WO2001019927A1 - Process for preparing pigment flush - Google Patents
Process for preparing pigment flush Download PDFInfo
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- WO2001019927A1 WO2001019927A1 PCT/US2000/025076 US0025076W WO0119927A1 WO 2001019927 A1 WO2001019927 A1 WO 2001019927A1 US 0025076 W US0025076 W US 0025076W WO 0119927 A1 WO0119927 A1 WO 0119927A1
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- WIPO (PCT)
- Prior art keywords
- extruder
- press cake
- feed
- pigment
- monitoring apparatus
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0021—Flushing of pigments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/72—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with helices or sections of helices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2131—Colour or luminescence
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2132—Concentration, pH, pOH, p(ION) or oxygen-demand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2136—Viscosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/80—Forming a predetermined ratio of the substances to be mixed
- B01F35/82—Forming a predetermined ratio of the substances to be mixed by adding a material to be mixed to a mixture in response to a detected feature, e.g. density, radioactivity, consumed power or colour
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
- B29C48/765—Venting, drying means; Degassing means in the extruder apparatus
- B29C48/766—Venting, drying means; Degassing means in the extruder apparatus in screw extruders
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/35—Mixing inks or toners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/365—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pumps, e.g. piston pumps
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
Definitions
- the present invention relates to processes for preparing pigment flushes, particularly pigment flushes for ink compositions.
- the present invention also relates to methods for preparing ink bases and finished ink compositions.
- Syntheses of many organic pigments include a coupling step in a dilute aqueous medium to produce a slurry of the pigment product, which is typically followed by filtering the slurry in a filter press to concentrate the pigment.
- the press cake that results is then either dried to provide a dry, particulate pigment or else is "flushed" with an organic medium such as an oil and/or resin to transfer the pigment particles from the aqueous press cake to the oil or resin phase. Flushing assists in keeping pigment particles non-agglomerated and easier to use in making inks or coatings.
- the flushing process requires additional time and materials over simply drying the pigment.
- pigment flushes have usually been prepared by batch processes in which the press cake is kneaded with an organic phase such as an oil and/or a resin, for example in a sigma blade mixer or dough mixer, to flush the pigment particles from the water phase to the organic medium phase and displace the water as a separate aqueous phase. The displaced water is separated and the dispersion of the pigment in the varnish can be used as a pigment paste in preparing an ink or paint.
- organic phase such as an oil and/or a resin
- the batch process has many shortcomings. First, the steps of adding varnish, kneading the dough to displace the water, and pouring off the water must usually be repeated a number of times in order to obtain the optimum yield and a product with the desired low water content. This is a labor-intensive process that requires careful monitoring. Further, in order to remove the residual water, the batch must be further treated, such as by heating and stripping under vacuum. For many pigments, the heat history from processing to remove the residual water may result in a color shift. Further, the process is time-consuming and inefficient. Finally, it is difficult to reduce the water content below about 3% by weight, even with the vacuum stripping.
- Anderson et al. U.S. Patent No. 5,151 ,026, discloses an extruder apparatus for removing liquid from an aqueous mass of comminuted solids such as crumb rubber, wood pulp, and ground plastic materials that are cleansed during recycling processes.
- the water is squeezed out of the aqueous mass in a pinch point.
- the pinch point pressure results from applying a backward force by means of a reverse-threaded section of the screw immediately at the liquid extraction location.
- the Anderson process removes from water relatively large solid pieces that do not appear to associate or agglomerate.
- the pigment flush process concerns transfer of fine pigment particles from aqueous press cake to an organic phase, usually including a resin, followed by separation of the two liquid phases (aqueous and organic).
- the pinch point method is unsuitable for the two-phase pigment flushing process because the pinching force would interfere with the necessary phase separation between aqueous and organic phases.
- the pigment particles also have a tendency to agglomerate. The pinch point would thus be unsuitable for the additional reason that squeezing the pigment would cause undesirable agglomeration of the pigment particles, which would in turn impair dispersion of the pigment.
- Another important consideration for continuous pigment and ink production processes is maintaining uniformity of the desired properties of the product. In a batch process, each batch is optimized individually. The properties are monitored and the batch processing may be continued or adjusted until the desired properties are achieved. Unlike batch processing, in the extruder continuous process the properties should be monitored and adjustments made continually so that the product is of the desired quality to avoid interrupting the continuous process.
- the invention provides a process for continuous production of pigment flush from conventional press cake.
- a first step at least one pigment press cake is homogenized to a fluidized mass.
- the homogenized press cake is fed at a controlled rate into a twin screw extruder.
- the twin screw extruder may receive more than one stream of fluidized press cake.
- An organic medium which may include organic components selected from solvent, varnish, oil, and/or resin, is also fed into the extruder, and the press cake and organic medium are mixed in a first zone of the extruder to wet the pigment with the organic medium, displacing water from the press cake and producing a crude pigment flush.
- the displaced water is removed in a second zone of the extruder.
