WO2003089167A1 - Can end - Google Patents

Can end Download PDF

Info

Publication number
WO2003089167A1
WO2003089167A1 PCT/EP2003/003716 EP0303716W WO03089167A1 WO 2003089167 A1 WO2003089167 A1 WO 2003089167A1 EP 0303716 W EP0303716 W EP 0303716W WO 03089167 A1 WO03089167 A1 WO 03089167A1
Authority
WO
WIPO (PCT)
Prior art keywords
bead
countersink
arc
wall
indentation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2003/003716
Other languages
English (en)
French (fr)
Inventor
Martin Watson
Brian Fields
Andrew Robert Lockley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Crown Packaging UK Ltd
Crown Packaging Technology Inc
Original Assignee
CarnaudMetalbox PLC
Metal Box PLC
Crown Cork and Seal Technologies Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=29225723&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003089167(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to JP2003585908A priority Critical patent/JP4280645B2/ja
Priority to BRPI0309446-4A priority patent/BR0309446B1/pt
Priority to EP03722438A priority patent/EP1497054B1/en
Priority to MXPA04010456A priority patent/MXPA04010456A/es
Priority to CA2482984A priority patent/CA2482984C/en
Priority to DE60324910T priority patent/DE60324910D1/de
Priority to HK06100609.7A priority patent/HK1080782B/xx
Priority to AU2003229636A priority patent/AU2003229636B2/en
Application filed by CarnaudMetalbox PLC, Metal Box PLC, Crown Cork and Seal Technologies Corp filed Critical CarnaudMetalbox PLC
Publication of WO2003089167A1 publication Critical patent/WO2003089167A1/en
Priority to US10/770,791 priority patent/US20040238546A1/en
Priority to ZA2004/08419A priority patent/ZA200408419B/en
Anticipated expiration legal-status Critical
Priority to US10/979,068 priority patent/US7591392B2/en
Priority to US11/540,238 priority patent/US7370774B2/en
Priority to US12/551,907 priority patent/US8157119B2/en
Priority to US13/425,934 priority patent/US8496132B2/en
Priority to US13/952,757 priority patent/US8851323B2/en
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D17/00Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
    • B65D17/06Integral, or permanently secured, end or side closures
    • B65D17/08Closures secured by folding or rolling and pressing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S220/00Receptacles
    • Y10S220/906Beverage can, i.e. beer, soda

