WO2002007883A3 - Production of hydrocarbons from a synthesis gas - Google Patents

Production of hydrocarbons from a synthesis gas Download PDF

Info

Publication number
WO2002007883A3
WO2002007883A3 PCT/IB2001/001310 IB0101310W WO0207883A3 WO 2002007883 A3 WO2002007883 A3 WO 2002007883A3 IB 0101310 W IB0101310 W IB 0101310W WO 0207883 A3 WO0207883 A3 WO 0207883A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst support
modifying component
hydrocarbons
production
synthesis gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2001/001310
Other languages
French (fr)
Other versions
WO2002007883A2 (en
Inventor
Berge Peter Jacobus Van
De Loosdrecht Jan Van
Sean Barradas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
Original Assignee
Sasol Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22824889&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2002007883(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to EP01954235A priority Critical patent/EP1303350B2/en
Priority to KR10-2003-7001020A priority patent/KR20030040374A/en
Priority to AU2001276578A priority patent/AU2001276578B2/en
Priority to DE60123621T priority patent/DE60123621T3/en
Application filed by Sasol Technology Pty Ltd filed Critical Sasol Technology Pty Ltd
Priority to AU7657801A priority patent/AU7657801A/en
Priority to BRPI0112706A priority patent/BRPI0112706B1/en
Priority to JP2002513610A priority patent/JP4949594B2/en
Publication of WO2002007883A2 publication Critical patent/WO2002007883A2/en
Publication of WO2002007883A3 publication Critical patent/WO2002007883A3/en
Priority to US10/349,330 priority patent/US6875720B2/en
Priority to NO20030346A priority patent/NO327405B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/648—Fischer-Tropsch-type reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A method of treating an untreated catalyst support includes contacting an untreated catalyst support which is partially soluble in an aqueous acid and/or a neutral aqueous solution with a modifying component precursor of the formula Me(OR)x where Me is a modifying component selected from Si, Zr, Ti, Cu, Zn, Mn, Ba, Co, Ni, Na, K, Ca, Sn, Cr, Fe, Li, Tl, Mg, Sr, Ga, Sb, V, Hf, Th, Ce, Ge, U, Nb, Ta, and W, R is an alkyl or acyl group, and x is an integer having a value of from 1 to 5. The modifying component is thereby introduced onto and/or into the catalyst support to form a protected modified catalyst support which is less soluble in the aqueous acid and/or the neutral aqueous solution. No calcination of the protected modified catalyst support is effected.
PCT/IB2001/001310 2000-07-24 2001-07-23 Production of hydrocarbons from a synthesis gas Ceased WO2002007883A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
BRPI0112706A BRPI0112706B1 (en) 2000-07-24 2001-07-23 methods for forming a fischer-tropsch catalyst precursor, and method for forming a fischer-tropsch catalyst
JP2002513610A JP4949594B2 (en) 2000-07-24 2001-07-23 Production of hydrocarbons from synthesis source gases
KR10-2003-7001020A KR20030040374A (en) 2000-07-24 2001-07-23 Production of hydrocarbons from a synthesis gas
AU2001276578A AU2001276578B2 (en) 2000-07-24 2001-07-23 Catalyst Supports, Catalyst Precursors and Catalysts
DE60123621T DE60123621T3 (en) 2000-07-24 2001-07-23 METHOD FOR PRODUCING HYDROCARBONS FROM A SYNTHESEGAS
EP01954235A EP1303350B2 (en) 2000-07-24 2001-07-23 Production of hydrocarbons from a synthesis gas
AU7657801A AU7657801A (en) 2000-07-24 2001-07-23 Production of hydrocarbons from a synthesis gas
US10/349,330 US6875720B2 (en) 2000-07-24 2003-01-22 Method of treating an untreated catalyst support, and forming a catalyst precursor and catalyst from the treated support
NO20030346A NO327405B1 (en) 2000-07-24 2003-01-23 Process for forming a catalyst precursor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US22076900P 2000-07-24 2000-07-24
US60/220,769 2000-07-24

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/349,330 Continuation US6875720B2 (en) 2000-07-24 2003-01-22 Method of treating an untreated catalyst support, and forming a catalyst precursor and catalyst from the treated support

Publications (2)

Publication Number Publication Date
WO2002007883A2 WO2002007883A2 (en) 2002-01-31
WO2002007883A3 true WO2002007883A3 (en) 2002-10-31

Family

ID=22824889

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2001/001310 Ceased WO2002007883A2 (en) 2000-07-24 2001-07-23 Production of hydrocarbons from a synthesis gas

