WO2002085874A1 - Process for the epoxidation of olefins - Google Patents
Process for the epoxidation of olefins Download PDFInfo
- Publication number
- WO2002085874A1 WO2002085874A1 PCT/EP2002/002288 EP0202288W WO02085874A1 WO 2002085874 A1 WO2002085874 A1 WO 2002085874A1 EP 0202288 W EP0202288 W EP 0202288W WO 02085874 A1 WO02085874 A1 WO 02085874A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- propene
- hydrogen peroxide
- liquid
- reaction
- epoxidation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
Definitions
- propene can be converted by hydrogen peroxide into propene oxide if a titanium- containing zeolite is used as catalyst.
- Unreacted hydrogen peroxide cannot be recovered economically from the epoxidation reaction mixture. Furthermore, unreacted hydrogen peroxide involves additional effort and expenditure in the working up of the reaction mixture.
- the epoxidation of propene is therefore preferably carried out with " an excess of propene and up to a high hydrogen peroxide conversion.
- a continuous flow reaction system may comprise either one or more continuous flow reactors or an arrangement of two or more flow mixing reactors connected in series. Examples of flow mixing reactors are stirred tank reactors, recycle reactors, fluidised bed reactors and fixed bed reactors with recycling of the liquid phase.
- Hydrogen peroxide is in general applied in the epoxidation reaction as aqueous solution.
- the epoxidation reaction takes place in the liquid aqueous phase. Therefore in order to achieve a high reaction velocity as high a propene concentration as possible in the liquid phase is necessary.
- the liquid phase predominantly comprises aqueous hydrogen peroxide solution and optionally an organic solvent solubility of propene in the aqueous phase is limited. So far in the prior art two different routes are described to achieve a high propene concentration in the aqueous phase.
- W099/01445 teaching a process for epoxidation of propene wherein temperature and pressure is increased during operation of the reactor in a manner effective to maintain a substantially constant concentration of propene in the liquid aqueous phase in order to compensate for catalyst deactivation.
- the temperature is increased during the course of reaction from 65.6°C to 71.1°C in order to maintain a constant H 2 0 2 conversion to compensate for catalyst deactivation.
- the pressure was held approximately constant at about 20 bar with the result that concentration of propene in the aqueous phase and propene oxide selectivity decreased.
- the pressure was increased to hold the propene concentration approximately constant with the result that propene oxide selectivity decreased to a lesser extent. But it would be still desirable to achieve a better propene oxide selectivity.
- EP-A 659473 describes an epoxidation process wherein according to the examples a liquid mixture of hydrogen peroxide, isopropanol as solvent and propene is led over a succession of fixed bed reaction zones connected in series in down-flow operation. In each reaction zone the reaction is performed to a partial conversion, the liquid reaction mixture is removed from each reaction zone, is led over an external heat exchanger to extract the heat of reaction, and the major proportion of this liquid phase is then recycled to this reaction zone and a minor proportion of the liquid phase is passed to the next zone.
- each reaction zone can be considered as an independent adiabatic reactor.
- gaseous propene is fed in together with the liquid feed stock mixture, is guided in a parallel stream to the liquid phase over the fixed bed reaction zones, and is extracted at the end of the reaction system in addition to the liquid reaction mixture as an oxygen- containing waste gas stream.
- reaction conditions were chosen that result in only one liquid aqueous phase wherein propene is dissolved.
- the increase in propene oxide yield compared to conventional tubular reactors is only related to the temperature control described in EP-A 659473. But on account of the complexity of the reaction system requi ed to carry out the process considerable additional costs are involved.
- the epoxidation reaction is conducted under conditions to have only one phase i.e. the liquid aqueous phase having a reasonably high propene concentration.
- an aqueous hydrogen peroxide solution, methanol and propene is fed to a fixed bed tubular reactor.
- By adjusting the relative amounts of the feeds to a low ratio of propene feed to total feed and a high ratio of methanol feed to total feed and by applying a pressure of 20 bar only one liquid phase is present.
- a hydrogen peroxide conversion of 98.4 % could be achieved the propene oxide selectivity of 80.3 % is still to low for a commercial application of the described process.
- the object of the present invention is to provide a process for the epoxidation of defines that results in improved product selectivity compared to W000/07965 which can be carried out using conventional reaction systems.
- This object is achieved by a process for the catalytic epoxidation of olefins with hydrogen peroxide in a multiphase reaction mixture comprising an liquid aqueous hydrogen peroxide rich phase containing an organic solvent having a solubility in water of at least 10 X by weight at 25°C and an liquid organic olefin rich phase.
