WO2000021143A1 - Radiation emitting semiconductor chip - Google Patents
Radiation emitting semiconductor chip Download PDFInfo
- Publication number
- WO2000021143A1 WO2000021143A1 PCT/DE1999/003211 DE9903211W WO0021143A1 WO 2000021143 A1 WO2000021143 A1 WO 2000021143A1 DE 9903211 W DE9903211 W DE 9903211W WO 0021143 A1 WO0021143 A1 WO 0021143A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- active layer
- semiconductor chip
- gan
- gainn
- radiation
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/26—Materials of the light emitting region
- H01L33/30—Materials of the light emitting region containing only elements of group III and group V of the periodic system
- H01L33/32—Materials of the light emitting region containing only elements of group III and group V of the periodic system containing nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/04—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a quantum effect structure or superlattice, e.g. tunnel junction
- H01L33/06—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a quantum effect structure or superlattice, e.g. tunnel junction within the light emitting region, e.g. quantum confinement structure or tunnel barrier
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
- H01L33/0062—Processes for devices with an active region comprising only III-V compounds
- H01L33/0066—Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
- H01L33/007—Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/26—Materials of the light emitting region
- H01L33/30—Materials of the light emitting region containing only elements of group III and group V of the periodic system
- H01L33/32—Materials of the light emitting region containing only elements of group III and group V of the periodic system containing nitrogen
- H01L33/325—Materials of the light emitting region containing only elements of group III and group V of the periodic system containing nitrogen characterised by the doping materials
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- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/02—Structural details or components not essential to laser action
- H01S5/0206—Substrates, e.g. growth, shape, material, removal or bonding
- H01S5/021—Silicon based substrates
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- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/305—Structure or shape of the active region; Materials used for the active region characterised by the doping materials used in the laser structure
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers]
- H01S5/3407—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers] characterised by special barrier layers
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers]
- H01S5/3425—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers] comprising couples wells or superlattices
-
- H—ELECTRICITY
- H01—BASIC ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers]
- H01S5/343—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers] in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/34333—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well lasers [SQW-lasers], multiple quantum well lasers [MQW-lasers] or graded index separate confinement heterostructure lasers [GRINSCH-lasers] in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer based on Ga(In)N or Ga(In)P, e.g. blue laser
Abstract
Description
description
Radiation-emitting semiconductor chip
The invention relates to a radiation-emitting semiconductor chip, in particular based on GaN / GaInN, wherein the active layer has a single or multiple quantum well structure, and in particular UV, blue - light or green light-emitting semiconductor chips.
The active layer comprises at a single quantum well typically two barrier layers and between these quantum film, and in a multiple quantum well typically x quantum wells and x + 1 barrier layers (where x> l), in the embedded quantum films are. Single and multiple quantum well structures are known and are not explained therefore at this point.
The wavelength of the radiation emitted by such known light emitting semiconductor chips (LED (Light
Emitting Diode) chip) is strongly dependent on the level of the operating current.
The reason for this may be the one in-segregation in the quantum well region and may be on the other piezoelectric fields, which are caused by internal tensions in the chip. An application of electrical voltage to the chip in the forward direction leads to a scanning of the internal fields and with increasing current through the chip to a wavelength shift of the emitted radiation to shorter wavelengths. The greater is the wavelength of the emitted radiation, the stronger this effect is.
The object of the invention is to develop a semiconductor chip of the type mentioned, in which the wavelength of the emitted radiation is substantially independent to changes in current through the chip.
This object is achieved by a semiconductor chip having the features of claim 1, 4, 5 or. 6 In such a semiconductor chip, the piezoelectric fields are kept small and / or very largely compensated by the installation of additional internal fields.
The former is achieved with a semiconductor chip of the type mentioned, in which the active layer has quantum thin films with a thickness of <3 nm.
A particularly preferred, schematically illustrated in Figure 1 embodiment, this is a
Semiconductor chip having an active layer 4, which has a GaN / GaInN multiple quantum well structure in which 3.5 GaInN quantum wells with a thickness of <3 nm disposed between GaN barrier layers and the fabricated on a SiC substrate 1, wherein further layers, in particular a buffer layer 2, located between the substrate 1 and the active layer 4 still.
The second option is achieved with a semiconductor chip of the type mentioned, wherein the barrier layers 3,5 and / or the quantum wells are electrically conductively doped. The doping is designed to present fields, so that they are compensated for. It is based on the strain in the active layer.
