WO2001064628A1 - Process for the preparation of organic polyisocyanates - Google Patents
Process for the preparation of organic polyisocyanates Download PDFInfo
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- WO2001064628A1 WO2001064628A1 PCT/EP2001/001519 EP0101519W WO0164628A1 WO 2001064628 A1 WO2001064628 A1 WO 2001064628A1 EP 0101519 W EP0101519 W EP 0101519W WO 0164628 A1 WO0164628 A1 WO 0164628A1
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- decomposition
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- polyisocyanates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/04—Preparation of derivatives of isocyanic acid from or via carbamates or carbamoyl halides
Definitions
- the present invention relates to a process for the preparation of organic polyisocyanates by thermal decomposition of the corresponding organic polycarbamates
- a method is desc ⁇ bed for manufactu ⁇ ng MDI from a N- phenylcarbamate which comp ⁇ ses methylenating a N-phenylcarbamate to produce a dmuclear diphenylmethane dicarbamate and subjecting the latter to a thermal decomposition process which involves dissolving the dinuclear diphenylmethane dicarbamate a solvent having a boiling point between 120 and 350°C, allowing the solution to flow down in a reactor and come into counterflow contact with a earner introduced into the reactor upwardly thereby producing an organic hydroxyl compound and recovering said hydroxyl compound as vapor and the earner at the upper end and the isocyanate solution at the lower end of the reactor
- EP-A 611.243 discloses the preparation of organic isocyanates by thermal decomposition of corresponding carbamates dissolved in a solvent to isocyanate and an alcohol in multiple and separate steps. In intermediate steps the solvent is treated with an inert stopping agent to remove the alcohol formed dunng the thermal treatment and finally an isocyanate-nch solution is recovered.
- JP-A 02.212.465 polyisocyanates are produced by a two-step thermal decomposition in the liquid phase of a polycarbamate in which first the thermal decomposition is earned out in a boiling organic solvent with removal of by-produced alcohol from the system and then a thin film is formed from the reacted solution and the thermal decomposition reaction is further performed.
- US-A 5.731.458 relates to a process for thermally cracking carbamic acid esters into the corresponding isocyanates and hydroxyl components in the liquid phase, wherein the reaction proceeds as a reactive rectification in the stripping zone of a column and an inert, high-boiling solvent acts as a buffer and keeps the reaction away from the evaporator region of the column.
- US-A 5 284.969 discloses a process for the continuous catalyst-free production of polyisocyanates by thermal decomposition of the N-substituted carbamic acid esters corresponding to the polyisocyanates, in which the carbamic acid esters to be decomposed, in the form of a 5 to 90% by weight solution in an inert high-boiling solvent, are heated to a temperature of 100-400 °C and are subsequently introduced with expansion as a sidestream into a distillation column, in the sump of which a pressure of 0.001-5 bar and a temperature of 150-400 °C are maintained so that the high boiler is kept boiling in the sump, and the decomposition products are simultaneously condensed continuously and selectively at the head of the distillation column.
- the high boiler which optionally contains abnormalties, is continuously removed via the sump outlet in a quantity substantially corresponding to the quantity of high boiler introduced into the column as solvent for the carbamic acid ester.
- US-A 5.043.471 concerns a process for the preparation of a polyisocyanate compnsing (a) thermally decomposing in a tube reactor a solution of an N-substituted carbamic acid ester corresponding to said polyisocyanate in a solvent used as decomposition medium, wherein said solvent (I) is capable of dissolving the carbamic acid ester, (n) is stable at the decomposition temperature and chemically inert towards the carbamic acid esters and the polyisocyanate product, (in) can be distilled without decomposing under the conditions of decomposition of carbamic acid estes, and (iv) has at least one miscibility gap with an extracting agent used according to the extraction step (c), said solutions being earned along the internal wall of reactor; (b) separating the gaseous matenals formed in the tube reactor by fractional condensation into a fraction I compnsed mainly of the alcohol by-product and a fraction II compnsed mainly of polyisocyanates, isocyanatoure
- polymethylene polyphenyl polycarbamate is subjected to a thermal decomposition reaction in a liquid phase at two stages.
- Polymethylene polyphenyl polycarbamate is heated in the absence of a catalyst in an organic solvent such as chloronaphthalene under normal pressure at 150-350 deg C and decomposed into polymethylene polyphenyl polyisocyanate and an alcohol.
- the prepared reaction product is distilled and separated into a low-boilmg component compnsmg methylene diphenyl dnsocyanate of substantially binuclear compound and a high-boilmg component containing a polynuclear polyisocyanate of tn- or more nuclear compound, an unreacted polycarbamate raw matenal and a carbamate isocyanate compound of intermediate
- the high- boiling component discharged from the bottom of the column is further thermally decomposed in a separate reactor.
