WO2001049119A1 - A stabilized isothiazolone composition and a method of stabilization of isothiazolone - Google Patents
A stabilized isothiazolone composition and a method of stabilization of isothiazolone Download PDFInfo
- Publication number
- WO2001049119A1 WO2001049119A1 PCT/KR2000/000526 KR0000526W WO0149119A1 WO 2001049119 A1 WO2001049119 A1 WO 2001049119A1 KR 0000526 W KR0000526 W KR 0000526W WO 0149119 A1 WO0149119 A1 WO 0149119A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- isothiazolone
- group
- isothiazolin
- halogen atom
- unsubstituted
- Prior art date
Links
- 0 **1NC(N)=*C1=O Chemical compound **1NC(N)=*C1=O 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Definitions
- the present invention relates to a stabilized isothiazolone
- composition and a method of stabilization of isothiazolone more particularly,
- R 1 and R 2 which may be the same or different, respectively
- R 3 represents a hydrogen atom; C, ⁇ C 10 alkyl group which is
- alkenyl group which is substituted or unsubstituted with a halogen atom
- C 2 ⁇ C 10 alkynyl group which is substituted or unsubstituted with a halogen atom
- the present invention also relates to a method of stabilization of
- disinfectant including an antibacterial and antimicrobial agent for dyes
- beneficial properties of the compound may be lost during storage.
- metal salt stabilizers react with emulsion components in a latex emulsion to
- a preferred disinfectant should be stable during use, but should be
- isothiazolone solution that is useful as a disinfectant and antimicrobial agent
- the present invention provides a
- R and R 2 which may be the same or different, respectively
- R 1 represents a hydrogen atom; a halogen atom; or a C, ⁇ C 4 alkyl group; or R 1
- R 2 together form a cyclic allyl group
- R 3 represents a hydrogen atom; C, ⁇ C 10 alkyl group which is
- the present invention also provides a method of stabilization of
- isothiazolone comprising stabilizing isothiazolone by blending isothiazolone
- the stabilizer is sulfuric acid.
- the present invention also provides a- method of sterilization of
- isothiazolone can be prevented, and completed the present invention.
- invention includes one or more compounds selected from the group
- the weight ratio is preferably about 50:50 ⁇
- the weight ratio is preferably about 99.5:0.5 ⁇ 90:10, more
- solution of the present invention preferably has high purity.
- the solvent contained in the stabilized isothiazolone solution can be any solvent contained in the stabilized isothiazolone solution.
- the solvent is water.
- the solvent may not be used.
- inventions may be made in the form of concentrated solution or diluted
- the isothiazolone solution comprises about
- solvent Preferably, it comprises 0.1 - 40 wt % of one or
- stabilizer can contain at most 14 wt % of active ingredient isothiazolone,
- the amount of stabilizer may vary according to the conditions of use
- stabilizer may be used, this is uneconomical. In the case of an extremely low
- diluted isothiazolone solution (about 1 ⁇ 10,000 ppm of isothiazolone in
- the weight ratio of isothiazolone : stabilizer is preferably in the
- the present invention is very stable in the air, its efficacy may be sustained
- the stabilized isothiazolone solution may be any organic compound.
- the stabilized isothiazolone solution may be any organic compound.
