WO2001045832A2 - Single stage denitration - Google Patents
Single stage denitration Download PDFInfo
- Publication number
- WO2001045832A2 WO2001045832A2 PCT/US2000/041323 US0041323W WO0145832A2 WO 2001045832 A2 WO2001045832 A2 WO 2001045832A2 US 0041323 W US0041323 W US 0041323W WO 0145832 A2 WO0145832 A2 WO 0145832A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- recited
- compounds
- steam
- reaction vessel
- bed
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/37—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by reduction, e.g. hydrogenation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
- B01D53/565—Nitrogen oxides by treating the gases with solids
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/26—Organic substances containing nitrogen or phosphorus
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/45—Inorganic substances containing nitrogen or phosphorus
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/40—Inorganic substances
- A62D2101/47—Inorganic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
Definitions
- the present invention relates generally to a single step process for removing NOx compounds from waste products, compounds and wastewaters. More specifically, the invention relates to a single step process utilizing a fluidized bed container to remove NOx compounds from explosive, hazardous and/or radioactive materials.
- Nitrogen oxides can be commonly found in many waste products and compounds.
- Nitrogen oxides include such compounds as nitric acid, aluminum nitrate, sodium nitrate, ammonium nitrate, potassium nitrate and the like.
- Dry contact reduction processes may be either catalytic or non-catalytic and may be either selective or non-selective.
- Selective reduction processes are characterized by the selective reduction of gaseous nitrogen oxides and their consequent removal in the presence of oxygen.
- a common selective reduction agent for gaseous NOx is ammonia. Ammonia, however, oxidizes to form unwanted nitrogen oxide at high temperatures. Moreover, excess ammonia is itself a pollutant.
- Other selective reduction methods employ catalysts such as indium. The problem with catalyst reduction is that the presence of particulates, sulfurous acid gases and other poisons reduce catalyst effectiveness and life thereby increasing costs. 2
- Non-selective reduction processes generally involve the addition of a reducing agent to the gaseous NOx containing material, consuming all free oxygen through combustion and reducing the NOx to nitrogen by the remaining reducing agent.
- Catalysts are typically utilized in these processes. Reducing agents useful in these processes are both scarce and expensive.
- Wet absorption processes typically require large and expensive equipment such as absorption towers.
- An example of a wet absorption process is the absorption of nitrogen oxides by water or alkali solution. Another shortcoming of the wet absorption process is that these methods are not economically effective where the NOx concentration in the gaseous waste stream is above 5,000 ppm.
- Rotary calciner and fluid bed processors have been utilized with typical results yielding less than 90% conversion of solid nitrates to gaseous NOx and nitrogen.
- the gaseous NOx generally exceeded 10,000 ppm which requires addition of extensive gaseous NOx removal methods as described above.
- severe agglomerations occur in processors as well as the presence of flammable or explosive mixtures of nitrates and reducing agents in the processors. 3
- Another problem associated with prior art waste processing methods involves sulfur- containing compounds.
- the presence of such sulfur compounds in a vitrification melter can cause a molten sulfur salt pool to accumulate on top of the molten inorganic residue (glass); this pool causes high corrosion rates for the melter equipment.
- the pool can also have a high electrical conductivity, which causes short-circuiting of the heating electrodes in the melter.
- the presence of heavy metals in the inorganic residues can render the final waste product hazardous, thereby requiring additional processing of the residue before disposal or higher disposal costs.
- the inorganic residue can contain soluble components that may form aqueous solutions after processing; these solutions can result in contamination of the surroundings after disposal.
- the present invention is a method and apparatus for converting nitrogen oxides directly to nitrogen using a single steam-reformer vessel.
- Nitrate compounds or wastes are fed into the single vessel along with a fluidized gas composed of steam and, optionally, oxygen.
- the single vessel contains an inert media bed made of high-density media, such as amorphous alumina beads up to 3000 microns in diameter.
