0308166 W EP 0308166W WO 2004011717 A1 WO2004011717 A1 WO 2004011717A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- siloxane
- independently
- paper
- additive
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/13—Silicon-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
Definitions
- the present invention relates to a method of deinking printed wastepaper.
- Growing awareness of environmental damage caused by deforestation has seen an increase in the recycling of wastepaper in recent years. It has been recognised that the ability to recycle wastepaper is commercially advantageous and has a significant impact on the conservation of virgin fibre resources.
- technological advances in printing inks and print media present ever-growing challenges to recyclers.
- Printing on paper is typically accomplished using one of two types of ink, namely, impact ink, which is physically pressed onto the paper, and non-impact ink, which is attracted to a charged image and is then transferred to the paper.
- Impact inks are typically wet inks, for example letterpress inks, offset litho inks, photogravure inks and flexographic inks.
- letterpress inks are generally composed of carbon black pigment in a mineral oil vehicle and are used in, for example, newspaper printing.
- Offset litho inks tend to contain more pigment than letterpress inks and contain drying oils such as linseed or alkyl resins.
- Flexographic inks are used in similar processes to letterpress inks but are water-based and contain emulsified ink in an alkali soluble binder. Such inks may easily be dislodged, but may form extremely fine particles that are difficult to capture and remove .
- Non-impact inks e.g. toners
- toners are generally dry, powdered inks and are used in laser printing, photocopying and facsimile machines and generally comprise thermoplastic resins and pigment .
- the wastepaper is disintegrated (pulped) by mechanical agitation in an aqueous medium to separate the ink and impurities from the paper fibre and disintegrate the ink into particles of approximately 0.1 to 1000 ⁇ m.
- a grey slurry is thus obtained in which the ink is present in a finely dispersed form.
- the impurities for example, plastic, aluminium foil, stones, screws, staples, paper clips etc., are removed during a large number of screening steps. Whilst ink detachment of non-impact, e.g.
- photocopy, paper can normally be achieved in neutral conditions, for other printed paper ink detachment is routinely accomplished at alkaline pH levels using alkali hydroxides, alkali silicates, oxidative-working bleaches and surfactants at temperatures between 30 and 50°C.
- alkali hydroxides alkali silicates
- oxidative-working bleaches oxidative-working bleaches and surfactants at temperatures between 30 and 50°C.
- anionic and nonionic tensides are used as surfactants, for example, soaps, ethoxylated fatty alcohols and/or ethoxylated alkyl phenols (see, for example, EP 0013758) .
- the ink particles are then removed from the fibre slurry by washing and/or flotation. Smaller ink particles are removed by washing, and larger ink particles and stickies
- the alkaline conditions used in traditional deinking methods cause water-soluble and/or colloidal solids and finely dispersed solids to contaminate the process water, for example, fillers, fine fibres and stickies. If these contaminants are insufficiently removed during washing, they can be concentrated by subsequent washings and reintroduced to the paper fibre, causing a loss of brightness in the resultant paper. Effluent containing the aforementioned chemicals conventionally used in deinking methods is also environmentally undesirable.
- the present invention seeks to provide a method of deinking wastepaper which can overcome disadvantages of conventional deinking methods.
- a method of deinking printed paper comprising pulping the paper to form an aqueous slurry, adding a deinking additive to the paper, and removing detached ink by flotation, wherein the additive comprises an organo-modified siloxane comprising units of the formula:
- each R 1 is independently selected from a hydrogen atom, an alkyl, aryl, alkenyl, aralkyl, alkaryl, alkoxy, alkanoyloxy, hydroxyl, ester or ether group; each Z is independently selected from an alkyl group substituted with an amine, amide, carboxyl, ester, or epoxy group, or a group -R 2 - (0C p H 2p ) q (0C r H 2r ) S -P n is an integer greater than 1; a and b are independently 0, 1, 2 or 3;
- R 2 is an alkylene group or a direct bond
- R 3 is a group as defined for R 1 or Z above
- p and r are independently an integer from 1 to 6
- q and s are independently 0 or an integer such that 1 ⁇ q + s > 400
- each molecule of the organo-modified siloxane contains at least one group Z.
- Z is preferably a group -R 2 - (OC p H 2p ) q (OC r H 2r ) S -R 3 , more preferably wherein p and/or r are independently 2, 3 or 4, i.e. a group comprising ethylene, propylene, and/or butylene oxide groups.