- US-A 5 453.536 descnbes the pyrolysis of polycarbamates in the substantial absence of a solvent under reduced pressure and at a temperature of about 150 to about 270°C to form the corresponding polyisocyanate and a secondary alcohol.
- the invention thus concerns a process for the preparation of organic polyisocyanates by decomposing the corresponding organic polycarbamates into organic polyisocyanates and alcohols, charactensed in that the alcohol and at least part of either the diisocyanates or monoisocyanatomonocarbamates, or both, formed upon decomposition of the said polycarbamates is being removed dunng the decomposition.
- Organic polyisocyanates can be obtained at low temperatures in high yields, even in the absence of a solvent or from concentrated solutions
- the polycarbamate composition which is subjected to decomposition may be a mixture of carbamate compounds of different functionalities including di- and optionally monocarbamates which, upon decomposition, result in a mixture of polyisocyanates
- the functionality is the number average of the functionalities of all species present in the polycarbamate mixture
- the average functionality should be more than 2 and less than 15, preferably is more than 2 and less than 10, and more preferably between 2 and 3
- Any organic polyisocyanate can be made according to the process of the present invention However, it is particularly suitable for making aromatic polyisocyanates
- aromatic polyisocyanates examples include 2,4,6-toluene tnisocyanate and polymethylene polyphenylene polyisocyanates
- the diisocyanates formed dunng the decomposition of the polycarbamate consist of methylene diphenylene diisocyanates (mainly 2,4'- and 4,4'- ⁇ somers)
- alcohols which readily split off under the reaction conditions are preferred Such alcohols include, for example, 2,2,2-tnfluoroethanol, 2,2,2-tnchloroethanol, tnchloromethanol, 1,1,1,3,3,3-hexafTuoro ⁇ sopropanol, nonafluoro tert butanol, phenol, fluorophenols such as 4-fluorophenol, chlorophenols and polysubstituted halogenated phenols, 2-ethoxy ethanol, 2-methoxy ethanol, 2- ⁇ sopropoxy ethanol, l-methoxy-2- propanol Phenol and fluorophenols are particularly suitable alcohols for use in the present invention.
- Removal of the alcohol and at least part of the diisocyanates and/or monoisocyanatomonocarbamates can be done in any suitable manner, such as by distillation or refluxing. Distillation however is preferred
- the reaction may be earned out in an inert solvent, 1 e. any solvent not interacting with isocyanates or alcohols under the applied reaction conditions.
- isocyanates formed in the decomposition reaction can serve as a solvent for the reaction as well.
- Suitable inert solvents which may be employed include, for example, aromatic hydrocarbons such as benzene, halogenated aromatic hydrocarbons such as monochlorobenzene, ortho-dichlorobenzene, tnchlorobenzene or 1-chloronaphthalene, alkylated aromatic hydrocarbons like toluene, xylene, ethylbenzene, cumene or tetrahydronaphthalene, other functiona sed aromatic hydrocarbons such as anisole, diphenylether, ethoxybenzene, benzonitnle, 2-fluoroan ⁇ sole, 2,3-d ⁇ methylan ⁇ sole or tnfluorotoluene or mixtures thereof.
- aromatic hydrocarbons such as benzene, halogenated aromatic hydrocarbons such as monochlorobenzene, ortho-dichlorobenzene, tnchlorobenzene or 1-chloronaphthalene, alkylated aromatic hydrocarbons like
- Preferred solvents compnse monochlorobenzene or ortho-dichlorobenzene.
- the earner gas serves to physically remove any alcohol without forming a chemical bond with it.
- Mixtures of at least one of the above solvents with a lower boiling inert solvent used as earner gas may also be used.
- alkanes such as n-pentane, n- hexane, n-heptane or higher or branched alkanes, cyclic alkanes like cyclopentane, cyclohexane or denvatives thereof, halogenated alkanes like chloroform, dichloromethane, carbontetrachloride, and alkanes with other functional groups like diethylether, acetonitrile, dioxane and the like.
- the process may be carried out at atmospheric pressure, preferably under nitrogen.
- the reaction preferably takes place under reduced pressure.
- the pressure is preferably reduced to between 10 " and 50 mbar, and more preferably to between 0.1 and 10 mbar.
- reaction time is dependent on the temperature and on the type and quantity of the carbamate compound, but will normally not exceed 5 hours. Reaction times of less than 3 hours are common, and reaction times of less than 20 minutes have been achieved without any problem.