Country Status (17)

Country Link
US (1) US6875720B2 (en)
EP (1) EP1303350B2 (en)
JP (1) JP4949594B2 (en)
KR (1) KR20030040374A (en)
CN (1) CN1444507A (en)
AT (1) ATE341396T1 (en)
AU (2) AU2001276578B2 (en)
BR (1) BRPI0112706B1 (en)
DE (1) DE60123621T3 (en)
EG (1) EG22794A (en)
ES (1) ES2271051T5 (en)
MY (1) MY136085A (en)
NO (1) NO327405B1 (en)
PE (1) PE20020250A1 (en)
RU (1) RU2299763C2 (en)
WO (1) WO2002007883A2 (en)
ZA (1) ZA200300567B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7176160B2 (en) 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE339484T1 (en) 2001-07-27 2006-10-15 Sasol Tech Pty Ltd METHOD FOR PRODUCING FISCHER TROPICAL WAXES
ATE298630T1 (en) * 2001-10-25 2005-07-15 Sasol Tech Pty Ltd METHOD FOR ACTIVATING COBALT CATALYSTS
US7341976B2 (en) 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
CA2500646C (en) 2002-10-16 2010-12-14 Conocophillips Company Fischer-tropsch processes and catalysts using stabilized supports
AU2003301247A1 (en) 2002-10-16 2004-05-04 Conocophillips Company Fischer-tropsch processes and catalysts made from a material comprising boehmite
WO2004035194A2 (en) * 2002-10-16 2004-04-29 Conocophillips Company High hydrothermal stability catalyst support
US7402612B2 (en) 2002-10-16 2008-07-22 Conocophillips Company Stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
WO2004043583A2 (en) 2002-11-11 2004-05-27 Conocophillips Company Improved supports for high surface area catalysts
US8022108B2 (en) 2003-07-02 2011-09-20 Chevron U.S.A. Inc. Acid treatment of a fischer-tropsch derived hydrocarbon stream
US7150823B2 (en) 2003-07-02 2006-12-19 Chevron U.S.A. Inc. Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream
US7163963B2 (en) 2003-09-08 2007-01-16 Conocophillips Company Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts
US7186757B2 (en) 2003-10-16 2007-03-06 Conocophillips Company Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same
WO2005046855A2 (en) 2003-10-16 2005-05-26 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
US7348293B2 (en) 2003-12-05 2008-03-25 Chevron U.S.A. Inc. Homogeneous modified-alumina Fischer-Tropsch catalyst supports
US7332073B2 (en) 2004-03-31 2008-02-19 Chevron U.S.A. Inc. Process for removing contaminants from Fischer-Tropsch feed streams
DE102005019103B4 (en) 2004-04-26 2023-09-21 Sasol Technology (Proprietary) Ltd. Process for producing a cobalt-based catalyst for Fischer-Tropsch synthesis and process for producing a Fischer-Tropsch hydrocarbon product
GB2430442B (en) * 2004-07-06 2009-04-15 Sasol Technology Method of treatment of Fischer-Tropsch hydrocarbons
RU2383581C2 (en) * 2004-07-06 2010-03-10 Сэйзол Текнолоджи (Пти) Лтд Method of processing hydrocarbons obtained using fischer-tropsch method
WO2006053350A1 (en) * 2004-11-10 2006-05-18 Sasol Technology (Pty) Ltd Treatment of high molar mass hydrocarbon streams
EP2081680B1 (en) * 2006-10-06 2016-01-06 W.R. Grace & Co.-Conn. Process for preparing a sulfur tolerant alumina catalyst support
CA2665997C (en) * 2006-10-06 2016-11-08 W.R. Grace & Co.-Conn. Sulfur tolerant alumina catalyst support
WO2008066103A1 (en) * 2006-11-29 2008-06-05 Tokyo Electron Limited Substrate processing apparatus
WO2008139407A2 (en) 2007-05-11 2008-11-20 Sasol Technology (Proprietary) Limited Catalysts
US20090098032A1 (en) * 2007-10-11 2009-04-16 Basf Catalysts Llc Methods of making aluminosilicate coated alumina
WO2009084716A1 (en) 2007-12-28 2009-07-09 Canon Kabushiki Kaisha Surface-modified inorganic pigment, colored surface-modified inorganic pigment, recording medium and production processes thereof, and image forming method and recorded image
KR20120084732A (en) 2009-10-08 2012-07-30 더블유.알. 그레이스 앤드 캄파니-콘. Sulfur tolerant alumina catalyst support