- the second zone of the extruder includes a port for removing the displaced water, especially by draining the water, and preferably includes a dam that retains the pigment flush in the second zone for a time sufficient to allow most of the displaced water to be removed from the crude flush mass.
- the extruder preferably includes a third zone that has one or more vacuum ports to draw off residual water clinging to the pigment flush.
- the invention also provides a method for continuous production of an ink base or a finished ink from a pigment press cake.
- the method includes the steps just outlined for the process of the invention for producing a pigment flush and at least one an additional step of introducing into the extruder, at some point before the pigment dispersion is discharged, preferably after the optional vacuum zone, one or more additional ink components, such as a varnish, pigmented tinting or toning compositions, solvent, and/or additives, to make an ink base or a finished ink composition.
- the invention further provides an apparatus that includes a press cake feed system and a twin screw extruder.
- the press cake feed system is used to fluidize the press cake and consistently feed the fluidized press cake to the extruder.
- the press cake feed system applies shear to the press cake to convert the crumbly, agglomerating material into a smooth, fluid dispersion.
- the feed system then transfers the fluidized press cake to the twin screw extruder.
- the twin screw extruder of the apparatus has at least two zones. In a first zone, the fluidized press cake and an organic medium are fed into the extruder and mixed. The action of the first zone transfers the pigment to the organic medium and produces a separate water phase. In a second zone of the extruder, the water phase is at least partially removed. In an optional third zone, a residual portion of water is removed from the pigment flush by vacuum.
- the extruder may also optionally have a fourth zone with at least one addition port by which additional ingredients are added and which provides additional mixing to prepare an ink base or finished ink
- the invention offers an advantage over previous processes in that it provides continuous processing of conventional press cakes.
- Press cakes are usually prepared having pigment contents of from about 15% to about 35%. Because the present invention can process press cakes as prepared, it is possible to eliminate a cumbersome preliminary evaporation step to increase pigment content of the press cake to the point at which the press cake can be flushed or a diluting step in which the press cake is reduced to a very low solids slurry for processing using the prior art methods.
- the invention offers a further advantage of providing more control for a continuous flushing process, which results in increased consistency of color and other properties of the pigment dispersion.
- the invention offers a still further advantage of providing a continuous process for manufacturing ink base or a finished ink product from a continuous feed of conventional press cake.
- the invention also includes a novel process for continuous production of a pigment flush or an ink composition that includes automated process adjustment by at least one step of monitoring the value of a property of the process, comparing the monitored value to a desired value of the property, and providing in process adjustment of at least one aspect of the processing in response to the comparison of monitored value and desired value.
- FIG. 1 is a schematic diagram of one embodiment of the press cake feed system of the invention.
- FIG. 2 is a schematic diagram of an alternative embodiment of the press cake feed system of the invention.
- FIG. 3 is a schematic diagram of one embodiment of the twin screw extruder of the present invention.
- FIG. 4 is a partial schematic view of the water separation zone of the invention.
- FIG. 5 is a partial schematic view of an alternative embodiment of the extruder showing the fourth zone.
- FIG. 6 is a flow diagram showing the process of adjusting parameters based on product color shade measurements.
- FIG. 7 is a flow diagram showing the process of adjusting parameters based on product color strength measurements.
- FIG. 8 is a flow diagram showing the process of adjusting parameters based on product water content measurements.
- FIG. 9 is a flow diagram showing the process of adjusting parameters based on product viscosity measurements.
- the invention provides a process in which a pigment in press cake form is flushed by transferring the pigment particles from the aqueous press cake to an organic medium, especially to an oil or resin phase.
- the press cake may be from the synthesis of any of a number of organic pigments.
- suitable press cakes include, without limitation, press cakes of diarrylide yellow pigments (e.g., Pigment Yellow 12), phthalocyanine pigments, calcium lithol red, alkali blue, barium lithol red, rhodamine yellow, rhodamine blue, and so on.
- Press cakes of organic pigments typically have a water content by weight of from about 12% to about 30%, although press cakes such as those of certain blue pigments may have a water content as high as 45%.
- the invention further provides an apparatus that includes at least one press cake feed system, a preferred embodiment of which is shown in FIG. 1 , and a twin screw extruder, a preferred embodiment of which is shown in FIG. 3.
- the press cake feed system fluidizes the press cake and feeds the fluidized press cake to the twin screw extruder.
- the press cake feed system may include two components that carry out these actions, a fluidizing component such as 1 in FIG. 1 and a feed component such as 2 in FIG. 1.
- the fluidizing component applies shear to the press cake to break up the bridging between the individual particles that gives the press cake its pasty or plaster-like consistency. The amount of shear is sufficient to produce a fluidized press cake.
- FIG 1 shows as one preferred embodiment of the fluidizing component a paddle mixer 3 driven by motor 13.
- Paddle mixer 3 shows ten paddle mixing elements 4, but the size of the paddle mixer and the number of mixing elements can be varied widely to suit the particular situation, such as the desired throughput of the continuous process.