- the reaction temperature largely depends on whether a solvent is present or not. Generally, it will be between 50 and 350°C. In a solvent-free process the temperatures will normally be between the melting point of the carbamate and 350°C, whereas in the presence of a solvent the temperature will be between 100 and 250°C. Preferably, the process of the invention is carried out at temperatures between 120 and 240°C.
- the process may be conducted in any suitable apparatus which can be equipped, if required, with agitation means and heating and/or cooling means to keep the temperature within the desired range.
- a distillation column is generally attached to said apparatus.
- the process of the present invention may be conducted batchwise or as a semi-continuous or continuous process.
- the order of addition of the reactants may be vaned to suit the particular apparatus and/or reactants employed
- the polyisocyanates and alcohols obtained by this process are generally of high and no additional treatment is required to further punfy said products Only the solvent, if present, needs to be removed
- reaction products formed be subjected to known punfication methods, such as filtration, extraction, recrystallisation or distillation
- polyphenylene polymethylene poly(4-fluorophenylcarbamate) was put into a suitable flask equipped with a reflux cooler and a condenser.
- the carbamate was molten at 220°C whereafter the pressure was reduced to 2 mbar At this given combination of temperature and pressure, 4-fluorophenol was removed from the reaction mixture and methylene diphenylene dnsocyanate was partly distilled After 20 minutes at 220°C, polyphenylene polymethylene polyisocyanate containing 29.5% by weight NCO groups was obtained.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
Process for the preparation of organic polyisocyanates by decomposing the corresponding organic polycarbamates into organic polyisocyanates and alcohols, characterised in that the alcohol and at least part of either the diisocyanates or the monoisocyanatomonocarbamates, or both, formed upon decomposition of the said polycarbamates is being removed during the decomposition.
Description
WO 01/64628 ^ PCT/EPOl/01519
Process for the preparation of organic polyisocyanates
The present invention relates to a process for the preparation of organic polyisocyanates by thermal decomposition of the corresponding organic polycarbamates
In US-A 4 547.322 a method is descπbed for manufactuπng MDI from a N- phenylcarbamate which compπses methylenating a N-phenylcarbamate to produce a dmuclear diphenylmethane dicarbamate and subjecting the latter to a thermal decomposition process which involves dissolving the dinuclear diphenylmethane dicarbamate a solvent having a boiling point between 120 and 350°C, allowing the solution to flow down in a reactor and come into counterflow contact with a earner introduced into the reactor upwardly thereby producing an organic hydroxyl compound and recovering said hydroxyl compound as vapor and the earner at the upper end and the isocyanate solution at the lower end of the reactor
EP-A 611.243 discloses the preparation of organic isocyanates by thermal decomposition of corresponding carbamates dissolved in a solvent to isocyanate and an alcohol in multiple and separate steps. In intermediate steps the solvent is treated with an inert stopping agent to remove the alcohol formed dunng the thermal treatment and finally an isocyanate-nch solution is recovered.
In JP-A 02.212.465 polyisocyanates are produced by a two-step thermal decomposition in the liquid phase of a polycarbamate in which first the thermal decomposition is earned out in a boiling organic solvent with removal of by-produced alcohol from the system and then a thin film is formed from the reacted solution and the thermal decomposition reaction is further performed.
US-A 5.731.458 relates to a process for thermally cracking carbamic acid esters into the corresponding isocyanates and hydroxyl components in the liquid phase, wherein the reaction proceeds as a reactive rectification in the stripping zone of a column and an inert, high-boiling solvent acts as a buffer and keeps the reaction away from the evaporator region of the column.
WO 01/64628 ^ PCT/EPOl/01519
US-A 5 284.969 discloses a process for the continuous catalyst-free production of polyisocyanates by thermal decomposition of the N-substituted carbamic acid esters corresponding to the polyisocyanates, in which the carbamic acid esters to be decomposed, in the form of a 5 to 90% by weight solution in an inert high-boiling solvent, are heated to a temperature of 100-400 °C and are subsequently introduced with expansion as a sidestream into a distillation column, in the sump of which a pressure of 0.001-5 bar and a temperature of 150-400 °C are maintained so that the high boiler is kept boiling in the sump, and the decomposition products are simultaneously condensed continuously and selectively at the head of the distillation column. The high boiler, which optionally contains impunties, is continuously removed via the sump outlet in a quantity substantially corresponding to the quantity of high boiler introduced into the column as solvent for the carbamic acid ester.