- p and/or r are independently 2, 3 or 4, i.e. a group comprising ethylene, propylene, and/or butylene oxide groups.
- q and s are each independently integers from 10 to 30, more preferably 15 to 25 (for example 18) .
- p is 2
- r is 3
- q and s are both 18.
- R 2 may be an alkylene group, for example having from 1 to 6 carbon atoms (i.e.
- R 3 may be a group as defined hereinabove for R 1 or Z, and is preferably a hydrogen atom or a hydroxyl group.
- Z may be an alkyl group substituted with an amine, amide, carboxyl, ester, or epoxy group, for example an alkyl group having from 1 to 6 carbon atoms, i.e. a substituted methyl, ethyl, propyl, butyl, pentyl or hexyl group.
- Z is a group -R 2 - (OC p H 2p ) q (0C r H 2r ) S -R 3
- R 3 is preferably a hydroxyl or alkanoyloxy group.
- siloxane molecule Preferably, 2 to 20 mole percent of silicon atoms in the siloxane molecule are substituted by a group Z, more preferably 5 to 16 mole percent.
- the siloxane preferably has a hydrophilic/lipophilic balance (HLB)in the range of 5.0 to 7.3.
- HLB hydrophilic/lipophilic balance
- the molecular weight of the siloxane is preferably in the range of 1,000 to 500,000, more preferably 10,000 to 100,000.
- a particularly preferred siloxane for use in the present invention is a hydroxy-endcapped linear polydimethylsiloxane having an HLB of 5.9 to 6.3, in which 10 to 12 mole percent of silicon atoms are substituted by Z groups of the formula -R 2 - (OC p H 2p ) q (OC r H 2r ) S -R 3 , in which p is 2, r is 3 and q and s are both 18, R 2 is an alkylene group having from 1 to 6 carbon atoms or a direct bond, and R 3 is a hydrogen atom or a hydroxyl, ester or ether group.
- the additive used in the present invention may comprise further components, in addition to the organo-modified siloxane.
- the additive may further ' comprise one or more components selected from a polydimethylsiloxane, an organic polyether, and a fatty acid.
- Suitable organic polyethers include those of the formula R 4 - (OC p H 2p ) q (OC r H 2r ) S -R 5 in which R 4 and R 5 are selected from a hydrogen atom, hydroxyl, alkyl and alkoxy groups, and p, q, r and s are as defined hereinabove.
- Suitable fatty acids include saturated and unsaturated monobasic aliphatic carboxylic acids, for example having from 8 to 22 carbon atoms, such as lauric, myristic, palmitic, stearic, arachidic, behenic, lignoceric, palmitolic, oleic, linoleic, linolenic, and arachidonic acids .
- the additive may be in the form of an emulsion, for example the organo-modified siloxane may be a gum based self- emulsifying siloxane. In the method of the present invention, the additive may be added to the paper before, during or after pulping.
- the amount of additive to be added to the paper is preferably within the range 0.1 to 1 wt% of the paper, more preferably 0.1 to 0.5 wt%.
- the additive may, for example, be added to the paper neat, as an emulsion, or in solution, for example an aqueous solution.
- the method of the present invention is preferably performed at substantially neutral pH, although the method may be performed under alkaline pH.
- the pulping and ink removal steps of the present invention may be performed as is conventional, as will be familiar to a person skilled in the art and described hereinabove .
- the paper may be pulped to form an aqueous slurry having a consistency of, for example, from 1 to 10% (for example, 1 to 5%) at a temperature of between 30 and 50°C, for example 35 to 45°C. Consistency is defined as wt% of pulp solids in the fibre suspension.
- Ink removal may be performed in a suitable flotation cell (for example, a Denver Lab flotation cell) at a suitable temperature, for example between 30 and 50°C (e.g. 35 to 45°C) , and number of revolutions per minute, for example from 500 to 1000 rpm.
- An additional advantage associated with the method of the present invention is that when used to treat flexographic printed waste, the process water is relatively clear, whereas with known deinking methods it is generally black. Moveover, the present method produces pulp of improved brightness.
- Steps a) and b) above were repeated using the siloxane used in Example 1 (Siloxane 1) and the siloxanes defined in Table 4 (Siloxanes 2 to 8) on fresh and aged wastepaper.
- Table 4 also contains viscosity data for each of the siloxanes.
