WO2003106548A2 - Composition pour reservoir a paroi monocouche - Google Patents
Composition pour reservoir a paroi monocouche Download PDFInfo
- Publication number
- WO2003106548A2 WO2003106548A2 PCT/FR2003/001671 FR0301671W WO03106548A2 WO 2003106548 A2 WO2003106548 A2 WO 2003106548A2 FR 0301671 W FR0301671 W FR 0301671W WO 03106548 A2 WO03106548 A2 WO 03106548A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- permeability
- composition
- polymer
- hydrocarbons
- fillers
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Definitions
- the present invention relates to a composition
- a composition comprising a blend of polymeric material and one or more mineral filler (s) specifically selected for improving the hydrocarbon-tightness of the polymeric material by trapping within the the polymeric material the hydrocarbons that pass through permeability in the polymer.
- the invention applies in particular to all storage structures, or transport, of hydrocarbons, in particular fuel tanks and diesel, pipes, motor vehicles.
- the amount of hydrocarbon vapor emitted to the outside because of the permeability of the tank walls is subject to standards, already rigorous, and will become even more severe .
- the most stringent current standards are the American standards (CARB and EPA) which recommend an emission of 0.5 g / 25 hours per vehicle, knowing that each manufacturer then allocates 25% to 35% of these 0.5 g to the permeability fuel tank, ie 100 to 200 mg / 25 hours.
- the new ZEN Emission Nehicle standard will reduce the vehicle's hydrocarbon emission level to 0.35 g / 25 hours with a virtually zero contribution (ie about 45 to 55 mg / 25 hours) of the fuel system, and above all a guarantee of extremely low emission levels throughout the life of the vehicle.
- EP-1,108,598 and EP-1,108,599 which describe multilayer reservoirs of which at least one layer is made of a nanocomposite material.
- the present invention relates to a hydrocarbon-controlled permeability composition
- a hydrocarbon-controlled permeability composition comprising a mixture of polymeric material and fillers.
- the fillers are mineral and selected to adsorb and trap a quantity of hydrocarbons emitted through the polymer so as to reduce the permeability of the composition.
- the adsorbent mineral fillers may be chosen from the following group: zeolite, activated carbon, carbon nanotubes and mixtures thereof.
- the polymer may be chosen from: polyolefins (PE, PP), polyamides, fluorinated polymers, polymer alloys (PE-PA), elastomers.
- the polymeric material may comprise reducing charges of permeability of the micrometric type, for example talc, metal particles, or nanometric type, for example clays.
- the invention relates to a structure whose wall is a monolayer of the composition defined above.
- At least one side of the wall may be treated, for example by fluorination, to reduce the permeability.
- the structure can be implemented by extrusion, or injection, or blowing, or rotational molding, or compression.
- the invention can be applied to the manufacture of automobile tanks.
- the invention can be applied to the manufacture of automotive fuel lines.
- the present invention relates to a monolayer material of reduced permeability through a function of adsorption trapping on specific charges of all or part of the hydrocarbons emitted through this monolayer.
- the present invention is based mainly on adsorption trapping of hydrocarbons by mineral fillers, for example, zeolites, activated carbons, carbon nanotubes. These known charges for their adsorption capacity, are already used in pure form in reserves, but not used in combination with a polymer matrix to obtain the advantages of the present invention.
- the amount of filler to be incorporated into the polymer is calculated from the knowledge of the permeability of the polymer alone and the amount of hydrocarbons potentially emitted during the life of the vehicle through the polymer.
- the polymeric materials used must be compatible with the implementation methods used for the manufacture of the type of structures envisaged (hydrocarbon storage tanks, or pipes) and may therefore be polyolefins (polyethylene, polypropylene), polyamides (11). , 12, 6, 6-6, 6-10, ...), fluorinated polymers (PVDF, ..), thermoplastic polymers, elastomers, or thermosetting resins.
- PVDF fluorinated polymers
- thermoplastic polymers thermoplastic polymers
- elastomers or thermosetting resins.
- charges of micrometric or nanometric particles may be added so as to reduce the permeability of the polymer, or by adding a surface treatment of the monolayer according to the invention (fluorination of polyolefins for example).
- FIG. 1 illustrates one of the structures of the prior art
- FIG. 2 schematizes the principle of the invention
- FIGS. 3a, 3b and 3c illustrate variants of the present invention.
- the most commonly used material is a two-sided fluorinated polyolefin layer 1 (2 and 3) for reducing the permeability of the polymer 1.
- These surface treatments are relatively expensive without completely solving the problems of permeability.
- FIG. 2 shows the principle of the composition according to the invention comprising a polymer matrix in which mineral fillers are dispersed.