US-A 5.043.471 concerns a process for the preparation of a polyisocyanate compnsing (a) thermally decomposing in a tube reactor a solution of an N-substituted carbamic acid ester corresponding to said polyisocyanate in a solvent used as decomposition medium, wherein said solvent (I) is capable of dissolving the carbamic acid ester, (n) is stable at the decomposition temperature and chemically inert towards the carbamic acid esters and the polyisocyanate product, (in) can be distilled without decomposing under the conditions of decomposition of carbamic acid estes, and (iv) has at least one miscibility gap with an extracting agent used according to the extraction step (c), said solutions being earned along the internal wall of reactor; (b) separating the gaseous matenals formed in the tube reactor by fractional condensation into a fraction I compnsed mainly of the alcohol by-product and a fraction II compnsed mainly of polyisocyanates, isocyanatourethanes, unreacted carbamic acid ester, and the solvent used in step (a); (c) extracting the polyisocyanate from said fraction II with an extracting agent that is at least partly immiscible with the decomposition medium and is a solvent for the polyisocyanate, and optionally distilling the resultant solution of the polyisocyanate in the extracting agent; and (d) recycling the portion of fraction II remaining after the polyisocyanate is extracted.
In JP-A 01.121.259 polymethylene polyphenyl polycarbamate is subjected to a thermal decomposition reaction in a liquid phase at two stages. Polymethylene polyphenyl polycarbamate is heated in the absence of a catalyst in an organic solvent such as
chloronaphthalene under normal pressure at 150-350 deg C and decomposed into polymethylene polyphenyl polyisocyanate and an alcohol. The prepared reaction product is distilled and separated into a low-boilmg component compnsmg methylene diphenyl dnsocyanate of substantially binuclear compound and a high-boilmg component containing a polynuclear polyisocyanate of tn- or more nuclear compound, an unreacted polycarbamate raw matenal and a carbamate isocyanate compound of intermediate The high- boiling component discharged from the bottom of the column is further thermally decomposed in a separate reactor.
US-A 5 453.536 descnbes the pyrolysis of polycarbamates in the substantial absence of a solvent under reduced pressure and at a temperature of about 150 to about 270°C to form the corresponding polyisocyanate and a secondary alcohol.
A method for the preparation of aromatic monomenc or polymenc isocyanates by decomposing aromatic monomenc or polymenc carbamates into aromatic monomenc or polymenc isocyanates and alcohols containing at least one halogen group is disclosed in WO-A 9854128
None of the cited documents however discloses or suggests a single-step process for making organic polyisocyanates by decomposing the corresponding polycarbamates wherein at least part of the volatile diisocyanates and optionally monoisocyanatomonocarbamates formed dunng the decomposition of the polycarbamates is being removed from the reaction mixture.
An improved process has now been found for the preparation of organic polyisocyanates by thermolysis of the corresponding organic polycarbamates.
The invention thus concerns a process for the preparation of organic polyisocyanates by decomposing the corresponding organic polycarbamates into organic polyisocyanates and alcohols, charactensed in that the alcohol and at least part of either the diisocyanates or monoisocyanatomonocarbamates, or both, formed upon decomposition of the said polycarbamates is being removed dunng the decomposition.
Organic polyisocyanates can be obtained at low temperatures in high yields, even in the absence of a solvent or from concentrated solutions
The prefix "poly-" as used herein refers to any functionality higher than 2
The polycarbamate composition which is subjected to decomposition may be a mixture of carbamate compounds of different functionalities including di- and optionally monocarbamates which, upon decomposition, result in a mixture of polyisocyanates In such instances the functionality is the number average of the functionalities of all species present in the polycarbamate mixture
The average functionality should be more than 2 and less than 15, preferably is more than 2 and less than 10, and more preferably between 2 and 3
Any organic polyisocyanate can be made according to the process of the present invention However, it is particularly suitable for making aromatic polyisocyanates
Examples of such aromatic polyisocyanates include 2,4,6-toluene tnisocyanate and polymethylene polyphenylene polyisocyanates
The process of the present invention can most advantageously be used for the preparation of polymethylene polyphenylene polyisocyanates
In that case, the diisocyanates formed dunng the decomposition of the polycarbamate consist of methylene diphenylene diisocyanates (mainly 2,4'- and 4,4'-ιsomers)
The type of alcohol formed upon decomposition of the polycarbamate is not cntical However, alcohols which readily split off under the reaction conditions are preferred Such alcohols include, for example, 2,2,2-tnfluoroethanol, 2,2,2-tnchloroethanol, tnchloromethanol, 1,1,1,3,3,3-hexafTuoroιsopropanol, nonafluoro tert butanol, phenol, fluorophenols such as 4-fluorophenol, chlorophenols and polysubstituted halogenated phenols, 2-ethoxy ethanol, 2-methoxy ethanol, 2-ιsopropoxy ethanol, l-methoxy-2- propanol
Phenol and fluorophenols are particularly suitable alcohols for use in the present invention.