- the experiment was also carried out using the commercially available fatty acid based deinking preparation used in Example 1. The results are shown in Table 2 (fresh wastepaper) and Table 3 (aged wastepaper) below. Whiteness was evaluated according to DIN 53145 Part 1.
- Example 1 were added as an aqueous solution. The pulp was floated for 8 minutes at 45°C in a Denver Lab Flotation Cell.
- Steps a) and b) above were repeated using the siloxane used in Example 1 (Siloxane 1) and two of the siloxanes defined in Table 4 (Siloxanes 4 and 7) .
- the experiment was also carried out using the commercially available fatty acid based deinking preparation used in Example 1. The results are shown in Table 5 below. Whiteness was evaluated according to DIN 53145 Part 1.
- Steps a) and b) of Example 1 were repeated using the siloxane used in Example 1 (Siloxane 1) , but were performed on 100% flexographic paper. In addition, 0.10 wt% sodium hydroxide and 1.20 wt% sodium silicate were added to the slurry.
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2493758A CA2493758C (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
US10/521,795 US20060102298A1 (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
DK03771095T DK1540075T3 (en) | 2002-07-24 | 2003-07-22 | Procedure for deinking |
EA200500058A EA008834B1 (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
EP03771095A EP1540075B1 (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
AU2003254593A AU2003254593B2 (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
JP2004523792A JP4478019B2 (en) | 2002-07-24 | 2003-07-22 | How to remove ink |
DE2003615477 DE60315477T2 (en) | 2002-07-24 | 2003-07-22 | Method of decoloring printed paper |
HR20050087A HRP20050087B1 (en) | 2002-07-24 | 2005-01-26 | Method of deinking |
NO20050989A NO334965B1 (en) | 2002-07-24 | 2005-02-23 | Method of de-digestion |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0217197.3 | 2002-07-24 | ||
GB0217197A GB0217197D0 (en) | 2002-07-24 | 2002-07-24 | Method of deinking |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004011717A1 true WO2004011717A1 (en) | 2004-02-05 |
WO2004011717A8 WO2004011717A8 (en) | 2005-03-31 |
Family
ID=9941040
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/008166 WO2004011717A1 (en) | 2002-07-24 | 2003-07-22 | Method of deinking |
Country Status (17)
Country | Link |
---|---|
US (1) | US20060102298A1 (en) |
EP (1) | EP1540075B1 (en) |
JP (2) | JP4478019B2 (en) |
KR (1) | KR101029233B1 (en) |
CN (1) | CN100357518C (en) |
AT (1) | ATE369458T1 (en) |
AU (1) | AU2003254593B2 (en) |
CA (1) | CA2493758C (en) |
DE (1) | DE60315477T2 (en) |
DK (1) | DK1540075T3 (en) |
EA (1) | EA008834B1 (en) |
ES (1) | ES2290508T3 (en) |
GB (1) | GB0217197D0 (en) |
HR (1) | HRP20050087B1 (en) |
NO (1) | NO334965B1 (en) |
PL (1) | PL216211B1 (en) |
WO (1) | WO2004011717A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006113896A1 (en) * | 2005-04-20 | 2006-10-26 | Dow Corning Corporation | Removal of organic deposits from recycled fibers used for producing paper |
GB2464376A (en) * | 2008-10-17 | 2010-04-21 | Stephenson Group Ltd | Method of removing ink using a polysiloxane |
EP2203105A1 (en) | 2007-10-05 | 2010-07-07 | Dental Equipment, LLC | Led-based dental exam lamp with variable chromaticity |
EP2386681A1 (en) | 2010-05-14 | 2011-11-16 | Universitat Politècnica de Catalunya | Process for recycling waste paper, product obtained there from and its uses |
WO2016059153A1 (en) * | 2014-10-15 | 2016-04-21 | Nopco Paper Technology Gmbh | A method for controlling the deposition of stickies in pulping and papermaking processes |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI112805B (en) * | 2001-10-10 | 2004-01-15 | Megatrex Oy | Process for removing dyes, especially inks from recycled fiber materials |