US20120122670A1 (en) * 2010-11-16 2012-05-17 Rhodia Operations Sulfur tolerant alumina catalyst support
EP2673081B1 (en) 2011-02-09 2014-12-24 Sasol Technology (Proprietary) Limited Method of preparing a catalyst precursor, method of preparing a catalyst and a hydrocarbon synthesis process
FR2978682B1 (en) 2011-06-01 2016-01-01 Sicat Llc CATALYTIC PROCESS FOR THE CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS
PE20141329A1 (en) 2011-12-14 2014-10-16 Sasol Tech Pty Ltd CATALYST
WO2014001697A1 (en) 2012-06-26 2014-01-03 Sicat Llc Catalyst supports made from silicon carbide covered with tio2 for fischer-tropsch synthesis
EP2879787B3 (en) * 2012-08-02 2017-04-26 Sasol Technology (Proprietary) Limited Method of preparing a catalyst precursor, method of preparing a catalyst, and hydrocarbon synthesis process employing the catalyst support
US9289750B2 (en) 2013-03-09 2016-03-22 Brigham Young University Method of making highly porous, stable aluminum oxides doped with silicon
WO2015104056A1 (en) 2014-01-09 2015-07-16 Statoil Petroleum As Catalyst support and catalyst for fischer-tropsch synthesis
US9233360B1 (en) 2014-09-10 2016-01-12 Chevron U.S.A. Inc. Stable support for Fischer-Tropsch catalyst
US9192921B1 (en) 2014-09-10 2015-11-24 Chevron U.S.A. Inc. Support for Fischer-Tropsch catalyst having improved activity
WO2016039896A1 (en) 2014-09-10 2016-03-17 Chevron U.S.A. Inc. Stable support for fischer-tropsch catalyst
US9168512B1 (en) 2014-09-10 2015-10-27 Chevron U.S.A. Inc. Stable support for Fischer-Tropsch catalyst
US9233358B1 (en) 2014-09-10 2016-01-12 Chevron U.S.A. Inc. Stable support for Fischer-Tropsch catalyst
US9687826B2 (en) 2014-09-10 2017-06-27 Chevron U.S.A. Inc. Support for fischer-tropsch catalyst having improved activity
CN104607223A (en) * 2015-02-04 2015-05-13 厦门大学 Ruthenium-containing cobalt-based Fischer-Tropsch synthesis catalyst and preparation method thereof
CN106140226B (en) * 2015-03-27 2018-06-19 中国石油化工股份有限公司 A kind of catalyst of alkene processed and preparation method and application
US9725381B2 (en) * 2015-07-07 2017-08-08 King Fahd University Of Petroleum And Minerals Fluidizable catalysts for oxidative dehydrogenation of hydrocarbons
EP3344725B1 (en) * 2015-09-04 2024-12-18 Clariant International Ltd Catalyst support materials and catalyst materials useful for fischer-tropsch processes
CN106588526B (en) * 2015-10-20 2019-07-23 中国石油化工股份有限公司 A system for producing olefins using coal and refinery dry gas as raw materials and a method for producing olefins
CN109304174B (en) * 2017-07-26 2021-08-10 国家能源投资集团有限责任公司 Method for preparing cobalt-based catalyst for Fischer-Tropsch synthesis
CN109289865A (en) * 2018-09-30 2019-02-01 中国科学院山西煤炭化学研究所 A silicon-containing catalyst for producing low-carbon mixed alcohol from synthesis gas and its production method and application
CN112391191B (en) * 2020-10-30 2022-09-02 山西潞安煤基清洁能源有限责任公司 Method for preventing catalyst from coagulating and scaling in Fischer-Tropsch synthesis process, catalyst and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3274120A (en) * 1964-02-20 1966-09-20 Cabot Corp Catalyst composition having increased hydroxyl groups bound thereto and method for producing same
US4547283A (en) * 1983-10-14 1985-10-15 Shell Oil Company Process for the hydroisomerization of petroleum waxes
US4748145A (en) * 1983-12-30 1988-05-31 The Dow Chemical Company Catalysts having alkoxide-modified supports and method of increasing the catalytic activity of a catalytic metal
WO1997033690A1 (en) * 1996-03-14 1997-09-18 Celanese International Corporation Colloidal palladium-gold alloy catalyst for vinyl acetate production
WO1999042214A1 (en) * 1998-02-20 1999-08-26 Sasol Technology (Proprietary) Limited Process for producing hydrocarbons from a synthesis gas, and catalysts therefor