Removal of the alcohol and at least part of the diisocyanates and/or monoisocyanatomonocarbamates can be done in any suitable manner, such as by distillation or refluxing. Distillation however is preferred
The reaction may be earned out in an inert solvent, 1 e. any solvent not interacting with isocyanates or alcohols under the applied reaction conditions. However, isocyanates formed in the decomposition reaction can serve as a solvent for the reaction as well.
Suitable inert solvents which may be employed include, for example, aromatic hydrocarbons such as benzene, halogenated aromatic hydrocarbons such as monochlorobenzene, ortho-dichlorobenzene, tnchlorobenzene or 1-chloronaphthalene, alkylated aromatic hydrocarbons like toluene, xylene, ethylbenzene, cumene or tetrahydronaphthalene, other functiona sed aromatic hydrocarbons such as anisole, diphenylether, ethoxybenzene, benzonitnle, 2-fluoroanιsole, 2,3-dιmethylanιsole or tnfluorotoluene or mixtures thereof.
Preferred solvents compnse monochlorobenzene or ortho-dichlorobenzene.
Any of the abovementioned solvents may also be used to generate the earner gas
The earner gas serves to physically remove any alcohol without forming a chemical bond with it.
Mixtures of at least one of the above solvents with a lower boiling inert solvent used as earner gas may also be used.
Exemplary of such additional lower boiling solvents are alkanes such as n-pentane, n- hexane, n-heptane or higher or branched alkanes, cyclic alkanes like cyclopentane, cyclohexane or denvatives thereof, halogenated alkanes like chloroform, dichloromethane,
carbontetrachloride, and alkanes with other functional groups like diethylether, acetonitrile, dioxane and the like.
The process may be carried out at atmospheric pressure, preferably under nitrogen.
However, in the absence of a solvent, the reaction preferably takes place under reduced pressure. In such case, the pressure is preferably reduced to between 10" and 50 mbar, and more preferably to between 0.1 and 10 mbar.
Superatmospheric pressures may sometimes be required, depending on the type of solvents used.
The reaction time is dependent on the temperature and on the type and quantity of the carbamate compound, but will normally not exceed 5 hours. Reaction times of less than 3 hours are common, and reaction times of less than 20 minutes have been achieved without any problem.
The reaction temperature largely depends on whether a solvent is present or not. Generally, it will be between 50 and 350°C. In a solvent-free process the temperatures will normally be between the melting point of the carbamate and 350°C, whereas in the presence of a solvent the temperature will be between 100 and 250°C. Preferably, the process of the invention is carried out at temperatures between 120 and 240°C.
With the process of the present invention yields of polyisocyanates of more than 90% can readily be obtained. Yields of at least 95% are possible.
The process may be conducted in any suitable apparatus which can be equipped, if required, with agitation means and heating and/or cooling means to keep the temperature within the desired range. A distillation column is generally attached to said apparatus.
The process of the present invention may be conducted batchwise or as a semi-continuous or continuous process.
The order of addition of the reactants may be vaned to suit the particular apparatus and/or reactants employed
The presence of any other compounds, such as catalysts or co-reactants, in addition to the carbamate compound and optionally the solvent is generally not required
The polyisocyanates and alcohols obtained by this process are generally of high
and no additional treatment is required to further punfy said products Only the solvent, if present, needs to be removed
If a particularly high grade of punty is required, the reaction products formed
be subjected to known punfication methods, such as filtration, extraction, recrystallisation or distillation
The invention is illustrated by, but not limited to, the following examples
o
Examples
Example T
3 g of polyphenylene polymethylene poly(phenylcarbamate) was put into a suitable flask equipped with a reflux cooler and a condenser The carbamate was molten at 220°C whereafter the pressure was reduced to 2 mbar. At this given combination of temperature and pressure, phenol was removed from the reaction mixture and methylene diphenylene dnsocyanate was partly distilled After 20 minutes at 220°C, polyphenylene polymethylene polyisocyanate containing 31 4% by weight NCO groups was obtained
Comparative Example 1.
3 g of polyphenylene polymethylene poly(phenylcarbamate) was put into a suitable flask equipped with a reflux cooler and a condenser. The carbamate was molten at 220°C whereafter the pressure was reduced to 50 mbar. At this given combination of temperature and pressure, phenol was removed from the reaction mixture The methylene diphenylene dnsocyanate was not distilled. After 20 minutes at 220°C, polyphenylene polymethylene polyisocyanate containing 25.9% by weight NCO groups was obtained. Longer reaction times did not result in improved yields.