- Scrapers 10 may be included to scrape the walls and keep the press cake inside the mixer. If necessary, the mixer may be cooled with the aid of a cooling jacket (not shown), by air cooling, or otherwise.
- the fluidizing component has a orifice 5 through which the fluidized press cake exits the fluidizing component.
- the fluidized press cake may be discharged from the fluidizing component by pushing the fluidized press cake through the orifice with a valve 6, as is shown in
- FIG. 1 to control the flow of fluidized press cake from the fluidizing component.
- the fluidized press cake may be drawn from the fluidizing component with vacuum or pumped from the fluidizing component.
- the fluidized press cake is fed into a holding tank 7 as shown in FIG. 1.
- Holding tank 7 is equipped with a blade 8 that rotates along the perimeter and serves both to prevent re-bridging between the pigment particles of the fluidized press cake and to aid in feeding the press cake to feed pump 9.
- Feed pump 9 provides fluidized press cake to the extruder.
- Holding tank 7 allows the fluidizing operation taking place in paddle mixer 3 to be carried out in a batch or semi-batch manner, with all or part of the fluidized press cake in the mixer being emptied to the holding tank at intervals.
- press cake can be fluidized in a batch method with a portion of press cake being introduced to the mixer, mixed until fluidized, then the fluidized portion passed on to the holding tank.
- the mixer may then be charged with a new batch of press cake, which is fluidized.
- the fluidized press cake may be immediately introduced to the holding tank or held in the mixer for a desired time and then introduced to the holding tank.
- a semi-batch process may be employed in which at certain intervals a part of the fluidized press cake is passed from the mixer to the holding tank, after which additional press cake is added to the material remaining in the mixer.
- the fluidized press cake is passed at a continuous rate from the mixer through the pump to the extruder.
- new press cake is fed into the mixer at a rate sufficient to insure that the mixer does not empty and that the average dwell time of the press cake in the mixer is adequate to fluidize the press cake.
- the feed component of the press cake feed system feeds the fluidized press cake to the extruder.
- the feed component includes a pump.
- the pump may be any type suitable for the viscosity of the fluidized press cake. Examples of suitable pumps include, without limitation, lobe pumps, gear pumps, or other positive displacement pumps.
- the press cake feed system has a fluidizing component that includes a conical container 101 that preferably rotates by gear 102 driven by motor 111 and a stationary two-screw auger 103 (front screw shown) with motor 113 that applies shear to the press cake.
- the press cake is fluidized by the action of the two-screw auger.
- the auger also serves to convey the fluidized press cake to an orifice 105 at the bottom of the conical container.
- the fluidized press cake expelled from the orifice is fed to the extruder, again for example by pump 109, with or without a holding tank for the fluidized material, as in the first embodiment.
- the feed component introduces the fluidized press cake to port
- the extruder has at least two zones, and optionally has a third and/or a fourth zone.
- a first zone represented in the figure by sections 1 through 5
- the fluidized press cake and organic medium are fed into the extruder and then mixed to flush the pigment from the aqueous phase to the organic phase.
- a second zone represented by sections 6 through 8
- at least a portion the water displaced during the flushing operation is removed by draining or drawing the liquid from the extruder.
- a third zone which is optional but preferred, represented by sections 9 through 11 , residual water is removed (as water vapor) by vacuum dehydrating the pigment flush through one or more vacuum ports.
- the flush is further mixed and one or more other ink components may be added and mixed with the pigment flush.
- the optional fourth zone can be used to produce an ink base or finished ink composition product.
- the extruder is a twin-screw extruder, with the screws being driven by motor 18.
- the screws are preferably co-rotating.
- At least one fluidized press cake is fed into the extruder through port 19.
- a second fluidized press cake is fed into the extruder through a port 19 or through a second port 119.
- a liquid organic medium preferably including at least an oil, a resin, or resin solution, is also fed into the extruder, which may be through port 19 or through a second port 119.
- the liquid organic medium is sufficiently hydrophobic to allow a non-aqueous phase to form in the process.
- organic materials that are suitable to prepare pigment are well-known in the art. If the extruder has two different fluidized press cake feeds by ports 19 and 119, the organic medium may be fed through either or through yet another separate port.
- Typical kinds of resins and oils that may be used for flushing varnishes include, without limitation, alkyd resins, phenolic resins, polyesters, hydrocarbon resins, maleic resins, rosin-modified varnishes of any of these, polyamide resins, polyvinyl chloride resins, vinyl acetate resins, vinyl chloride/vinyl acetate copolymer resins, chlorinated polyolefins, polystyrene resins, acrylic resins, polyurethane resins, ketone resins, vegetable oils including linseed oil, soybean oil, neatsfoot oil, coconut oil, tung oil, mineral oils, and so on. Combinations of such resins and oils may also be employed.
- the resin, oil, or combination thereof may be combined with a hydrophobic organic solvent or liquid, including high boiling petroleum distillates.
- the organic medium may be introduced in the same barrel, or section, of the extruder as the fluidized press cake, whether in the same port or a different port.