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2722504A (en) † 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
US4032550A (en) † 1975-11-26 1977-06-28 Emery Industries, Inc. Process for the production of esters
US4086261A (en) † 1975-12-08 1978-04-25 Mobil Oil Corporation Methanation over synthetic amorphous silicas
DE3365337D1 (en) * 1982-11-22 1986-09-18 Shell Int Research Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
ATE54065T1 (en) † 1984-11-02 1990-07-15 Shell Int Research CATALYST MANUFACTURE.
US4681867A (en) * 1985-06-05 1987-07-21 Air Products And Chemicals, Inc. Supported fischer-tropsch catalyst and method of making the catalyst
EP0206172B1 (en) † 1985-06-17 1991-07-24 Idemitsu Petrochemical Co. Ltd. Method for producing polyolefins
CA1270002A (en) † 1986-01-27 1990-06-05 Max P. Mcdaniel Ethylene dimerization and polymerization
US5169821A (en) † 1991-11-14 1992-12-08 Exxon Research And Engineering Company Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process
FR2688149B1 (en) † 1992-03-06 1994-04-29 Total Raffinage Distribution NEW AQUEOUS SOLUTION FOR IMPREGNATION OF CATALYST SUPPORTS, CATALYSTS PREPARED FROM THIS SOLUTION AND APPLICATIONS OF THESE CATALYSTS.
BE1007148A3 (en) * 1993-05-17 1995-04-11 Solvay Support for catalyst, method for producing gel precursor media for catalyst, method for preparing a catalyst support, catalyst for olefin polymerization and method for olefin polymerization using the catalyst .
DE19506843A1 (en) † 1995-02-28 1996-08-29 Studiengesellschaft Kohle Mbh Microporous amorphous mixed metal oxides for shape-selective catalysis
DZ2013A1 (en) 1995-04-07 2002-10-23 Sastech Ltd Catalysts.
DE19545042A1 (en) † 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphous microporous mixed oxide catalysts with controlled surface polarity for selective heterogeneous catalysis adsorption and material separation
FR2746672B1 (en) * 1996-04-02 1998-04-24 Atochem Elf Sa CATALYTIC COMPONENT AND ITS USE IN OLEFIN POLYMERIZATION
US6207128B1 (en) * 1997-05-05 2001-03-27 Akzo Nobel N.V. Method of producing a catalyst
NZ504988A (en) * 1997-12-30 2001-08-31 Shell Int Research Cobalt and titania based fisher-tropsch catalyst
DE19828364A1 (en) † 1998-06-25 1999-12-30 Degussa Hydrophobic precipitated silica
DE19831804A1 (en) † 1998-07-15 2000-01-27 Univ Bayreuth Heterogeneous catalyst for olefin polymerization, comprises organometallic compounds of Main Group 3 or 4 metals and compounds of Subgroup 3-8 transition metals on a kaolin support
DE69909112T2 (en) * 1998-10-05 2003-12-24 Sasol Technology (Proprietary) Ltd., Johannesburg DRINKING PROCESS FOR CATALYSTS
EG22489A (en) * 1999-02-05 2003-02-26 Sasol Technology Process for producing liquid and optionally gaseous products from gaseous reactants
US6313062B1 (en) * 1999-10-29 2001-11-06 Exxon Reserach And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst composition, use of the catalysts for conducting such reactions, and the products of such reactions
FR2804689B1 (en) * 2000-02-08 2002-03-15 Inst Francais Du Petrole PROCESS FOR THE SYNTHESIS OF HYDROCARBONS IN THE PRESENCE OF A CATALYST COMPRISING A GROUP VIII METAL SUPPORTED ON SILICA-ALUMIN

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3274120A (en) * 1964-02-20 1966-09-20 Cabot Corp Catalyst composition having increased hydroxyl groups bound thereto and method for producing same
US4547283A (en) * 1983-10-14 1985-10-15 Shell Oil Company Process for the hydroisomerization of petroleum waxes
US4748145A (en) * 1983-12-30 1988-05-31 The Dow Chemical Company Catalysts having alkoxide-modified supports and method of increasing the catalytic activity of a catalytic metal
WO1997033690A1 (en) * 1996-03-14 1997-09-18 Celanese International Corporation Colloidal palladium-gold alloy catalyst for vinyl acetate production
WO1999042214A1 (en) * 1998-02-20 1999-08-26 Sasol Technology (Proprietary) Limited Process for producing hydrocarbons from a synthesis gas, and catalysts therefor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7176160B2 (en) 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support