- greasing agents chemical products for the treatment of foods, daily chemical
- non-woven fabric non-woven fabric, petroleum reservoirs, paste material, rubber, sugar
- 65 ° C during one week corresponds to that measured at 25 ° C during 7
- Stabilized isothiazolone solution was prepared by blending 25 wt %
- Stabilized isothiazolone solution was prepared by blending 25 wt %
- Stabilized isothiazolone solution was prepared by blending 25 wt %
- Stabilized isothiazolone solution was prepared by blending 25 wt %
- isothiazolone solution was prepared by blending 32 wt % of a
- Isothiazolone solution was prepared by blending 2 wt % of a mixture
- Isothiazolone solution was prepared by blending 10 wt % of a mixture
- Isothiazolone solution was prepared by blending 14 wt % of an
- isothiazolone mixture comprising 5-chloro-2-methyl-4-isothiazolin-3-one
- isothiazolone solution using metal salt stabilizer remain stable for a long
- stabilizer can contain at most 14 wt % of active isothiazolone, while the
- stabilized isothiazolone solution of the present invention may contain active
- solution of the present invention was dissociated in water more rapidly than
- ..-the present, invention has the effects of stabilizing the active ingredient for a long term without forming precipitates in
- conventional metlal salt stabilizer may form nitrosamine in product by nitrite
- invention can stabilize isothiazolone solution without using metal salt
- present invention does not contain metal ion, it prevents heavy metals such
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU46228/00A AU4622800A (en) | 1999-12-31 | 2000-05-24 | A stabilized isothiazolone composition and a method of stabilization of isothiazolone |
DE60026292T DE60026292D1 (en) | 1999-12-31 | 2000-05-24 | A STABILIZED ISOTHIAZOLONE COMPOSITION AND A METHOD FOR STABILIZING ISOTHIAZOLONE |
JP2001549497A JP4621401B2 (en) | 1999-12-31 | 2000-05-24 | Stabilized isothiazolone composition and method for stabilizing isothiazolone |
EP00927924A EP1244358B1 (en) | 1999-12-31 | 2000-05-24 | A stabilized isothiazolone composition and a method of stabilization of isothiazolone |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1999/67757 | 1999-12-31 | ||
KR19990067757 | 1999-12-31 | ||
KR2000/27455 | 2000-05-22 | ||
KR10-2000-0027455A KR100385714B1 (en) | 1999-12-31 | 2000-05-22 | A stabilized isothiazolone composition and method of stabilization of isothiazolone |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001049119A1 true WO2001049119A1 (en) | 2001-07-12 |
Family
ID=36129242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2000/000526 WO2001049119A1 (en) | 1999-12-31 | 2000-05-24 | A stabilized isothiazolone composition and a method of stabilization of isothiazolone |
Country Status (9)
Country | Link |
---|---|
US (1) | US6534076B1 (en) |
EP (1) | EP1244358B1 (en) |
JP (1) | JP4621401B2 (en) |
KR (1) | KR100385714B1 (en) |
CN (1) | CN1216532C (en) |
AT (1) | ATE318517T1 (en) |
AU (1) | AU4622800A (en) |
DE (1) | DE60026292D1 (en) |
WO (1) | WO2001049119A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100385714B1 (en) * | 1999-12-31 | 2003-05-27 | 에스케이케미칼주식회사 | A stabilized isothiazolone composition and method of stabilization of isothiazolone |
WO2003099799A1 (en) * | 2002-05-29 | 2003-12-04 | Sk Chemicals Co., Ltd. | Isothiazolone composition and method for stabilizing isothiazolone |
EP1389424A1 (en) * | 2002-08-14 | 2004-02-18 | Air Liquide Santé (International) | Aqueous dispersion with fungicidal and algicidal action |
KR100975373B1 (en) * | 2002-05-29 | 2010-08-11 | 에스케이케미칼주식회사 | Isothiazolone composition and method for stabilizing isothiazolone |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6946023B2 (en) * | 2002-06-06 | 2005-09-20 | Avery Dennison Corporation | Smear-resistant ink compositions |
MX2008008079A (en) * | 2005-12-23 | 2008-10-22 | Perkinelmer Las Inc | Comparative genomic hybridization on encoded multiplex particles. |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0281911A2 (en) * | 1987-03-04 | 1988-09-14 | Takeda Chemical Industries, Ltd. | Stabilized composition |
JPH02142706A (en) * | 1989-07-13 | 1990-05-31 | Ichikawa Gosei Kagaku Kk | Agent for preventing marine organism from attaching itself to fishing net of raising |
EP0913091A1 (en) * | 1997-11-03 | 1999-05-06 | Nalco Chemical Company | Composition and method for inhibiting the growth of microorganisms including stabilized sodium hypobromite and isothiazolones |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3870795A (en) | 1973-02-28 | 1975-03-11 | Rohm & Haas | Stabilization of solutions of 3-isothiazolones employing certain metal nitrates and nitrites |