- the present invention refers to a process for the epoxidation of propene with hydrogen peroxide in presence of a titanium-containing zeolite as catalyst in a multiphase reaction mixture comprising an liquid aqueous hydrogen peroxide rich phase containing methanol and dissolved propene and an liquid organic propene rich phase
- a multiphase reaction mixture comprising an liquid aqueous hydrogen peroxide rich phase and an liquid organic olefin rich phase product selectivity compared to the prior art can be considerably improved without compromising hydrogen peroxide conversion.
- the essential feature of the present invention is the presence of two immiscible liquid phases i.e an liquid aqueous hydrogen peroxide rich phase and an liquid organic olefin rich phase while having a water miscible organic solvent present in the aqueous phase.
- two immiscible phases in a reaction system comprising an olefin, an water miscible organic solvent and an aqueous hydrogen peroxide solution will depend on many different factors.
- Second of all the presence of an additional olefin rich liquid organic phase will depend on the temperature and pressure applied in the reactor and the selected olefin.
- the applied pressure is at or above the vapor pressure of the olefin at the chosen temperature.
- the organic solvent will depend on the selection of the organic solvent.
- Suitable as organic solvent are all solvents that are not oxidised or are oxidised only to a slight extent by hydrogen peroxide under the chosen reaction conditions, and that dissolve in an amount of more than 10 vit.Z in water at 25°C.
- Preferred are solvents that dissolve in an amount of more than 30 wt.X in water at 25°C preferably more than 50 wt.# in water at 25°C. The most preferred solvents are completely miscible with water.
- Suitable solvents include alcohols such as methanol, ethanol or tert.-butanol; glycols such as for example ethylene glycol, 1,2-propanediol or 1,3-propanediol ; cyclic ethers such as for example tetrahydrofuran, dioxane or propylene oxide; glycol ethers such as for example ethylene glycol onomethyl ether, ethylene glycol onoethyl ether, ethylene glycol monobutyl ether or propylene glycol monomethyl ether, and ketones such as for example acetone or 2-butanone. Methanol is particularly preferred.
- any olefins can be epoxidized in particular olefins with 2 to 6 carbon atoms.
- the process according to the invention is most particularly suitable for the epoxidation of propene to propene oxide.
- propene for economic reasons it would be preferred for an industrial scale process to use propene not in a pure form but as a technical mixture with propane that as a rule contains 1 to 15 vol.# of propane.
- a second organic olefin rich phase will depend on the relative amounts of olefin, water and solvent.
- the amount of solvent is chosen to achieve sufficient solubility of the olefin in the hydrogen peroxide rich aqueous phase in order to get the desired rate of reaction.
- pressure, olefin and solvent the relative amounts of ingredients can be adjusted to ensure formation of a second liquid organic phase. I.e. to ensure the formation of a second liquid organic olefin rich phase the amount of olefin has to be selected in excess of the amount soluble in the aqueous phase at the chosen temperature and pressure.
- a simple means of experimentally confirming the presence of a second liquid organic phase at the reaction conditions is by collecting a sample of the reaction mixture in a container equipped with a sight glass at the temperature and pressure used in the process.
- the reactor may be equipped with a sight glass at a suitable position to observe the phase boundary directly during the reaction.
- the sight glass is preferably positioned near the outlet of the reactor effluent to have an optimal control that two liquid phases are present through out the entire residence time within the reactor.
- the olefin is selected to be propene, and methanol is used as a solvent.
- a pressure from 5 to 50 bar the ratio of propene flow to total flow in case of a continuous flow system can be adjusted to be in the range of 0.1 to 1, preferably 0.2 to 1 in order to obtain a second liquid organic phase.
- Specific reaction conditions are shown in the examples.
- a further advantage of a process of the present invention is, that even if the feed stream to the reactor contains olefin oxide either due the presence of olefin oxide in the feed stream or due to partial recycling of the reactor effluent, the product selectivity is not considerably effected, although a person skilled in the art would expect that an increased concentration of product in the reaction mixture should be detrimental for product selectivity.
- An additional gas phase comprising olefin vapor and optionally an inert gas i.e. a gas that does not interfere with the epoxidation can be additionally present according to the present invention.
- an inert gas is useful to maintain a constant pressure inside the reactor and to remove oxygen gas formed by the decomposition of a small part of the hydrogen peroxide charged to the reactor.