Also Published As

Publication number Publication date
US6875720B2 (en) 2005-04-05
NO327405B1 (en) 2009-06-22
ATE341396T1 (en) 2006-10-15
EG22794A (en) 2003-08-31
EP1303350B9 (en) 2007-05-30
EP1303350B1 (en) 2006-10-04
JP4949594B2 (en) 2012-06-13
MY136085A (en) 2008-08-29
EP1303350A2 (en) 2003-04-23
US20030162849A1 (en) 2003-08-28
WO2002007883A2 (en) 2002-01-31
NO20030346L (en) 2003-03-24
CN1444507A (en) 2003-09-24
NO20030346D0 (en) 2003-01-23
BR0112706A (en) 2003-07-01
RU2299763C2 (en) 2007-05-27
AU7657801A (en) 2002-02-05
DE60123621D1 (en) 2006-11-16
BRPI0112706B1 (en) 2016-01-19
DE60123621T2 (en) 2007-01-11
ZA200300567B (en) 2004-07-14
JP2004504136A (en) 2004-02-12
PE20020250A1 (en) 2002-04-24
KR20030040374A (en) 2003-05-22
EP1303350B2 (en) 2010-01-27
DE60123621T3 (en) 2010-07-01
AU2001276578B2 (en) 2005-11-03
ES2271051T5 (en) 2010-05-07
ES2271051T3 (en) 2007-04-16

Similar Documents

Publication Publication Date Title
WO2002007883A3 (en) Production of hydrocarbons from a synthesis gas
NO331172B1 (en) Process for preparing a cobalt-based Fischer-Tropsch synthesis catalyst
DZ2724A1 (en) Process for the production of hydrocarbons from a synthesis gas and their catalysts.
PE20030220A1 (en) PRODUCTION OF WAX OBTAINED BY FISCHER-TROPSCH SYNTHESIS
RU2003104989A (en) PRODUCTION OF HYDROCARBONS FROM SYNTHESIS GAS
EP1323775A4 (en) Diene rubber/inorganic compound composite and method for producing the same and rubber composition
Spencer Precursors of copper/zinc oxide catalysts
JP2005522536A5 (en)
BG103280A (en) Molybdenum-promoted vanadium-antimony oxide catalyst for acrylonitrile or methacrylonitrile production
DE3686719D1 (en) MULTIPLE METAL TONER PRODUCTS WITH BRIDGED LAYER STRUCTURES AND METHOD FOR THE PRODUCTION THEREOF.
EP1871522B8 (en) Process for preparing improved catalysts for selective oxidation of propane into acrylic acid
WO2000036176A3 (en) Polymetalate and heteropolymetalate conversion coatings for metal substrates
WO2008060647A3 (en) A process for preparing nano size zeolites
JPS5466619A (en) Preparation of methacrylic acid and its catalyst
HK1042079A1 (en) Process for the preparation of carboxylic acid salts from primary alcohols
DE69730256D1 (en) Synthetic chalcoalumite compounds and process for their preparation
CA2469783A1 (en) A method for preparing a sensitised emulsion explosive
JPH0122204B2 (en)
ATE119430T1 (en) METHOD FOR PRODUCING A PRECIPITATION CATALYST PRECURSOR FOR AMMONIA SYNTHESIS.
EP1378502A4 (en) Chain oligolactic acid ester
WO2004102595A3 (en) Ferrite material for a permanent magnet and method for production therof
WO2002018403A1 (en) Process for producing erythromycin derivative
JPS551880A (en) Catalyst
EP1174407A3 (en) A process for the preparation of 6,6-dimethylhept-1-en-4-yn-3-ol
JPS6483515A (en) Production of flat fibrous material of metal titanate

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 2003/00567

Country of ref document: ZA

Ref document number: 200300567

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: 10349330

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2001954235

Country of ref document: EP

Ref document number: 1020037001020

Country of ref document: KR

Ref document number: 2001276578

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 018133142

Country of ref document: CN

ENP Entry into the national phase

Ref document number: 2003104989

Country of ref document: RU

Kind code of ref document: A

Ref country code: RU

Ref document number: RU A

WWP Wipo information: published in national office

Ref document number: 2001954235

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1020037001020

Country of ref document: KR

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

ENP Entry into the national phase

Ref document number: 2003131403

Country of ref document: RU

Kind code of ref document: A

WWG Wipo information: grant in national office

Ref document number: 2001276578

Country of ref document: AU

WWG Wipo information: grant in national office

Ref document number: 2001954235

Country of ref document: EP