- the fluidizing gases are injected at relatively high speeds, ranging up to 800 feet per second. 4
- carbonaceous materials are used as the heat source to evaporate water in the waste feed and as the principal reducing agent, or reductant.
- reducing agent and reductant are well-understood by those skilled in the art of removing nitrogen oxides from waste feeds to mean chemicals or materials that are useful in removing oxygen from a compound or adding hydrogen to a compound.
- the vessel is divided into three zones with the lowest most zone operated under oxidizing conditions via the addition of superheated steam with oxygen that reacts with the carbon to form CO/CO 2 and generate heat to evaporate water content and heat nitrate compounds to reduction temperature.
- the middle zone is operated under strongly reducing conditions in which NO 3 , NO, N 2 O and NO 2 are reduced to N 2 .
- Steam reforming of carbonaceous materials in this zone forms CO, H 2 and CH 4 that serve as strong gaseous reducing agents.
- the upper zone is operated under oxidizing conditions via the addition of more oxygen that oxidizes the remaining C, CO, CH 4 and H 2 form in the second or middle zone to form CO 2 and water. This process result in only trace NOx, CO and H 2 in off-gas from the single vessel and requires little auxiliary energy to be added.
- the lowest zone is operated under oxidizing conditions and the middle and upper segments operated under strongly reducing conditions. This process results in less NOx, more CO and H 2 output and also requires low auxiliary energy. Auxiliary energy can be provided by electrical heaters.
- all three segments are operated under strongly reducing conditions. This process results in less NOx, increased CO and H 2 and requires additional auxiliary energy. 5
- the lower and middle segments are operated under strongly reducing conditions and the upper segment is operated under oxidizing conditions. This process results in low NOx, no CO and H 2 output but requires auxiliary energy to be added.
- Fig. 1 is a schematic illustration of a system for removing NOx from a waste stream or compound according to a preferred embodiment of the present invention.
- the present invention is an apparatus and process for removing NOx from nitrate bearing compounds and waste product feeds.
- the present apparatus and processes will be described in particular with respect to radioactive waste but any nitrogen oxide containing waste or product stream can be processed in accordance with the following process and with the components of the system.
- the process is based on a single fluidized bed reactor vessel using steam for fluidizing which may be operated under strongly reducing conditions or under strongly reducing conditions in combination with oxidizing conditions.
- Other fluidizing gases or additives may be utilized to modify the oxidizing or reducing conditions in the reactor. Typical other fluidizing gases include: hydrogen, oxygen (when oxidizing conditions are desired), methane, ammonia, etc.
- System 10 includes a single reactor vessel 12.
- Waste feed which may be comprised of liquid slurries and sludges 14 and/or solids 16, are fed into the reactor vessel 12.
- a pneumatic pump, peristaltic pump or progressive cavity 18 may be employed for delivery of the pumpable fluids to the reactor vessel 12.
- a screw auger 20 may be employed to deliver the solid waste stream into the reactor vessel 12.
- inert media 22 is used in the fluid bed.
- Media 22 is preferably an inert material which may serve as a heat sink such as silica or alumina, most preferably, amorphous alumina beads at least 200 and preferably up to 1000 microns in diameter, however beads up to 5,000 microns in diameter can be utilized. Such size beads do not easily elutriate out of the vessel and therefore minimize carryover.
- Another advantage of the amorphous alumina is that it will not form eutectic salt/glasses that can form harmful agglomerates that affect reactor efficiency as when common silica sand is utilized.
- the amorphous alumina is also exceptionally strong and hard and resists attrition due to bed friction and impact.
- charcoal, sugar and/or other carbonaceous materials are added to reactor vessel 12, optionally other reductants or catalysts such as iron or nickel oxalates, oxides, or nitrates may be used. 7
- Reaction bed materials can be modified to include these, or other metals, in order to further improve the denitration process.
- the addition of 5 to 10% iron oxide to the reaction bed medium can improve NOx reduction by more than two-fold.
- Fluidizing medium gases
- Steam is preferred to combustion gases as the fluidizing medium because it is more reactive, and generates CO and H 2 that are highly reducing by steam reformation of carbonaceous materials.