- the organic medium may be introduced in another section close to the front of the extruder in the first zone, as shown in FIG. 3 by the port 119.
- the organic medium may be fed from a line or tank, which may have a stirrer, and may be metered in with, for example, a pump.
- the organic medium and the fluidized press cake are each introduced at fairly constant rates.
- the relative amounts of the organic medium and the fluidized press cake for optimum processing can be determined based upon the particular materials chosen, but in general the amounts remain the same as those expected for conventional batch processing.
- the amount of organic medium introduced per unit of time may be from about 0.6 to about 2 times the amount of solid pigment introduced in the same unit of time.
- the ratio of organic medium to solid pigment may be adjusted according to factors known in the art, such as the type of pigment and the type of organic medium and may be controlled by the automated process control described below and shown in the Figures.
- the fluidized press cake and organic medium are mixed in one or more sections of the first zone of the extruder to wet the pigment with the organic medium, displacing water from the press cake and producing a crude pigment flush.
- a special screw section with a plurality of kneading disks may be used in the first zone where the flushing takes place.
- the screw profile in the first zone tapers from a deep channel used in the section or sections having a feeding port gradually to a shallow channel in a later (downstream) section or section of the first zone.
- the length of the first zone of the extruder in which the fluidized press cake and the organic medium are mixed is sufficiently long so that the pigment is flushed completely.
- the rotational speed of the screw also is a factor for efficient flushing.
- a preferred range for rotational speed of the screw is from about 150 to about 550 rpm, and a more preferred range for rotational speed is from about 450 to about 550 rpm.
- the displaced water and the crude pigment flush continue in the extruder to the second zone of the extruder where at least a portion of the displaced water is removed.
- a major portion of the displaced water is removed, more preferably at least about 80%, still more preferably at least about 90%, and even more preferably all but a residual amount of water that clings to the pigment flush is removed.
- the second zone of the extruder includes sections 6-8.
- the second zone of the extruder includes a port or vent 20 for removing, preferably by draining off, the displaced water. While the water may be withdrawn by other means, gravity draining is the simplest and is therefore preferred.
- the port 20 shown in the figure is connected on the other side to a section 21 having therein a screw turned by motor 22 that drives the relatively viscous pigment-containing flush back into the section 6 while letting the water drain out of section 6. Collected water is drained via valve 23.
- the dam that retains the pigment flush for a time sufficient to allow most of the displaced water to drain from the crude flush mass.
- the dam causes the kneaded press cake / organic medium to dwell over the port long enough to allow more of the displaced water to drain from the kneaded pigment.
- a portion of the mixture of press cake and organic medium is carried into the dammed section of the extruder and remains in that section until the portion works its way out of the pocket of retained material and is carried into the next section by the grabbing action of the screw.
- the dam is shown in more detail in FIG. 4.
- FIG. 4 shows the screw sections in sections 6 to 8 of the second zone.
- the features of section 6 are the port 20, side section 21 (shown in part) containing screw 121 , and screw section 130. Screw section 130 has relatively tight threads to remove material from the mixing zone. Screw sections
- 131 and 132 in marked barrels 6 and 7a have threads that are less tight to increase residence time and allow open room for water to drain.
- the screw sections designated by 133 are reverse threaded in a tight thread to provide sufficient reverse flow to cause the material to fill a section of 7a (for example, about 30 mm).
- the reverse flow force that causes the damming effect is limited so that there is no squeezing, as squeezing would tend to produce an emulsion of the aqueous and organic phases, impairing the desired separation of water from organic phase.
- the draining port 20 is relatively far upstream from the reverse screws, the effect of the reverse flow is to cause material to accumulate before eventually flowing over the created dam and/or being pulled on by forward-turning screws located further downstream. The water is not engaged by the forward screws and does not flow over the accumulated material. Instead, the water is held in the second zone to drain.
- the third zone of the extruder which is optional but preferred, includes one or more vacuum ports 24 connected to vacuum at valves
- Suitable vacuum ports are known to be used with extruders and typically can include a section 26 containing a screw turned by motor 27 in the vacuum port to help retain the flush in the extruder.
- a vacuum pump is typically connected to the vacuum port to provide the reduced pressure.
- the profile of the screw used for the vacuum section preferably has a shallow channel, which tends to increase the efficiency of vacuum dehydration by shaping the material in a thin layer form.
- FIG. 3 shows identical vacuum ports on consecutive extruder sections.
- the present process is particularly advantageous for preparing flushes of pigments that are heat-sensitive, including, without limitation, diarrylide and rhodamine pigments such as diarrylide yellow, rhodamine yellow, and rhodamine blue. Because the time during which the pigment is exposed to higher temperatures is minimized by the process of the invention, pigments that may discolor when exposed to heat may be made more reproducibly and without significant color degradation.
- the pigment flush produced by the inventive process may be used to prepare an ink composition according to usual methods. Additional resins, oils, solvents or other components of the organic medium may be added after the vacuum port to adjust the composition of the pigment flush.