- any known reaction system for the epoxidation of olefins is applicable including batch reactors and continuous flow reactors. It is preferred to use a non-adiabatic reaction system , i.e. a reaction system wherein the reaction heat is at least partially removed during the course of the reaction. Reactor systems with external or intermediate cooling are less preferred due to cost considerations. Continuous flow reaction system, especially those wherein the reaction mixture is passed through a fixed catalyst bed are particularly preferred.
- any usual reactor having a fixed catalyst bed and cooling means can be used.
- tubular reactors having a cooling jacket are applied since they are standardly available at relatively low cost.
- As cooling medium that is pumped through the cooling means preferably the cooling jacket, preferably water is used.
- the temperature of the cooling medium is controlled by a thermostat and the flow rate of the cooling medium is adjusted to keep the temperature difference between entry of the cooling medium into the cooling means and exit below 5°C.
- the reaction mixture is passed through the catalyst bed in a continuous flow operation mode with a superficial velocity from 1 to 100 m/h, preferably 5 to 50 m/h, most preferred 5 to 30 m/h.
- the superficial velocity is defined as the ratio of volume flow rate/cross section of the catalyst bed. Consequently the superficial velocity can be varied in a given tubular reactor by adjusting the flow rate of the reaction mixture.
- LHSV liquid hourly space velocity
- the process is conducted in down-flow operation mode especially the catalyst bed is maintained in a trickle bed state.
- the overall feed stream to the reactor comprises an aqueous hydrogen peroxide solution, an olefin and the organic solvent.
- these components may be introduced into the reactor as independent feeds or one or more of these feeds are mixed prior to introduction into the reactor.
- two or more reactors may if desired also be operated in parallel or in series in the aforedescribed manner.
- titanium-containing zeolites especially those of the composition (Ti0 2 ) x (Si0 2 ) 1 . x where x is from 0.001 to 0.05 and having a MFI or MEL crystalline structure, known as titanium silicalite-1 and titanium silicalite-2, are suitable as catalysts for the epoxidation process according to the invention.
- Such catalysts may be produced for example according to the process described in US-A 4,410,501.
- the titanium silicalite catalyst may be employed as a shaped catalyst in the form of granules, extrudates or shaped bodies.
- the catalyst may contain 1 to 99* of a binder or carrier material, all binders and carrier materials being suitable that do not react with hydrogen peroxide or with the epoxide under the reaction conditions employed for the epoxidation.
- Extrudates with a diameter of 1 to 5 mm are preferably used as fixed bed catalysts.
- the hydrogen peroxide is used in the process according to the invention in the form of an aqueous solution with a hydrogen peroxide content of 1 to 90 wt.*, preferably 10 to 70 wt.* and particularly preferably 30 to 50 wt.*.
- the hydrogen peroxide may be used in the form of the commercially available, stabilised solutions. Also suitable are unstabilised, aqueous hydrogen peroxide solutions such as are obtained in the anthraquinone process for producing hydrogen peroxide.
- the process according to the invention for the epoxidation of olefins, preferably propene, is typically carried out at a temperature of 30° to 80°C, preferably at 40° to 60°C.
- a temperature profile within the reactor in maintained such that the cooling medium temperature of the cooling means, preferably the cooling liquid in the cooling jacket of the tubular reactor is at least 40°C and the maximum temperature within the catalyst bed is 60°C at the most.
- the pressure within the reactor is usually maintained at a pressure at or above the vapor pressure of the olefin at the selected temperature for example at 10 to 50 bar, preferably at 20 to 50, most preferred 21 to 30 bar. With propene this translates to a pressure of at least 16.5 bar at a reaction temperature of 40°C and at least 25 bar at a reaction temperature of 60°C.
- the olefin is preferably employed in excess relative to the hydrogen peroxide and in an amount sufficient to maintain a second liquid olefin rich phase during the reaction.
- the molar ratio of olefin, preferably propene, to hydrogen peroxide preferably being chosen in the range from 1.1 to 30.
- the solvent is preferably added in a weight ratio of 0.5 to 20 relative to the amount of hydrogen peroxide solution used.
- the amount of catalyst employed may be varied within wide limits and is preferably chosen so that a hydrogen peroxide consumption of more than 90*, preferably more than 95*, is achieved within 1 minute to 5 hours under the employed reaction conditions.
- a titanium-silicate catalyst was employed in all examples.
- the titanium- silicate powder was shaped into 2 mm extrudates using a silica sol as binder in accordance with example 5 in EP 00106671.1.
- the H 2 0 2 employed was prepared according to the anthraquinone process as a 40 wt-* aqueous solution.
- Epoxidation is carried out continuously in down-flow operation mode in a reaction tube of 300 ml volume, a diameter of 10 mm and a length of 4 m.
