WO2002092564A3 - Synthesis of cyclopentadiene derivatives - Google Patents

Synthesis of cyclopentadiene derivatives Download PDF

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Publication number
WO2002092564A3
WO2002092564A3 PCT/EP2002/005094 EP0205094W WO02092564A3 WO 2002092564 A3 WO2002092564 A3 WO 2002092564A3 EP 0205094 W EP0205094 W EP 0205094W WO 02092564 A3 WO02092564 A3 WO 02092564A3
Authority
WO
WIPO (PCT)
Prior art keywords
synthesis
cyclopentadiene derivatives
membered heterocycle
obtained compound
heterocycle ring
Prior art date
Application number
PCT/EP2002/005094
Other languages
French (fr)
Other versions
WO2002092564A2 (en
Inventor
Ev Ilya E Nifant
Igor A Kashulin
Pavel V Ivchenko
Peter A A Klusener
Frans M Korndorffer
Kloe Kees P De
Jos J H Rijsemus
Original Assignee
Basell Polyolefine Gmbh
Ev Ilya E Nifant
Igor A Kashulin
Pavel V Ivchenko
Peter A A Klusener
Frans M Korndorffer
Kloe Kees P De
Jos J H Rijsemus
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh, Ev Ilya E Nifant, Igor A Kashulin, Pavel V Ivchenko, Peter A A Klusener, Frans M Korndorffer, Kloe Kees P De, Jos J H Rijsemus filed Critical Basell Polyolefine Gmbh
Priority to JP2002589450A priority Critical patent/JP2004530689A/en
Priority to DE60229054T priority patent/DE60229054D1/en
Priority to US10/477,315 priority patent/US7253292B2/en
Priority to EP02742976A priority patent/EP1387827B1/en
Publication of WO2002092564A2 publication Critical patent/WO2002092564A2/en
Publication of WO2002092564A3 publication Critical patent/WO2002092564A3/en
Priority to US11/819,560 priority patent/US7635781B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/80—[b, c]- or [b, d]-condensed
    • C07D209/94—[b, c]- or [b, d]-condensed containing carbocyclic rings other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Furan Compounds (AREA)
  • Indole Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process for preparing cyclopentadiene derivatives comprising the steps of: a) coupling a five membered heterocycle ring with a five or six membered heterocycle ring; b) reacting the obtained compound with a carbonilating system: c) reducing the obtained compound.
PCT/EP2002/005094 2001-05-15 2002-05-08 Synthesis of cyclopentadiene derivatives WO2002092564A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2002589450A JP2004530689A (en) 2001-05-15 2002-05-08 Synthesis of cyclopentadiene derivatives
DE60229054T DE60229054D1 (en) 2001-05-15 2002-05-08 SYNTHESIS OF CYCLOPENTADIVES DERIVATIVES
US10/477,315 US7253292B2 (en) 2001-05-15 2002-05-08 Synthesis of cyclopentadiene derivatives
EP02742976A EP1387827B1 (en) 2001-05-15 2002-05-08 Synthesis of cyclopentadiene derivatives
US11/819,560 US7635781B2 (en) 2001-05-15 2007-06-27 Synthesis of cyclopentadiene derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01201821 2001-05-15
EP01201821.4 2001-05-15

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US10477315 A-371-Of-International 2002-05-08
US11/819,560 Division US7635781B2 (en) 2001-05-15 2007-06-27 Synthesis of cyclopentadiene derivatives

Publications (2)

Publication Number Publication Date
WO2002092564A2 WO2002092564A2 (en) 2002-11-21
WO2002092564A3 true WO2002092564A3 (en) 2003-04-17

Family

ID=8180316

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/005094 WO2002092564A2 (en) 2001-05-15 2002-05-08 Synthesis of cyclopentadiene derivatives

Country Status (6)