- the mineral fillers chosen have the function of adsorbing the hydrocarbon molecules which can pass through the polymer matrix.
- the charge has no significant effect on the value of the permeability of the matrix, but acts as a trap for hydrocarbon molecules to prevent their complete crossing of the wall to dissipate into the atmosphere.
- FIG. 3a has undergone a surface treatment 6, 7, for example by fluorination.
- FIG. 3b is a variant of the invention in which the monolayer consists of a composition similar to that of FIG. 2, but in which the permeability of the polymer matrix is reduced by the addition of micro or nanometric particles .
- FIG. 3c is a variant of the invention according to the variant of FIG. 3b in which the faces of the layer are treated 9, 10. This last variant is the most efficient in the case of motor vehicle tanks from the point of view of permeability .
- a motor vehicle fuel tank made of polymer is manufactured in most cases by extrusion blow molding and the amount of material used is about 6 kg in the case of polyethylene.
- hydrocarbon emissions measured by SHED test on this type of structures according to the standards in force can be estimated between 150 and 400 mg / 25 hours.
- Measurements of the absorption of fuels on polyethylene + adsorbent feed mixtures according to the invention have made it possible to obtain capture rates of the load of the order of 15% to 25%, which corresponds to an adsorption of 150%. mg to 250 mg / g load.
- micrometric or nanometric charges makes it possible to obtain a permeability reduction by a factor of 2 to 5. Considering average hydrocarbon emission values of a reservoir
- the emission of this structure is calculated for a period of 10 years: about 850 g in 10 years.
- hydrocarbon emissions will be between 170 g and 425 g.
- the invention and its variants, has a certain advantage for the reduction of hydrocarbon emissions of a structure containing it.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Cooling, Air Intake And Gas Exhaust, And Fuel Tank Arrangements In Propulsion Units (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Sealing Material Composition (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003255631A AU2003255631A1 (en) | 2002-06-13 | 2003-06-03 | Composition for tank with single-layer wall |
JP2004513371A JP2005529226A (ja) | 2002-06-13 | 2003-06-03 | 単層壁を有するタンク用の組成物 |
EP03759998A EP1517948A2 (fr) | 2002-06-13 | 2003-06-03 | Composition pour reservoir a paroi monocouche |
US10/517,630 US20060013973A1 (en) | 2002-06-13 | 2003-06-03 | Composition for tank with single-layer wall |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0207246A FR2840913B1 (fr) | 2002-06-13 | 2002-06-13 | Composition pour reservoir a paroi monocouche |
FR02/07246 | 2002-06-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2003106548A2 true WO2003106548A2 (fr) | 2003-12-24 |
WO2003106548A3 WO2003106548A3 (fr) | 2004-08-12 |
Family
ID=29595181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2003/001671 WO2003106548A2 (fr) | 2002-06-13 | 2003-06-03 | Composition pour reservoir a paroi monocouche |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060013973A1 (fr) |
EP (1) | EP1517948A2 (fr) |
JP (1) | JP2005529226A (fr) |
AU (1) | AU2003255631A1 (fr) |
FR (1) | FR2840913B1 (fr) |
WO (1) | WO2003106548A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8092884B2 (en) | 2009-07-02 | 2012-01-10 | Basf Se | Single layer fuel tank |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090257796A1 (en) * | 2008-04-09 | 2009-10-15 | Houston Advanced Research Center | Nanotechnology based image reproduction device |
FR2932870B1 (fr) † | 2008-06-18 | 2010-06-18 | Inst Francais Du Petrole | Conduite avec gaine a permeabilite reduite aux composes acides |
US20100050619A1 (en) * | 2008-09-03 | 2010-03-04 | Houston Advanced Research Center | Nanotechnology Based Heat Generation and Usage |
ITMI20082206A1 (it) * | 2008-12-12 | 2010-06-13 | Getters Spa | Materiale composito per la protezione di dispositivi sensibili ad h2o costituito da nanozeoliti disperse in una matrice polimerica |
DE102014010129A1 (de) * | 2014-07-09 | 2016-01-14 | Kautex Textron Gmbh & Co. Kg | Vorratsbehälter zur Aufnahme einer wässrigen Harnstofflösung |
