WO2002020438A3 - Fischer-tropsch catalyst enhancement - Google Patents

Fischer-tropsch catalyst enhancement Download PDF

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Publication number
WO2002020438A3
WO2002020438A3 PCT/US2001/025157 US0125157W WO0220438A3 WO 2002020438 A3 WO2002020438 A3 WO 2002020438A3 US 0125157 W US0125157 W US 0125157W WO 0220438 A3 WO0220438 A3 WO 0220438A3
Authority
WO
WIPO (PCT)
Prior art keywords
treatment
dam
hydrogen
containing gas
metal oxides
Prior art date
Application number
PCT/US2001/025157
Other languages
French (fr)
Other versions
WO2002020438A2 (en
Inventor
Albert L Vovich Lapidus
Alla Jurievna Krylova
Lilia Vadimovna Sineva
Russell John Koveal
Michael A Daage
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Priority to AU2001281235A priority Critical patent/AU2001281235B2/en
Priority to AU8123501A priority patent/AU8123501A/en
Priority to CA002419797A priority patent/CA2419797C/en
Priority to DK01959708T priority patent/DK1313558T3/en
Priority to DE60127141T priority patent/DE60127141T2/en
Priority to EP01959708A priority patent/EP1313558B1/en
Publication of WO2002020438A2 publication Critical patent/WO2002020438A2/en
Publication of WO2002020438A3 publication Critical patent/WO2002020438A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process of enhancing both the activity and the methane selectivity of a particulate Dispersed Active Metal ('DAM') hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form a stable, unique oxidized catalyst precursor that is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature, wherein one or more promoter metal oxides of chromium, lanthanum and manganese are added to the DAM. Precursors of the promoter metal oxides may be combined with the DAMs prior to or during formation of the initial slurry, during the oxidation step or between recovery of the oxidized catalyst precursor and treatment of it with hydrogen-containing gas to reactivate the catalyst. Conversion of the precursors to the promoter metal oxides is carried out prior to the treatment with hydrogen-containing gas unless said treatment itself produces the conversion.
PCT/US2001/025157 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement WO2002020438A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2001281235A AU2001281235B2 (en) 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement
AU8123501A AU8123501A (en) 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement
CA002419797A CA2419797C (en) 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement
DK01959708T DK1313558T3 (en) 2000-09-01 2001-08-10 The Fischer-Tropsch catalyst improvement
DE60127141T DE60127141T2 (en) 2000-09-01 2001-08-10 PROCESS FOR IMPROVING A FISCHER TROPHATE CATALYST
EP01959708A EP1313558B1 (en) 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/653,915 2000-09-01
US09/653,915 US6531518B1 (en) 2000-09-01 2000-09-01 Fischer-Tropsch catalyst enhancement

Publications (2)

Publication Number Publication Date
WO2002020438A2 WO2002020438A2 (en) 2002-03-14
WO2002020438A3 true WO2002020438A3 (en) 2002-06-06

Family

ID=24622785

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/025157 WO2002020438A2 (en) 2000-09-01 2001-08-10 Fischer-tropsch catalyst enhancement

Country Status (9)

Country Link
US (2) US6531518B1 (en)
EP (1) EP1313558B1 (en)
AT (1) ATE355901T1 (en)
AU (2) AU2001281235B2 (en)
CA (1) CA2419797C (en)
DE (1) DE60127141T2 (en)
DK (1) DK1313558T3 (en)
ES (1) ES2282280T3 (en)
WO (1) WO2002020438A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7361619B2 (en) * 2003-04-11 2008-04-22 Exxonmobil Research And Engineering Company Fischer-Tropsch catalyst production
US7253136B2 (en) * 2003-04-11 2007-08-07 Exxonmobile Research And Engineering Company Preparation of titania and cobalt aluminate catalyst supports and their use in Fischer-Tropsch synthesis
US7419928B2 (en) * 2003-04-11 2008-09-02 Exxonmobil Research And Engineering Company Fischer-Tropsch catalyst production
WO2008131049A1 (en) * 2007-04-18 2008-10-30 H Gen Innovations Inc Hydrogen production process
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
AU2009228933B2 (en) * 2008-03-28 2012-05-31 Shell Internationale Research Maatschappij B.V. Process for regenerating a catalyst
US9878314B2 (en) 2013-11-26 2018-01-30 Infra XTL Technology Ltd. Catalyst for direct production of isoparaffins-rich synthetic oil and a method for preparing the catalyst