- the reactor was additionally equipped with a sight glass located near the reactor outlet to allow visible verification whether two liquid phases were present as described above.
- the equipment is furthermore comprised of three containers for liquids and relevant pumps and a liquid separating vessel.
- the three containers for liquids comprised methanol, the 40* H 2 0 2 and propene.
- the 40* H 2 0 2 was adjusted with ammonia to a pH of 4.5.
- the reaction temperature was controlled via an aqueous cooling liquid circulating in a cooling jacket whereby the cooling liquid temperature is adjusted to 40°C by a thermostat.
- the reactor pressure was adjusted as indicated in Table 1.
- Mass flow of the feeding pumps was adjusted to result in a methanol flow of 0.2 kg/h, a H 2 0 2 flow of 0.033 kg/h.
- the propene flow in example 1 and comparative example 1 was adjusted to 0.0753 kg/h and to 0.125 kg/h in example 2.
- Comparative example 1 was repeated using reaction parameters as disclosed in Example 2 of W000/07965 and reported in Table 1.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002583401A JP4301814B2 (en) | 2001-03-05 | 2002-03-04 | Process for epoxidizing olefins |
BRPI0207824A BRPI0207824B1 (en) | 2001-03-05 | 2002-03-04 | process for catalytic epoxidation of propene with hydrogen peroxide |
DE60202273T DE60202273T2 (en) | 2001-03-05 | 2002-03-04 | PROCESS FOR EPOXIDING PROPES |
CA2440027A CA2440027C (en) | 2001-03-05 | 2002-03-04 | Process for the catalytic epoxidation of propene in a multiphase reaction mixture |
EP02727350A EP1377563B1 (en) | 2001-03-05 | 2002-03-04 | Process for the epoxidation of propene |
AT02727350T ATE284877T1 (en) | 2001-03-05 | 2002-03-04 | PROCESS FOR EPOXIDIZING PROPENE |
PL362617A PL210709B1 (en) | 2001-03-05 | 2002-03-04 | Process for the epoxidation of olefins |
KR1020037011615A KR100862177B1 (en) | 2001-03-05 | 2002-03-04 | Process for the epoxidation of olefins |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01105248.7 | 2001-03-05 | ||
EP01105248A EP1258483A1 (en) | 2001-03-05 | 2001-03-05 | Process for the epoxidation of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002085874A1 true WO2002085874A1 (en) | 2002-10-31 |
Family
ID=8176671
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/002288 WO2002085874A1 (en) | 2001-03-05 | 2002-03-04 | Process for the epoxidation of olefins |
Country Status (13)
Country | Link |
---|---|
EP (2) | EP1258483A1 (en) |
JP (1) | JP4301814B2 (en) |
KR (1) | KR100862177B1 (en) |
CN (1) | CN1235893C (en) |
AT (1) | ATE284877T1 (en) |
BR (1) | BRPI0207824B1 (en) |
CA (1) | CA2440027C (en) |
DE (1) | DE60202273T2 (en) |
ES (1) | ES2235035T3 (en) |
PL (1) | PL210709B1 (en) |
RU (1) | RU2303035C2 (en) |
WO (1) | WO2002085874A1 (en) |
ZA (1) | ZA200306921B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011017401A1 (en) * | 2009-08-05 | 2011-02-10 | Dow Global Technologies, Inc. | Process for producing an oxirane |
US7973183B2 (en) | 2007-05-08 | 2011-07-05 | Basf Sf | Process for the preparation of an olefin oxide |
US20120130096A1 (en) * | 2009-08-05 | 2012-05-24 | Crampton Hannah L | Process for producing propylene oxide |
EP3202764A4 (en) * | 2014-09-29 | 2018-04-04 | China Petroleum & Chemical Corporation | Olefin oxidation method, and reaction apparatus and system |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX362989B (en) * | 2015-11-26 | 2019-02-28 | Evonik Degussa Gmbh | Process for the epoxidation of an olefin. |
DE102018219557A1 (en) | 2018-11-15 | 2020-05-20 | Thyssenkrupp Ag | Process for the production and purification of propylene glycol |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4833260A (en) * | 1982-07-28 | 1989-05-23 | Anic S.P.A. | Process for the epoxidation of olefinic compounds |