Definitions

  • This invention relates to a can end and a method of manufacture of such a can end.
  • it relates to a can end which has improved performance characteristics .
  • Containers such as cans which are used for the packaging beverages, for example, may contain a carbonated beverage which is at a higher than atmospheric pressure.
  • Can end design has been developed to withstand this "positive" buckle pressure (sometimes also referred to as “peaking" pressure) up to defined minimum values (currently 90psi for carbonated soft drinks) under normal operating conditions before failure.
  • Peaking pressure sometimes also referred to as “peaking” pressure
  • failure of conventional can ends involves loss of the circular profile and buckling of the end which, ultimately, leads to eversion of the end profile.
  • Abuse conditions may also arise when a container is dropped or distorted, or when the product within the container undergoes thermal processing.
  • the can end shell (that is, the unseamed can end) of that patent includes a peripheral curl, a seaming panel, a chuck wall at an angle of between 30° and 60°, a narrow anti-peaking bead and a centre panel.
  • the chuck wall is deformed at its upper end by contact with an anvil portion of the seaming chuck.
  • the resulting profile provides a very strong double seam since the annulus formed by the seam has very high hoop strength and will resist distortion from its circular profile when subjected to thermal processing or when packaging carbonated beverages .
  • Stiffness is also provided to the beverage can end by the anti-peaking or countersink bead.
  • This is an outwardly concave bead comprising inner and outer walls, joined by a curved portion.
  • this bead has walls which are substantially upright, although either may vary by up to +/- 15°.
  • This patent uses a small base radius (best fit) for the bead, typically 0.75 mm or less .
  • the width of the anti-peaking bead can be reduced by free drawing of the inner wall of the bead. This latter method avoids undue thinning of the bead as it is reworked.
  • the resultant narrower bead optimises the stiffness of the can and, consequently, its resistance to buckling when attached to a can body having high internal pressure in the can.
  • Can ends such as those described in the above patents have high hoop strength and/or improved buckle performance such that they resist deformation when subjected to high internal pressure.
  • the buckle pressure of the end of EP-B-0828663 is well above the 90 psi can making industry minimum standard.
  • This invention seeks to control the failure mode and to avoid catastrophic failure and leaking, whilst still achieving buck e pressure performance well above the industry stipulated pressure of 90 psi.
  • a can end shell comprising a centre panel, a countersink bead, an inclined chuck wall portion, and a seaming panel, and further including one or more control features, each feature extending around an arc of part of the countersink bead and/or the chuck wall whereby the failure mode of the can end, when seamed to a can body, is controlled, and in which the or each control feature comprises one or more of: an expansion of the countersink bead, a shelf in the outer wall of the countersink, an indentation in the chuck wall, and/or coining.
  • arc as used herein is intended to include a 360° arc, i.e. a control feature or features which extend around the whole circumference of the can end shell .
  • inclined is not intended to be limiting and the inclined chuck wall may have one or more parts, any of which may be linear or curved, for example.
  • a control feature such as a selectively weakened region, may be introduced onto the can end in a variety of different ways, all of which are intended to limit or prevent the concentration of strain. Control features or weakenings may be achieved by increasing the radial position of the outer wall of the countersink bead, a shelf in the countersink bead, an indentation in the chuck wall, or coining. Numerous variations are possible within the scope of the invention, including those set out below.
  • a shelf in the countersink bead will be in the outer wall of the bead, and may be at any position up that wall. Clearly when the shelf is at the lower end of the outer wall it effectively corresponds to an expansion in the bead radius .
  • a shelf or groove may be provided on any part of a radial cross-section through the bead but as the inner wall diameter position is often used as a reference for machine handling purposes and the thickness of the base of the countersink should ideally not be reduced, the outer wall is the preferred location.
  • an indentation in the chuck wall should be made so that in the seamed can end, the indentation is positioned approximately at the root of the seam.
  • the indentation should be made about half way up the chuck wall or in the upper half of the chuck wall, depending on the type of seam.