Country Link
US (2) US7253292B2 (en)
EP (1) EP1387827B1 (en)
JP (1) JP2004530689A (en)
AT (1) ATE409180T1 (en)
DE (1) DE60229054D1 (en)
WO (1) WO2002092564A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002092564A2 (en) * 2001-05-15 2002-11-21 Basell Polyolefine Gmbh Synthesis of cyclopentadiene derivatives
JP4418228B2 (en) 2001-06-22 2010-02-17 バーゼル・ポリオレフィン・ゲーエムベーハー Use in catalyst systems for metallocene and olefin polymer production
WO2003008496A1 (en) 2001-07-17 2003-01-30 Basell Polyolefine Gmbh Multistep process for the (co)polymerization of olefins
JP4528526B2 (en) * 2003-03-03 2010-08-18 ダウ グローバル テクノロジーズ インコーポレイティド Polycyclic fused heterocyclic compound, metal complex and polymerization method
ATE451377T1 (en) * 2005-09-19 2009-12-15 Basell Polyolefine Gmbh SYNTHESIS OF CYCLOPENTADIENEDITHIOPHENE DERIVATIVES
DE102005061326A1 (en) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Preparation of metallocene compound, useful e.g. in the preparation of isotactic polypropylene, comprises using a cyclopentadienyl derivative that is recycled from the filtrate obtained from the preparation of e.g. metallocene compound
US20100222601A1 (en) * 2006-12-12 2010-09-02 Basell Polyolefine Gmbh Synthesis of cyclopentadiene derivatives
KR101555076B1 (en) * 2008-03-17 2015-09-22 바스프 에스이 Substituted oligo- or polythiophenes
KR101268026B1 (en) 2010-06-11 2013-05-27 광주과학기술원 A method of controlling the bromination of thiophene derivatives
KR101637982B1 (en) * 2014-11-07 2016-07-11 주식회사 엘지화학 Ligand compound, transition metal compound, and catalystic composition comprising the same
CN104892459A (en) * 2015-06-16 2015-09-09 苏州明锐医药科技有限公司 Riociguat intermediate and preparation method thereof
KR101910701B1 (en) 2015-07-02 2018-10-22 주식회사 엘지화학 Transition metal compound and catalystic composition comprising the same
KR101920401B1 (en) * 2016-12-06 2019-02-08 한화케미칼 주식회사 Transition metal compound used to prepare catalyst for polymerizing olefin, catalyst for polymerizing olefin comprising the same and polyolefin polymerized by using the same
US11225495B2 (en) 2017-07-27 2022-01-18 Lg Chem, Ltd. Transition metal compound and method for preparing the same
WO2019132471A1 (en) * 2017-12-26 2019-07-04 주식회사 엘지화학 Olefin-based polymer
US11440984B2 (en) 2017-12-26 2022-09-13 Lg Chem, Ltd. Olefin-based polymer
CN108467384A (en) * 2018-05-10 2018-08-31 上海合全药物研发有限公司 The synthetic method of 4- bromothiophene -2- formaldehyde

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999024446A1 (en) * 1997-11-12 1999-05-20 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL129600A0 (en) 1996-11-15 2000-02-29 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts
AU783097B2 (en) 1999-12-28 2005-09-22 Basell Technology Company B.V. Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
WO2002092564A2 (en) 2001-05-15 2002-11-21 Basell Polyolefine Gmbh Synthesis of cyclopentadiene derivatives

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999024446A1 (en) * 1997-11-12 1999-05-20 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ALLERT WIERSEMA AND SALO GRONOWITZ: "Thiophene analogues of fluorene III. On the synthesis of methylated cyclopentadithiophenes", ACTA CHEMICA SCANDINAVICA., vol. 24, no. 7, - 1970, MUNKSGAARD, COPENHAGEN., DK, pages 2593 - 2611, XP002226315, ISSN: 0904-213X *
S.M. HUMAYUN KABIR ET AL.: "New syntheses of tricyclic thiophenes and cyclic tetrathiophenes using transition-metal-catalyzed cyclization", HETEROCYCLES., vol. 52, no. 2, - 2000, ELSEVIER SCIENCE PUBLISHERS B.V. AMSTERDAM., NL, pages 761 - 774, XP002226316, ISSN: 0385-5414 *

Also Published As

Publication number Publication date
DE60229054D1 (en) 2008-11-06
EP1387827B1 (en) 2008-09-24
JP2004530689A (en) 2004-10-07
US20080287692A1 (en) 2008-11-20
WO2002092564A2 (en) 2002-11-21
US7635781B2 (en) 2009-12-22
US20040236115A1 (en) 2004-11-25
US7253292B2 (en) 2007-08-07
ATE409180T1 (en) 2008-10-15
EP1387827A2 (en) 2004-02-11

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