Comparative Example 2:
A mixture of 1.8 g polyphenylene polymethylene polyisocyanate and 2.2 g phenol was put into a suitable flask equipped with a reflux cooler and a condenser The mixture was molten at 220°C whereafter the pressure was reduced to 300 mbar. At this given combination of temperature and pressure, phenol was removed from the reaction mixture The methylene diphenylene dnsocyanate was not distilled. After 20 minutes at 220°C, polyphenylene polymethylene polyisocyanate containing 10.2% by weight NCO groups was obtained. LR-analysis proved the presence of carbamate in the isocyanate.
Example 2
2.3 g of polyphenylene polymethylene poly(4-fluorophenylcarbamate) was put into a suitable flask equipped with a reflux cooler and a condenser. The carbamate was molten at 220°C whereafter the pressure was reduced to 2 mbar At this given combination of temperature and pressure, 4-fluorophenol was removed from the reaction mixture and methylene diphenylene dnsocyanate was partly distilled After 20 minutes at 220°C, polyphenylene polymethylene polyisocyanate containing 29.5% by weight NCO groups was obtained.
Claims
1. Process for the preparation of organic polyisocyanates by decomposing the corresponding organic polycarbamates into organic polyisocyanates and alcohols, charactensed m that the alcohol and at least part of either the diisocyanates or the monoisocyanatomonocarbamates, or both, formed upon decomposition of the said polycarbamates is being removed dunng the decomposition.
2. Process according to claim 1 wherein the organic polyisocyanate compnses polymethylene polyphenylene polyisocyanate.
3. Process according to claim 1 or 2 wherein the removal of at least part of either the diisocyanates or the monoisocyanatomonocarbamates, or both, is effected by distillation.
4. Process according to anyone of the preceding claims wherein the alcohol is phenol or a fluorophenol
5. Process according to any one of the preceding claims wherein the decomposition is earned out in the presence of a solvent.
6. Process according to claim 5 wherein the decomposition temperature is between 100 and 250°C.
7. Process according any one of the claims 1 to 6 wherein the solvent is mixed with a lower boiling solvent used to generate a earner gas.
8. Process according to any one of the claims 1 to 4 wherein the decomposition is earned out in the absence of a solvent.
9. Process according to claim 8 wherein the decomposition is earned out at a temperature between the melting point of the polycarbamate and 350°C. Process according to claim 8 or 9 wherein the decomposition is carried out under reduced pressure.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT01915226T ATE305918T1 (en) | 2000-02-29 | 2001-02-12 | METHOD FOR PRODUCING ORGANIC POLYISOCYANATES |
| DE60113814T DE60113814T2 (en) | 2000-02-29 | 2001-02-12 | PROCESS FOR PREPARING ORGANIC POLYISOCYANATES |
| JP2001563472A JP2003525267A (en) | 2000-02-29 | 2001-02-12 | Production method of organic polyisocyanate |
| EP01915226A EP1259480B1 (en) | 2000-02-29 | 2001-02-12 | Process for the preparation of organic polyisocyanates |
| CA002397683A CA2397683A1 (en) | 2000-02-29 | 2001-02-12 | Process for the preparation of organic polyisocyanates |
| US10/202,584 US20030055282A1 (en) | 2000-02-29 | 2002-07-24 | Process for the preparation of organic polyisocyanates |
| HK03106741.6A HK1054374B (en) | 2000-02-29 | 2003-09-19 | Process for the preparation of organic polyisocyanates |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00104174.8 | 2000-02-29 | ||
| EP00104174 | 2000-02-29 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/202,584 Continuation US20030055282A1 (en) | 2000-02-29 | 2002-07-24 | Process for the preparation of organic polyisocyanates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2001064628A1 true WO2001064628A1 (en) | 2001-09-07 |
Family
ID=8167985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2001/001519 WO2001064628A1 (en) | 2000-02-29 | 2001-02-12 | Process for the preparation of organic polyisocyanates |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20030055282A1 (en) |