An optimum compensation of the piezo fields is achieved by a high doping of the active layer. Thus, the piezoelectric fields are virtually shorted. Thus, the carrier densities also occur during subsequent operation are anticipated. Technically, this is possible, for example by high n-doping in the region of the active zone. To the highest possible ratio p / (p + n) to achieve high p-type doping is needed.
The charge carrier densities needed for compensation of the internal fields are greater than 10 19 cιrf. 3 They are obtained by doping the quantum well region or by remote doping of barrier layers.
Alternatively, the barrier layers can be doped bipolar. An effective compensation can be achieved by acceptors and donors directly on the quantum well. The charge carrier densities greater than 10 19 cιrf. 3 Advantageously, for effective doping p- above the quantum well and heavily n-doped under the quantum well. The piezoelectric fields are canceled by the caused by the ionized donors and acceptors fields.
A particularly preferred embodiment is a semiconductor chip with an active layer having a GaN / GalnN- multiple quantum well structure in which between the GaN
Barrier layers GaInN quantum wells are arranged and which is formed on a SiC substrate, and in which, may be located between the substrate and the active layer, further layers, in particular a buffer layer, the GaN barrier layers and / or the GaInN -
Quantum films electrically conductively doped, that is n- or p- doped. The doping is based on the strain, not the structure, ie, for example on a n- or p-doped buffer layer.
In a third solution possibility of a relaxed semiconductor layer is disposed between the substrate and the active layer having the same lattice constant as the lattice constant in the quantum well.
A particularly preferred, schematically illustrated in Figure 2 embodiment this is a semiconductor chip having an active layer 4, which has a GaN / GaInN multiple quantum well structure in which 3.5 GaInN Quantenfil e are arranged between GaN barrier layers and the on a SiC substrate 1 is manufactured, said active between the substrate 1 and the
Layer 4 is a relaxed InGaAlN film 6 having the same lattice constant as that of the quantum well. The barrier layers 5, 6 are made of AlGaInN.
The structures shown above may be applied to all the GaInN / GaN-based LEDs, as well as for all the structures that contain substantial internal Verspannungsfeider.
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19845748 | 1998-10-05 | ||
DE19845748.0 | 1998-10-05 |
Publications (1)
Publication Number | Publication Date |
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WO2000021143A1 true WO2000021143A1 (en) | 2000-04-13 |
Family
ID=7883410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1999/003211 WO2000021143A1 (en) | 1998-10-05 | 1999-10-05 | Radiation emitting semiconductor chip |
Country Status (1)
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WO (1) | WO2000021143A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001092428A1 (en) * | 2000-06-02 | 2001-12-06 | Erhard Kohn | Heterostructure with rear-face donor doping |
WO2002097904A2 (en) * | 2001-05-30 | 2002-12-05 | Cree, Inc. | Group iii nitride based light emitting diode structures with a quantum well and superlattice |
WO2003012877A2 (en) * | 2001-07-20 | 2003-02-13 | Erhard Kohn | Field effect transistor |
US7692182B2 (en) | 2001-05-30 | 2010-04-06 | Cree, Inc. | Group III nitride based quantum well light emitting device structures with an indium containing capping structure |
WO2011098799A2 (en) | 2010-02-10 | 2011-08-18 | Pulmagen Therapeutics (Inflammation) Limited | Respiratory disease treatment |
US8772757B2 (en) | 2005-05-27 | 2014-07-08 | Cree, Inc. | Deep ultraviolet light emitting devices and methods of fabricating deep ultraviolet light emitting devices |
US9012937B2 (en) | 2007-10-10 | 2015-04-21 | Cree, Inc. | Multiple conversion material light emitting diode package and method of fabricating same |
US9041139B2 (en) | 2007-01-19 | 2015-05-26 | Cree, Inc. | Low voltage diode with reduced parasitic resistance and method for fabricating |
US20170213868A1 (en) * | 2014-04-01 | 2017-07-27 | Centre National De La Recherche Scientifique | Semiconducting pixel, matrix of such pixels, semiconducting structure for the production of such pixels and their methods of fabrication |