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3939097A (en) * 1972-12-07 1976-02-17 Hitachi Shipbuilding And Engineering Co., Ltd. Exhaust gas cleaning catalysts and method of producing same
DE2530818A1 (en) * 1975-07-10 1977-01-27 Basf Ag Passivation of pyrophoric metal catalyst - in which the wet material is treated with an oxygen contg. gas at a defined temp. and lower pressure
US4176092A (en) * 1977-03-25 1979-11-27 Bayer Aktiengesellschaft Process for the depyrophorization of pyrophoric metal catalysts and catalysts prepared by the process
GB2117400A (en) * 1982-03-18 1983-10-12 Alloy Surfaces Co Inc Catalytic metal
WO2000027525A1 (en) * 1998-11-05 2000-05-18 E.I. Du Pont De Nemours And Company Raney iron catalyst and a process for hydrogenating organic compounds using said catalyst

Family Cites Families (21)

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US2583619A (en) 1944-03-15 1952-01-29 Standard Oil Co Preparation of a raney catalyst surface
GB1038256A (en) * 1964-05-20 1966-08-10 Marchon Products Ltd Regeneration of copper chromite
FR2036937B1 (en) 1969-04-18 1976-04-16 Inst Francais Du Petrole
US4089812A (en) 1976-07-30 1978-05-16 The United States Of America As Represented By The Secretary Of The Interior Massive catalyst
US4399234A (en) 1981-10-13 1983-08-16 Gulf Research & Development Company Process for preparing gasoline range hydrocarbons from synthesis gas and catalyst used therefor
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US4670414A (en) 1981-10-13 1987-06-02 Kobylinski Thaddeus P Activated cobalt catalyst and synthesis gas conversion using same
US4585798A (en) 1981-10-13 1986-04-29 Gulf Research & Development Company Synthesis gas conversion using ruthenium-promoted cobalt catalyst
US4492774A (en) 1982-12-27 1985-01-08 Gulf Research & Development Company Method for converting synthesis gas using an activated cobalt-substituted layered aluminosilicate
US4977126A (en) 1987-05-07 1990-12-11 Exxon Research And Engineering Company Process for the preparation of surface impregnated dispersed cobalt metal catalysts
US4895994A (en) 1988-04-14 1990-01-23 W. R. Grace & Co.-Conn. Shaped catalysts and processes
US4826799A (en) 1988-04-14 1989-05-02 W. R. Grace & Co.-Conn. Shaped catalyst and process for making it
US4910175A (en) 1988-12-12 1990-03-20 E. I. Du Pont De Nemours And Company Catalyst recovery
US5348982A (en) 1990-04-04 1994-09-20 Exxon Research & Engineering Co. Slurry bubble column (C-2391)
US5168091A (en) 1990-10-15 1992-12-01 Exxon Research And Engineering Company Activation conditions to maximize the HSC activity of supported cobalt catalysts
US5283216A (en) 1992-09-24 1994-02-01 Exxon Research And Engineering Company Rejuvenation of hydrocarbon synthesis catalyst
US5292705A (en) 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
US5260239A (en) 1992-12-18 1993-11-09 Exxon Research & Engineering Company External catalyst rejuvenation system for the hydrocarbon synthesis process
US5382748A (en) 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5268344A (en) 1992-12-18 1993-12-07 Exxon Research & Engineering Company Draft tube for catalyst rejuvenation and distribution
DE4345265A1 (en) * 1993-10-16 1995-09-21 Degussa Prodn. of shaped Raney metal catalysts for use in a fixed bed

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3939097A (en) * 1972-12-07 1976-02-17 Hitachi Shipbuilding And Engineering Co., Ltd. Exhaust gas cleaning catalysts and method of producing same
DE2530818A1 (en) * 1975-07-10 1977-01-27 Basf Ag Passivation of pyrophoric metal catalyst - in which the wet material is treated with an oxygen contg. gas at a defined temp. and lower pressure
US4176092A (en) * 1977-03-25 1979-11-27 Bayer Aktiengesellschaft Process for the depyrophorization of pyrophoric metal catalysts and catalysts prepared by the process
GB2117400A (en) * 1982-03-18 1983-10-12 Alloy Surfaces Co Inc Catalytic metal
WO2000027525A1 (en) * 1998-11-05 2000-05-18 E.I. Du Pont De Nemours And Company Raney iron catalyst and a process for hydrogenating organic compounds using said catalyst

Also Published As

Publication number Publication date
US20020115733A1 (en) 2002-08-22
CA2419797C (en) 2009-12-15
ATE355901T1 (en) 2007-03-15
DK1313558T3 (en) 2007-05-29
AU2001281235B2 (en) 2006-04-06
WO2002020438A2 (en) 2002-03-14
EP1313558A2 (en) 2003-05-28
CA2419797A1 (en) 2002-03-14
DE60127141T2 (en) 2007-11-15
EP1313558B1 (en) 2007-03-07
DE60127141D1 (en) 2007-04-19
ES2282280T3 (en) 2007-10-16
US6531518B1 (en) 2003-03-11
AU8123501A (en) 2002-03-22

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