GB0217197D0 (en) * | 2002-07-24 | 2002-09-04 | Dow Corning | Method of deinking |
Citations (2)
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EP0745648A2 (en) * | 1995-06-01 | 1996-12-04 | Dow Corning Corporation | Stable dispersible silicone compositions |
US5624569A (en) * | 1996-01-23 | 1997-04-29 | Nalco Chemical Company | Clarification of deinking process water |
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CA1249903A (en) * | 1984-05-10 | 1989-02-14 | Christopher C. Mollett | Composition and method of deinking of recycled cellulosic material |
GB8411888D0 (en) * | 1984-05-10 | 1984-06-13 | Albright & Wilson | Deinking of recycled cellulosic material |
JPH02210082A (en) * | 1989-02-06 | 1990-08-21 | Nippon Oil & Fats Co Ltd | Deinking assistant for reclaiming waste paper |
CA1339231C (en) * | 1989-03-30 | 1997-08-05 | Ratana Kanluen | Polyfunctional polymers as deinking agents |
MY114292A (en) * | 1989-10-26 | 2002-09-30 | Momentive Performance Mat Jp | Method for removing residual liquid cleaning agent using a rinsing composition containing a polyorganosiloxane |
JPH04242742A (en) * | 1990-12-28 | 1992-08-31 | Konica Corp | Surface treatment method of electrophotographic photoconductor substrate |
US5288369A (en) * | 1990-12-28 | 1994-02-22 | Kao Corporation | Deinking method and deinking composition |
US5248388A (en) * | 1991-04-25 | 1993-09-28 | Betz Paperchem, Inc. | Use of surfactants having an HLB less than 10 in the deinking of dry toner electrostatic printed wastepaper |
US5200034A (en) * | 1991-04-25 | 1993-04-06 | Betz Paperchem, Inc. | Use of surfactants having an HLB less than 10 in the deinking of dry toner electrostatic printed wastepaper |
CA2063351C (en) * | 1992-03-18 | 1996-08-13 | Stanley Alan Heimburger | Process for bleaching hardwood pulp |
JP3256862B2 (en) * | 1992-12-25 | 2002-02-18 | レンゴー株式会社 | Disintegration promoter composition for pulp recovery |
US5759983A (en) * | 1993-08-04 | 1998-06-02 | Colgate-Palmolive Co. | Aqueous cleaning composition which may be in microemulsion form comprising polyalkylene oxide -polydimethyl siloxane and ethoxylated secondary alcohol |
US5651861A (en) * | 1995-12-18 | 1997-07-29 | Rhone-Poulenc Inc. | Process for removing inks from waste paper |
JP3051826B2 (en) * | 1996-06-03 | 2000-06-12 | 花王株式会社 | Deinking method |
GB9620887D0 (en) * | 1996-10-07 | 1996-11-27 | Allied Colloids Ltd | Separation of solids from aqueous suspensions |
GB0217197D0 (en) * | 2002-07-24 | 2002-09-04 | Dow Corning | Method of deinking |
-
2002
- 2002-07-24 GB GB0217197A patent/GB0217197D0/en not_active Ceased
-
2003
- 2003-07-22 PL PL373198A patent/PL216211B1/en unknown
- 2003-07-22 EA EA200500058A patent/EA008834B1/en not_active IP Right Cessation
- 2003-07-22 AU AU2003254593A patent/AU2003254593B2/en not_active Ceased
- 2003-07-22 EP EP03771095A patent/EP1540075B1/en not_active Expired - Lifetime
- 2003-07-22 KR KR20057001154A patent/KR101029233B1/en active IP Right Grant
- 2003-07-22 US US10/521,795 patent/US20060102298A1/en not_active Abandoned
- 2003-07-22 CA CA2493758A patent/CA2493758C/en not_active Expired - Lifetime
- 2003-07-22 DE DE2003615477 patent/DE60315477T2/en not_active Expired - Lifetime
- 2003-07-22 DK DK03771095T patent/DK1540075T3/en active
- 2003-07-22 AT AT03771095T patent/ATE369458T1/en active
- 2003-07-22 WO PCT/EP2003/008166 patent/WO2004011717A1/en active IP Right Grant
- 2003-07-22 CN CNB038174766A patent/CN100357518C/en not_active Expired - Lifetime
- 2003-07-22 ES ES03771095T patent/ES2290508T3/en not_active Expired - Lifetime
- 2003-07-22 JP JP2004523792A patent/JP4478019B2/en not_active Expired - Fee Related