  • the indentation may be made using radial and indent spacers to control the radial and penetration depth of the tool.
  • a control feature may extend over a single arc behind the heel of the tab, centred on a diameter through the tab rivet and nose.
  • the arc length may be anything up to 90° in order to encompass any "thin point" due to orientation relative to grain orientation.
  • a control feature may comprise a combination of different types of control features, usually over at least a portion of the same arc of the can end such that, where the arcs are not fully circumferential, the different types are centred on the same can end diameter.
  • the indentation in the chuck wall may extend over the same length of arc as the bead expansion, a longer or a shorter arc length, with the centres of the arcs being on the same end diameter.
  • the countersink bead may have its base radius enlarged and then incorporate a control feature comprising a shelf in its outer wall.
  • a control feature comprising a shelf in its outer wall.
  • the arc length of the bead expansion (and, where present, the shelf) is less than the arc length of the chuck wall indentation, such that the bead expansion (and shelf) acts as a trigger for local peaking.
  • control feature comprises an indentation or coined region on the chuck wall
  • this may extend either internally or externally, or a combination of these around the arc.
  • it is the side of the can end to which a tab is fixed which is referred to as “external” as this side will be external in the finished can.
  • the indentation extends inwardly as otherwise it may be removed by the seaming tool during seaming.
  • the end shell may additionally include coining of a shoulder between the inner wall of the countersink and the centre panel over an arc or pair of arcs.
  • the control feature is preferably made in a conversion press but it may be made in a shell press or even in a combination of the shell and conversion presses providing that orientation of the end is not an issue.
  • Figure 1 is a perspective view of a conventional beverage can end
  • Figure 2 is a plan view of another type of beverage can end
  • Figure 3 is a partial side section of the can end of figure 2, prior to seaming;
  • Figure 4 is a partial side section of the can end of figure 2, after seaming to a can body;
  • Figure 5 is a sectioned perspective view of a seamed can end having two types of control features .
  • the can end of figure 1 is a conventional beverage end shell 1 comprising a peripheral curl 2 which is connected to a centre panel 3 via a chuck wall 4 and anti-peaking reinforcing bead or countersink 5.
  • the centre panel has a score line 6 which defines an aperture for dispensing beverage.
  • a tab 7 is fixed to the centre panel 3 by a rivet 8, as is usual practice. Beads 9 are provided for stiffening the panel.
  • the can end of figure 1 when attached by seaming to a can body which is filled with carbonated beverage, for example, is typically able to withstand an internal pressure of 98 psi before buckling, 8 psi above the required minimum buckle pressure of 90 psi.
  • an internal pressure of 98 psi before buckling, 8 psi above the required minimum buckle pressure of 90 psi When the pressure approaches and exceeds this value, the circular shape of the periphery of the end will distort and become oval. Eventually the centre panel will be forced outwardly so that the countersink "unravels" and flips over an arc of its circumference. Whilst a can which is buckled in such a manner is unlikely to be acceptable to a consumer, the can end itself is still intact, the tab 7 is still accessible and there is no compromise to the sealing of the container by such failure which could result in leaking of the contents.
  • a container has an end which is, by virtue of its design, substantially stiffer and has greater hoop strength than that of figure 1, the buckle failure mode differs from that described above.
  • a can end is that of EP-B-0828663, shown for reference in figures 2 to 4.
  • the can end 20 is attached to a can body 21 by a double seam 22, as shown in figure 4.
  • Inner portion 23 of the seam 22, which is substantially upright, is connected to a countersink bead 25 by a chuck wall 24.
  • the countersink, or anti-peaking bead 25 has inner and outer walls 26 and 27, the inner wall 26 depending from the centre panel 28 of the end.
  • a preferential "soft" peak is obtainable when the can end fails.
  • the can end may fail at a lower buckle pressure, the softer, less explosive nature of the peak results in a failure mode without pin hole or tearing.
  • the introduction of a control feature thus controls the failure mode and avoids concentration of the forces at a single point.
  • the radial position of the outer wall 27 of the countersink bead may be increased;
  • the chuck wall 24 may be coined or have indentations at or above approximately the mid-point such that this control feature is at the root of the seam 22 in the seamed can end (denoted as B');