EP3047969B1 (fr) * | 2015-01-22 | 2018-04-25 | Kautex Textron Gmbh&Co. Kg | Matériau composite multicouches et objets constitués de celui-ci |
US11559964B2 (en) | 2019-06-06 | 2023-01-24 | Northrop Grumman Systems Corporation | Composite structures, composite storage tanks, vehicles including such composite storage tanks, and related systems and methods |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3120070A1 (de) * | 1980-05-28 | 1982-03-18 | Výzkumný ústav gumárenské a plastikářské technologie, 76422 Gottwaldov | "folien aus modifiziertem polyvinylchlorid" |
EP1108598A2 (fr) * | 1999-12-18 | 2001-06-20 | Delphi Technologies, Inc. | Réservoir de carburant avec une barrière imperméable |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4048361A (en) * | 1974-10-29 | 1977-09-13 | Valyi Emery I | Composite material |
US4107362A (en) * | 1976-11-22 | 1978-08-15 | Valyi Emery I | Multilayered container |
US4523548A (en) * | 1983-04-13 | 1985-06-18 | Michigan Consolidated Gas Company | Gaseous hydrocarbon fuel storage system and power plant for vehicles |
US5508330A (en) * | 1994-11-03 | 1996-04-16 | Ciba-Geigy Corporation | Barrier property enhancement of films and molded articles |
CA2226925C (fr) * | 1995-07-14 | 2006-10-17 | Subhas K. Sikdar | Membranes remplies d'absorbant, utilisees pour eliminer les composes organiques volatils des eaux usees |
FR2758564B1 (fr) * | 1997-01-20 | 1999-03-26 | Atochem Elf Sa | Materiau barriere resistant a l'humidite et a la transformation par etirage et/ou thermoformage a base de copolyamide pa-6,1/6,t/6,6 |
DE19853097C2 (de) * | 1998-11-18 | 2001-02-01 | Mannesmann Vdo Ag | Kraftstoffbehälter |
US6552114B2 (en) * | 1998-12-07 | 2003-04-22 | University Of South Carolina Research Foundation | Process for preparing a high barrier amorphous polyamide-clay nanocomposite |
US6661339B2 (en) * | 2000-01-24 | 2003-12-09 | Nextreme, L.L.C. | High performance fuel tank |
FR2806348B1 (fr) * | 2000-03-17 | 2002-11-15 | Rhodia Engineering Plastics Sa | Articles comprenant un element a base de polyolefine assemble a un element a base de polyamide, et leur procede d'obtention |
US6250081B1 (en) * | 2000-06-15 | 2001-06-26 | Visteon Global Technologies, Inc. | Method for producing carbon/plastic bricks for use in an evaporative control system |
JP2002276862A (ja) * | 2001-01-12 | 2002-09-25 | Tokai Rubber Ind Ltd | 低透過燃料系ホース |
DE10104882B4 (de) * | 2001-02-01 | 2005-01-05 | Helsa-Werke Helmut Sandler Gmbh & Co. Kg | Aktivkohleformkörper, Verfahren zu dessen Herstellung, dessen Verwendung sowie Verfahren zur Regeneration desselben |
CH695222A5 (de) * | 2001-04-25 | 2006-01-31 | Eva Maria Moser | Gasdichter Behälter. |
US20020195453A1 (en) * | 2001-05-02 | 2002-12-26 | Mcleod David G. | Fuel tanks and fuel transport lines |
EP1449885B1 (fr) * | 2003-02-18 | 2013-10-02 | Arkema France | Utilisation de nanotubes de carbone dans des mélanges de polyamide et de polyoléfine |
-
2002
- 2002-06-13 FR FR0207246A patent/FR2840913B1/fr not_active Expired - Fee Related
-
2003
- 2003-06-03 WO PCT/FR2003/001671 patent/WO2003106548A2/fr active Application Filing
- 2003-06-03 US US10/517,630 patent/US20060013973A1/en not_active Abandoned
- 2003-06-03 JP JP2004513371A patent/JP2005529226A/ja active Pending
- 2003-06-03 AU AU2003255631A patent/AU2003255631A1/en not_active Abandoned
- 2003-06-03 EP EP03759998A patent/EP1517948A2/fr not_active Ceased
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3120070A1 (de) * | 1980-05-28 | 1982-03-18 | Výzkumný ústav gumárenské a plastikářské technologie, 76422 Gottwaldov | "folien aus modifiziertem polyvinylchlorid" |
EP1108598A2 (fr) * | 1999-12-18 | 2001-06-20 | Delphi Technologies, Inc. | Réservoir de carburant avec une barrière imperméable |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8092884B2 (en) | 2009-07-02 | 2012-01-10 | Basf Se | Single layer fuel tank |
Also Published As
Publication number | Publication date |
---|---|
FR2840913B1 (fr) | 2005-02-04 |
FR2840913A1 (fr) | 2003-12-19 |
EP1517948A2 (fr) | 2005-03-30 |
US20060013973A1 (en) | 2006-01-19 |
JP2005529226A (ja) | 2005-09-29 |
WO2003106548A3 (fr) | 2004-08-12 |
AU2003255631A1 (en) | 2003-12-31 |
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