-
2005
- 2005-01-26 HR HR20050087A patent/HRP20050087B1/en not_active IP Right Cessation
- 2005-02-23 NO NO20050989A patent/NO334965B1/en not_active IP Right Cessation
-
2009
- 2009-11-19 JP JP2009264247A patent/JP5117477B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0745648A2 (en) * | 1995-06-01 | 1996-12-04 | Dow Corning Corporation | Stable dispersible silicone compositions |
US5624569A (en) * | 1996-01-23 | 1997-04-29 | Nalco Chemical Company | Clarification of deinking process water |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4854733B2 (en) * | 2005-04-20 | 2012-01-18 | ダウ コーニング コーポレーション | Removal of organic deposits from recycled fibers used to produce paper |
KR101292611B1 (en) | 2005-04-20 | 2013-08-05 | 다우 코닝 코포레이션 | Removal of organic deposits from recycled fibers used for producing paper |
WO2006113896A1 (en) * | 2005-04-20 | 2006-10-26 | Dow Corning Corporation | Removal of organic deposits from recycled fibers used for producing paper |
EP2203105A1 (en) | 2007-10-05 | 2010-07-07 | Dental Equipment, LLC | Led-based dental exam lamp with variable chromaticity |
GB2464376A (en) * | 2008-10-17 | 2010-04-21 | Stephenson Group Ltd | Method of removing ink using a polysiloxane |
EP2350382A1 (en) | 2008-10-17 | 2011-08-03 | Stephenson Group Limited | Recycling of fibre products |
EP2362015A1 (en) | 2008-10-17 | 2011-08-31 | Stephenson Group Limited | Recycling of fibre products |
WO2011141899A1 (en) | 2010-05-14 | 2011-11-17 | Universitat Politecnica De Catalunya | Process for reclying waste paper, product obtained therefrom and its uses |
EP2386681A1 (en) | 2010-05-14 | 2011-11-16 | Universitat Politècnica de Catalunya | Process for recycling waste paper, product obtained there from and its uses |
US8986499B2 (en) | 2010-05-14 | 2015-03-24 | Universitat Politecnica De Catalunya | Process for recycling waste paper, product obtained therefrom and its uses |
WO2016059153A1 (en) * | 2014-10-15 | 2016-04-21 | Nopco Paper Technology Gmbh | A method for controlling the deposition of stickies in pulping and papermaking processes |
US10253454B2 (en) | 2014-10-15 | 2019-04-09 | Nopco Paper Technology Gmbh | Method for controlling the deposition of stickies in pulping and papermaking processes |
AU2015332714B2 (en) * | 2014-10-15 | 2019-06-20 | Nopco Paper Technology Gmbh | A method for controlling the deposition of stickies in pulping and papermaking processes |
RU2693604C2 (en) * | 2014-10-15 | 2019-07-03 | Нопко Пейпер Текнолоджи Гмбх | Method of controlling deposits of sticky substances in pulp cooking and paper making processes |
Also Published As
Publication number | Publication date |
---|---|
EA008834B1 (en) | 2007-08-31 |
ATE369458T1 (en) | 2007-08-15 |
EA200500058A1 (en) | 2005-08-25 |
EP1540075A1 (en) | 2005-06-15 |
NO334965B1 (en) | 2014-08-11 |
CN100357518C (en) | 2007-12-26 |
AU2003254593B2 (en) | 2009-03-19 |
JP2006503990A (en) | 2006-02-02 |
AU2003254593A1 (en) | 2004-02-16 |
PL216211B1 (en) | 2014-03-31 |
JP5117477B2 (en) | 2013-01-16 |
DK1540075T3 (en) | 2007-12-27 |
KR101029233B1 (en) | 2011-04-18 |
WO2004011717A8 (en) | 2005-03-31 |
JP4478019B2 (en) | 2010-06-09 |
CA2493758C (en) | 2011-09-20 |
CN1671920A (en) | 2005-09-21 |
KR20050036959A (en) | 2005-04-20 |
NO20050989L (en) | 2005-02-23 |
DE60315477D1 (en) | 2007-09-20 |
HRP20050087A2 (en) | 2005-10-31 |
DE60315477T2 (en) | 2007-11-29 |
GB0217197D0 (en) | 2002-09-04 |
JP2010053504A (en) | 2010-03-11 |
PL373198A1 (en) | 2005-08-22 |
ES2290508T3 (en) | 2008-02-16 |
HRP20050087B1 (en) | 2008-06-30 |
CA2493758A1 (en) | 2004-02-05 |
EP1540075B1 (en) | 2007-08-08 |
US20060102298A1 (en) | 2006-05-18 |
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