WO2000034341A3 - Catalyst and process for olefin polymerization - Google Patents

Catalyst and process for olefin polymerization Download PDF

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Publication number
WO2000034341A3
WO2000034341A3 PCT/GB1999/004124 GB9904124W WO0034341A3 WO 2000034341 A3 WO2000034341 A3 WO 2000034341A3 GB 9904124 W GB9904124 W GB 9904124W WO 0034341 A3 WO0034341 A3 WO 0034341A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
olefin polymerization
metallocene
bound
catalysed
Prior art date
Application number
PCT/GB1999/004124
Other languages
French (fr)
Other versions
WO2000034341A2 (en
Inventor
Ove Andell
Kalle Kallio
Hilkka Knuuttila
Original Assignee
Borealis As
Peroxid Chemie Gmbh
Cockbain Julian
Ove Andell
Kalle Kallio
Hilkka Knuuttila
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As, Peroxid Chemie Gmbh, Cockbain Julian, Ove Andell, Kalle Kallio, Hilkka Knuuttila filed Critical Borealis As
Priority to JP2000586782A priority Critical patent/JP2002531646A/en
Priority to BR9915991-0A priority patent/BR9915991A/en
Priority to US09/857,370 priority patent/US6730756B1/en
Priority to EP99961187A priority patent/EP1137677A2/en
Priority to AU17880/00A priority patent/AU748860B2/en
Priority to CA002349821A priority patent/CA2349821A1/en
Publication of WO2000034341A2 publication Critical patent/WO2000034341A2/en
Publication of WO2000034341A3 publication Critical patent/WO2000034341A3/en
Priority to NO20012785A priority patent/NO20012785L/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Olefin polymerisation may be catalysed by a wide range of catalytic materials. Described herein is a heterogeneous olefin polymerization catalyst comprising a porous particulate support material having impregnated therein a metallocene catalyst the metal atom whereof is bound to an amide group which is not bound to an θ-ligand of the metallocene, or the reaction product of a said metallocene catalyst and a co-catalyst.
PCT/GB1999/004124 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization WO2000034341A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2000586782A JP2002531646A (en) 1998-12-07 1999-12-07 process
BR9915991-0A BR9915991A (en) 1998-12-07 1999-12-07 Heterogeneous olefin polymerization catalyst and processes for the preparation of a heterogeneous olefin polymerization catalyst, for the homo or copolymerization of an olefin and for the production of an olefin polymer, and, use of a catalyst
US09/857,370 US6730756B1 (en) 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization
EP99961187A EP1137677A2 (en) 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization
AU17880/00A AU748860B2 (en) 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization
CA002349821A CA2349821A1 (en) 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization
NO20012785A NO20012785L (en) 1998-12-07 2001-06-06 Catalyst and olefin polymerization process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9826874.1 1998-12-07
GBGB9826874.1A GB9826874D0 (en) 1998-12-07 1998-12-07 Process

Publications (2)

Publication Number Publication Date
WO2000034341A2 WO2000034341A2 (en) 2000-06-15
WO2000034341A3 true WO2000034341A3 (en) 2000-08-31

Family

ID=10843768

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/004124 WO2000034341A2 (en) 1998-12-07 1999-12-07 Catalyst and process for olefin polymerization

Country Status (11)

Country Link
US (1) US6730756B1 (en)
EP (1) EP1137677A2 (en)
JP (1) JP2002531646A (en)
CN (1) CN1146593C (en)
AU (1) AU748860B2 (en)
BR (1) BR9915991A (en)
CA (1) CA2349821A1 (en)
GB (1) GB9826874D0 (en)
NO (1) NO20012785L (en)
TW (1) TW476764B (en)
WO (1) WO2000034341A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12146019B2 (en) 2018-11-30 2024-11-19 Borealis Ag Washing process

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CA2349821A1 (en) 2000-06-15
CN1146593C (en) 2004-04-21
US6730756B1 (en) 2004-05-04
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TW476764B (en) 2002-02-21
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