| EP (1) | EP1259480B1 (en) |
| JP (1) | JP2003525267A (en) |
| KR (1) | KR100670885B1 (en) |
| CN (1) | CN1186317C (en) |
| AT (1) | ATE305918T1 (en) |
| CA (1) | CA2397683A1 (en) |
| DE (1) | DE60113814T2 (en) |
| ES (1) | ES2245685T3 (en) |
| HK (1) | HK1054374B (en) |
| PT (1) | PT1259480E (en) |
| WO (1) | WO2001064628A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2147909A1 (en) * | 2007-03-30 | 2010-01-27 | Asahi Kasei Chemicals Corporation | Method for production of isocyanate using composition comprising carbamic acid ester and aromatic hydroxy compound, and composition for transport or storage of carbamic acid ester |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101002385B1 (en) * | 2006-11-17 | 2010-12-20 | 아사히 가세이 케미칼즈 가부시키가이샤 | Method for producing isocyanate |
| ES2357865T3 (en) * | 2006-11-17 | 2011-05-03 | Asahi Kasei Chemicals Corporation | PROCESS TO PRODUCE ISOCIANATES. |
| JP2008127293A (en) * | 2006-11-17 | 2008-06-05 | Asahi Kasei Chemicals Corp | Carbamic acid ester compound |
| TW200844080A (en) | 2007-01-11 | 2008-11-16 | Asahi Kasei Chemicals Corp | Process for producing isocyanate |
| JP5592786B2 (en) | 2008-05-15 | 2014-09-17 | 旭化成ケミカルズ株式会社 | Isocyanate production method |
| KR101363232B1 (en) | 2008-05-15 | 2014-02-12 | 아사히 가세이 케미칼즈 가부시키가이샤 | Process for producing isocyanate using diaryl carbonate |
| US8835673B2 (en) | 2009-12-04 | 2014-09-16 | Basf Se | Process for preparing isocyanates |
| CN102260193B (en) * | 2010-05-26 | 2013-11-06 | 中国科学院过程工程研究所 | Method and reaction device for preparing isocyanate through thermal decomposition of carbamate by molecular distillation technology |
| CN103848758A (en) * | 2012-12-06 | 2014-06-11 | 中国科学院成都有机化学有限公司 | Method for preparing isocyanate by catalytic thermal decomposition |
| CN107207422B (en) * | 2015-01-30 | 2020-12-11 | 巴斯夫欧洲公司 | Low by-product polyphenylene polymethylene polyisocyanate |
| EP3450424A1 (en) * | 2017-09-04 | 2019-03-06 | Covestro Deutschland AG | Method for making isocyanates |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919278A (en) * | 1974-06-13 | 1975-11-11 | Atlantic Richfield Co | Production of isocyanates from lower alkyl esters of mononuclear aromatic carbamic acids |
| JPS5488222A (en) * | 1977-12-20 | 1979-07-13 | Mitsubishi Chem Ind Ltd | Preparation of isocyanate from carbamate |
| EP0092738A1 (en) * | 1982-04-27 | 1983-11-02 | Bayer Ag | Process for the continuous thermal decomposition of carbamic-acid esters |
| US4547322A (en) | 1983-03-18 | 1985-10-15 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for manufacture of diphenylmethane diisocyanates |
| JPS63150255A (en) * | 1986-12-15 | 1988-06-22 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| JPH01121259A (en) | 1987-11-04 | 1989-05-12 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| JPH02212465A (en) | 1989-02-13 | 1990-08-23 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| US5043471A (en) | 1989-05-10 | 1991-08-27 | Bayer Aktiengesellschaft | Process for the preparation of polyisocyanates |
| US5284969A (en) | 1991-11-14 | 1994-02-08 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates |
| EP0611243A1 (en) | 1993-02-12 | 1994-08-17 | Haldor Topsoe A/S | Process for the preparation of organic isocyanates |
| US5453536A (en) | 1994-03-10 | 1995-09-26 | The Dow Chemical Company | Polycarbamates, process for preparing polycarbamates, and process for preparing polyisocyanates |
| US5731458A (en) | 1996-03-15 | 1998-03-24 | Bayer Aktiengesellschaft | Process for thermally cracking carbamic acid esters |
| WO1998054128A1 (en) | 1997-05-31 | 1998-12-03 | Huntsman Ici Chemicals Llc | Method for the preparation of organic isocyanates |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3054819A (en) * | 1958-08-29 | 1962-09-18 | Union Carbide Corp | Preparation of organic isocyanates |
| US4487713A (en) * | 1981-06-26 | 1984-12-11 | Exxon Research & Engineering Co. | Production of isocyanates from esters of aromatic carbamic acids (urethanes) |
-
2001
- 2001-02-12 KR KR1020027011274A patent/KR100670885B1/en not_active IP Right Cessation