EP0795537A1 (en) * | 1996-03-12 | 1997-09-17 | ENICHEM S.p.A. | Process for the synthesis of 2-butene -1,4-diesters |
DE19723950A1 (en) * | 1997-06-06 | 1998-12-10 | Basf Ag | Process for the oxidation of an organic compound having at least one C-C double bond |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2137310C (en) * | 1993-12-20 | 2004-02-17 | John C. Jubin Jr. | Catalytic converter and method for highly exothermic reactions |
US5912367A (en) * | 1997-07-01 | 1999-06-15 | Arco Chemical Technology, L.P. | High efficiency epoxidation process |
-
2001
- 2001-03-05 EP EP01105248A patent/EP1258483A1/en not_active Withdrawn
-
2002
- 2002-03-04 ES ES02727350T patent/ES2235035T3/en not_active Expired - Lifetime
- 2002-03-04 CA CA2440027A patent/CA2440027C/en not_active Expired - Fee Related
- 2002-03-04 PL PL362617A patent/PL210709B1/en unknown
- 2002-03-04 CN CNB028060091A patent/CN1235893C/en not_active Ceased
- 2002-03-04 DE DE60202273T patent/DE60202273T2/en not_active Expired - Lifetime
- 2002-03-04 JP JP2002583401A patent/JP4301814B2/en not_active Expired - Fee Related
- 2002-03-04 RU RU2003129070/04A patent/RU2303035C2/en not_active IP Right Cessation
- 2002-03-04 BR BRPI0207824A patent/BRPI0207824B1/en not_active IP Right Cessation
- 2002-03-04 WO PCT/EP2002/002288 patent/WO2002085874A1/en active IP Right Grant
- 2002-03-04 EP EP02727350A patent/EP1377563B1/en not_active Expired - Lifetime
- 2002-03-04 AT AT02727350T patent/ATE284877T1/en not_active IP Right Cessation
- 2002-03-04 KR KR1020037011615A patent/KR100862177B1/en active IP Right Grant
-
2003
- 2003-09-04 ZA ZA200306921A patent/ZA200306921B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4833260A (en) * | 1982-07-28 | 1989-05-23 | Anic S.P.A. | Process for the epoxidation of olefinic compounds |
EP0795537A1 (en) * | 1996-03-12 | 1997-09-17 | ENICHEM S.p.A. | Process for the synthesis of 2-butene -1,4-diesters |
DE19723950A1 (en) * | 1997-06-06 | 1998-12-10 | Basf Ag | Process for the oxidation of an organic compound having at least one C-C double bond |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7973183B2 (en) | 2007-05-08 | 2011-07-05 | Basf Sf | Process for the preparation of an olefin oxide |
EP2537838A1 (en) | 2007-05-08 | 2012-12-26 | Basf Se | A process for the preparation of an olefin oxide |
WO2011017401A1 (en) * | 2009-08-05 | 2011-02-10 | Dow Global Technologies, Inc. | Process for producing an oxirane |
US20120130096A1 (en) * | 2009-08-05 | 2012-05-24 | Crampton Hannah L | Process for producing propylene oxide |
US8697895B2 (en) | 2009-08-05 | 2014-04-15 | Dow Global Technologies, Llc | Process for producing an oxirane |
EP3202764A4 (en) * | 2014-09-29 | 2018-04-04 | China Petroleum & Chemical Corporation | Olefin oxidation method, and reaction apparatus and system |
US10400179B2 (en) | 2014-09-29 | 2019-09-03 | China Petroleum & Chemical Corporation | Olefin oxidation process, reaction apparatus and system |
Also Published As
Publication number | Publication date |
---|---|
CA2440027A1 (en) | 2002-10-31 |
BRPI0207824B1 (en) | 2016-11-01 |
BR0207824A (en) | 2004-03-02 |
DE60202273D1 (en) | 2005-01-20 |
KR20040023592A (en) | 2004-03-18 |
RU2303035C2 (en) | 2007-07-20 |
EP1377563B1 (en) | 2004-12-15 |
JP2004524373A (en) | 2004-08-12 |
EP1258483A1 (en) | 2002-11-20 |
CN1235893C (en) | 2006-01-11 |
ES2235035T3 (en) | 2005-07-01 |
ATE284877T1 (en) | 2005-01-15 |
DE60202273T2 (en) | 2005-12-08 |
EP1377563A1 (en) | 2004-01-07 |
PL362617A1 (en) | 2004-11-02 |
JP4301814B2 (en) | 2009-07-22 |
CN1494535A (en) | 2004-05-05 |
PL210709B1 (en) | 2012-02-29 |
RU2003129070A (en) | 2005-04-10 |
ZA200306921B (en) | 2004-09-01 |
CA2440027C (en) | 2010-05-18 |
KR100862177B1 (en) | 2008-10-09 |
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