- Gaseous NOx compounds can be co-injected with the fluidizing gases through inlet 24.
- the heat generated by the steam allows the reaction vessel to be operated at the temperature required for reduction of the nitrogen oxides.
- This heat can also volatize sulfur- containing compounds, thereby separating them from the inorganic residues.
- the presence of such sulfur compounds can cause an equipment-damaging corrosive molten sulfur salt pool to accumulate on top of the molten inorganic residue.
- the electrically- conductive pool would also cause short-circuiting of the heating electrodes or potentially explosive conditions if contacted by large quantities of water.
- the present method for example, converts sulfates such as Na2SO4 by reduction into volatile SOx and/or H2S. By volatizing such sulfur-containing compounds, the present method avoids these problems that are traditionally associated with the reduction of nitrogen oxide-containing waste streams.
- the sulfur reduced residue can then be melted into glass without forming a sulfur salt pool on top of the melter glass pool.
- the fluidizing medium can be an inert gas, but is preferably a reforming gas and may have oxygen present. Most preferably, the medium is superheated steam.
- the fluidizing velocity can range from about 1.0 feet per second or higher depending on the bed media, 8 preferably 3 to 10 feet per second (FPS) depending upon the size of the bed media.
- Fluidizing gas distributors are designed to provide higher than normal gas/orifice velocities. Typical gas distributor velocities are 100 to 200 FPS, however, in the preferred embodiment gas velocities of >400 FPS are desired.
- the high fluidizing gas jet speed has several advantages.
- High velocity fluidizing gas jets in a vertically oriented bed provides jet impingement on the media to help break down the softer, friable feed and to break-up agglomerates. Moreover, the media beads become self-cleaning due to abrasion in the high impact area around the fluidizing gas distributor.
- Reactor vessel 12 is preferably operated in elutriating mode. Sodium and other low melting eutectics are thereby present in only low concentration ( ⁇ 2%) and are quickly carried out of the bed. The media beads are self-cleaning through abrasion. The low inventory of unconverted nitrates or sodium compounds greatly minimizes agglomeration potential.
- the reactor vessel 12 may be operated using one of four methods, in the first method, the lower portion of the media bed is operated under oxidizing conditions. To achieve this condition oxygen is mixed with the steam and introduced into the reactor vessel 12 via inlet 24 and may be optionally superheated.
- the pressure in the reactor vessel 12 is preferably about 13 to 15 psia.
- the reactor vessel 12 is preferably operated at 600 to 800 degrees centigrade.
- the media bed depth is preferably between about 3 to 8 feet, expanded.
- the middle portion of media bed in reactor vessel 12 is operated under strongly reducing conditions, and the upper portion of the media bed is operated under oxidizing conditions by the addition of oxygen via inlet 25.
- Temperature is maintained within reactor vessel 12 by heater 26 or by super heating fluidizing gases which provides auxiliary energy as needed, particularly during start-up.
- the nitrogen, steam and other syn gases leave the reaction vessel 12 via port 28.
- Small sized reformed residues, including entrained particulates also leave via port 28.
- Heavier solids and debris leave via port 30 and are carried away by screw auger 32 to collector 34.
- Auger 32 is preferably water cooled. From collector 34 the larger solids and debris may be directed to stabilization processor 36 or to final reformed residue waste collector
- the screw auger 32 can be optionally fitted with water washing capability. Water can be introduced into the bottom of screw auger 32 through inlet 60. Water dissolves any soluble sodium salt or other agglomerates that collect in the bottom of the reactor vessel 12. Salt water solution is removed from the bottom of reactor vessel 12 through screened outlet port 62. If desired, the salt water solution from outlet 62 can be collected in residue separator 42.
- the nitrogen gas, steam, other syn gas and fine particulates pass through scrubber/evaporator 40.
- Any non- gaseous reformed residue or particulates collected in the scrubber/evaporator 40 is directed to residue separator 42 wherein the insoluble reformed residue are separated from the soluble salt solution.