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-
1999
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EP0772249A2 (en) * | 1995-11-06 | 1997-05-07 | Nichia Chemical Industries, Ltd. | Nitride semiconductor device |
DE19613265C1 (en) * | 1996-04-02 | 1997-04-17 | Siemens Ag | Circuit element, e.g. laser diode |
Non-Patent Citations (4)
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AKASAKI I ET AL: "STIMULATED EMISSION BY CURRENT INJECTION FROM AN ALGAN/GAN/GAINN QUANTUM WELL DEVICE", JAPANESE JOURNAL OF APPLIED PHYSICS,JP,PUBLICATION OFFICE JAPANESE JOURNAL OF APPLIED PHYSICS. TOKYO, vol. 34, PART 2, no. 11B, 15 November 1995 (1995-11-15), pages L1517 - L1519, XP000735115, ISSN: 0021-4922 * |
CHICHIBU S ET AL: "EFFECTS OF SI-DOPING IN THE BARRIERS OF INGAN MULTIQUANTUM WELL PURPLISH-BLUE LASER DIODES", APPLIED PHYSICS LETTERS,US,AMERICAN INSTITUTE OF PHYSICS. NEW YORK, vol. 73, no. 4, 27 July 1998 (1998-07-27), pages 496 - 498, XP000774917, ISSN: 0003-6951 * |
DEGUCHI T ET AL: "Luminescence spectra from InGaN multiquantum wells heavily doped with Si", APPLIED PHYSICS LETTERS, 22 JUNE 1998, AIP, USA, vol. 72, no. 25, pages 3329 - 3331, XP002129502, ISSN: 0003-6951 * |
SUN C J ET AL: "QUANTUM SHIFT OF BAND-EDGE STIMULATED EMISSION IN INGAN-GAN MULTIPLE QUANTUM WELL LIGHT-EMITTING DIODES", APPLIED PHYSICS LETTERS,US,AMERICAN INSTITUTE OF PHYSICS. NEW YORK, vol. 70, no. 22, 2 June 1997 (1997-06-02), pages 2978 - 2980, XP000694810, ISSN: 0003-6951 * |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001092428A1 (en) * | 2000-06-02 | 2001-12-06 | Erhard Kohn | Heterostructure with rear-face donor doping |
WO2001092428A3 (en) * | 2000-06-02 | 2002-05-30 | Erhard Kohn | Heterostructure with rear-face donor doping |
US7352008B2 (en) * | 2000-06-02 | 2008-04-01 | Microgan Gmbh | Heterostructure with rear-face donor doping |
US9112083B2 (en) | 2001-05-30 | 2015-08-18 | Cree, Inc. | Group III nitride based light emitting diode structures with a quantum well and superlattice, group III nitride based quantum well structures and group III nitride based superlattice structures |
WO2002097904A3 (en) * | 2001-05-30 | 2003-02-20 | Cree Inc | Group iii nitride based light emitting diode structures with a quantum well and superlattice |
US9054253B2 (en) | 2001-05-30 | 2015-06-09 | Cree, Inc. | Group III nitride based quantum well light emitting device structures with an indium containing capping structure |
US6958497B2 (en) | 2001-05-30 | 2005-10-25 | Cree, Inc. | Group III nitride based light emitting diode structures with a quantum well and superlattice, group III nitride based quantum well structures and group III nitride based superlattice structures |
US7312474B2 (en) | 2001-05-30 | 2007-12-25 | Cree, Inc. | Group III nitride based superlattice structures |
WO2002097904A2 (en) * | 2001-05-30 | 2002-12-05 | Cree, Inc. | Group iii nitride based light emitting diode structures with a quantum well and superlattice |
US7692182B2 (en) | 2001-05-30 | 2010-04-06 | Cree, Inc. | Group III nitride based quantum well light emitting device structures with an indium containing capping structure |
WO2003012877A3 (en) * | 2001-07-20 | 2003-09-18 | Erhard Kohn | Field effect transistor |
WO2003012877A2 (en) * | 2001-07-20 | 2003-02-13 | Erhard Kohn | Field effect transistor |
US8772757B2 (en) | 2005-05-27 | 2014-07-08 | Cree, Inc. | Deep ultraviolet light emitting devices and methods of fabricating deep ultraviolet light emitting devices |
US9041139B2 (en) | 2007-01-19 | 2015-05-26 | Cree, Inc. | Low voltage diode with reduced parasitic resistance and method for fabricating |
US9012937B2 (en) | 2007-10-10 | 2015-04-21 | Cree, Inc. | Multiple conversion material light emitting diode package and method of fabricating same |
WO2011098799A2 (en) | 2010-02-10 | 2011-08-18 | Pulmagen Therapeutics (Inflammation) Limited | Respiratory disease treatment |
US20170213868A1 (en) * | 2014-04-01 | 2017-07-27 | Centre National De La Recherche Scientifique | Semiconducting pixel, matrix of such pixels, semiconducting structure for the production of such pixels and their methods of fabrication |
US10103195B2 (en) * | 2014-04-01 | 2018-10-16 | Centre National De La Recherche Scientifique | Semiconducting pixel, matrix of such pixels, semiconducting structure for the production of such pixels and their methods of fabrication |
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