US4173643A (en) * | 1973-12-20 | 1979-11-06 | Rohm And Haas Company | Synergistic microbiocidal compositions |
US4067878A (en) | 1976-03-05 | 1978-01-10 | Rohm And Haas Company | Stabilization of solutions of 3-isothiazolones |
JP2851611B2 (en) * | 1987-10-26 | 1999-01-27 | 株式会社片山化学工業研究所 | Industrial sterilization method |
CA2027241A1 (en) * | 1989-10-24 | 1991-04-25 | Andrew B. Law | Stabilized metal salt/3-isothiazolone combinations |
CA2056711A1 (en) * | 1990-12-11 | 1992-06-12 | Ramesh B. Petigara | Process for 3-isothiazolone compounds |
JP3176676B2 (en) * | 1991-12-24 | 2001-06-18 | ローム アンド ハース カンパニー | Sterilizing composition |
US5869510A (en) * | 1993-01-15 | 1999-02-09 | Rohm And Haas Company | Iron stabilizers for 3-isothiazolones |
US5559083A (en) * | 1994-04-04 | 1996-09-24 | Takeda Chemical Industries, Ltd. | Composition comprising an isothiazolone compound |
JPH08301704A (en) * | 1995-05-10 | 1996-11-19 | Mitsubishi Corp | Industrial antiseptic and antifungal agent compositon and underwater antifouling agent composition |
JP2000128716A (en) * | 1998-10-20 | 2000-05-09 | Kurita Water Ind Ltd | Antimicrobial composition |
JP3692835B2 (en) * | 1999-06-08 | 2005-09-07 | 栗田工業株式会社 | Antibacterial composition |
KR100385714B1 (en) * | 1999-12-31 | 2003-05-27 | 에스케이케미칼주식회사 | A stabilized isothiazolone composition and method of stabilization of isothiazolone |
KR100383098B1 (en) * | 2000-05-10 | 2003-05-12 | 에스케이케미칼주식회사 | A method inhibiting precipitation of isothiazolone solution and a composition the same |
-
2000
- 2000-05-22 KR KR10-2000-0027455A patent/KR100385714B1/en not_active IP Right Cessation
- 2000-05-24 AU AU46228/00A patent/AU4622800A/en not_active Abandoned
- 2000-05-24 DE DE60026292T patent/DE60026292D1/en not_active Expired - Lifetime
- 2000-05-24 WO PCT/KR2000/000526 patent/WO2001049119A1/en active IP Right Grant
- 2000-05-24 EP EP00927924A patent/EP1244358B1/en not_active Expired - Lifetime
- 2000-05-24 AT AT00927924T patent/ATE318517T1/en not_active IP Right Cessation
- 2000-05-24 JP JP2001549497A patent/JP4621401B2/en not_active Expired - Fee Related
- 2000-05-24 CN CN008181055A patent/CN1216532C/en not_active Expired - Fee Related
- 2000-06-05 US US09/586,874 patent/US6534076B1/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0281911A2 (en) * | 1987-03-04 | 1988-09-14 | Takeda Chemical Industries, Ltd. | Stabilized composition |
JPH02142706A (en) * | 1989-07-13 | 1990-05-31 | Ichikawa Gosei Kagaku Kk | Agent for preventing marine organism from attaching itself to fishing net of raising |
EP0913091A1 (en) * | 1997-11-03 | 1999-05-06 | Nalco Chemical Company | Composition and method for inhibiting the growth of microorganisms including stabilized sodium hypobromite and isothiazolones |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100385714B1 (en) * | 1999-12-31 | 2003-05-27 | 에스케이케미칼주식회사 | A stabilized isothiazolone composition and method of stabilization of isothiazolone |
WO2003099799A1 (en) * | 2002-05-29 | 2003-12-04 | Sk Chemicals Co., Ltd. | Isothiazolone composition and method for stabilizing isothiazolone |
KR100975373B1 (en) * | 2002-05-29 | 2010-08-11 | 에스케이케미칼주식회사 | Isothiazolone composition and method for stabilizing isothiazolone |
KR100975375B1 (en) * | 2002-05-29 | 2010-08-11 | 에스케이케미칼주식회사 | Isothiazolone composition and method for stabilizing isothiazolone |
KR100975374B1 (en) * | 2002-05-29 | 2010-08-11 | 에스케이케미칼주식회사 | Isothiazolone composition and method for stabilizing isothiazolone |
KR100975372B1 (en) * | 2002-05-29 | 2010-08-11 | 에스케이케미칼주식회사 | Isothiazolone composition and method for stabilizing isothiazolone |
EP1389424A1 (en) * | 2002-08-14 | 2004-02-18 | Air Liquide Santé (International) | Aqueous dispersion with fungicidal and algicidal action |
Also Published As
Publication number | Publication date |
---|---|
AU4622800A (en) | 2001-07-16 |
EP1244358A4 (en) | 2003-01-15 |
EP1244358A1 (en) | 2002-10-02 |
JP2003519161A (en) | 2003-06-17 |
CN1216532C (en) | 2005-08-31 |
JP4621401B2 (en) | 2011-01-26 |
US6534076B1 (en) | 2003-03-18 |
DE60026292D1 (en) | 2006-04-27 |
ATE318517T1 (en) | 2006-03-15 |
KR100385714B1 (en) | 2003-05-27 |
EP1244358B1 (en) | 2006-03-01 |
CN1424874A (en) | 2003-06-18 |
KR20000054080A (en) | 2000-09-05 |
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