- the reformed residue is directed to the stabilization processor 36 while the salt solution is directed to salt separator 44 then to a salt dryer 46 and finally to a salt package 48.
- An optional filter (not shown) can be installed between the reactor gas outlet 28 and the scrubber/evaporator 40. Solids collected by the optional filter can be directed to residue stabilization processor 36. The cooled and scrubbed syn gas and water vapors then pass to condenser 50.
- the resultant water is directed to the recycled water tank 52 while the syn gas moves to thermal converter 54.
- Off-gases (OG) from the thermal converter 54 are then monitored for compliance with the applicable environmental requirements prior to release. 10
- the process treatment results in final gaseous effluent very low in NOx with no CO and H 2 output.
- the system generally requires low auxiliary energy addition. This system does not require the removal of NOx in the off gas scrubber system as NOx levels exiting the reactor 12 are routinely ⁇ 25 ppm.
- the addition of thermal converter 54 for CO and CH 4 oxidation is also not required.
- the lower portion of the media bed in reactor vessel 12 may be operated under oxidizing conditions, as discussed above, the middle portion and the upper portions of the media bed are operated under strongly reducing conditions.
- Method 2 results in lowered NOx exiting reactor 12 as compared to method 1 but has increased levels of CO and H 2 and other trace volatile organics in the reactor 12 output. Additional auxiliary energy is generally needed in the reactor 12 and thermal converter 54 is required.
- Method 3 the reactor vessel 12 is operated only under strongly reducing conditions.
- Method 3 results in lowered NOx, increased CO and H 2 and requires increased auxiliary energy and use of thermal converter 54.
- method 4 only the upper portion of the reactor vessel 12 media bed is operated under oxidizing conditions.
- Method 4 results in low NOx, no CO and H 2 output and increased auxiliary energy.
- the thermal converter 54 is not required in the practice of this method.
- gaseous NOx can also be processed by direct introduction to reactor 12 with other waste feeds.
- high NOx offgas from a vitrification melter or thermal denitration process can be used as both the waste stream and the fluidizing gas; however, steam is co-injected to keep the total gas flow through the reaction bed at greater than 20%. steam and to provide uniform fluidizing gas velocities. 11
- Metal additives are not always required but are useful in maximizing NOx conversion to nitrogen gas.
- Typical metals that can be used include copper, cobalt, iron or nickel oxalate or nitrates that can be co-injected with the waste feed in concentrations of less than 0.5%.
- the addition of charcoal or carbonaceous solids to the bed in sizes ranging up to 0.5 inches in diameter is unique to the preferred embodiment.
- the large particles of carbon maintain a constant inventory of carbon that is not possible with typical fine sugars, organic powders or liquid chemicals previously used to facilitate nitrate reduction.
- the presence of larger carbon solids together with addition of soluble carbon in the form of formic acid, sugars, etc. provides superior nitrate reductions.
- the presence of carbon compounds in the bed will produce highly reducing CO and H 2 in the bed via steam reformation.
- certain additives such as aluminum metal and phosphate salts or oxides can be added to form high melting point salts with alkaline earth elements.
- sodium phosphate is a high melting point sodium salt compared with sodium eutectics that have relatively low temperature melting points. These combining elements help minimize formations of agglomerations in the bed.
- heavy metals or inorganic cations can be converted into volatile fluoride or chloride compounds by the addition of appropriate fluorides and chlorides.
- the presence of heavy metals in the inorganic residues can render the final waste product hazardous, thereby requiring additional processing of the residue before disposal.
- chloride additives can convert the Cesium to very volatile CsCb, thereby separating the heavy metal cation from 12 the inorganic residue.
- the present method avoids this problem that is traditionally associated with the reduction of nitrogen oxide- containing waste streams.
- the present method can use additives to tailor the solubility of the resulting inorganic residue. As discussed above, soluble components in the residue may form aqueous solutions that can result in contamination of the surroundings after disposal.