  • a shelf may be made in the outer wall 27 of the countersink bead.
  • a type D region is at the lower part of the outer countersink wall, this may be equivalent to a type A control feature. Higher up the outer wall, a type D region takes the clear form of a shelf.
  • the shell of figures 2 to 4 was modified by a local groove in the outer wall of the countersink.
  • This groove was ideally adjacent the handle of the tab so that any failure of the can end would be away from the score. Positioning either side of the tab or, indeed, at any position around the countersink was also considered possible.
  • the groove was typically about 8 mm in arc length and was positioned approximately half way down the outer wall of the countersink bead, in the form of a shelf . Computer modelling has showed that the provision of such a groove resulted in a failure mode similar to that of a conventional can end such as that of figure 1, with no leakage.
  • Can ends were modified in the conversion press by expanding the countersink bead over a 60° arc at positions +/- 90° of the tab heel. These ends were then seamed onto filled cans and dropped vertically, tab end down, onto a steel plate, the sheet steel being inclined at 30°. This extreme test is non-standard and tested the cans for severe abuse performance.
  • Can ends modified in this way were also tested by pressurising a can to which the end was seamed ("seamed end test”) . These results are shown in table 2. Whilst the cans all peaked on the indentation site and were still openable after peaking, only 25% survived testing without leaking on the peak location.
  • the combination of a countersink bead expansion and indentation in the chuck wall increases the average height at which peaking occurs.
  • the countersink bead expansion was found to act as a trigger and this combination of a trigger and chuck wall indentation controls the peaking better than a countersink bead expansion alone (example 1) .
  • the chuck wall indentations comprised a indentation on each side of the tab, set at 90° to the tab.
  • Spacer conditions were as in example 3, but with a 9 mm indent ring spacer (rather than 8.75 mm) .
  • the countersink "trigger” comprised a single bead expansion within the arc of the chuck wall indentation and centred on the same diameter (arc mid-point) . This bead expansion was selected to trigger a peak within the chuck wall indentation as identified in example 2.
  • the control can ends give very low survival figures in both drop tests and seamed end testing (SET), i.e. the control can ends leak when they peak.
  • the chuck wall indentation alone gives good hot drop (100°F) and SET performance but seems to have higher incidence of score bursts during hot drop testing.
  • the countersink (“c'sk”) bead trigger creates a very symmetric end shape from the hot drop test and is very effective in determining the peak location.
  • the countersink trigger reduces the SET performance to 89 psi average, but this is believed to be attributable to the tooling used to create the indentations.
  • “1” means yes and "0” means no, except in position in which 1 indicates the position of peak on the control feature.
  • control features of the invention are particularly intended for use on beverage can ends which are to be fixed to a can body and thereby subjected to internal pressure.
  • control features may be used on can ends having any chuck wall angle whether conventional (less than 15°) or larger, such as that of EP-B-0828663, i.e. 30° to 60°.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Containers With Two Or More Constituent Elements (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Closures For Containers (AREA)
  • Pressure Vessels And Lids Thereof (AREA)
  • Wrappers (AREA)
  • Cartons (AREA)
  • Packages (AREA)
  • Mechanical Pencils And Projecting And Retracting Systems Therefor, And Multi-System Writing Instruments (AREA)
PCT/EP2003/003716 2002-04-22 2003-04-10 Can end Ceased WO2003089167A1 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
JP2003585908A JP4280645B2 (ja) 2002-04-22 2003-04-10 缶エンド
BRPI0309446-4A BR0309446B1 (pt) 2002-04-22 2003-04-10 Cobertura de extremidade de lata, e, lata
EP03722438A EP1497054B1 (en) 2002-04-22 2003-04-10 Can end
MXPA04010456A MXPA04010456A (es) 2002-04-22 2003-04-10 Extremo de bote.
CA2482984A CA2482984C (en) 2002-04-22 2003-04-10 Can end
DE60324910T DE60324910D1 (de) 2002-04-22 2003-04-10 Dosendeckel
HK06100609.7A HK1080782B (en) 2002-04-22 2003-04-10 Can end
AU2003229636A AU2003229636B2 (en) 2002-04-22 2003-04-10 Can end
US10/770,791 US20040238546A1 (en) 2002-04-22 2004-02-03 Can end
ZA2004/08419A ZA200408419B (en) 2002-04-22 2004-10-18 Can end
US10/979,068 US7591392B2 (en) 2002-04-22 2004-11-01 Can end
US11/540,238 US7370774B2 (en) 2002-04-22 2006-09-28 Can end
US12/551,907 US8157119B2 (en) 2002-04-22 2009-09-01 Can end
US13/425,934 US8496132B2 (en) 2002-04-22 2012-03-21 Can end
US13/952,757 US8851323B2 (en) 2002-04-22 2013-07-29 Can end