- FIG. 5 shows an alternative fourth zone having ports 130 and 131 for addition of one or more further materials.
- the pigment flush may be made into an ink base or a finished ink composition as a further step of the continuous process of the invention by introducing additional materials such as varnish, other resins, organic solvent and/or additives into the extruder at some point before the pigment flush is discharged, preferably after the vacuum zone, such as into port 130 or port 131.
- additional materials such as varnish, other resins, organic solvent and/or additives
- the flushed pigment dispersion and other ink component(s) are combined in the extruder so that the output from the extruder is an ink base or ink composition.
- Typical resins used as ink varnishes that may be added include, without limitation, alkyd resins, polyesters, phenolic resins, rosins, cellulosics, and derivatives of these such as rosin-modified phenolics, phenolic- modified rosins, hydrocarbon-modified rosins, maleic modified rosin, fumaric modified rosins; hydrocarbon resins, vinyl resins including acrylic resins, polyvinyl chloride resins, vinyl acetate resins, polystyrene, and copolymers thereof; polyurethanes, polyamide resins, and so on. Combinations of such resins may also be employed.
- organic solvents include, without limitation, aliphatic hydrocarbons such as petroleum distillate fractions and normal and isoparaffinic solvents with limited aromatic character.
- Illustrative examples of these include, without limitation, pour point depressants, surfactants, wetting agents, waxes, emulsifying agents and dispersing agents, defoamers, antioxidants, UV absorbers, dryers (e.g., for formulations containing vegetable oils), flow agents and other rheology modifiers, gloss enhancers, and anti-settling agents.
- additives are typically included in amounts of at least about 0.001 % of the ink composition, and the additives may be included in amounts of up to about 7% by weight or more of the ink composition.
- the extruder further includes at least one monitoring apparatus that continually monitors a property of the material being processed in the extruder.
- the apparatus measures the property of the material and compares the value measured to a desired value for the property. The apparatus then uses the comparison to adjust one or more parameters of the process.
- the monitoring apparatus keeps the product of the extruder usable.
- apparatuses that provide continuing monitoring of properties of the material during the processing with automated or semi-automated adjustment of processing parameters are important in order to avoid producing large amounts of unusable off-specification material.
- the choice of adjustment is preferably made according to predetermined logic and is made and applied to the process by a computer processing unit or "programmable logic controller" (the "PLC” shown in the Figures). Suitable microprocessors that can be so programmed are known and need not be described further here.
- the monitoring apparatus may include one or more measuring devices selected from spectrophotometers, viscometers, thermocouples, pH meters, turbidity meters, conductivity meters, moisture content meters, particle size analyzers, and combinations of these.
- the monitoring apparatus may also include one or more control devices for the extruder selected from mass flow meters, motor amp meters, devices that control the motor speed and/or the screw rotation speed, devices that control the rate of feed of one or more feed components, devices that begin or stop feed from auxiliary feed components, devices that control the amount of vacuum applied, devices that control the processing temperature at a point in the process, and combinations of these.
- the monitoring apparatus may be located at any point along the extruder at an outlet or in a sample loop. The monitoring apparatus is preferably located at the exit of the extruder.
- the monitoring apparatus may include a diverter to isolate out-of-specification material from the product stream until the value of the measured property is again acceptable.
- an on-line monitoring apparatus includes a spectrophotometer.
- the spectrophotometer measures the color properties of the pigment flush and/or ink product as a particular point in the process.
- preferred spectrophotometers are near infrared analyzers.
- a near infrared analyzer can be used to monitor a number of parameters, including color hue, color shade, color strength, moisture content, and particle size of the pigment flush and/or of the ink product. The measured value may then be compared to a desired value of the property.
- color adjustments may be made to a pigment flush, for example and without limitation, by beginning a feed of a press cake having a different shade (e.g., a different lot of press cake) or, if multiple press cakes are being fed, by ending a feed of one of the press cakes or by adjusting the relative feed rates of the different press cakes; by adjusting the temperature of the processed material at one or more points of the process; by adjusting the rotation rate of the screws; by adjusting the feed rate of the organic medium relative to that of the press cake or, if more than one organic medium is being fed, adjusting the relative feed rates of the various organic mediums; by adjusting the amount of vacuum applied; by adding, adjusting the addition rate, or ending the addition of a different pigment flush of a different color shade; or by combinations of such actions.
- a different shade e.g., a different lot of press cake
- the different materials may be added into separate ports of the extruder or through the same port of the extruder, for example after having been mixed or blended in the desired ratio in a preliminary mixer.
- the adjustment may include an automated addition, or an automated signal indicating a need for a manual addition, of a different press cake in a determined amount to the fluidizing component.
- additional or alternative adjustments may include addition, or adjustment in the rate of addition, of one or more tinting pastes.
- the measured moisture content is an indication of how effective the flush process has been.