- 2001-02-12 WO PCT/EP2001/001519 patent/WO2001064628A1/en active IP Right Grant
- 2001-02-12 EP EP01915226A patent/EP1259480B1/en not_active Revoked
- 2001-02-12 CA CA002397683A patent/CA2397683A1/en not_active Abandoned
- 2001-02-12 CN CNB018057845A patent/CN1186317C/en not_active Expired - Fee Related
- 2001-02-12 DE DE60113814T patent/DE60113814T2/en not_active Revoked
- 2001-02-12 AT AT01915226T patent/ATE305918T1/en not_active IP Right Cessation
- 2001-02-12 ES ES01915226T patent/ES2245685T3/en not_active Expired - Lifetime
- 2001-02-12 PT PT01915226T patent/PT1259480E/en unknown
- 2001-02-12 JP JP2001563472A patent/JP2003525267A/en active Pending
-
2002
- 2002-07-24 US US10/202,584 patent/US20030055282A1/en not_active Abandoned
-
2003
- 2003-09-19 HK HK03106741.6A patent/HK1054374B/en not_active IP Right Cessation
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919278A (en) * | 1974-06-13 | 1975-11-11 | Atlantic Richfield Co | Production of isocyanates from lower alkyl esters of mononuclear aromatic carbamic acids |
| JPS5488222A (en) * | 1977-12-20 | 1979-07-13 | Mitsubishi Chem Ind Ltd | Preparation of isocyanate from carbamate |
| EP0092738A1 (en) * | 1982-04-27 | 1983-11-02 | Bayer Ag | Process for the continuous thermal decomposition of carbamic-acid esters |
| US4547322A (en) | 1983-03-18 | 1985-10-15 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for manufacture of diphenylmethane diisocyanates |
| JPS63150255A (en) * | 1986-12-15 | 1988-06-22 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| JPH01121259A (en) | 1987-11-04 | 1989-05-12 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| JPH02212465A (en) | 1989-02-13 | 1990-08-23 | Sumitomo Metal Ind Ltd | Production of polyisocyanate |
| US5043471A (en) | 1989-05-10 | 1991-08-27 | Bayer Aktiengesellschaft | Process for the preparation of polyisocyanates |
| US5284969A (en) | 1991-11-14 | 1994-02-08 | Bayer Aktiengesellschaft | Process for the production of polyisocyanates |
| EP0611243A1 (en) | 1993-02-12 | 1994-08-17 | Haldor Topsoe A/S | Process for the preparation of organic isocyanates |
| US5453536A (en) | 1994-03-10 | 1995-09-26 | The Dow Chemical Company | Polycarbamates, process for preparing polycarbamates, and process for preparing polyisocyanates |
| US5731458A (en) | 1996-03-15 | 1998-03-24 | Bayer Aktiengesellschaft | Process for thermally cracking carbamic acid esters |
| WO1998054128A1 (en) | 1997-05-31 | 1998-12-03 | Huntsman Ici Chemicals Llc | Method for the preparation of organic isocyanates |
Non-Patent Citations (3)
| Title |
|---|
| DATABASE CHEMABS CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; XP002168946 * |
| DATABASE CHEMABS CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; XP002168947 * |
| PATENT ABSTRACTS OF JAPAN vol. 003, no. 109 12 September 1979 (1979-09-12) * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2147909A1 (en) * | 2007-03-30 | 2010-01-27 | Asahi Kasei Chemicals Corporation | Method for production of isocyanate using composition comprising carbamic acid ester and aromatic hydroxy compound, and composition for transport or storage of carbamic acid ester |
| EP2147909A4 (en) * | 2007-03-30 | 2013-08-14 | Asahi Kasei Chemicals Corp | Method for production of isocyanate using composition comprising carbamic acid ester and aromatic hydroxy compound, and composition for transport or storage of carbamic acid ester |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1259480B1 (en) | 2005-10-05 |
| US20030055282A1 (en) | 2003-03-20 |
| CN1406224A (en) | 2003-03-26 |
| ATE305918T1 (en) | 2005-10-15 |
| HK1054374B (en) | 2005-09-16 |
| DE60113814D1 (en) | 2006-02-16 |
| CN1186317C (en) | 2005-01-26 |
| CA2397683A1 (en) | 2001-09-07 |
| HK1054374A1 (en) | 2003-11-28 |
| KR100670885B1 (en) | 2007-01-18 |
| PT1259480E (en) | 2005-11-30 |
| KR20020091102A (en) | 2002-12-05 |
| JP2003525267A (en) | 2003-08-26 |
| EP1259480A1 (en) | 2002-11-27 |
| ES2245685T3 (en) | 2006-01-16 |
| DE60113814T2 (en) | 2006-06-29 |
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