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02252800.4 2002-04-22
EP02252800A EP1361164A1 (en) 2002-04-22 2002-04-22 Can end

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US10770791 A-371-Of-International 2003-04-10
US10/770,791 Continuation US20040238546A1 (en) 2002-04-22 2004-02-03 Can end
US10/979,068 Continuation-In-Part US7591392B2 (en) 2002-04-22 2004-11-01 Can end

Publications (1)

Publication Number Publication Date
WO2003089167A1 true WO2003089167A1 (en) 2003-10-30

Family

ID=29225723

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/003716 Ceased WO2003089167A1 (en) 2002-04-22 2003-04-10 Can end

Country Status (14)

Country Link
US (2) US20040238546A1 (https=)
EP (2) EP1361164A1 (https=)
JP (1) JP4280645B2 (https=)
CN (1) CN100393443C (https=)
AT (1) ATE415217T1 (https=)
AU (1) AU2003229636B2 (https=)
BR (1) BR0309446B1 (https=)
CA (1) CA2482984C (https=)
DE (1) DE60324910D1 (https=)
ES (1) ES2318126T3 (https=)
MX (1) MXPA04010456A (https=)
RU (1) RU2319571C2 (https=)
WO (1) WO2003089167A1 (https=)
ZA (1) ZA200408419B (https=)

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DE102005024219B3 (de) * 2005-05-25 2006-07-13 Ball Packaging Europe Gmbh Deckel mit Führungssäulen für einen Behälter
US8877111B2 (en) 2005-05-25 2014-11-04 Ball Packaging Europe Gmbh Method for producing a metal lid with guide posts for a container