- the response may include adjusting the temperature of the processed material at one or more points of the process; adjusting the rotation rate of the screws; adjusting the feed rate of the press cake; adjusting the feed rate of the organic medium relative to that of the press cake or, if more than one organic medium is being fed, adjusting the relative feed rates of the various organic mediums; adjusting the amount of vacuum applied; or combinations of such actions.
- an on-line monitoring apparatus includes a viscometer.
- the viscometer measures the viscosity of the pigment flush and/or ink product as a particular point in the process.
- suitable viscometers include, without limitation, falling rod viscometers, vibrating fork viscometers, mass flow meters, rotor stators, and rotating disk viscometers. Viscosity may also be monitored with a device that measures the speed and motor load of the extruder rotation motor. At a given speed, a more viscous material with produce a higher motor load.
- an on-line monitoring apparatus includes a volumetric flow meter.
- the volumetric flow meter can be used to determine the volumetric flow rate at different points of the process. For example, the volumetric flow meter can monitor the flow of the water from the port 20.
- volumetric flow meters examples include, without limitation, positive displacement rotary vanes, Doppler flow meters, coriolis flow meters, turbine flow meters, transit time flow meters, and ultrasonic flow meters. If the flow rate measurement obtained is different from the specified desired flow rate measurement, adjustments may be made to the extruder process, for example and without limitation, by adjusting the temperature of the processed material at one or more points of the process; by adjusting the rotation rate of the screws; by adjusting the feed rate of the organic medium relative to that of the press cake or, if more than one press cake or organic medium is being fed, adjusting the relative feed rates of each; by adjusting the speed of the motor; or by combinations of such actions.
- a turbidity meter may be used to measure the turbidity of the water taken off at port 20.
- the turbidity meter may work, without limitation, on the radiometric principle.
- Turbidity of the water is an indicator of how effective the water phase separation or "break" is.
- a higher turbidity of the water taken off is an indication of increased pigment being flushed out along with the water.
- the effectiveness of the water break can be increased by adjusting the temperature of the processed material at one or more points of the process; by adjusting the rotation rate of the screws; by adjusting the feed rate of the organic medium relative to that of the press cake or, if more than one press cake or organic medium is being fed, adjusting the relative feed rates of each; by adjusting the speed of the motor; or by combinations of such actions.
- a pH meter for example with a combination or differential electrode, may be used to measure the pH of the water taken off at port 20.
- the desired pH may depend upon the type of pigment and the type of organic system (e.g., type of resin) used to make the pigment flush.
- the pH may be used, for example, to monitor for ionic impurities or other abnormalities or changes of the process.
- a conductivity meter may be used to measure the conductivity of the water taken off at port 20.
- the conductivity measurement reflects the concentration of salts, acids, or based in the water.
- the conductivity meter may use either a non-contacting or a contacting type sensor.
- a contacting sensor typically includes two electrodes separated at a known distance by an insulator.
- a non-contacting sensor works by inducing an alternating current around the probe and measuring the magnitude of the current after passing through the sample.
- the microprocessor may trigger adjustments to the extruder process such as, for example and without limitation, adjusting the temperature of the processed material at one or more points of the process; adjusting the rotation rate of the screws; adjusting the feed rate of the organic medium relative to that of the press cake or, if more than one press cake or organic medium is being fed, adjusting the relative feed rates of each; by adjusting the speed of the motor; or by combinations of such actions.
- FIG. 6 is a flow diagram showing the process of adjusting parameters based on product shade measurement.
- a sample taken from the extruder is measured using a spectrophotomer.
- the spectrophotographic information is evaluated via computer and the measured shade information is compared to the desired shade standard.
- a computer or programmed logic controller causes an adjustment of one or more of the operations as discussed above.
- FIG. 7 shows adjustment of press cake feed ratio, which may be the ratio of press cake to organic phase or may be the ratio of different press cakes, and adjustment of control of a "shader resin" pump to add a pigment flush of a different color shade.
- FIG. 7 is a flow diagram showing the process of adjusting parameters based on pigment strength measurement.
- a sample taken from the extruder is measured using a spectrophotomer.
- the spectrum is evaluated via computer and the measured pigment strength is compared to the desired pigment strength standard.
- a computer or programmed logic controller causes an adjustment of one or more of the operations as discussed above.
- FIG. 7 shows adjustment of mass flow rate at the press cake feed pump.
- FIG. 7 also shows measurement and control of the mass flow rate using an mass flow meter.
- FIG. 8 is a flow diagram showing the process of adjusting parameters based on product water content measurements.
- a sample taken from the extruder is measured using a spectrophotomer.
- the spectrum is evaluated via computer and the measured water content is compared to the desired water content standard.
- the pump feeding the organic medium is adjusted to increase the feed rate of organic medium.
- FIG. 9 is a flow diagram showing the process of adjusting parameters based on product viscosity measurements.
- a sample taken from the extruder is measured using a viscometer.
- the viscosity measurement is compared to the desired viscosity standard.
- the relative amount of organic medium is adjusted by controlling the pump used to introduce the organic medium to the extruder.