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- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrology & Water Resources (AREA)
- General Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biomedical Technology (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Toxicology (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Treating Waste Gases (AREA)
- Processing Of Solid Wastes (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Description
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Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002387802A CA2387802C (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
JP2001546768A JP4029320B2 (en) | 1999-10-20 | 2000-10-19 | Single-stage denitration |
US10/111,148 US7125531B1 (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
AT00993080T ATE511190T1 (en) | 1999-10-20 | 2000-10-19 | ONE-STAGE DENITRIDITY |
AU50748/01A AU5074801A (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
EP00993080A EP1225973B1 (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
US10/246,266 US7011800B1 (en) | 2000-10-19 | 2002-09-18 | Single stage denitration |
US10/374,293 US7531152B2 (en) | 2000-10-19 | 2003-02-26 | Mineralization of alkali metals, sulfur, and halogens |
US10/972,068 US7476194B2 (en) | 1999-10-20 | 2004-10-22 | In-container mineralization |
US11/666,045 US20080119684A1 (en) | 1999-10-20 | 2005-09-27 | In-Container Mineralization |
US11/349,030 US20060167331A1 (en) | 1999-10-20 | 2006-02-07 | Single stage denitration |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/421,612 | 1999-10-20 | ||
US09/421,612 US6280694B1 (en) | 1999-10-20 | 1999-10-20 | Single stage denitration |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/421,612 Continuation US6280694B1 (en) | 1999-10-20 | 1999-10-20 | Single stage denitration |
Related Child Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10111148 A-371-Of-International | 2000-10-19 | ||
US10/111,148 Continuation-In-Part US7125531B1 (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
US10/185,616 Continuation-In-Part US20030198584A1 (en) | 1999-10-20 | 2002-06-28 | Single stage denitration |
US10/209,090 Continuation-In-Part US7491861B2 (en) | 1999-10-20 | 2002-07-31 | In-drum pyrolysis |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2001045832A2 true WO2001045832A2 (en) | 2001-06-28 |
WO2001045832A3 WO2001045832A3 (en) | 2002-01-03 |
WO2001045832B1 WO2001045832B1 (en) | 2002-01-31 |
Family
ID=23671289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/041323 WO2001045832A2 (en) | 1999-10-20 | 2000-10-19 | Single stage denitration |
Country Status (9)
Country | Link |
---|---|
US (1) | US6280694B1 (en) |
EP (1) | EP1225973B1 (en) |
JP (1) | JP4029320B2 (en) |
AT (1) | ATE511190T1 (en) |
AU (1) | AU5074801A (en) |
CA (1) | CA2387802C (en) |
RU (1) | RU2216396C1 (en) |
WO (1) | WO2001045832A2 (en) |
ZA (1) | ZA200203941B (en) |
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WO2003044448A1 (en) * | 2001-11-22 | 2003-05-30 | GFE GmbH & Co. KG Gesellschaft für Entsorgung | Method and device for disposing of materials, in particular, shells containing chemical warfare agents |
CN103111242A (en) * | 2011-11-16 | 2013-05-22 | 斯塔德斯维克公司 | Method and system for stabilizing volatile radionuclides during denitration at high temperatures |
CN110237596A (en) * | 2019-05-24 | 2019-09-17 | 苏州品立环保系统有限公司 | The small oil water separator in kitchen |
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UA57884C2 (en) * | 1999-10-14 | 2003-07-15 | Дейвід БРЕДБЕРІ | Method for treatment of radioactive graphite |