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US6419110B1 (en) 2001-07-03 2002-07-16 Container Development, Ltd. Double-seamed can end and method for forming
US7591392B2 (en) 2002-04-22 2009-09-22 Crown Packaging Technology, Inc. Can end
EP1361164A1 (en) 2002-04-22 2003-11-12 Crown Cork & Seal Technologies Corporation Can end
USD600116S1 (en) * 2003-09-19 2009-09-15 Gabe Cherian Lid with pull tab
USD612724S1 (en) * 2003-09-19 2010-03-30 Gabe Cherian Lid with pull tab
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US9580204B2 (en) * 2004-09-14 2017-02-28 Gabe Cherian PT2 pull tab lids stacking
USD579771S1 (en) * 2004-09-14 2008-11-04 Gabe Cherian Lid with pull tab
US20060071005A1 (en) 2004-09-27 2006-04-06 Bulso Joseph D Container end closure with improved chuck wall and countersink
DE602006011610D1 (de) * 2005-05-17 2010-02-25 Toyo Seikan Kaisha Ltd Quadratische dose und verfahren und vorrichtung zum doppeltwalzen derselben
US7506779B2 (en) 2005-07-01 2009-03-24 Ball Corporation Method and apparatus for forming a reinforcing bead in a container end closure
US8109406B2 (en) * 2006-10-26 2012-02-07 Charles Chang Beverage container construction
US8875936B2 (en) 2007-04-20 2014-11-04 Rexam Beverage Can Company Can end with negatively angled wall
US8011527B2 (en) * 2007-08-10 2011-09-06 Rexam Beverage Can Company Can end with countersink
US8973780B2 (en) 2007-08-10 2015-03-10 Rexam Beverage Can Company Can end with reinforcing bead
CN101445170B (zh) * 2008-11-24 2012-09-05 波尔亚太(佛山)金属容器有限公司 铝易拉罐印刷罐盖的制备方法
US20100213194A1 (en) * 2009-02-21 2010-08-26 Junsong Liu Pop Can Beak Spout Design
US8939308B2 (en) * 2009-09-04 2015-01-27 Crown Packaging Technology, Inc. Full aperture beverage end
EP2490955B1 (en) 2009-10-23 2018-01-10 Barry W. Chapin Beverage can accessory
US9566634B2 (en) 2010-06-07 2017-02-14 Rexam Beverage Can Company Can end produced from downgauged blank
USD640141S1 (en) * 2010-07-09 2011-06-21 Chapin Barry W Countersink groove cover on a beverage can
EP2502838B1 (de) * 2010-07-19 2013-12-25 Red Bull GmbH Dichtungskonstruktion, insbesondere für wiederverschließbaren Gebindedeckel, wiederverschließbarer Gebindedeckel, enthaltend diese Dichtungskonstruktion, sowie Gebinde, enthaltend diesen Gebindedeckel
USD669781S1 (en) 2010-08-23 2012-10-30 Crown Packaging Technology, Inc. Full transversely oriented oval aperture can
USD653109S1 (en) 2010-10-18 2012-01-31 Stolle Machinery Company, Llc Can end
US9550604B2 (en) 2010-10-18 2017-01-24 Silgan Containers Llc Can end with strengthening bead configuration
USD685266S1 (en) 2010-10-18 2013-07-02 Silgan Containers Llc Can end
US8727169B2 (en) 2010-11-18 2014-05-20 Ball Corporation Metallic beverage can end closure with offset countersink
WO2012174058A1 (en) 2011-06-14 2012-12-20 Crown Packaging Technology, Inc. Methos and system for forming high - strength beverage can ends of aluminum magnesium alloy and such can ends
US8939695B2 (en) 2011-06-16 2015-01-27 Sonoco Development, Inc. Method for applying a metal end to a container body
US8998027B2 (en) 2011-09-02 2015-04-07 Sonoco Development, Inc. Retort container with thermally fused double-seamed or crimp-seamed metal end
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US10131455B2 (en) 2011-10-28 2018-11-20 Sonoco Development, Inc. Apparatus and method for induction sealing of conveyed workpieces
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GB201205243D0 (en) 2012-03-26 2012-05-09 Kraft Foods R & D Inc Packaging and method of opening
US10399139B2 (en) 2012-04-12 2019-09-03 Sonoco Development, Inc. Method of making a retort container
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GB2510623B (en) * 2013-02-11 2015-10-21 Crown Packaging Technology Inc Seated end process
GB2511560B (en) 2013-03-07 2018-11-14 Mondelez Uk R&D Ltd Improved Packaging and Method of Forming Packaging
GB2511559B (en) 2013-03-07 2018-11-14 Mondelez Uk R&D Ltd Improved Packaging and Method of Forming Packaging
US9114451B2 (en) 2013-03-15 2015-08-25 Ball Corporation Container end closure with buckle control feature
RU2655906C2 (ru) 2013-05-31 2018-05-29 Краун Пэкэджинг Текнолоджи, Инк. Торцевая крышка банки для напитка, имеющая дугообразную стенку панели и изогнутую переходную стенку
US9714114B2 (en) 2013-11-08 2017-07-25 Crown Packaging Technology, Inc. Full aperture can end
USD763969S1 (en) * 2015-06-16 2016-08-16 Claudius Jeager Flying disk toy
CN107883583A (zh) * 2016-09-29 2018-04-06 青岛经济技术开发区海尔热水器有限公司 一种热水器的外壳及热水器
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EP1497054B1 (en) 2008-11-26
JP4280645B2 (ja) 2009-06-17
CN100393443C (zh) 2008-06-11
US20040238546A1 (en) 2004-12-02
ES2318126T3 (es) 2009-05-01
EP1497054A1 (en) 2005-01-19
US7370774B2 (en) 2008-05-13
BR0309446A (pt) 2005-02-09
RU2004133891A (ru) 2005-09-10
CN1646243A (zh) 2005-07-27
JP2006514595A (ja) 2006-05-11
CA2482984A1 (en) 2003-10-30
DE60324910D1 (de) 2009-01-08
EP1361164A1 (en) 2003-11-12
ZA200408419B (en) 2005-11-30
AU2003229636A1 (en) 2003-11-03
RU2319571C2 (ru) 2008-03-20
AU2003229636B2 (en) 2008-06-26
BR0309446B1 (pt) 2014-10-07
MXPA04010456A (es) 2005-07-14
ATE415217T1 (de) 2008-12-15
CA2482984C (en) 2012-06-26
US20070029324A1 (en) 2007-02-08
HK1080782A1 (zh) 2006-05-04

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