- a 22% lithol rubine press cake was fluidized to a homogenous mixture in a 5 hp ribbon mixer. After mixing, the fluidized press cake was put into a feeder (a 25 hp helical mixer). The fluidized press cake was fed at 124 Ibs/hr using a gear pump, through a mass flow meter and into barrel 1. The alkyd varnish was feed at 7 Ibs/hr into barrel 1 using a gear pump. A first hydrocarbon varnish was charged into barrel 2 at 29 Ibs/hr. This mass was then mixed through the end of barrel 5. The water was drained from the pigment/varnish mass in barrels 6-8. The water was fairly clear and exited at 210°F. Barrels 7b- 11 were the vacuum dehydration zone. Vacuum ports were installed at barrels 9 and 11.
- the flush was further mixed in Section 12.
- the pigment flush was reduced by addition of 11 Ibs/hr of a hydrocarbon varnish and 3.3 Ibs/hr of a hydrocarbon oil and allowed to cool.
- the pigment flush, hydrocarbon varnish and hydrocarbon oil were further mixed and cooled in Section 14.
- the resulting product was a shade converted flush with less than 2% water content.
- a rubine flush is produced at a rate of 80 Ibs./hr. in an extruder according to Example 1.
- the extruder is equipped with a near infrared spectrophotometer located at the outlet of section 14. In the process, the spectrophotometer continually measures pigment strength. The pigment strength value is compared to a desired pigment strength range of 97-100% by a CPU. When strength drops below 97%, the
- CPU sends a signal to the press cake feeder to increase the feed rate.
- the feed rate of the press cake is measured using a mass flow meter located at the press cake feed port of section 1. The feed rate is increased incrementally until the measured pigment strength is once again above 97%
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Detergent Compositions (AREA)
- Accessories For Mixers (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60008254T DE60008254T2 (en) | 1999-09-17 | 2000-09-13 | METHOD FOR PRODUCING A PIGMENT FLUSH |
BR0014080-5A BR0014080A (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment discharge |
AU74820/00A AU7482000A (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment flush |
EP00963404A EP1212378B1 (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment flush |
KR1020027003590A KR20020056891A (en) | 1999-09-17 | 2000-09-13 | Processs for preparing pigment flush |
HU0202792A HUP0202792A2 (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment flush |
MXPA02002785A MXPA02002785A (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment flush. |
AT00963404T ATE259399T1 (en) | 1999-09-17 | 2000-09-13 | METHOD FOR PRODUCING A PIGMENT FLOW |
JP2001523700A JP2003509195A (en) | 1999-09-17 | 2000-09-13 | Method of manufacturing pigment flash |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/398,486 | 1999-09-17 | ||
US09/398,486 US6348091B1 (en) | 1999-09-17 | 1999-09-17 | Process and apparatus for preparing pigment flush in response to a material property value |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001019927A1 true WO2001019927A1 (en) | 2001-03-22 |
Family
ID=23575558
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/025076 WO2001019927A1 (en) | 1999-09-17 | 2000-09-13 | Process for preparing pigment flush |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1212378B1 (en) |
JP (1) | JP2003509195A (en) |
KR (1) | KR20020056891A (en) |
CN (1) | CN1208395C (en) |
AT (1) | ATE259399T1 (en) |
AU (1) | AU7482000A (en) |
BR (1) | BR0014080A (en) |
CZ (1) | CZ296532B6 (en) |
DE (1) | DE60008254T2 (en) |
ES (1) | ES2215725T3 (en) |
HU (1) | HUP0202792A2 (en) |
MX (1) | MXPA02002785A (en) |
PT (1) | PT1212378E (en) |
WO (1) | WO2001019927A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003080740A1 (en) * | 2002-03-20 | 2003-10-02 | Sun Chemical Corporation | Continuous process for preparing pigment flush |
EP1854848A2 (en) * | 2006-05-01 | 2007-11-14 | Sun Chemical Corporation | Continuous process for preparing of a pigment flush |
CN110695027A (en) * | 2019-09-20 | 2020-01-17 | 湖州名洛科技有限公司 | Full-automatic CIP belt cleaning device |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006023464A2 (en) * | 2004-08-17 | 2006-03-02 | Flint Group Incorporated | Processes for preparing organic pigment dispersions and ink |