US7125531B1 (en) | 1999-10-20 | 2006-10-24 | Studsvik, Inc. | Single stage denitration |
US7476194B2 (en) * | 1999-10-20 | 2009-01-13 | Studsvik, Inc. | In-container mineralization |
US7011800B1 (en) | 2000-10-19 | 2006-03-14 | Studsvik, Inc. | Single stage denitration |
US7531152B2 (en) * | 2000-10-19 | 2009-05-12 | Studsvik, Inc. | Mineralization of alkali metals, sulfur, and halogens |
US20060167331A1 (en) * | 1999-10-20 | 2006-07-27 | Mason J B | Single stage denitration |
US20030198584A1 (en) * | 2002-04-19 | 2003-10-23 | Mason Bradley J. | Single stage denitration |
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CN112642275A (en) * | 2020-11-30 | 2021-04-13 | 山东省科学院能源研究所 | Organic waste pyrolysis, gasification, combustion, co-sintering and denitration integrated system and method |
CN115121575B (en) * | 2022-06-27 | 2023-11-24 | 中国矿业大学 | Method for preparing gangue-based active powder and solidifying nuclide Se |
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US4609537A (en) * | 1984-08-13 | 1986-09-02 | Standard Oil Company (Indiana) | Process for simultaneously removing nitrogen oxides, sulfur oxides, and particulates |
US4665632A (en) | 1985-09-27 | 1987-05-19 | Uop Inc. | Apparatus for uniformly distributing fluid through a bed of particulate material |
US4662081A (en) | 1985-09-27 | 1987-05-05 | Uop Inc. | Process for uniformly distributing fluid through a bed of particulate material |
US4966101A (en) | 1988-05-17 | 1990-10-30 | Ube Industries, Ltd. | Fluidized bed apparatus |
DE19619764C2 (en) * | 1996-05-17 | 2003-12-18 | Infraserv Gmbh & Co Hoechst Kg | Process for minimizing the NO¶x¶ content in flue gases |
-
1999
- 1999-10-20 US US09/421,612 patent/US6280694B1/en not_active Expired - Lifetime
-
2000
- 2000-10-19 CA CA002387802A patent/CA2387802C/en not_active Expired - Fee Related
- 2000-10-19 AU AU50748/01A patent/AU5074801A/en not_active Abandoned
- 2000-10-19 RU RU2002113563/12A patent/RU2216396C1/en not_active IP Right Cessation
- 2000-10-19 JP JP2001546768A patent/JP4029320B2/en not_active Expired - Lifetime
- 2000-10-19 EP EP00993080A patent/EP1225973B1/en not_active Expired - Lifetime
- 2000-10-19 AT AT00993080T patent/ATE511190T1/en not_active IP Right Cessation
- 2000-10-19 WO PCT/US2000/041323 patent/WO2001045832A2/en active Application Filing
-
2002
- 2002-05-17 ZA ZA200203941A patent/ZA200203941B/en unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003044448A1 (en) * | 2001-11-22 | 2003-05-30 | GFE GmbH & Co. KG Gesellschaft für Entsorgung | Method and device for disposing of materials, in particular, shells containing chemical warfare agents |
CN103111242A (en) * | 2011-11-16 | 2013-05-22 | 斯塔德斯维克公司 | Method and system for stabilizing volatile radionuclides during denitration at high temperatures |
GB2496704A (en) * | 2011-11-16 | 2013-05-22 | Studsvik Inc | Nitrogen oxide removal |
CN110237596A (en) * | 2019-05-24 | 2019-09-17 | 苏州品立环保系统有限公司 | The small oil water separator in kitchen |
Also Published As
Publication number | Publication date |
---|---|
ZA200203941B (en) | 2003-01-02 |
RU2002113563A (en) | 2005-01-10 |
CA2387802C (en) | 2009-01-06 |
JP4029320B2 (en) | 2008-01-09 |
CA2387802A1 (en) | 2001-06-28 |
RU2216396C1 (en) | 2003-11-20 |
JP2003534111A (en) | 2003-11-18 |
EP1225973B1 (en) | 2011-05-25 |
US6280694B1 (en) | 2001-08-28 |
ATE511190T1 (en) | 2011-06-15 |
WO2001045832B1 (en) | 2002-01-31 |
EP1225973A4 (en) | 2007-10-10 |
EP1225973A2 (en) | 2002-07-31 |
WO2001045832A3 (en) | 2002-01-03 |
AU5074801A (en) | 2001-07-03 |
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