CN101284963B (en) * | 2007-12-17 | 2012-05-23 | 上海牡丹油墨有限公司 | Water-expelling production process for offset printing magenta printing ink |
JP5109760B2 (en) * | 2008-03-28 | 2012-12-26 | カシオ電子工業株式会社 | Method and apparatus for producing toner for electrophotography |
CN103045010B (en) * | 2012-12-27 | 2014-12-17 | 茂名阪田油墨有限公司 | Preparation method of black basic ink for manufacturing planographic printing ink |
CN103045004B (en) * | 2012-12-27 | 2014-06-18 | 茂名阪田油墨有限公司 | Preparation method for producing basic ink of printing ink through staged kneading |
CN115594989A (en) * | 2022-11-28 | 2023-01-13 | 宇虹颜料股份有限公司(Cn) | Preparation method of polyamide pigment preparation |
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US4300954A (en) * | 1980-01-03 | 1981-11-17 | Basf Wyandotte Corporation | Flushing process for pigments |
US4309223A (en) * | 1980-01-03 | 1982-01-05 | Basf Wyandotte Corporation | Flushing process for pigments |
JPS5753568A (en) * | 1980-09-16 | 1982-03-30 | Sumitomo Chem Co Ltd | Preparation of readily dispersible pigment |
US4474473A (en) * | 1982-06-28 | 1984-10-02 | Sakata Shokai Ltd. | Method and equipment for manufacturing pigment dispersion |
EP0255667A1 (en) * | 1986-08-08 | 1988-02-10 | BASF Aktiengesellschaft | Continuous flushing process |
-
2000
- 2000-09-13 MX MXPA02002785A patent/MXPA02002785A/en active IP Right Grant
- 2000-09-13 KR KR1020027003590A patent/KR20020056891A/en not_active Application Discontinuation
- 2000-09-13 ES ES00963404T patent/ES2215725T3/en not_active Expired - Lifetime
- 2000-09-13 CZ CZ20020950A patent/CZ296532B6/en not_active IP Right Cessation
- 2000-09-13 CN CNB008148333A patent/CN1208395C/en not_active Expired - Fee Related
- 2000-09-13 DE DE60008254T patent/DE60008254T2/en not_active Expired - Fee Related
- 2000-09-13 HU HU0202792A patent/HUP0202792A2/en unknown
- 2000-09-13 EP EP00963404A patent/EP1212378B1/en not_active Expired - Lifetime
- 2000-09-13 AU AU74820/00A patent/AU7482000A/en not_active Abandoned
- 2000-09-13 WO PCT/US2000/025076 patent/WO2001019927A1/en active IP Right Grant
- 2000-09-13 BR BR0014080-5A patent/BR0014080A/en not_active IP Right Cessation
- 2000-09-13 JP JP2001523700A patent/JP2003509195A/en active Pending
- 2000-09-13 PT PT00963404T patent/PT1212378E/en unknown
- 2000-09-13 AT AT00963404T patent/ATE259399T1/en not_active IP Right Cessation
Patent Citations (5)
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US4300954A (en) * | 1980-01-03 | 1981-11-17 | Basf Wyandotte Corporation | Flushing process for pigments |
US4309223A (en) * | 1980-01-03 | 1982-01-05 | Basf Wyandotte Corporation | Flushing process for pigments |
JPS5753568A (en) * | 1980-09-16 | 1982-03-30 | Sumitomo Chem Co Ltd | Preparation of readily dispersible pigment |
US4474473A (en) * | 1982-06-28 | 1984-10-02 | Sakata Shokai Ltd. | Method and equipment for manufacturing pigment dispersion |
EP0255667A1 (en) * | 1986-08-08 | 1988-02-10 | BASF Aktiengesellschaft | Continuous flushing process |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003080740A1 (en) * | 2002-03-20 | 2003-10-02 | Sun Chemical Corporation | Continuous process for preparing pigment flush |
US7914615B2 (en) | 2002-03-20 | 2011-03-29 | Sun Chemical Corporation | Continuous process for preparing pigment flush |
EP1854848A2 (en) * | 2006-05-01 | 2007-11-14 | Sun Chemical Corporation | Continuous process for preparing of a pigment flush |
EP1854848A3 (en) * | 2006-05-01 | 2009-11-04 | Sun Chemical Corporation | Continuous process for preparing of a pigment flush |
CN110695027A (en) * | 2019-09-20 | 2020-01-17 | 湖州名洛科技有限公司 | Full-automatic CIP belt cleaning device |
CN110695027B (en) * | 2019-09-20 | 2020-12-01 | 杭州名洛机械有限公司 | Full-automatic CIP belt cleaning device |
Also Published As
Publication number | Publication date |
---|---|
ES2215725T3 (en) | 2004-10-16 |
BR0014080A (en) | 2002-05-21 |
CZ296532B6 (en) | 2006-04-12 |
CZ2002950A3 (en) | 2002-09-11 |
CN1208395C (en) | 2005-06-29 |
DE60008254T2 (en) | 2004-12-30 |
DE60008254D1 (en) | 2004-03-18 |
KR20020056891A (en) | 2002-07-10 |
MXPA02002785A (en) | 2003-07-21 |
PT1212378E (en) | 2004-06-30 |
EP1212378A1 (en) | 2002-06-12 |
HUP0202792A2 (en) | 2002-12-28 |
ATE259399T1 (en) | 2004-02-15 |
CN1382191A (en) | 2002-11-27 |
AU7482000A (en) | 2001-04-17 |
JP2003509195A (en) | 2003-03-11 |
EP1212378B1 (en) | 2004-02-11 |
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